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Thomas W. Stringfield, Ph.D.

Affiliations: 
2002 University of Pittsburgh, Pittsburgh, PA, United States 
Area:
Inorganic Chemistry
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Rex E. Shepherd grad student 2002 University of Pittsburgh
 (Tungsten(0), palladium(II), and ruthenium(II) complexes with bio -compatible ligands for potential antitumor applications.)

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Shepherd RE, Slocik JM, Stringfield TW, et al. (2004) Electrospray mass spectrometry of cis-[Ru(NO)Cl(bpy)2] 2+ (bpy=2,2′-bipyridine): Fragmentation from desolvated {[Ru(NO)Cl(bpy)2]2+, Cl-}+ ion pairs by electron transfer and internal Lewis base pathways Inorganica Chimica Acta. 357: 965-979
Stringfield TW, Somayajula KV, Muddiman DC, et al. (2003) 1H NMR and electrospray mass spectrometry of the mono-ionized bis(2,2′-bis(4,5-dimethylimidazole)chloronitrosylruthenium(II) complex ([Ru(NO)Cl(LH2)2]+, LH2=2,2′-bis(4,5-dimethylimidazole) Inorganica Chimica Acta. 343: 317-328
Stringfield TW, Shepherd RE. (2003) Tipping the energy balance toward exocyclic-amino coordination of W(CO)5 by methylation of the amino group of 2- and 4-aminopyridines, but not with adenosine Inorganica Chimica Acta. 343: 156-168
Stringfield TW, Shepherd RE. (2001) Preferred exocyclic-amino coordination of W(CO)5 on 2-aminopyrimidine and 4-aminopyrimidine vs. heterocyclic N-1 coordination for 2-aminopyridine Inorganic Chemistry Communications. 4: 760-765
Stringfield TW, Shepherd RE. (2001) Formation of a W(CO)5 -furanosylidene complex from ribose without the use of protective groups Inorganica Chimica Acta. 325: 51-57
Stringfield TW, Shepherd RE. (2000) Substitution of inosine and guanosine 5'-monophosphate for chloride, and water on Pd(II)(polyaminopolycarboxylate) complexes: Mechanistic controls in forming Pd(II)(pac)L or Pd(II)(pac)L2 products Inorganica Chimica Acta. 309: 28-44
Kortes RA, Stringfield TW, Ward MS, et al. (2000) The structures of mononuclear [Pd(II)(hdta)]2- and [Pd(II)(dhpta)]2- and binuclear [Pd2/(II)(hdta)(H2O2] and [Pd(II)(H2O)Pt(II)Cl(hdta)]- complexes in aqueous solution Inorganica Chimica Acta. 304: 60-71
Stringfield TW, Shepherd RE. (1999) Coordination of W(CO)5 to DNA and RNA nucleobases: Development of a possible heavy-metal labeling complex Transition Metal Chemistry. 24: 571-576
Chen Y, Pasquinelli R, Ataai M, et al. (1999) Coordination of the six-mer peptide Gly-His-Pro-His-His-Gly to CuII and PdII N-methyliminodiacetate complexes as IMAC chelation site models Journal of Inorganic Biochemistry. 76: 211-220
Stringfield TW, Shepherd RE. (1999) Absence of 1,3-metallotropic shifts in M(CO)5 complexes of pyrimidine and 1,3,5-triazine (M=W, Mo, Cr) Inorganica Chimica Acta. 292: 225-230
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