Nathan A. Siladke, Ph.D.

Affiliations: 
2012 Chemistry - Ph.D. University of California, Irvine, Irvine, CA 
Area:
Inorganic and Organometallic Chemistry; Rare Earth, Actinide, and Bismuth Metal Chemistry
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"Nathan Siladke"
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William J. Evans grad student 2012 UC Irvine
 (Reactivity and Structural Effects of Subtle Changes to Cyclopentadienyl Ligands in Actinide Metallocenes.)
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Publications

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Siladke NA, Webster CL, Walensky JR, et al. (2013) Actinide metallocene hydride chemistry: C-H activation in tetramethylcyclopentadienyl ligands to form [μ-η5-C 5Me3H(CH2)-κc ]2- tuck-over ligands in a tetrathorium octahydride complex Organometallics. 32: 6522-6531
Siladke NA, LeDuc J, Ziller JW, et al. (2012) Synthesis and insertion chemistry of mixed tether uranium metallocene complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 14820-7
Demir S, Siladke NA, Ziller JW, et al. (2012) Scandium and yttrium metallocene borohydride complexes: comparisons of (BH4)1- vs. (BPh4)1- coordination and reactivity. Dalton Transactions (Cambridge, England : 2003). 41: 9659-66
Siladke NA, Meihaus KR, Ziller JW, et al. (2012) Synthesis, structure, and magnetism of an f element nitrosyl complex, (C5Me4H)3UNO. Journal of the American Chemical Society. 134: 1243-9
Siladke NA, Ziller JW, Evans WJ. (2011) Insertion, isomerization, and cascade reactivity of the tethered silylalkyl uranium metallocene (η(5)-C5Me4SiMe2CH2-κC)2U. Journal of the American Chemical Society. 133: 3507-16
Takase MK, Siladke NA, Ziller JW, et al. (2011) Synthesis and Insertion Chemistry of a Cyclooctatetraenyl Uranium "tuck-in" Metallocene, (η8-C8H 8)(η5:η1-C5Me 4CH2)U Organometallics. 30: 458-465
Evans WJ, Siladke NA, Ziller JW. (2010) Synthesis and reactivity of a silylalkyl double tuck-in uranium metallocene [(eta(5):eta(1)-C(5)Me(4)SiMe(2)CH(2))(2)U] and its conversion to bis(tethered) metallocenes. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 796-800
Evans WJ, Siladke NA, Ziller JW. (2010) Reactivity of the tethered alkyl uranium bonds of (η5:k 1-C5Me4SiMe2CH2) 2U Comptes Rendus Chimie. 13: 775-780
Siladke NA, Ziller JW, Evans WJ. (2010) Synthesis, structure, and reactivity of the sterically crowded complex (C5Me4SiMe3)3U Zeitschrift Fur Anorganische Und Allgemeine Chemie. 636: 2347-2351
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