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John R. Stille, Ph.D.

Affiliations:

1987-1994

Chemistry

Michigan State University, East Lansing, MI

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Mean distance: 6.58

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Parents

Robert Howard Grubbs	grad student	1981-1986	Caltech
Gilbert Stork	post-doc	1986-1987	Columbia

Children

Pascal Rigollier	grad student	1991	Michigan State
Jonathan R. Young	grad student	1992	Michigan State
Gregory R. Cook	grad student	1993	Michigan State
Arthur E. Harms	grad student	1993	Michigan State
Kumarapandian Paulvannan	grad student	1993	Michigan State
Nancy S. Barta	grad student	1994	Michigan State
Lars G. Beholz	grad student	1994	Michigan State
Subramani Iyer	grad student	1995	Michigan State

Collaborators

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Publications

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Benovsky P, Stephenson GA, Stille JR. (1998) Asymmetric formation of quaternary centers through aza-annulation of chiral β-enamino amides with acrylate derivatives Journal of the American Chemical Society. 120: 2493-2500
Beholz LG, Benovsky P, Ward DL, et al. (1997) Formation of dihydropyridone- and pyridone-based peptide analogs through aza-annulation of β-enamino ester and amide substrates with α-amido acrylate derivatives Journal of Organic Chemistry. 62: 1033-1042
Benovsky P, Stille JR. (1997) Aza-annulation as a versatile approach to the synthesis of non-benzodiazepene compounds for the treatment of sleep disorders Tetrahedron Letters. 38: 8475-8478
Stille JR, Barta NS. (1995) Aza-annulation of enamine related substrates with a,b-unsaturated carboxylate derivatives as a route to the selective synthesis of d-lactams and pyridones Studies in Natural Products Chemistry. 18: 315-389
Barta NS, Kirk BA, Stille JR. (1995) Competitive intramolecular TiC versus AlC alkene insertions: Examining the role of Lewis acid cocatalysts in Ziegler-Natta alkene insertion and chain transfer reactions Journal of Organometallic Chemistry. 487: 47-53
Barta NS, Paulvannan K, Schwarz JB, et al. (1994) An apparatus for the efficient removal of H2O from reaction mixtures Synthetic Communications. 24: 583-590
Harms AE, Stille JR, Taylor SK. (1994) Ring formation through intramolecular SN′ displacement of an allylic methoxy substituent Organometallics. 13: 1456-1464
Cook GR, Beholz LG, Stille JR. (1994) Construction of Hydroxylated Alkaloids (.+-.)-Mannonolactam, (.+-.)-Deoxymannojirimycin, and (.+-.)-Prosopinine through Aza-Annulation The Journal of Organic Chemistry. 59: 3575-3584
Paulvannan K, Stille JR. (1994) Heterocycle formation through aza-annulation: Stereochemically controlled syntheses of (±)-5-epitashiromine and (±)-tashiromine Journal of Organic Chemistry. 59: 1613-1620
Barta NS, Kirk BA, Stille JR. (1994) .alpha.- and .beta.-Deuterium Isotope Effects in the MgX2 and Methylaluminoxane Promoted Intramolecular Olefin Insertion of Cp2TiClR Complexes. Insight into Cocatalyst Dependence and Chain End Control in Ziegler-Natta Polymerization Journal of the American Chemical Society. 116: 8912-8919

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