Leon J. Tilley, Ph. D. Indiana University; B. A. Chemistry, B. A. Russian Language, Grinnell College

Affiliations: 
1996- Chemistry Stonehill College, Easton, MA, United States 
Area:
Strained Rings, Organofluorine, Carbocations, Organosilicon
Website:
http://www.stonehill.edu/directory/leon-j-tilley/
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"Leon Tilley"
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Children

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Christopher B. Kelly research assistant 2007-2010 Stonehill College
Michael A. Mercadante research assistant 2008-2010
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Kelly CB, Milligan JA, Tilley LJ, et al. (2022) Bicyclobutanes: from curiosities to versatile reagents and covalent warheads. Chemical Science. 13: 11721-11737
Hamlin TA, Kelly CB, Ovian JM, et al. (2015) Toward a Unified Mechanism for Oxoammonium Salt-Mediated Oxidation Reactions: A Theoretical and Experimental Study Using a Hydride Transfer Model. The Journal of Organic Chemistry. 80: 8150-67
Hamlin TA, Kelly CB, Ovian JM, et al. (2015) Toward a Unified Mechanism for Oxoammonium Salt-Mediated Oxidation Reactions: A Theoretical and Experimental Study Using a Hydride Transfer Model Journal of Organic Chemistry. 80: 8150-8167
Kelly CB, Mercadante MA, Carnaghan ER, et al. (2015) Synthesis of Perfluoroalkyl-Substituted Vinylcyclopropanes by Way of Enhanced Neighboring Group Participation European Journal of Organic Chemistry
Mercadante MA, Kelly CB, Hamlin TA, et al. (2014) 1,3-γ-Silyl-elimination in electron-deficient cationic systems Chemical Science. 5: 3983-3994
Bobbitt JM, Eddy NA, Richardson JJ, et al. (2014) Discussion Addendum for: Preparation of 4-Acetylamino-2, 2, 6, 6-tetramethylpiperidine-1- oxoammonium Tetrafluoroborate and the Oxidation of Geraniol to Geranial (2,6-Octadienal, 3,7-dimethyl-, (2e)-) Organic Syntheses. 215-228
Mercadante MA, Kelly CB, Bobbitt JM, et al. (2013) Synthesis of 4-acetamido-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate and 4-acetamido-(2,2,6,6-tetramethyl-piperidin-1-yl)oxyl and their use in oxidative reactions. Nature Protocols. 8: 666-76
Tilley LJ, Bobbitt JM, Murray SA, et al. (2013) A revised preparation of (4-Acetamido-2,2,6,6-tetramethylpiperidin-1-yl) oxyl and 4-acetamido-2,2,6,6-tetramethyl-1-oxopiperidinium tetrafluoroborate: Reagents for stoichiometric oxidations of alcohols Synthesis (Germany). 45: 326-329
Kelly CB, Colthart AM, Constant BD, et al. (2011) Enabling the synthesis of perfluoroalkyl bicyclobutanes via 1,3 γ-silyl elimination. Organic Letters. 13: 1646-9
Tilley LJ, Shiner VJ. (1999) γ‐Silyl‐stabilized tertiary ions? Solvolysis of­4‐(trimethylsilyl)‐2‐chloro‐2‐methylbutane Journal of Physical Organic Chemistry. 12: 564-576
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