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Thomas G. Richmond

Affiliations: 
Chemistry University of Utah, Salt Lake City, UT 
Area:
organometallic chemistry of fluorocarbons
Website:
http://www.chem.utah.edu/faculty/richmond/richmond.html
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"Thomas Richmond"
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Fred Basolo grad student 1984 Northwestern
 (Part I. Reactions of molecular Lewis acids with transition metal carbonyl hydride, alkyl and perfluoroalkyl complexes. Part II. Mechanism of carbon monxoide substitution and Lewis based induced disproportionation of vanadium hexacarbonyl.)
Duward Felix Shriver grad student 1984 Northwestern
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Publications

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Ivanova SM, Ivanov SV, Miller SM, et al. (2000) Mono-, di-, tri-, and tetracarbonyls of copper(I), including the structures of Cu(CO)2(1-Bn-CB11F11) and [Cu(CO)4][1-Et-CB11F11] Chemtracts. 13: 103-107
Yang H, Gao H, Angelici RJ, et al. (2000) Hydrodefluorination of fluorobenzene and 1,2-difluorobenzene under mild conditions over rhodium pyridylphosphine and bipyridyl complexes tethered on a silica-supported palladium catalyst Chemtracts. 13: 134-138
Benvenutti MHA, Hitchcock PB, Kiplinger JL, et al. (1997) Carbon monoxide–phosphaalkyne coupling and C–Hactivation of an N–Me group in the4e-η2-phosphaalkyne complex[WF(C6H4CH2NMeCH2CH2NMe2)(CO)(η2-PCBut)].Crystal and molecular structure of[WF{CH2N(CH2Ph)CH2CH2NMe2}(CO){η4-PCBut(CO)CButP}] Chemical Communications. 1539-1540
Kiplinger JL, Arif AM, Richmond TG. (1997) Influence of π-conflict on structure and reactivity. Comparative study of η2-nitriles and η2-alkynes as four-electron donor ligands in tungsten(II) fluoride carbonyl systems Organometallics. 16: 246-254
Kiplinger JL, Richmond TG. (1997) Preparation of molybdenum(II) η2-vinyl complexes via sequential C - Cl activation and alkyne insertion Polyhedron. 16: 409-415
Benvenutti MHA, Hitchcock PB, Kiplinger JL, et al. (1997) Carbon monoxide-phosphaalkyne coupling and C-H activation of an N-Me group in the 4e-η2-phosphaalkyne complex [WF(C6H4CH2NMeCH2CH 2NMe2)(CO)(η2-P≡CBut)] Chemical Communications. 1539-1540
Kiplinger JL, Arif AM, Richmond TG. (1996) Synthesis and reactivity of tungsten(II) carbonyl η2-nitrile complexes: Crystal structure of tetrafluoroterephthalonitrile as a four-electron donor ligand Chemical Communications. 1691-1692
Kiplinger JL, Richmond TG. (1996) Selective room temperature hydrogenolysis of aromatic fluorocarbons mediated by a low-valent zirconium complex Chemical Communications. 1115-1116
Kiplinger JL, King MA, Fechtenkötter A, et al. (1996) An investigation of carbon-fluorine bond functionalization. Versatile reactivity of tungsten(II) fluoride carbonyl metallacycles with alkynes Organometallics. 15: 5292-5301
Kiplinger JL, Richmond TG, Arif AM, et al. (1996) Synthesis and characterization of highly fluorinated tungsten(II) metallacyclopropene complexes. Kinetics and mechanism of an unprecedented η2-vinyl isomerization Organometallics. 15: 1545-1564
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