George L. Heard, Ph.D.
Affiliations: | 1999- | Chemistry | University of North Carolina at Asheville |
Area:
Inorganic and computational chemistryWebsite:
https://chemistry.unca.edu/faces/dr-george-heardGoogle:
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Publications
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| Brown TM, Gillespie BR, Rothrock MM, et al. (2019) Unimolecular HBr and HF Elimination Reactions of Vibrationally Excited CHCHBr and CDCHFBr: Identification of the 1,1-HBr Elimination Reaction from CDCHFBr and Search for the CD(F)C:HBr Adduct. The Journal of Physical Chemistry. A |
| Gillespie BR, Patel CA, Rothrock MM, et al. (2019) Experimental and Computational Studies of Unimolecular 1,1-HX (X = F, Cl) Elimination Reactions of CDCHFCl: The Role of Carbene:HF and HCl Adducts in the Exit Channel of RCHFCl and RCHCl Reactions. The Journal of Physical Chemistry. A |
| Brown TM, Gillespie BR, Smith CA, et al. (2018) Analysis of the Five Unimolecular Reaction Pathways of CDClCHFCl with Emphasis on CDCl(F)C: and CDCl(Cl)C: Formed by 1,1-HCl and 1,1-HF Elimination. The Journal of Physical Chemistry. A |
| Smith CA, Gillespie BR, Heard GL, et al. (2017) The Unimolecular Reactions of CF3CHF2 Studied by Chemical Activation: Assignment of Rate Constants and Threshold Energies to the 1,2-H-Atom Transfer, 1,1-HF Elimination and 1,2-HF Elimination Reactions and the Dependence of Threshold Energies on the Number of F-Atom Substituents in the Fluoroethane Molecules. The Journal of Physical Chemistry. A |
| Smith CA, Heard GL, Setser DW, et al. (2016) Reinvestigation of the Unimolecular Reactions of CHF2CHF2: Identification of the 1,1-HF Elimination Component from Addition of CHF2CF to trans-2-Butene. The Journal of Physical Chemistry. A |
| Larkin AC, Nestler MJ, Smith CA, et al. (2016) A Chemical Activation Study of the Unimolecular Reactions of CD3CD2CHCl2 and CHCl2CHCl2 with Analysis of the 1,1-HCl Elimination Pathway. The Journal of Physical Chemistry. A |
| Kim J, Brandt LM, Heard GL, et al. (2016) Computational study of the threshold energy for the 1,2-interchange of X and R (X, R = halogens, pseudohalogens, and monovalent hydrocarbon groups) on CH2XCH2R Canadian Journal of Chemistry. 94: 1038-1043 |
| Brown TM, Nestler MJ, Rossabi SM, et al. (2015) Characterization of the 1,1-HCl Elimination Reaction of Vibrationally Excited CD3CHFCl Molecules and Assignment of Threshold Energies for 1,1-HCl and 1,2-DCl plus 1,1-HF and 1,2-DF Elimination Reactions. The Journal of Physical Chemistry. A. 119: 9441-51 |
| Wormack LN, McGreal ME, McClintock CE, et al. (2015) Characterization of the 1,1-HF Elimination Reaction from the Competition between the 1,1-HF and 1,2-DF Unimolecular Elimination Reactions of CD3CD2CHF2. The Journal of Physical Chemistry. A. 119: 3887-96 |
| Rossabi SM, Smith KC, Heard GL, et al. (2015) Unimolecular Rate Constants for the HF and HCl Elimination Reactions from Chemically Activated CF |