Douglass R. Sillars, Ph.D.

Affiliations: 
2003 University of Wisconsin, Madison, Madison, WI 
Area:
catalysis involving transition metal complexes
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"Douglass Sillars"
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Clark R. Landis grad student 2003 UW Madison
 (Mechanistic investigations in metallocene-catalyzed alkene polymerization through direct observation of the catalytic species.)
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Publications

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Landis CR, Sillars DR, Batterton JM. (2004) Reactivity of secondary metallocene alkyls and the question of dormant sites in catalytic alkene polymerization. Journal of the American Chemical Society. 126: 8890-1
Sillars DR, Landis CR. (2003) Catalytic propene polymerization: determination of propagation, termination, and epimerization kinetics by direct NMR observation of the (EBI)Zr(MeB(C6F5)3)propenyl catalyst species. Journal of the American Chemical Society. 125: 9894-5
Landis CR, Rosaaen KA, Sillars DR. (2003) Direct observation of insertion events at rac-(C2H4(1-indenyl)2)Zr(MeB(C6F5)3)-polymeryl intermediates: distinction between continuous and intermittent propagation modes. Journal of the American Chemical Society. 125: 1710-1
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