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Gerard T. Rowe

Affiliations: 
2009 Boston University, Boston, MA, United States 
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"Gerard Rowe"
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John P. Caradonna grad student 2009 Boston University
 (Kinetic and mechanistic investigations into the workings of a binuclear nonheme iron monooxygenase model compound.)

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Gregor LC, Rowe GT, Rybak-Akimova E, et al. (2012) Mechanistic investigation of cyclohexane oxidation by a non-heme iron complex: evidence of product inhibition by UV/vis stopped-flow studies. Dalton Transactions (Cambridge, England : 2003). 41: 777-82
Thomas CM, Napoline JW, Rowe GT, et al. (2010) Oxidative addition across Zr/Co multiple bonds in early/late heterobimetallic complexes. Chemical Communications (Cambridge, England). 46: 5790-2
Greenwood BP, Rowe GT, Chen CH, et al. (2010) Metal-metal multiple bonds in early/late heterobimetallics support unusual trigonal monopyramidal geometries at both Zr and Co. Journal of the American Chemical Society. 132: 44-5
Greenwood BP, Forman SI, Rowe GT, et al. (2009) Multielectron redox activity facilitated by metal-metal interactions in early/late heterobimetallics: Co/Zr complexes supported by phosphinoamide ligands. Inorganic Chemistry. 48: 6251-60
Cappillino PJ, Tarves PC, Rowe GT, et al. (2009) Synthesis and characterization of a family of binuclear non-heme iron monooxygenase model compounds: Evidence for a "phenolate/amide carbonyl (PAC) shift" upon oxidation Inorganica Chimica Acta. 362: 2136-2150
Rowe GT, Rybak-Akimova EV, Caradonna JP. (2008) Heterolytic cleavage of peroxide by a diferrous compound generates metal-based intermediates identical to those observed with reactions utilizing oxygen-atom-donor molecules. Chemistry (Weinheim An Der Bergstrasse, Germany). 14: 8303-11
Cong H, Ledbetter D, Rowe GT, et al. (2008) Electron transfer-initiated Diels-Alder cycloadditions of 2'-hydroxychalcones. Journal of the American Chemical Society. 130: 9214-5
Rowe GT, Rybak-Akimova EV, Caradonna JP. (2007) Unraveling the reactive species of a functional non-heme iron monooxygenase model using stopped-flow UV-vis spectroscopy. Inorganic Chemistry. 46: 10594-606
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