Evan L. Werkema, Ph.D.

Affiliations: 
2005 University of California, Berkeley, Berkeley, CA, United States 
Area:
organometallic, and inorganic chemistry
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"Evan Werkema"
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Richard A. Andersen grad student 2005 UC Berkeley
 (Synthesis, structure, and reactivity of bis(1,2,4 -tri -t -butylcyclopentadienyl) complexes of cerium.)
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Publications

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Perrin L, Werkema EL, Eisenstein O, et al. (2014) Two [1,2,4-(Me3C)3C5H2]2CeH molecules are involved in hydrogenation of pyridine to piperidine as shown by experiments and computations. Inorganic Chemistry. 53: 6361-73
Werkema EL, Castro L, Maron L, et al. (2013) Cleaving bonds in CH3OSO2CF3 with [1,2,4-(Me3C)3C5H2]2CeH; An experimental and computational study New Journal of Chemistry. 37: 132-142
Werkema EL, Castro L, Maron L, et al. (2012) Selectivity in the C-H activation reaction of CH 3OSO 2CH 3 with [1,2,4-(Me 3C) 3C 5H 2] 2CeH or [1,2,4-(Me 3C) 3C 5H 2][1,2-(Me 3C) 2-4-(Me 2CCH 2)C 5H 2]Ce: To choose or not to choose Organometallics. 31: 870-881
Booth CH, Kazhdan D, Werkema EL, et al. (2010) Intermediate-valence tautomerism in decamethylytterbocene complexes of methyl-substituted bipyridines. Journal of the American Chemical Society. 132: 17537-49
Werkema EL, Andersen RA, Maron L, et al. (2010) The reaction of bis(1,2,4-tri-t-butylcyclopentadienyl)ceriumbenzyl, Cp'2CeCH2Ph, with methylhalides: a metathesis reaction that does not proceed by a metathesis transition state. Dalton Transactions (Cambridge, England : 2003). 39: 6648-60
Werkema EL, Yahia A, Maron L, et al. (2010) Splitting a C-O bond in dialkylethers with bis(1,2,4-tri-tert- butylcyclopentadienyl)cerium hydride does not occur by a σ-bond metathesis pathway: A combined experimental and DFT computational study New Journal of Chemistry. 34: 2189-2196
Werkema EL, Yahia A, Maron L, et al. (2010) Bridging silyl groups in σ-bond metathesis and [1,2]-shifts. Experimental and computational study of the reaction between cerium metallocenes and MeOSiMe3 Organometallics. 29: 5103-5110
Werkema EL, Andersen RA, Yahia A, et al. (2009) Hydrogen for X-group exchange in CH 3X (X ) Cl, Br, I, OMe, and NMe 2) by monomeric [1,2,4-(Me 3C) 3C 5H 2] 2CeH: Experimental and computational support for a carbenoid mechanism Organometallics. 28: 3173-3185
Werkema EL, Andersen RA. (2008) Fluorine for hydrogen exchange in the hydrofluorobenzene derivatives C6H(x)F(6-x), where x = 2, 3, 4 and 5 by monomeric [1,2,4-(Me3C)3C5H2]2CeH: the solid state isomerization of [1,2,4-(Me3C)3C5H2]2Ce(2,3,4,5-C6HF4) to [1,2,4-(Me3C)3C5H2]2Ce(2,3,4,6-C6HF4). Journal of the American Chemical Society. 130: 7153-65
Werkema EL, Maron L, Eisenstein O, et al. (2007) Reactions of monomeric [1,2,4-(Me3C)3C5H2]2CeH and CO with or without H2: an experimental and computational study. Journal of the American Chemical Society. 129: 2529-41
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