Brenda Ann Frazier

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2010 Cornell University, Ithaca, NY, United States 
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"Brenda Frazier"
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Peter T. Wolczanski grad student 2010 Cornell
 (Synthesis, characterization, and reactivity of first row dipyridylazaallyl transition metal complexes.)
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Frazier BA, Williams VA, Wolczanski PT, et al. (2013) C-C bond formation and related reactions at the CNC backbone in (smif)FeX (smif = 1,3-di-(2-pyridyl)-2-azaallyl): dimerizations, 3 + 2 cyclization, and nucleophilic attack; transfer hydrogenations and alkyne trimerization (X = N(TMS)2, dpma = (di-(2-pyridyl-methyl)-amide)). Inorganic Chemistry. 52: 3295-312
Frazier BA, Wolczanski PT, Keresztes I, et al. (2012) Synthetic approaches to (smif)2Ti (smif = 1,3-di-(2-pyridyl)-2-azaallyl) reveal redox non-innocence and C-C bond-formation. Inorganic Chemistry. 51: 8177-86
Frazier BA, Bartholomew ER, Wolczanski PT, et al. (2011) Synthesis and characterization of (smif)2M(n) (n = 0, M = V, Cr, Mn, Fe, Co, Ni, Ru; n = +1, M = Cr, Mn, Co, Rh, Ir; smif =1,3-di-(2-pyridyl)-2-azaallyl). Inorganic Chemistry. 50: 12414-36
Hachmann J, Frazier BA, Wolczanski PT, et al. (2011) A theoretical study of the 3d-M(smif)2 complexes: structure, magnetism, and oxidation states. Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry. 12: 3236-44
Frazier BA, Wolczanski PT, Lobkovsky EB. (2009) Aryl-containing chelates and amine debenzylation to afford 1,3-di-2-pyridyl-2-azaallyl (smif): structures of {kappa-C,N,N(py)(2)-(2-pyridylmethyl)(2)N(CH(2)(4-(t)Bu-phenyl-2-yl))}FeBr and (smif)CrN(TMS)(2). Inorganic Chemistry. 48: 11576-85
Frazier BA, Wolczanski PT, Lobkovsky EB, et al. (2009) Unusual electronic features and reactivity of the dipyridylazaallyl ligand: characterizations of (smif)2M [M = Fe, Co, Co+, Ni; smif = {(2-py)CH}2N] and [(TMS)2NFe]2(smif)2. Journal of the American Chemical Society. 131: 3428-9
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