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Matthew B. Harney, Ph.D.

Affiliations: 
2006 University of Maryland, College Park, College Park, MD 
Area:
Transition and Main Group Metal Inorganic and Organometallic Chemistry, New Synthetic Methodology, Catalyst Development, Polymers, Chemically-Tailored Surfaces and Interfaces, Molecular and Mesoscopic Self-Assembly, New Nanofabrication Processes
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"Matthew Harney"
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Lawrence R. Sita grad student 2006 University of Maryland
 (Examination of dynamic processes in living Ziegler -Natta polymerization and new polypropylene architectures through bimolecular control.)

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Harney MB, Zhang Y, Sita LR. (2006) Bimolecular control over polypropene stereochemical microstructure in a well-defined two-state system and a new fundamental form: stereogradient polypropene. Angewandte Chemie (International Ed. in English). 45: 6140-4
Harney MB, Zhang Y, Sita LR. (2006) Discrete, multiblock isotactic-atactic stereoblock polypropene microstructures of differing block architectures through programmable stereomodulated living Ziegler-Natta polymerization. Angewandte Chemie (International Ed. in English). 45: 2400-4
Harney MB, Keaton RJ, Fettinger JC, et al. (2006) Living Ziegler-Natta polymerization by early transition metals: synthesis and evaluation of cationic zirconium alkyl complexes bearing beta-hydrogens as models for propagating centers. Journal of the American Chemical Society. 128: 3420-32
Kissounko DA, Zhang Y, Harney MB, et al. (2005) Evaluation of (η5-C5Me5)Hf(R) 2[N(Et)C(Me)N(t-Bu)] (R = Me and i-Bu) for the stereospecific living and degenerative transfer living Ziegler-Natta polymerization of α-olefins Advanced Synthesis and Catalysis. 347: 426-432
Harney MB, Keaton RJ, Sita LR. (2004) End-group-confined chain walking within a group 4 living polyolefin and well-defined cationic zirconium alkyl complexes for modeling this behavior. Journal of the American Chemical Society. 126: 4536-7
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