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Malcolm H. Chisholm - Publications

Affiliations: 
1972-1978 Princeton University, Princeton, NJ 
 1978-2000 Indiana University, Bloomington, Bloomington, IN, United States 
 2000-2015 Ohio State University, Columbus, Columbus, OH 
Area:
inorganic, organometallic and materials chemistry
Website:
https://chemistry.osu.edu/news/passing-dr.-malcolm-chisholm
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Year Citation  Score
2019 Praban S, Piromjitpong P, Balasanthiran V, Jayaraj S, Chisholm MH, Tantirungrotechai J, Phomphrai K. Highly efficient metal(iii) porphyrin and salen complexes for the polymerization of rac-lactide under ambient conditions. Dalton Transactions (Cambridge, England : 2003). PMID 30628615 DOI: 10.1039/C8Dt04699A  0.709
2017 Jiang C, Young PJ, Brown-Xu SE, Kender WT, Hamilton EJM, Gallucci JC, Chisholm MH. Probing Interligand Electron Transfer in the (1)MLCT S1 Excited State of trans-Mo2L2L'2 Compounds: A Comparative Study of Auxiliary Ligands and Solvents. Inorganic Chemistry. PMID 28783352 DOI: 10.1021/Acs.Inorgchem.7B01164  0.825
2017 Anker M, Balasanthiran C, Balasanthiran V, Chisholm MH, Jayaraj S, Mathieu K, Piromjitpong P, Praban S, Raya B, Simonsick WJ. A new route for the preparation of enriched iso-polylactide from rac-lactide via a Lewis acid catalyzed ring-opening of an epoxide. Dalton Transactions (Cambridge, England : 2003). PMID 28418053 DOI: 10.1039/C6Dt03198F  0.352
2017 Jiang C, Young PJ, Brown-Xu S, Gallucci JC, Chisholm MH. Femtosecond Study of Dimolybdenum Paddlewheel Compounds with Amide/Thioamide Ligands: Symmetry, Electronic Structure, and Charge Distribution in the (1)MLCT S1 State. Inorganic Chemistry. PMID 28075120 DOI: 10.1021/Acs.Inorgchem.6B02517  0.823
2017 Balasanthiran V, Chisholm MH, Choojun K, Durr CB, Jing S, Wambua PM. TMPMg Bu(L), where L = THF, 2-MeTHF, pyridine and dimethylaminopyridine and TMP = 1,5,9-trimesityldipyrromethene: Reaction with lactide and ε-caprolactone Journal of Organometallic Chemistry. 842: 74-81. DOI: 10.1016/J.Jorganchem.2017.05.016  0.8
2016 Jiang C, Young PJ, Durr CB, Spilker TF, Chisholm MH. Synthesis, Structure, and Photophysical Properties of Mo2(NN)4 and Mo2(NN)2(T(i)PB)2, Where NN = N,N'-Diphenylphenylpropiolamidinate and T(i)PB = 2,4,6-Triisopropylbenzoate. Inorganic Chemistry. PMID 27249173 DOI: 10.1021/Acs.Inorgchem.6B00096  0.829
2015 Chisholm MH, Ziehm CJ. Metal-Metal Quadruple Bonds (M = Mo or W) Supported by 4-[2-(4-Pyridinyl)ethenyl] Benzoates and their Complexes with Tris(pentafluorophenyl)boron. Inorganic Chemistry. PMID 26595198 DOI: 10.1021/Acs.Inorgchem.5B01520  0.503
2015 Brown-Xu SE, Chisholm MH, Durr CB, Spilker TF, Young PJ. MM Quadruply Bonded Complexes Supported by Vinylbenzoate Ligands: Synthesis, Characterization, Photophysical Properties and Application as Synthons. Chemical Science (Royal Society of Chemistry : 2010). 6: 1780-1791. PMID 26417424 DOI: 10.1039/C4Sc02542C  0.826
2015 Chisholm MH, Gustafson TL, Kender WT, Spilker TF, Young PJ. Electronic and Spectroscopic Properties of Avobenzone Derivatives Attached to Ditungsten Quadruple Bonds. Inorganic Chemistry. 54: 9438-46. PMID 26389702 DOI: 10.1021/Acs.Inorgchem.5B01221  0.831
2015 Chisholm MH, Durr CB, Gustafson TL, Kender WT, Spilker TF, Young PJ. Electronic and Spectroscopic Properties of Avobenzone Derivatives Attached to Mo₂ Quadruple Bonds: Suppression of the Photochemical Enol-to-Keto Transformation. Journal of the American Chemical Society. 137: 5155-62. PMID 25856290 DOI: 10.1021/Jacs.5B01495  0.829
2015 Balasanthiran V, Chisholm MH, Durr CB. Bismuth-lithium bonding in the ion pairs: LiBiL2, where L = a porphyrin or a salen ligand. Dalton Transactions (Cambridge, England : 2003). 44: 8205-13. PMID 25846257 DOI: 10.1039/C5Dt00256G  0.742
2015 Chisholm MH, Brown-Xu SE, Spilker TF. Photophysical studies of metal to ligand charge transfer involving quadruply bonded complexes of molybdenum and tungsten. Accounts of Chemical Research. 48: 877-85. PMID 25695495 DOI: 10.1021/Ar500256F  0.821
2015 Balasanthiran V, Chatterjee C, Chisholm MH, Harrold ND, RajanBabu TV, Warren GA. Coupling of propylene oxide and lactide at a porphyrin chromium(III) center. Journal of the American Chemical Society. 137: 1786-9. PMID 25629656 DOI: 10.1021/Ja512554T  0.571
2015 Brown-Xu SE, Chisholm MH, Durr CB, Spilker TF, Young PJ. MM quadruply bonded complexes supported by vinylbenzoate ligands: Synthesis, characterization, photophysical properties and application as synthons Chemical Science. 6: 1780-1791. DOI: 10.1039/c4sc02542c  0.802
2015 Chisholm MH, Brown-Xu SE, Spilker TF. Photophysical Studies of Metal to Ligand Charge Transfer Involving Quadruply Bonded Complexes of Molybdenum and Tungsten Accounts of Chemical Research. 48: 877-885. DOI: 10.1021/ar500256f  0.808
2015 Balasanthiran V, Chisholm MH, Choojun K, Durr CB, Wambua PM. TMPZnN(SiMe3)2, [TMPZn(μ-OiPr)]2 and TMPZn[OCMe2C(O)OEt]. Their role in the ring-opening of rac-lactide and ε-caprolactone where TMP = 1,5,9-trimesityldipyrromethene Journal of Organometallic Chemistry. DOI: 10.1016/J.Jorganchem.2016.01.001  0.814
2015 Chisholm MH. Charge distribution in metal to ligand charge transfer states of quadruply bonded metal complexes Coordination Chemistry Reviews. 282: 60-65. DOI: 10.1016/J.Ccr.2014.03.034  0.423
2015 Balasanthiran V, Chisholm MH, Durr CB. Corrigendum: On the Molecular Structure and Bonding in a Lithium Bismuth Porphyrin Complex: LiBi(TPP)2 Angewandte Chemie International Edition. 54: 1698-1698. DOI: 10.1002/Anie.201411818  0.713
2014 Brown-Xu SE, Chisholm MH, Durr CB, Gustafson TL, Spilker TF. Photophysical properties of cis-Mo2 quadruply bonded complexes and observation of photoinduced electron transfer to titanium dioxide. Journal of the American Chemical Society. 136: 11428-35. PMID 25047088 DOI: 10.1021/Ja504944D  0.817
2014 Alberding BG, Chisholm MH, Durr CB, Gallucci JC, Ghosh Y, Spilker TF. 4-Nitrophenyl- and 4'-nitro-1,1'-biphenyl-4-carboxylates attached to Mo2 quadruple bonds: ground versus excited state M2δ-ligand conjugation. Dalton Transactions (Cambridge, England : 2003). 43: 11397-403. PMID 24930899 DOI: 10.1039/C4Dt01073F  0.835
2014 Balasanthiran V, Chisholm MH, Durr CB. On the molecular structure and bonding in a lithium bismuth porphyrin complex: LiBi(TPP)(2). Angewandte Chemie (International Ed. in English). 53: 1594-7. PMID 24376116 DOI: 10.1002/Anie.201308672  0.744
2014 Brown-Xu SE, Chisholm MH, Durr CB, Lewis SA, Spilker TF, Young PJ. Mo2 paddlewheel complexes functionalized with a single MLCT, S1 infrared-active carboxylate reporter ligand: preparation and studies of ground and photoexcited states. Inorganic Chemistry. 53: 637-44. PMID 24359530 DOI: 10.1021/Ic402775S  0.823
2014 Balasanthiran V, Chisholm MH, Choojun K, Durr CB. Ethyl 2-hydroxy-2-methylpropanoate derivatives of magnesium and zinc. The effect of chelation on the homo- and copolymerization of lactide and ε-caprolactone. Dalton Transactions (Cambridge, England : 2003). 43: 2781-8. PMID 24201652 DOI: 10.1039/C3Dt52553H  0.81
2014 Brown-Xu SE, Chisholm MH, Durr CB, Lewis SA, Spilker TF, Young PJ. Molybdenum-molybdenum quadruple bonds supported by 9,10-anthraquinone carboxylate ligands. Molecular, electronic, ground state and unusual photoexcited state properties Chemical Science. 5: 2657-2666. DOI: 10.1039/C4Sc00341A  0.83
2014 Balasanthiran V, Chisholm MH, Choojun K, Durr CB, Wambua PM. BDI*MgX(L) where X= n Bu and O t Bu and L=THF, py and DMAP. The rates of kinetic exchange of L where BDI* =CH{C( t Bu)N-2,6- i Pr2C6H3}2 Polyhedron. DOI: 10.1016/J.Poly.2015.02.024  0.804
2014 Chisholm MH. The use of alkoxides and related π-donors in organotransition metal chemistry as illustrated by M2(OR)6 compounds (M = Mo or W) Journal of Organometallic Chemistry. 751: 55-59. DOI: 10.1016/J.Jorganchem.2013.08.028  0.436
2014 Chisholm MH, Durr CB, Spilker TF, Young PJ. Molecular ordering by halide-halide interactions in dimolybdenum p-halobenzoates Inorganica Chimica Acta. 424: 300-307. DOI: 10.1016/J.Ica.2014.08.016  0.799
2013 Chatterjee C, Chisholm MH. Ring-opening polymerization reactions of propylene oxide catalyzed by porphyrin metal 3+ complexes of aluminum, chromium and cobalt. Chemical Record (New York, N.Y.). 13: 549-60. PMID 24307523 DOI: 10.1002/Tcr.201300018  0.606
2013 Brown-Xu SE, Chisholm MH, Durr CB, Spilker TF. Concerning the ground state and S1 and T1 photoexcited states of the homoleptic quadruply bonded complexes Mo2(O2CC6H4-p-X)4, where X = C≡C-H or C≡N. The Journal of Physical Chemistry. A. 117: 13893-8. PMID 24205848 DOI: 10.1021/Jp408667M  0.831
2013 Chisholm MH, Choojun K, Chow AS, Fraenkel G, Gallucci JC. THF exchange and molecular dynamics in the series (BDI)MgX(THF), where X = Bu(n), NEt2, and OBu(t) and BDI = 2-[(2,6-diisopropylphenyl)amino]-4-[(2,6-diisopropylphenyl)imino]pent-2-ene. Inorganic Chemistry. 52: 11302-10. PMID 24066833 DOI: 10.1021/Ic401559B  0.79
2013 Brown-Xu SE, Chisholm MH, Durr CB, Spilker TF, Young PJ. Modulating the M2δ-to-ligand charge transfer transition by the use of diarylboron substituents. Dalton Transactions (Cambridge, England : 2003). 42: 14491-7. PMID 23969875 DOI: 10.1039/C3Dt51684A  0.836
2013 Balasanthiran V, Chisholm MH, Durr CB, Gallucci JC. Single-site bismuth alkoxide catalysts for the ring-opening polymerization of lactide. Dalton Transactions (Cambridge, England : 2003). 42: 11234-41. PMID 23812609 DOI: 10.1039/C3Dt50629K  0.754
2013 Brown-Xu SE, Chisholm MH, Durr CB, Spilker TF. Metal-metal quadruple bonds supported by 5-ethynylthiophene-2-carboxylato ligands: preparation, molecular and electronic structures, photoexcited state dynamics, and application as molecular synthons. Journal of the American Chemical Society. 135: 8254-9. PMID 23705765 DOI: 10.1021/Ja400508U  0.843
2013 Brown-Xu SE, Chisholm MH, Durr CB, Gustafson TL, Spilker TF. Coordination of N,N-chelated Re(CO)3Cl units across a Mo2 quadruple bond: synthesis, characterization, and photophysical properties of a Re-Mo2-Re triad and its component pieces. The Journal of Physical Chemistry. A. 117: 5997-6006. PMID 23570541 DOI: 10.1021/Jp311830H  0.834
2013 Chatterjee C, Chisholm MH, El-Khaldy A, McIntosh RD, Miller JT, Wu T. Influence of the metal (Al, Cr, and Co) and substituents of the porphyrin in controlling reactions involved in copolymerization of propylene oxide and carbon dioxide by porphyrin metal(III) complexes. 3. Cobalt chemistry. Inorganic Chemistry. 52: 4547-53. PMID 23556475 DOI: 10.1021/ic400068y  0.621
2013 Chisholm MH, Choojun K, Chow AS, Fraenkel G. Molecular dynamics and ligand exchange in magnesium complexes: evidence for both dissociative and associative ligand exchange. Angewandte Chemie (International Ed. in English). 52: 3264-6. PMID 23436348 DOI: 10.1002/Anie.201209542  0.774
2013 Alberding BG, Brown-Xu SE, Chisholm MH, Epstein AJ, Gustafson TL, Lewis SA, Min Y. Photoinduced charge transfer involving a MoMo quadruply bonded complex to a perylene diimide. Dalton Transactions (Cambridge, England : 2003). 42: 5275-80. PMID 23412626 DOI: 10.1039/C3Dt32750G  0.795
2013 Chisholm MH, Gustafson TL, Turro C. Photophysical properties of MM quadruply bonded complexes supported by carboxylate ligands, MM = Mo2, MoW, or W2. Accounts of Chemical Research. 46: 529-38. PMID 23145921 DOI: 10.1021/Ar3002206  0.664
2013 Brown-Xu SE, Chisholm MH, Durr CB, Lewis SA, Naseri V, Spilker TF. MM quadruple bonds supported by cyanoacrylate ligands. Extending photon harvesting into the near infrared and studies of the MLCT states Chemical Science. 4: 2105-2116. DOI: 10.1039/C3Sc50322D  0.834
2013 Harrold ND, Li Y, Chisholm MH. Studies of ring-opening reactions of styrene oxide by chromium tetraphenylporphyrin initiators. Mechanistic and stereochemical considerations Macromolecules. 46: 692-698. DOI: 10.1021/Ma302492P  0.327
2013 Chisholm MH, Choojun K, Chow AS, Fraenkel G, Gallucci JC. THF exchange and molecular dynamics in the series (BDI)MgX(THF), where X = Bun, NEt2, and OBut and BDI = 2-[(2,6-diisopropylphenyl)amino]-4-[(2,6-diisopropylphenyl)imino]pent-2-ene Inorganic Chemistry. 52: 11302-11310. DOI: 10.1021/ic401559b  0.74
2013 Bernard A, Chatterjee C, Chisholm MH. The influence of the metal (Al, Cr and Co) and the substituents of the porphyrin in controlling the reactions involved in the copolymerization of propylene oxide and cyclic anhydrides by porphyrin metal(III) complexes Polymer (United Kingdom). 54: 2639-2646. DOI: 10.1016/J.Polymer.2013.02.033  0.733
2013 Chisholm MH, Durr CB, Lewis SA. Molecular and electronic structure of MM quadruply bonded complexes containing O2CC6H4N(Ph)2 supporting ligands Polyhedron. 64: 339-345. DOI: 10.1016/J.Poly.2013.06.002  0.836
2013 Chisholm MH. Mixed valency and metal-metal quadruple bonds Coordination Chemistry Reviews. 257: 1576-1583. DOI: 10.1016/J.Ccr.2012.10.021  0.388
2013 Chisholm MH, Choojun K, Chow AS, Fraenkel G. Molecular dynamics and ligand exchange in magnesium complexes: Evidence for both dissociative and associative ligand exchange Angewandte Chemie - International Edition. 52: 3264-3266. DOI: 10.1002/anie.201209542  0.761
2012 Brown-Xu SE, Chisholm MH, Durr CB, Gustafson TL, Naseri V, Spilker TF. Electronic structure and excited-state dynamics of the molecular triads: trans-M2(T(i)PB)2[O2CC6H5-η6-Cr(CO)3]2, where M = Mo or W, and T(i)PB = 2,4,6-triisopropylbenzoate. Journal of the American Chemical Society. 134: 20820-6. PMID 23198709 DOI: 10.1021/Ja310651Y  0.837
2012 Chatterjee C, Chisholm MH. Influence of the metal (Al, Cr, and Co) and the substituents of the porphyrin in controlling the reactions involved in the copolymerization of propylene oxide and carbon dioxide by porphyrin metal(III) complexes. 2. Chromium chemistry. Inorganic Chemistry. 51: 12041-52. PMID 23094802 DOI: 10.1021/Ic302137W  0.632
2012 Alberding BG, Brown-Xu SE, Chisholm MH, Gustafson TL, Reed CR, Naseri V. Photophysical properties of MM quadruply bonded complexes (M = Mo, W) supported by carboxylate ligands: charge delocalization and dynamics in S1 and T1 states. Dalton Transactions (Cambridge, England : 2003). 41: 13097-104. PMID 23011580 DOI: 10.1039/C2Dt30490B  0.834
2012 Alberding BG, Brown-Xu SE, Chisholm MH, Gallucci JC, Gustafson TL, Naseri V, Reed CR, Turro C. Molecular and electronic structures and photophysical properties of quadruply bonded dimetal complexes (M = Mo or W) supported by trans-arylethynylcarboxylate ligands where aryl = p-tolyl or 9-anthrancenyl. Dalton Transactions (Cambridge, England : 2003). 41: 12270-81. PMID 22930257 DOI: 10.1039/C2Dt31359F  0.819
2012 Brown-Xu SE, Chisholm MH, Gallucci JC, Ghosh Y, Gustafson TL, Reed CR. Furan- and selenophene-2-carboxylato derivatives of dimolybdenum and ditungsten (M[quadruple bond]M): a comparison of their chemical and photophysical properties. Dalton Transactions (Cambridge, England : 2003). 41: 2257-63. PMID 22186951 DOI: 10.1039/C1Dt11889G  0.832
2012 Alberding BG, Chisholm MH, Gustafson TL. Detection of the singlet and triplet MM δδ* states in quadruply bonded dimetal tetracarboxylates (M = Mo, W) by time-resolved infrared spectroscopy. Inorganic Chemistry. 51: 491-8. PMID 22129155 DOI: 10.1021/Ic201957A  0.828
2012 Chisholm MH, Choojun K, Gallucci JC, Wambua PM. Chemistry of magnesium alkyls supported by 1,5,9-trimesityldipyrromethene and 2-[(2,6-diisopropylphenyl)amino]-4-[(2,6-diisopropylphenyl)imino]pent-2-ene. A comparative study Chemical Science. 3: 3445-3457. DOI: 10.1039/C2Sc21017G  0.821
2012 Bernard A, Chisholm MH. Synthesis of core-shell (nano)particles involving TiO 2, SiO 2, Al 2O 3 and polylactide Polyhedron. 46: 1-7. DOI: 10.1016/J.Poly.2012.07.017  0.542
2012 Chisholm MH, Durr CB, Hadad CM, Spilker TF. Oxalate Bridged MM Quadruply Bonded Oligomers: Considerations of Electronic Structure and Synthetic Strategies Journal of Cluster Science. 23: 767-780. DOI: 10.1007/S10876-012-0495-6  0.83
2012 Chisholm MH. Incorporating MM quadruple bonds into conjugated organic oligomers: Syntheses and optoelectronic properties Macromolecular Chemistry and Physics. 213: 800-807. DOI: 10.1002/Macp.201100656  0.436
2011 Alberding BG, Chisholm MH, Lear BJ, Naseri V, Reed CR. Synthesis and characterization of trans-M2(T(i)PB)2(O2C-CH=CH-2-C4H3S)2 (M = Mo or W) and comments on the metal-to-ligand charge transfer bands in MM quadruply bonded complexes of the type trans-M2(T(i)PB)2L2, where T(i)PB = 2,4,6-triisopropylbenzoate and L = π-accepting carboxylate ligand. Dalton Transactions (Cambridge, England : 2003). 40: 10658-63. PMID 21931912 DOI: 10.1039/C1Dt10788G  0.836
2011 Chisholm MH, Lear BJ. M2δ to ligand π-conjugation: testbeds for current theories of mixed valence in ground and photoexcited states of molecular systems. Chemical Society Reviews. 40: 5254-65. PMID 21720650 DOI: 10.1039/C1Cs15061H  0.729
2011 Alberding BG, Chisholm MH, Gallucci JC, Ghosh Y, Gustafson TL. Electron delocalization in the S1 and T1 metal-to-ligand charge transfer states of trans-substituted metal quadruply bonded complexes. Proceedings of the National Academy of Sciences of the United States of America. 108: 8152-6. PMID 21525414 DOI: 10.1073/Pnas.1103082108  0.841
2011 Chatterjee C, Chisholm MH. The influence of the metal (Al, Cr, and Co) and the substituents of the porphyrin in controlling the reactions involved in the copolymerization of propylene oxide and carbon dioxide by porphyrin metal(III) complexes. 1. Aluminum chemistry. Inorganic Chemistry. 50: 4481-92. PMID 21495626 DOI: 10.1021/Ic200142F  0.626
2011 Bunting P, Chisholm MH, Gallucci JC, Lear BJ. Extent of M2 δ to ligand π-conjugation in neutral and mixed valence states of bis(4-isonicotinate)-bis(2,4,6-triisopropylbenzoate) dimetal complexes (MM), where M = Mo or W, and their adducts with tris(pentafluorophenyl)boron. Journal of the American Chemical Society. 133: 5873-81. PMID 21434631 DOI: 10.1021/Ja109522B  0.728
2011 Alberding BG, Chisholm MH, Lear BJ, Naseri V, Reed CR. Synthesis and characterization of trans-M2(TiPB) 2(O2C-CHCH-2-C4H3S)2 (M = Mo or W) and comments on the metal-to-ligand charge transfer bands in MM quadruply bonded complexes of the type trans-M2(TiPB) 2L2, where TiPB = 2,4,6-triisopropylbenzoate Dalton Transactions. 40: 10658-10663. DOI: 10.1039/c1dt10788g  0.829
2011 Chisholm MH, Lear BJ. M2δ to ligand π-conjugation: Testbeds for current theories of mixed valence in ground and photoexcited states of molecular systems Chemical Society Reviews. 40: 5254-5265. DOI: 10.1039/c1cs15061h  0.658
2011 Bunting P, Chisholm MH, Gallucci JC, Lear BJ. Extent of M2 δ to ligand π-conjugation in neutral and mixed valence states of bis(4-isonicotinate)-bis(2,4,6-triisopropylbenzoate) dimetal complexes (MM), where M = Mo or W, and their adducts with tris(pentafluorophenyl)boron Journal of the American Chemical Society. 133: 5873-5881. DOI: 10.1021/ja109522b  0.722
2010 Alberding BG, Chisholm MH, Gustafson TL, Liu Y, Reed CR, Turro C. Photophysical studies of trans-bis(phenylethynyldiisopropylamidinato)bis(acetato)dimetal complexes involving MM quadruple bonds where M = Mo or W. The Journal of Physical Chemistry. A. 114: 12675-81. PMID 21067133 DOI: 10.1021/Jp108544V  0.825
2010 Alberding BG, Chisholm MH, Gallucci JC, Gustafson TL, Reed CR, Turro C. Concerning the photophysical properties of Re2(4+) and Re2(6+) carboxylate compounds. Dalton Transactions (Cambridge, England : 2003). 39: 11587-93. PMID 21052590 DOI: 10.1039/C0Dt00968G  0.818
2010 Chisholm MH, Patmore NJ, Reed CR, Singh N. Oxalate bridged triangles incorporating Mo2(4+) units. Electronic structure and bonding. Inorganic Chemistry. 49: 7116-22. PMID 20593790 DOI: 10.1021/Ic1009237  0.477
2010 Chisholm MH, Lear BJ, Moscatelli A, Peteanu LA. Electroabsorption of dimers containing MM (M = Mo, W) quadruply bonded units: insights into the electronic structure of neutral coupled redox centers and their relationship with mixed valence ions. Inorganic Chemistry. 49: 3706-13. PMID 20232822 DOI: 10.1021/Ic901387Q  0.736
2010 Alberding BG, Barybin MV, Chisholm MH, Gustafson TL, Reed CR, Robinson RE, Patmore NJ, Singh N, Turro C. Molecular, electronic structure and spectroscopic properties of MM quadruply bonded units supported by trans-6-carboethoxy-2-carboxylatoazulene ligands. Dalton Transactions (Cambridge, England : 2003). 39: 1979-84. PMID 20148214 DOI: 10.1039/B919282D  0.842
2010 Chisholm MH. Concerning the ring-opening polymerization of lactide and cyclic esters by coordination metal catalysts Pure and Applied Chemistry. 82: 1647-1662. DOI: 10.1351/Pac-Con-09-09-24  0.311
2009 Ayala CN, Chisholm MH, Gallucci JC, Krempner C. Chemistry of BDI*M(2+) complexes (M = Mg, Zn) and their role in lactide polymerization where BDI* is the anion derived from methylenebis(C-tBu, N-2,6-diisopropylphenyl)imine BDI*H Dalton Transactions. 9237-9245. PMID 20449201 DOI: 10.1039/B910669C  0.443
2009 Alberding BG, Chisholm MH, Chou YH, Ghosh Y, Gustafson TL, Liu Y, Turro C. 2-Thienylcarboxylato and 2-thienylthiocarboxylato ligands bonded to MM quadruple bonds (M = Mo or W): a comparison of ground state, spectroscopic and photoexcited state properties. Inorganic Chemistry. 48: 11187-95. PMID 19888750 DOI: 10.1021/Ic901607U  0.835
2009 Lear BJ, Chisholm MH. Oxalate bridged MM (MM = Mo2, MoW, and W2) quadruply bonded complexes as test beds for current mixed valence theory: looking beyond the intervalence charge transfer transition. Inorganic Chemistry. 48: 10954-71. PMID 19860456 DOI: 10.1021/Ic900995U  0.711
2009 Chen S, Chisholm MH. Concerning the reaction pathway of the metathesis reaction involving WW and CN triple bonds: a theoretical study. Inorganic Chemistry. 48: 10358-63. PMID 19817388 DOI: 10.1021/Ic901528C  0.408
2009 Alberding BG, Chisholm MH, Ghosh Y, Gustafson TL, Liu Y, Turro C. Sexithiophenes mediated by MM quadruple bonds: MM = Mo2, MoW, and W2. Inorganic Chemistry. 48: 8536-43. PMID 19673538 DOI: 10.1021/Ic901303A  0.829
2009 Chisholm MH, Singh N. Are tetrathiooxalate and diborinate bridged compounds related to oxalate bridged quadruply bonded compounds of molybdenum? Dalton Transactions (Cambridge, England : 2003). 5867-72. PMID 19623386 DOI: 10.1039/B901734H  0.441
2009 Alberding BG, Chisholm MH, Chou YH, Gallucci JC, Ghosh Y, Gustafson TL, Patmore NJ, Reed CR, Turro C. Quadruply bonded dimetal units supported by 2,4,6-triisopropylbenzoates MM(TiPB)(4) (MM = Mo(2), MoW, and W(2)): preparation and photophysical properties. Inorganic Chemistry. 48: 4394-9. PMID 19378951 DOI: 10.1021/Ic900092C  0.805
2009 Chisholm MH, Gallucci JC, Yaman G, Young T. On the remarkable structural diversity and kinetic lability of TpC*CaX complexes (X = NSi2Me6, OC6H4-p-Me, TpC*) where TpC* = tris[3-(2-methoxy-1,1-dimethylethyl)pyrazolyl]hydroborate. Chemical Communications (Cambridge, England). 1828-30. PMID 19319415 DOI: 10.1039/B818375A  0.429
2009 Chen S, Chisholm MH, Davidson ER, English JB, Lichtenberger DL. Theoretical and spectroscopic investigations of the bonding and reactivity of (RO)3M[triple bond]N molecules, where M = Cr, Mo, and W. Inorganic Chemistry. 48: 828-37. PMID 19099428 DOI: 10.1021/Ic801786U  0.433
2009 Chisholm MH, Gallucci JC, Yaman G. Synthesis and coordination chemistry of TpC*MI complexes where M=Mg, Ca, Sr, Ba and Zn and TpC*=tris[3-(2-methoxy-1,1-dimethyl)pyrazolyl]hydroborate. Dalton Transactions (Cambridge, England : 2003). 368-74. PMID 19089019 DOI: 10.1039/B812228H  0.457
2009 Chisholm MH, Patmore NJ. Oxalate bridged heteronuclear compounds containing MM quadruple bonds (M = Mo and W) and their radical cations Canadian Journal of Chemistry. 87: 88-94. DOI: 10.1139/V08-093  0.443
2009 Yoon WJ, Ghosh Y, Alberding B, Chisholm MH, Berger PR. Efficient organic bulk heterojunction solar cells through near infrared absorbing metallated thiophene complexes Conference Record of the Ieee Photovoltaic Specialists Conference. 000942-000944. DOI: 10.1109/PVSC.2009.5411134  0.707
2009 Lear BJ, Chisholm MH. Oxalate bridged MM (MM = Mo2, MoW, and W2) quadruply bonded complexes as test beds for current mixed valence theory: Looking beyond the intervalence charge transfer transition Inorganic Chemistry. 48: 10954-10971. DOI: 10.1021/ic900995u  0.665
2009 Chisholm MH. Trispyrazolylborate ligands as ancillary ligands in the development of single-site metal alkoxide catalysts for ring-opening polymerization of cyclic esters Inorganica Chimica Acta. 362: 4284-4290. DOI: 10.1016/J.Ica.2009.05.051  0.402
2009 Alberding BG, Chisholm MH, Gustafson TL, Reed CR, Singh N, Turro C. [Bis(trispivalatodimolybdenum (II))-μ-bis(4′-carboxylato-2,2′:6′,2″-terpyridine) ruthenium (II)] (2+) Tetrafluoroborate: Photophysical studies Journal of Cluster Science. 20: 307-317. DOI: 10.1007/S10876-009-0232-Y  0.806
2008 Burdzinski GT, Chisholm MH, Chou PT, Chou YH, Feil F, Gallucci JC, Ghosh Y, Gustafson TL, Ho ML, Liu Y, Ramnauth R, Turro C. The remarkable influence of M2delta to thienyl pi conjugation in oligothiophenes incorporating MM quadruple bonds. Proceedings of the National Academy of Sciences of the United States of America. 105: 15247-52. PMID 18832150 DOI: 10.1073/Pnas.0807411105  0.808
2008 Chisholm MH, Dann AS, Dielmann F, Gallucci JC, Patmore NJ, Ramnauth R, Scheer M. Dimolybdenum bis-2,4,6-triisopropyl-benzoate bis-4-isonicotinate: a redox active analogue of 4,4'-bipyridine with ambivalent properties. Inorganic Chemistry. 47: 9248-55. PMID 18817375 DOI: 10.1021/Ic800693R  0.444
2008 Burroughs BA, Bursten BE, Chen S, Chisholm MH, Kidwell AR. Metathesis of nitrogen atoms within triple bonds involving carbon, tungsten, and molybdenum. Inorganic Chemistry. 47: 5377-85. PMID 18459728 DOI: 10.1021/Ic8003917  0.598
2008 Chisholm MH, Chou PT, Chou YH, Ghosh Y, Gustafson TL, Ho ML. Preparations and photophysical properties of fused and nonfused thienyl bridged MM (M = Mo or W) quadruply bonded complexes. Inorganic Chemistry. 47: 3415-25. PMID 18338849 DOI: 10.1021/Ic800090N  0.794
2008 Brown DJ, Chisholm MH, Gallucci JC. Amidinate-carboxylate complexes of dimolybdenum and ditungsten: M2(O2CR)2((NiPr)2CR')2. Preparations, molecular and electronic structures and reactions. Dalton Transactions (Cambridge, England : 2003). 1615-24. PMID 18335145 DOI: 10.1039/B715258B  0.494
2008 Chisholm MH, Gallucci JC, Quisenberry KT, Zhou Z. Complexities in the ring-opening polymerization of lactide by chiral salen aluminum initiators. Inorganic Chemistry. 47: 2613-24. PMID 18327904 DOI: 10.1021/Ic7019704  0.533
2008 Krempner C, Chisholm MH, Gallucci J. The multidentate ligand (MeOMe2Si)3Si-: unusual coordination modes in alkali metal silanides. Angewandte Chemie (International Ed. in English). 47: 410-3. PMID 18022882 DOI: 10.1002/Anie.200703575  0.311
2008 Chisholm MH. Mixed valence complexes involving MM quadruple bonds (M=Mo or W). Philosophical Transactions. Series a, Mathematical, Physical, and Engineering Sciences. 366: 101-12. PMID 17846014 DOI: 10.1098/Rsta.2007.2143  0.403
2008 Chisholm MH, Gallucci JC, Quisenberry KT, Zhou Z. Complexities in the ring-opening polymerization of lactide by chiral salen aluminum initiators Inorganic Chemistry. 47: 2613-2624. DOI: 10.1021/ic7019704  0.416
2008 Bursten BE, Chen S, Chisholm MH. Ligand effects on the stability of the insertion products: A DFT study of oxidative addition of NH3 to iridium(I) complex Journal of Organometallic Chemistry. 693: 1547-1551. DOI: 10.1016/J.Jorganchem.2008.01.013  0.584
2008 Chisholm MH. Catalytic formation of cyclic-esters and -depsipeptides and chemical amplification by complexation with sodium ions Journal of Organometallic Chemistry. 693: 808-818. DOI: 10.1016/J.Jorganchem.2007.09.037  0.342
2008 Chisholm MH, Hadad CM, Heinze K, Hempel K, Singh N, Vyas S. (2+) Tetrafluoroborate. Preparation, electronic structure and physical properties Journal of Cluster Science. 19: 209-218. DOI: 10.1007/S10876-007-0167-0  0.454
2008 Krempner C, Chisholm M, Gallucci J. Der mehrzähnige Ligand (MeOMe2Si)3Si−: ungewöhnliche Koordinationsweisen in Alkalimetallsilaniden Angewandte Chemie. 120: 416-420. DOI: 10.1002/Ange.200703575  0.319
2007 Chisholm MH, Gallucci JC, Yin H. 18-Membered cyclic esters derived from glycolide and lactide: Preparations, structures and coordination to sodium ions Dalton Transactions. 4811-4821. PMID 17955133 DOI: 10.1039/B709081A  0.548
2007 Chisholm MH, Gallucci JC, Yaman G. Catalysis design for ring-opening polymerization of cyclic esters: 1. Group 1 metal and thallium(I) trispyrazolylborate complexes with hemilabile ligands Inorganic Chemistry. 46: 8676-8683. PMID 17867677 DOI: 10.1021/Ic700965D  0.438
2007 Barybin MV, Chisholm MH, Patmore NJ, Robinson RE, Singh N. Concerning the molecular and electronic structure of a tungsten-tungsten quadruply bonded complex supported by two 6-carboethoxy-2-carboxylatoazulene ligands. Chemical Communications (Cambridge, England). 3652-4. PMID 17728883 DOI: 10.1039/B708746B  0.407
2007 Brown DJ, Chisholm MH, Gribble CW. Substitution chemistry of MM quadruply bonded complexes (M = Mo or W) supported by the anion of 2-hydroxy-6-methylpyridine. Dalton Transactions (Cambridge, England : 2003). 1793-801. PMID 17471374 DOI: 10.1039/B618957A  0.444
2007 Chisholm MH. Metal to metal multiple bonds in ordered assemblies. Proceedings of the National Academy of Sciences of the United States of America. 104: 2563-70. PMID 17299047 DOI: 10.1073/Pnas.0610364104  0.445
2007 Chisholm MH, Patmore NJ. Studies of electronic coupling and mixed valency in metal-metal quadruply bonded complexes linked by dicarboxylate and closely related ligands Accounts of Chemical Research. 40: 19-27. PMID 17226942 DOI: 10.1021/Ar068100I  0.432
2007 Chisholm MH, Patmore NJ. 2,5-Dianilinoterephthalate bridged MM quadruply bonded complexes of molybdenum and tungsten. Dalton Transactions (Cambridge, England : 2003). 91-6. PMID 17160178 DOI: 10.1039/B607709A  0.465
2007 Chisholm M, Gallucci J, Yin H. A Reusable Ring-Enlarging Catalyst Synfacts. 2007: 0037-0037. DOI: 10.1055/s-2006-955680  0.429
2007 Chisholm MH, Gallucci JC, Krempner C. Ring-opening polymerization of l-lactide by organotin(IV)alkoxides, R2Sn(OPri)2: Estimation of the activation parameters Polyhedron. 26: 4436-4444. DOI: 10.1016/J.Poly.2007.06.002  0.379
2007 Chisholm MH, D'acchioli JS, Hadad CM. The physical and electronic structure of M2 quadruply bonded complexes: A density functional theory study Journal of Cluster Science. 18: 27-49. DOI: 10.1007/S10876-006-0074-9  0.805
2007 Chisholm MH, Rothwell IP. Chemical Reactions of Metal‐Metal Bonded Compounds of the Transition Elements Cheminform. 13: 1-72. DOI: 10.1002/9780470166307.Ch1  0.585
2007 Chen S, Bursten BE, Chisholm MH. Ligand effects on the stability of the insertion products: A DFT study of oxidative addition of ammonia to iridium (I) complex Acs National Meeting Book of Abstracts.  0.505
2006 Chisholm MH, D'Acchioli JS, Hadad CM, Patmore NJ. Concerning the electronic coupling of MoMo quadruple bonds linked by 4,4'-azodibenzoate and comparison with t2g 6-Ru(II) centers by 4,4'-azodiphenylcyanamido ligands. Inorganic Chemistry. 45: 11035-42. PMID 17173463 DOI: 10.1021/Ic060956W  0.809
2006 Chisholm MH, Gallucci JC, Yin H. Cyclic esters and cyclodepsipeptides derived from lactide and 2,5-morpholinediones. Proceedings of the National Academy of Sciences of the United States of America. 103: 15315-20. PMID 17032774 DOI: 10.1073/Pnas.0602662103  0.558
2006 Chisholm MH, Patmore NJ. Electronic coupling in 1,4-(COS)2C6H4 linked MM quadruple bonds (M = Mo, W): the influence of S for O substitution. Dalton Transactions (Cambridge, England : 2003). 3164-9. PMID 16802033 DOI: 10.1039/B600983B  0.429
2006 Burdzinski GT, Ramnauth R, Chisholm MH, Gustafson TL. Direct observation of a 1MLCT state by ultrafast transient absorption spectroscopy in Mo2(O2C-9-anthracene)4. Journal of the American Chemical Society. 128: 6776-7. PMID 16719443 DOI: 10.1021/Ja057687D  0.587
2006 Chisholm MH, Gallucci JC, Yaman G. A tris-pyrazolylborate ligand with hemilabile O-donor groups. Examples of eta3, eta5, eta6 and bridging modes of bonding to Li+, Na+, K+, Tl+ and Ca2+ ions. Chemical Communications (Cambridge, England). 1872-4. PMID 16622513 DOI: 10.1039/B517640A  0.322
2006 Chisholm MH, Galucci J, Krempner C, Wiggenhorn C. Comments on the ring-opening polymerization of morpholine-2,5-dione derivatives by various metal catalysts and characterization of the products formed in the reactions involving R2SnX2, where X = OPr(i) and NMe2 and R = Bu(n), Ph and p-Me2NC6H4. Dalton Transactions (Cambridge, England : 2003). 846-51. PMID 16437180 DOI: 10.1039/B510580C  0.414
2006 Chisholm MH, Gallucci JC, Yin H. Cyclic esters and cyclodepsipeptides derived from lactide and 2,5-morpholinediones Proceedings of the National Academy of Sciences of the United States of America. 103: 15315-15320. DOI: 10.1073/pnas.0602662103  0.453
2006 Lee JH, Choi SM, Pate BD, Chisholm MH, Han YS. Magnetic uniaxial alignment of the columnar superstructure of discotic metallomesogens over the centimetre length scale Journal of Materials Chemistry. 16: 2785-2791. DOI: 10.1039/B603902B  0.57
2006 Chisholm MH, Gallucci JC, Hollandsworth CB. Crystal and molecular structure of W2(OBut) 6 and electronic structure calculations on various conformers of W2(OMe)6 Polyhedron. 25: 827-833. DOI: 10.1016/J.Poly.2005.07.010  0.808
2006 Chisholm MH, Gallucci JC, Hollandsworth CB. Unexpected formation of anti-1,2-W2(SBut) 2(NMe2)4 in the thiolysis of gauche-1,2-W 2Cp2(NMe2)4 and W 2COT(NMe2)4 with ButSH Journal of Organometallic Chemistry. 691: 93-96. DOI: 10.1016/J.Jorganchem.2005.08.046  0.823
2006 Chisholm MH, Gallucci JC, Hollandsworth CB. Alcoholysis of gauche-1,2-(η3-Cp)2W2(NMe2)4: Structural evidence for W{triple bond, long}W bond cleavage and proton transfer to bound cyclopentadiene Inorganic Chemistry Communications. 9: 982-985. DOI: 10.1016/J.Inoche.2006.04.035  0.822
2005 Chisholm MH, Feil F, Hadad CM, Patmore NJ. Electronically coupled MM quadruply-bonded complexes (M = Mo or W) employing functionalized terephthalate bridges: toward molecular rheostats and switches. Journal of the American Chemical Society. 127: 18150-8. PMID 16366568 DOI: 10.1021/Ja0550982  0.435
2005 Byrnes MJ, Chisholm MH, Gallucci JA, Liu Y, Ramnauth R, Turro C. Observation of 1MLCT and 3MLCT excited states in quadruply bonded Mo2 and W2 complexes. Journal of the American Chemical Society. 127: 17343-52. PMID 16332084 DOI: 10.1021/Ja055136H  0.441
2005 Byrnes MJ, Chisholm MH, Patmore NJ. New metal-organic polygons involving MM quadruple bonds: M8(O2CtBu)4(mu-SC4H2-3,4-{CO2}2)6 (M=Mo, W). Inorganic Chemistry. 44: 9347-52. PMID 16323919 DOI: 10.1021/Ic051516S  0.472
2005 Barybin MV, Chisholm MH, Dalal NS, Holovics TH, Patmore NJ, Robinson RE, Zipse DJ. Long-range electronic coupling of MM quadruple bonds (M = Mo or W) via a 2,6-azulenedicarboxylate bridge. Journal of the American Chemical Society. 127: 15182-90. PMID 16248660 DOI: 10.1021/Ja0541884  0.472
2005 Chisholm MH, Gallucci JC, Phomphrai K. Comparative study of the coordination chemistry and lactide polymerization of alkoxide and amide complexes of zinc and magnesium with a beta-diiminato ligand bearing ether substituents. Inorganic Chemistry. 44: 8004-10. PMID 16241150 DOI: 10.1021/Ic048363D  0.735
2005 Chisholm MH, Patmore NJ. Electronically-coupled MM quadruply-bonded complexes of molybdenum and tungsten. Chemical Record (New York, N.Y.). 5: 308-20. PMID 16211587 DOI: 10.1002/Tcr.20053  0.444
2005 Chisholm MH, Epstein AJ, Gallucci JC, Feil F, Pirkle W. Oligothiophenes incorporating metal-metal quadruple bonds. Angewandte Chemie (International Ed. in English). 44: 6537-40. PMID 16163772 DOI: 10.1002/Anie.200500138  0.304
2005 Bursten BE, Chisholm MH, D'Acchioli JS. Oxalate-bridged dinuclear M2 units: dimers of dimers, cyclotetramers, and extended sheets (m = Mo, W, Tc, Ru, and Rh). Inorganic Chemistry. 44: 5571-9. PMID 16060606 DOI: 10.1021/Ic050053N  0.817
2005 Chisholm MH, Gallucci JC, Yin H, Zhen H. Arylzinc alkoxides: [ArZnOCHPr(i)2]2 and Ar2Zn3(OCHPr(i)2)4 when Ar = C6H5, p-CF3C6H4, 2,4,6-Me3C6H2, and C6F5. Inorganic Chemistry. 44: 4777-85. PMID 15962986 DOI: 10.1021/Ic048332I  0.596
2005 Chisholm MH, D'Acchioli JS, Hadad CM, Patmore NJ. Studies of oxalate-bridged MM quadruple bonds and their radical cations (M=Mo or W): on the matter of linkage isomers. Dalton Transactions (Cambridge, England : 2003). 1852-7. PMID 15877158 DOI: 10.1039/B501938A  0.814
2005 Chisholm MH, D'Acchioli JS, Pate BD, Patmore NJ, Dalal NS, Zipse DJ. Cations M2(O2CtBu)4+, where M = Mo and W, and MoW(O2CtBu)4+. Theoretical, spectroscopic, and structural investigations. Inorganic Chemistry. 44: 1061-7. PMID 15859287 DOI: 10.1021/Ic049081G  0.822
2005 Chen P, Chisholm MH, Gallucci JC, Zhang X, Zhou Z. Binding of propylene oxide to porphyrin- and salen-M(III) cations, where M = Al, Ga, Cr, and Co. Inorganic Chemistry. 44: 2588-95. PMID 15819543 DOI: 10.1021/Ic048597X  0.553
2005 Chisholm MH, Patmore NJ, Zhou Z. Concerning the relative importance of enantiomorphic site vs. chain end control in the stereoselective polymerization of lactides: reactions of (R,R-salen)- and (S,S-salen)-aluminium alkoxides LAlOCH2R complexes (R = CH3 and S-CHMeCl). Chemical Communications (Cambridge, England). 127-9. PMID 15614395 DOI: 10.1039/B413266A  0.504
2005 Chisholm MH, Gallucci JC, Hollandsworth CB. Tetra-μ-6-methylpyridin-2-olato-ditungsten toluene sesquisolvate Acta Crystallographica Section E: Structure Reports Online. 61: m2503-m2504. DOI: 10.1107/S1600536805035397  0.806
2005 Chisholm MH, D'Acchioli JS, Pate BD, Patmore NJ, Dalal NS, Zipse DJ. Cations M2(O2CtBu)4 +, where M = Mo and W, and MoW(O2CtBu) 4 +. Theoretical, spectroscopic, and structural investigations Inorganic Chemistry. 44: 1061-1067. DOI: 10.1021/ic049081g  0.805
2005 Chisholm MH, Gallucci JC, Hollandsworth CB. Interconverting WW triple bonds and W4 clusters: Structures of W4(OPrn )16 and [Li2W 2(OPrn )8(DME)]2 Journal of Cluster Science. 16: 231-249. DOI: 10.1007/S10876-005-4546-0  0.8
2004 Schön E, Zhang X, Zhou Z, Chisholm MH, Chen P. Gas-phase and solution-phase polymerization of epoxides by Cr(salen) complexes: evidence for a dinuclear cationic mechanism. Inorganic Chemistry. 43: 7278-80. PMID 15530075 DOI: 10.1021/Ic049120O  0.475
2004 Chisholm MH, Gallucci JC, Phomphrai K. Well-defined calcium initiators for lactide polymerization. Inorganic Chemistry. 43: 6717-25. PMID 15476371 DOI: 10.1021/Ic0490730  0.714
2004 Byrnes MJ, Chisholm MH, Clark RJ, Gallucci JC, Hadad CM, Patmore NJ. Thienyl carboxylate ligands bound to and bridging MM quadruple bonds, M = Mo or W: models for polythiophenes incorporating MM quadruple bonds. Inorganic Chemistry. 43: 6334-44. PMID 15446881 DOI: 10.1021/Ic040086N  0.508
2004 Chisholm MH, Zhou Z. Concerning the mechanism of the ring opening of propylene oxide in the copolymerization of propylene oxide and carbon dioxide to give poly(propylene carbonate). Journal of the American Chemical Society. 126: 11030-9. PMID 15339189 DOI: 10.1021/Ja0394232  0.536
2004 Byrnes MJ, Chisholm MH, Dye DF, Hadad CM, Pate BD, Wilson PJ, Zaleski JM. 9,10-Anthracene dicarboxylate bridged complexes with M2 quadruply bonded dimetal units: [[M2(O2CtBu)3]2(mu-9,10-An(CO2)2)], where M = Mo or W. Dalton Transactions (Cambridge, England : 2003). 523-9. PMID 15252513 DOI: 10.1039/B312613G  0.686
2004 Chisholm MH, Clark RJ, Gallucci J, Hadad CM, Patmore NJ. Electronically-coupled tungsten-tungsten quadruple bonds: comparisons of electron delocalization in 3,6-dioxypyridazine and oxalate-bridged compounds. Journal of the American Chemical Society. 126: 8303-13. PMID 15225073 DOI: 10.1021/Ja048768X  0.489
2004 Chisholm MH, Clark RJ, Hadad CM, Patmore NJ. 3,6-dioxypyridazine bridged tungsten-tungsten quadruple bonds. Comparisons of electron delocalisation with oxalate bridged compounds. Chemical Communications (Cambridge, England). 80-2. PMID 14737342 DOI: 10.1039/B310982H  0.424
2004 Chisholm MH, Zhou Z. New generation polymers: The role of metal alkoxides as catalysts in the production of polyoxygenates Journal of Materials Chemistry. 14: 3081-3092. DOI: 10.1039/B405489J  0.463
2004 Chisholm MH, Delbridge EE, Gallucci JC. Modeling the catalyst resting state in aryl tin(IV) polymerizations of lactide and estimating the relative rates of transamidation, transesterification and chain transfer New Journal of Chemistry. 28: 145-152. DOI: 10.1039/B306700A  0.422
2004 Byrnes MJ, Chisholm MH, Hadad CM, Zhou Z. Regioregular and regioirregular oligoether carbonates: A 13C{ 1H} NMR investigation Macromolecules. 37: 4139-4145. DOI: 10.1021/Ma049850F  0.335
2004 Chisholm MH, Patmore NJ. On the solvatochromic properties of the oxalate-bridged complexes [( tBuCO2)3M2]2(μ-O 2C2O2) where M = Mo or W Inorganica Chimica Acta. 357: 3877-3882. DOI: 10.1016/J.Ica.2004.07.030  0.443
2003 Chisholm MH, Gallucci J, Hadad CM, Huffman JC, Wilson PJ. M2(hpp)4Cl2 and M2(hpp)4, where M = Mo and W: preparations, structure and bonding, and comparisons with C2, C2H2, and C2Cl2 and the hypothetical molecules M2(hpp)4(H)2. Journal of the American Chemical Society. 125: 16040-9. PMID 14677996 DOI: 10.1021/Ja0301065  0.431
2003 Chisholm MH, Delbridge EE, Kidwell AR, Quinlan KB. Nitrogen atom exchange between molybdenum, tungsten and carbon. A convenient method for N-15 labeling. Chemical Communications (Cambridge, England). 126-7. PMID 12610998 DOI: 10.1039/B210286B  0.752
2003 Chisholm MH, Gallucci J, Phomphrai K. Lactide polymerization by well-defined calcium coordination complexes: comparisons with related magnesium and zinc chemistry. Chemical Communications (Cambridge, England). 48-9. PMID 12610959 DOI: 10.1039/B208679D  0.676
2003 Chisholm MH. Electronic coupling between molybdenum or tungsten quadruple bonds linked by dicarboxylate ligands Journal of the Chemical Society. Dalton Transactions. 3821-3828. DOI: 10.1039/B307167G  0.452
2003 Chisholm MH, Click DR, Gallucci JC, Hadad CM. Reactions of [W2(OCH2 tBu)8] (M=M) with diazobenzene and trimethylsilyldiazomethane. Preparation and structures of W2(OCH2 tBu)8(NPh) and W2(OCH2 tBu)8(N2C(H) SiMe3) Dalton Transactions. 3205-3210. DOI: 10.1039/B304587K  0.826
2003 Chisholm MH, Delbridge EE. A study of the ring-opening polymerization (ROP) of L-lactide by Ph 2SnX2 precursors (X = NMe2, OPri): The notable influence of initiator group New Journal of Chemistry. 27: 1177-1183. DOI: 10.1039/B300351E  0.327
2003 Chisholm MH, Delbridge EE. A study of the ring-opening of lactides and related cyclic esters by Ph2SnX2 and Ph3SnX compounds (X = NMe 2, OR) New Journal of Chemistry. 27: 1167-1176. DOI: 10.1039/B300101F  0.361
2003 Chisholm MH, Lin CC, Gallucci JC, Ko BT. Binolate complexes of lithium, zinc, aluminium, and titanium; preparations, structures, and studies of lactide polymerization Journal of the Chemical Society. Dalton Transactions. 406-412. DOI: 10.1039/B211582B  0.436
2003 Chisholm MH, Click DR, Gallucci JC, Hadad CM, Wilson PJ. Alkyne adducts of [W2(OCH2 tBu)8]. Cases of perpendicular and skewed bridges in equilibrium with terminal bonded isomers Organometallics. 22: 4725-4733. DOI: 10.1021/Om030498O  0.804
2003 Chisholm MH, Gallucci J, Navarro-Llobet D, Zhen H. Further investigation of the ring-opening polymerization of propylene oxide. Catecholate derivatives of Zn(II) and Al(III) Polyhedron. 22: 557-561. DOI: 10.1016/S0277-5387(02)01414-6  0.795
2003 Chisholm MH, Davidson ER, Quinlan KB. An investigation into the relative influence of alkoxide and thiolate ligands on the metal-carbon triple bond in X3M≡CH compounds, where M = CR, MO and W and X = OH, SH, OCH3, SCH3, OCF3 and SCF3 from electronic structure calculations Polyhedron. 22: 145-152. DOI: 10.1016/S0277-5387(02)01260-3  0.815
2003 Chisholm MH, Gallucci JC, Hollandsworth CB. Tetranuclear tungsten cyclooctatetraenyl alkoxides [W2COT (OR)4]2, where R=Me, Et and Pr Journal of Organometallic Chemistry. 684: 269-276. DOI: 10.1016/S0022-328X(03)00757-5  0.816
2003 Chisholm MH, Phomphrai K. Conformational effects in β-diiminate ligated magnesium and zinc amides. Solution dynamics and lactide polymerization Inorganica Chimica Acta. 350: 121-125. DOI: 10.1016/S0020-1693(02)01510-4  0.724
2002 Chisholm MH, Davidson ER, Quinlan KB. Insights into the metathesis reaction involving M-M, C-C, and M-C triple bonds from computations employing density functional theory on model compounds M2(OH)6 and M2(SH)6, where M = Mo and W. Journal of the American Chemical Society. 124: 15351-8. PMID 12487610 DOI: 10.1021/Ja020847Q  0.798
2002 Chisholm MH, Davidson ER, Pink M, Quinlan KB. Insights into the Schrock 'chop-chop' reaction gained from density functional theory and preparation and structure of W2(mu-PhCCPh)(SC6H4-2-Me)6. Chemical Communications (Cambridge, England). 2770-1. PMID 12478738 DOI: 10.1039/B208819C  0.791
2002 Chisholm MH, Click DR, Gallucci JC, Hadad CM, Wilson PJ. Alkyne adducts of [W2(OCH2tBu)8]n (M = M): comparisons of bridging and terminal addition products. Journal of the American Chemical Society. 124: 14518-9. PMID 12465945 DOI: 10.1021/Ja027478I  0.799
2002 Bursten BE, Chisholm MH, Clark RJ, Firth S, Hadad CM, Wilson PJ, Woodward PM, Zaleski JM. Perfluoroterephthalate bridged complexes with M-M quadruple bonds: ((t)BuCO(2))(3)M(2)(mu-O(2)CC(6)F(4)CO(2))M(2)(O(2)C(t)Bu)(3), where M = Mo or W. Studies of solid-state, molecular, and electronic structure and correlations with electronic and Raman spectral data. Journal of the American Chemical Society. 124: 12244-54. PMID 12371866 DOI: 10.1021/Ja020248J  0.623
2002 Byrnes MJ, Chisholm MH. Thienyl carboxylate ligands bound to M2 quadruple bonds involving molybdenum and tungsten. Models for dimetallated polythiophenes. Chemical Communications (Cambridge, England). 2040-1. PMID 12357769 DOI: 10.1039/B205082J  0.423
2002 Chisholm MH, Pate BD, Wilson PJ, Zaleski JM. On the electron delocalization in the radical cations formed by oxidation of MM quadruple bonds linked by oxalate and perfluoroterephthalate bridges. Chemical Communications (Cambridge, England). 1084-5. PMID 12122676 DOI: 10.1039/B202344J  0.682
2002 Chisholm MH, Wilson PJ, Woodward PM. Intermolecular recognition and crystal packing in molybdenum and tungsten coordination polymers as deduced from powder X-ray diffraction data. Chemical Communications (Cambridge, England). 566-7. PMID 12120126 DOI: 10.1039/B200362G  0.376
2002 Chisholm MH, Davidson ER, Pink M, Quinlan KB. Tristhiolatomolybdenum nitrides, (RS)(3)Mo[triple bond]N where R = (i)Pr and (t)Bu, preparation, characterization and comparisons with related trialkoxymolybdenumnitrides. Inorganic Chemistry. 41: 3437-43. PMID 12079462 DOI: 10.1021/Ic020106Q  0.803
2002 Chisholm MH, Gallucci J, Phomphrai K. Coordination chemistry and reactivity of monomeric alkoxides and amides of magnesium and zinc supported by the diiminato ligand CH(CMeNC(6)H(3)-2,6-(i)Pr(2))(2). A comparative study. Inorganic Chemistry. 41: 2785-94. PMID 12005504 DOI: 10.1021/Ic020148E  0.76
2002 Pate BD, Thorne JR, Click DR, Chisholm MH, Denning RG. Third-order nonlinear optical properties of complexes with MM triple and quadruple bonds (M = Mo, W) at 1064 nm by degenerate four-wave mixing. Inorganic Chemistry. 41: 1975-8. PMID 11925196 DOI: 10.1021/Ic0112138  0.81
2002 Bursten BE, Chisholm MH, Clark RJ, Firth S, Hadad CM, MacIntosh AM, Wilson PJ, Woodward PM, Zaleski JM. Oxalate-bridged complexes of dimolybdenum and ditungsten supported by pivalate ligands: ((t)BuCO(2))(3)M(2)(mu-O(2)CCO(2))M(2)(O(2)C(t)Bu)(3). Correlation of the solid-state, molecular, and electronic structures with Raman, resonance Raman, and electronic spectral data. Journal of the American Chemical Society. 124: 3050-63. PMID 11902897 DOI: 10.1021/Ja011786J  0.631
2002 Bursten BE, Chisholm MH, Drummond ML, Gallucci JC, Hollandsworth CB. Cyclooctatetraene ditungsten alkoxides: W2(μ-η5,η5-COT)(OR)4, where R = CH2 tBu, iPr, and tBu Journal of the Chemical Society, Dalton Transactions. 4077-4083. DOI: 10.1039/B205130N  0.838
2002 Byrnes MJ, Chisholm MH, Gallucci J, Wilson PJ. Alkyne adducts of ditungsten tetrapivalate: [W2(κ2-O2CtBu)4( μ-RCCR′)2], where R = R′ = Me, Et, Ph and R = Me, R′ = Ph Organometallics. 21: 2240-2247. DOI: 10.1021/Om020074E  0.403
2002 Chisholm MH, Navarro-Llobet D, Zhou Z. Poly(propylene carbonate). 1. More about poly(propylene carbonate) formed from the copolymerization of propylene oxide and carbon dioxide employing a zinc glutarate catalyst Macromolecules. 35: 6494-6504. DOI: 10.1021/Ma020348+  0.789
2002 Chisholm MH, Navarro-Llobet D. NMR assignments of regioregular poly(propylene oxide) at the triad and tetrad level Macromolecules. 35: 2389-2392. DOI: 10.1021/Ma0119934  0.778
2002 Chisholm MH, Click DR, Gallucci JC, Hadad CM, Wilson PJ. Alkyne adducts of [W2(OCH2 tBu)8]n (M = M): Comparisons of bridging and terminal addition products Journal of the American Chemical Society. 124: 14518-14519. DOI: 10.1021/ja027478i  0.762
2002 Pate BD, Choi SM, Werner-Zwanziger U, Baxter DV, Zaleski JM, Chisholm MH. Structure and magnetic alignment of metalloporphyrazine columnar aggregates in their mesophases and crystalline phases Chemistry of Materials. 14: 1930-1936. DOI: 10.1021/Cm010428C  0.618
2002 Chisholm MH. Electronic coupling in covalently-linked MM quadruple bonds: M2δ to ligand π conjugation Journal of Organometallic Chemistry. 641: 15-25. DOI: 10.1016/S0022-328X(01)01365-1  0.438
2002 Chisholm MH, Davidson ER, Pink M, Quinlan KB. Insights into the Schrock 'chop-chop' reaction gained from density functional theory and preparation and structure of W2(μ-PhCCPh)(SC6H4-2-Me)6 Chemical Communications. 2770-2771.  0.743
2002 Jones RB, Green-Church KB, Pate BD, Byrnes MJ, Chisholm MH. Extending the applications of LDI-MS and ESI-MS to include air-sensitive inorganic complexes Proceedings 50th Asms Conference On Mass Spectrometry and Allied Topics. 459-460.  0.522
2002 Zhou Z, Chisholm MH, Navarro-Llobet D. Investigations on a zinc glutarate catalytic system in the copolymerization of propylene oxide and carbon dioxide American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 43: 942-943.  0.763
2001 Bursten BE, Chisholm MH, Hadad CM, Li J, Wilson PJ. M2 delta-to-oxalate pi* conjugation in oxalate-bridged complexes containing M-M quadruple bonds. Chemical Communications (Cambridge, England). 2382-3. PMID 12240086 DOI: 10.1039/B103898M  0.623
2001 Chisholm MH. Factors influencing the reductive cleavage of C-x multiple bonds in their reactions with meal-meal multiple bonds (X = C, N, O, S). Chemical Record (New York, N.Y.). 1: 12-23. PMID 11893053 DOI: 10.1002/1528-0691(2001)1:1<12::Aid-Tcr4>3.0.Co;2-5  0.42
2001 Chisholm MH, Navarro-Llobet D, Gallucci J. Siloxide and triflate gallium(III) complexes supported by the BDI ligand. Inorganic Chemistry. 40: 6506-8. PMID 11720510 DOI: 10.1021/Ic010771J  0.801
2001 Chisholm MH, Davidson ER, Huffman JC, Quinlan KB. A comparison of the influences of alkoxide and thiolate ligands on the electronic structure and reactivity of molybdenum(3+) and tungsten(3+) complexes. preparation and structures of M(2)(O(T)Bu)(2)(S(t)Bu)(4), [Mo(S(t)Bu)(3)(NO)](2), and W(S(t)Bu)(3)(NO)(py). Journal of the American Chemical Society. 123: 9652-64. PMID 11572687 DOI: 10.1021/Ja001208N  0.801
2001 Chisholm MH, Gallucci JC, Zhen H, Huffman JC. Three-coordinate zinc amide and phenoxide complexes supported by a bulky Schiff base ligand. Inorganic Chemistry. 40: 5051-4. PMID 11531458 DOI: 10.1021/Ic010560E  0.39
2001 Bursten BE, Chisholm MH, Hadad CM, Li J, Wilson PJ. Electronic coupling between molybdenum and tungsten quadruple bonds in molecular squares and extended chains linked by oxalate, acetylenedicarboxylate, and perfluoroterephthalate bridges Israel Journal of Chemistry. 41: 187-195. DOI: 10.1560/6820-Jh3K-Ea64-9Tt6  0.614
2001 Bollinger JC, Chisholm MH, Click DR, Folting K, Hadad CM, Tiedtke DB, Wilson PJ. Chalcogenide-bridged ditungsten (M-M) complexes: An experimental and theoretical study of the electronic structure and bonding in W2(μ-E)(μ-OCH2 tBu)2(OCH 2 tBu)6, where E = O, S, Se or Te Journal of the Chemical Society, Dalton Transactions. 2074-2082. DOI: 10.1039/B101346G  0.794
2001 Chisholm MH, Huffman JC, Phomphrai K. Monomeric metal alkoxides and trialkyl siloxides: (BDI)Mg(OtBu)(THF) and (BDI)Zn(OSiPh3)(THF). Comments on single site catalysts for ring-opening polymerization of lactides Journal of the Chemical Society, Dalton Transactions. 222-224. DOI: 10.1039/B008158M  0.709
2001 Baxter DV, Caulton KG, Chiang WC, Chisholm MH, DiStasi VF, Dutremez SG, Martin JD, Streib WE. Synthesis and structural characterization of tricarbomethoxymethanate complexes of copper(II) and barium(II) and evaluation of their suitability for MOCVD applications New Journal of Chemistry. 25: 400-407. DOI: 10.1039/B008147G  0.592
2001 Chisholm MH, Navarro-Llobet D, Simonsick WJ. A comparative study in the ring-opening polymerization of lactides and propylene oxide Macromolecules. 34: 8851-8857. DOI: 10.1021/Ma011328V  0.804
2001 Antelmann B, Chisholm MH, Iyer SS, Huffman JC, Navarro-Llobet D, Pagel M, Simonsick WJ, Zhong W. Molecular design of single site catalyst precursors for the ring-opening polymerization of cyclic ethers and esters. 2. Can ring-opening polymerization of propylene oxide occur by a cis-migratory mechanism? Macromolecules. 34: 3159-3175. DOI: 10.1021/Ma0102316  0.823
2001 Baxter DV, Caulton KG, Chiang WC, Chisholm MH, DiStasi VF, Dutremez SG, Folting K. Synthesis, structural characterization, thermolysis and volatility study of the Schiff base complex Cu[CH3C(O)CHC(NCH2CH2OCH3) CH3]2 Polyhedron. 20: 2589-2595. DOI: 10.1016/S0277-5387(01)00825-7  0.378
2001 Chisholm MH, Lynn MA. The electronic structure and bonding in W2(μ-H)2(OiPr)4(DMPE)2 and a comparison with Mo2(OiPr)4(DMPE)2 Journal of Organometallic Chemistry. 621: 66-69. DOI: 10.1016/S0022-328X(00)00849-4  0.383
2001 Bursten BE, Chisholm MH, Hadad CM, Li J, Wilson PJ. M2 δ-to-oxalate π* conjugation in oxalate-bridged complexes containing M-M quadruple bonds Chemical Communications. 2382-2383.  0.553
2000 Chisholm MH, Glasgow KC, Klein LJ, Macintosh AM, Peters DG. Heterogeneous electron-transfer rate constants for M2(O2CR)4(0)/+, where M = Mo, W, Ru, or Rh and R = alkyl or aryl. Inorganic Chemistry. 39: 4354-7. PMID 11196932 DOI: 10.1021/Ic9910108  0.822
2000 Chisholm MH, Macintosh AM, Huffman JC, Wu D, Davidson ER, Clark RJ, Firth S. Dimolybdenum bis((S,S,S)-triisopropanolaminate(3-)): a blue compound with an unusual Mo-Mo triple bond. Inorganic Chemistry. 39: 3544-50. PMID 11196813 DOI: 10.1021/Ic991352D  0.467
2000 Chisholm MH. One-dimensional polymers and mesogens incorporating multiple bonds between metal atoms. Accounts of Chemical Research. 33: 53-61. PMID 10639076 DOI: 10.1021/Ar9800901  0.385
2000 Chisholm MH, Huffman JC, Iyer SS. Some studies of the substitution chemistry of [Rh2(OAc)2(CH3CN)4]-[BF 4]2 with monodentate and bidentate tertiary phosphines Journal of the Chemical Society, Dalton Transactions. 1483-1489. DOI: 10.1039/B001444N  0.722
2000 Chisholm MH, Iyer SS, Streib WE. Chiral C2 and C1 symmetric (cyclooctane-1,5-diyl)bis(2- pyrazolyl)borate complexes of potassium and thallium. Preparation, structures and solution behavior New Journal of Chemistry. 24: 393-398. DOI: 10.1039/A906582B  0.663
2000 Chisholm MH, Folting K, Glasgow KC, Lucas E, Streib WE. Reductive Cleavage of Aldehydes to Oxo-Alkylidene and Oxo-Alkylidyne Complexes in Their Reactions with W2(OCH2 tBu)6(py)2 Organometallics. 19: 884-890. DOI: 10.1021/Om9902636  0.823
2000 Chisholm MH, Click DR, Huffman JC. Further studies on the substitutional behavior of 1,2-Mo2Br2(CH2SiMe3)4. Alkyl, amide, phosphide, alkoxide, and thiolate for bromide exchange and isomerizations of 1,1- and 1,2-Mo2X2(CH2SiMe3)4 compounds Organometallics. 19: 3916-3924. DOI: 10.1021/Om0003584  0.788
2000 Chisholm M, Eilerts NW, Huffman JC, Iyer SS, Pacold M, Phomphrai K. Molecular design of single-site metal alkoxide catalyst precursors for ring-opening polymerization reactions leading to polyoxygenates. 1. Polylactide formation by achiral and chiral magnesium and zinc alkoxides, (η3-L)MOR, where L = trispyrazolyl- and trisindazolylborate ligands Journal of the American Chemical Society. 122: 11845-11854. DOI: 10.1021/Ja002160G  0.802
2000 Chisholm MH, Folting K, Huffman JC, Li H, Macintosh AM, Wu DD. d3-d3 Diolates of dimolybdenum and ditungsten. Part 4. Molybdenum derivatives of S(-)-1,1-diphenyl-1,2-propanediol, S(-)-1,1,2-triphenyl-1,2-ethanediol and (1R, 2R)-(-)-1,2-dicyclohexyl-1,2-ethanediol Polyhedron. 19: 375-380. DOI: 10.1016/S0277-5387(99)00348-4  0.408
2000 Chisholm MH, Click DR, Huffman JC. Octakis(trimethylsilylmethyl)dioxotetramolybdenum. a novel tetranuclear compound with two localized metal-metal triple bonds Journal of Organometallic Chemistry. 614: 238-242. DOI: 10.1016/S0022-328X(00)00628-8  0.791
1999 Chisholm MH, Cotton FA, Daniels LM, Folting K, Huffman JC, Iyer SS, Lin C, Macintosh AM, Murillo CA. Compounds in which the Mo2 4+ unit is embraced by one, two or three formamidinate ligands together with acetonitrile ligands Journal of the Chemical Society - Dalton Transactions. 1387-1391. DOI: 10.1039/A900389D  0.685
1999 Chisholm MH, Macintosh AM. On the mechanism of carboxylate ligand scrambling at Mo2 4+ centers: Evidence for a catalyzed mechanism Journal of the Chemical Society - Dalton Transactions. 1205-1207. DOI: 10.1039/A900388F  0.384
1999 Barry JT, Bollinger JC, Chisholm MH, Glasgow KC, Huffman JC, Lucas EA, Lubkovsky EB, Streib WE. Preparation and Characterization of 1,3-Butadiene and Isoprene Complexes, W2(OCH2 tBu)6(diene)(py), and Studies of the Selective Hydrogenation of 1,3-Dienes Organometallics. 18: 2300-2308. DOI: 10.1021/Om990059I  0.813
1999 Chisholm MH, Iyer SS, McCollum DG, Pagel M, Werner-Zwanziger U. Microstructure of Poly(lactide). Phase-Sensitive HETCOR Spectra of Poly(meso-lactide), Poly(rac-lactide), and Atactic Poly(lactide) Macromolecules. 32: 963-973. DOI: 10.1021/ma9806864  0.58
1999 Lichtenberger DL, Lynn MA, Chisholm MH. Quadruple metal-metal bonds with strong donor ligands. Ultraviolet photoelectron spectroscopy of M2(form)4 (M = Cr, Mo, W; form = N,N'- diphenylformamidinate) Journal of the American Chemical Society. 121: 12167-12176. DOI: 10.1021/Ja993065E  0.468
1999 Chisholm MH, Folting K, Streib WE, Wu DD. Dinuclear molybdenum and tungsten complexes with metal-metal triple bonds supported by p-tert-butylcalix[4]arene ligands Inorganic Chemistry. 38: 5219-5229. DOI: 10.1021/Ic990513A  0.484
1999 Chisholm MH, Folting K, Lynn ML, Tiedtke DB, Lemoigno F, Eisenstein O. Nitrido dimers and trimers of Tungsten supported by tBuMe2SiO and CF3Me2CO ligands, respectively. Factors influencing the reductive cleavage of nitriles by Tungsten - Tungsten triple bonds and an analysis of the structure of the cyclotrimer Chemistry - a European Journal. 5: 2318-2326. DOI: 10.1002/(Sici)1521-3765(19990802)5:8<2318::Aid-Chem2318>3.0.Co;2-G  0.37
1998 Chisholm MH, Folting K, Streib WE, Wu DD. Dinuclear (d(3)-d(3)) Diolate Complexes of Molybdenum and Tungsten. 3.(1) Bridging and Chelating Isomers of M(2)(NMe(2))(2)(O approximately approximately CHMe approximately approximately O)(2), Where O approximately approximately CHMe approximately approximately O Is the Dianion of 2,2'-Ethylidenebis(4,6-di-tert-butylphenol). Kinetic versus Thermodynamic Considerations. Inorganic Chemistry. 37: 50-55. PMID 11670259 DOI: 10.1021/Ic9708430  0.347
1998 Budzichowski TA, Chisholm MH, Huffman JC, Kramer KS, Eisenstein O. Polynuclear metal hydrido alkoxides. Preparation and characterization of Mo4(μ-H)3(OBut)7(HNMe 2) and [K(18-crown-6)][Mo4(μ4-H)(OR)12] (R = Pri or CH2But) Journal of the Chemical Society - Dalton Transactions. 2563-2568. DOI: 10.1039/A803253J  0.403
1998 Chisholm MH, Folting K, Wu D. Preparation and characterization of the kinetic and thermodynamic isomers of dinuclear molybdenum and tungsten complexes with metal–metal triple bonds supported by p-tert-butylcalix[4]arene anions† Chemical Communications. 379-380. DOI: 10.1039/A708268A  0.415
1998 Chisholm MH, Folting K, Kramer KS, Streib WE. Preparation and Characterization of (iPrO)4WW(η2-dmpe)2(CO), (η1-O2CH)(iPrO)4WW(η2-dmpe)2(H), [H(η2-dmpe)WWO2]2(μ-O), and W2(O)4(μ-O)[W(η2-dmpe)2CO]2(dmpe = Bisdimethylphosphinomethane), Compounds with W−W Bonds between Metal Atoms in Greatly Differing Oxidation States Inorganic Chemistry. 37: 1549-1554. DOI: 10.1021/Ic9705249  0.387
1998 Xue Z, Chuang S, Caulton KG, Chisholm MH. Molecular Routes to Metal−Carbides, −Nitrides, and −Oxides. 3.1 Chemical Vapor Deposition Employing X3W⋮*CCMe3, Where X = CH2CMe3, OtBu, and OtBu-d9 and *C = 12C or 13C, and a Comparison with the Chemistry of (tBuO)3W⋮N Chemistry of Materials. 10: 2365-2370. DOI: 10.1021/Cm970675+  0.504
1998 Baxter DV, Chisholm MH, Lynn MA, Putilina EF, Trzaska ST, Swager T. Studies of Thermotropic Properties and the Mesophase of Mixtures of n-Alkanoates and Perfluoro-n-alkanoates of Dimolybdenum (MM) Chemistry of Materials. 10: 1758-1763. DOI: 10.1021/Cm970617O  0.335
1998 Chisholm MH, Folting K, Scheer M. A study of the photochemical reaction between W2(OCH2 tBu) 6P4. Characterization of the phosphidocluster W4 (P) 2 (OCH2 tBu) 10 Polyhedron. 17: 2931-2935. DOI: 10.1016/S0277-5387(98)00079-5  0.406
1998 Budzichowski TA, Chisholm MH, Tiedtke DB, Gruhn NE, Lichtenberger DL. Preparation, characterization and electronic structure of W2(NMe2)2(ORf)4, where Rf = CMe2CF3, CMe(CF3)2 and C(CF3)3, as deduced by photoelectron spectroscopic studies and the single crystal X-ray structure for Rf = OCMe(CF3)2 Polyhedron. 17: 705-711. DOI: 10.1016/S0277-5387(97)00360-4  0.462
1998 Chisholm MH, Lynn MA. The non-perpendicular and non-parallel alkyne bridge in W2(μ-C2H2)(μ-OCH2tBu)2(OCH2tBu)61Dedicated to Professor Ken Wade, FRS, on the occasion of his 65th birthday.1 Journal of Organometallic Chemistry. 550: 141-150. DOI: 10.1016/S0022-328X(97)00536-6  0.409
1998 Chisholm MH, Streib WE, Tiedtke DB, Wu D. Organometallic Chemistry of [W2(OCH2tBu)8] (M=M): Substrate Uptake and Activation at a Tungsten-Tungsten Double Bond Chemistry - a European Journal. 4: 1470-1479. DOI: 10.1002/(Sici)1521-3765(19980807)4:8<1470::Aid-Chem1470>3.0.Co;2-8  0.435
1997 Wesemann JL, Chisholm MH. Incorporation of Ru(2)(O(2)C(CH(2))(6)CH(3))(4) into Extended Chains: Interaction of Ru(2)(O(2)C(CH(2))(6)CH(3))(4) with Pyrazine, 4-Cyanopyridine, TCNE, and p-Benzoquinone. Inorganic Chemistry. 36: 3258-3267. PMID 11669990 DOI: 10.1021/Ic970173Y  0.395
1997 Pinkas J, Huffman JC, Bollinger JC, Streib WE, Baxter DV, Chisholm MH, Caulton KG. Syntheses, Structures, and Thermal Behavior of Cu(hfacac) Complexes Derived from Ethanolamines. Inorganic Chemistry. 36: 2930-2937. PMID 11669939 DOI: 10.1021/Ic960370H  0.32
1997 Chisholm MH, Huang JH, Huffman JC, Parkin IP. Dinuclear (d(3)-d(3)) Diolate Complexes of Molybdenum and Tungsten. 2.(1) Derivatives of 2,2'-Methylenebis(6-tert-butyl-4-methylphenoxide). Direct Observation of the Conversion of Bridged to Chelate Isomers (M = Mo) and Reversible Carbon-Hydrogen Bond Oxidative Addition (M = W). Inorganic Chemistry. 36: 1642-1651. PMID 11669755 DOI: 10.1021/Ic961429N  0.383
1997 Chisholm MH, Parkin IP, Folting K, Lobkovsky E. Dinuclear (d(3)-d(3)) Diolate Complexes of Molybdenum and Tungsten. 1. Preparation and Characterization of Complexes Derived from 2,5-Dimethylhexane-2,5-diol. Inorganic Chemistry. 36: 1636-1641. PMID 11669754 DOI: 10.1021/Ic961133H  0.439
1997 Cayton RH, Chisholm MH, Folting K, Wesemann JL, Moodley KG. Further studies of the reactivity of cyclopentadienyl, substitutedcyclopentadienyl and indenyl ligands withM2Cl2(NMe2)4(M = Mo or W). Crystal and molecular structuresofMo2(C9H7)2(NMe2)4 andW2(C5H4Me)2(NMe2)4 Journal of the Chemical Society-Dalton Transactions. 3161-3166. DOI: 10.1039/A701727H  0.459
1997 Chisholm MH, McInnes JM. Tertiary phosphine ligand-exchange reactions involving theM>M quadruply bonded complexesM2Cl4L4, whereL = PMe3, PEt3,PBun3 or PMe2Ph Journal of the Chemical Society-Dalton Transactions. 2735-2744. DOI: 10.1039/A701222E  0.423
1997 Chisholm MH, Folting K, Kramer KS, Streib WE. Polynuclear Metal Hydrido Alkoxides. 2. Hydrogenation of 1,2-W2(iBu)2(OiPr)4. Preparation, Characterization, and Some Reactions of W6H5(CiPr)(OiPr)12, W2(H)2(OiPr)4(dmpe)2, and W4(H)4(dmpm)3, Where dmpe = Bis(dimethylphosphino)ethane and dmpm = Bis(dimethylphosphino)methane Journal of the American Chemical Society. 119: 5528-5539. DOI: 10.1021/Ja9643634  0.363
1997 Chisholm MH, Haubrich ST, Huffman JC, Streib WE. Ring-Opening of σ-Thienyl and σ-Furyl Ligands at Ditungsten (M⋮M) Centers Journal of the American Chemical Society. 119: 1634-1647. DOI: 10.1021/Ja962978V  0.394
1997 Chisholm MH, Huang J, Huffman JC, Streib WE, Tiedtke D. Syntheses and structural characterization of 2,2′-methylene-bis(6-t-butyl-4-methyl-phenoxide complexes of titanium, zirconium and tantalum Polyhedron. 16: 2941-2949. DOI: 10.1016/S0277-5387(97)00058-2  0.473
1997 Barry JT, Chisholm MH, Folting K, Huffman JC, Streib WE. Reactions of W2(H)(OR)7, W2(OR)6(py)2 and W4(OCH2cC4H7)12 compounds (R = Pri, CH2But, cC5H9) with azobenzene, 1,2-diphenylhydrazine and 1,1-dimethylhydrazine Polyhedron. 16: 2113-2133. DOI: 10.1016/S0277-5387(96)00490-1  0.449
1997 Chisholm MH, Huang J, Huffman JC. Reversible carbon-hydrogen bond oxidative addition across a W—W multiple bond Journal of Organometallic Chemistry. 528: 221-223. DOI: 10.1016/S0022-328X(96)06597-7  0.371
1997 Chisholm MH, Folting K, Lynn MA, Streib WE, Tiedtke DB. Organometallic Chemistry of[W2(OCH2tBu)8] Angewandte Chemie International Edition in English. 36: 52-54. DOI: 10.1002/Anie.199700521  0.323
1997 Kemp RA, Cowley AH, Schulz H, Chisholm MH. (Chloromethylene)bis[trimethylsilane] [bis(trimethylsilyl)chloromethane] Inorganic Syntheses. 31: 128-130. DOI: 10.1002/9780470132623.Ch20  0.365
1996 Schoonover JR, Zietlow TC, Clark DL, Heppert JA, Chisholm MH, Gray HB, Sattelberger AP, Woodruff WH. Resonance Raman Spectra of [M(6)X(8)Y(6)](2)(-) Cluster Complexes (M = Mo, W; X, Y = Cl, Br, I). Inorganic Chemistry. 35: 6606-6613. PMID 11666811 DOI: 10.1021/Ic960184B  0.567
1996 Chisholm MH, Eilerts NW, Huffman JC. {H(3-(t)Bupz)B(3-(t)Bupz)(2)-eta(2)}AlEt(2) and {H(3-(t)Bupz)B(3-(t)Bupz)(5-(t)Bupz)-eta(2)}AlEt(2). Structure, Dynamic Solution Behavior, and the 1,2-Borotropic Shift. Inorganic Chemistry. 35: 445-450. PMID 11666227 DOI: 10.1021/Ic950582Z  0.355
1996 Budzichowski TA, Chisholm MH, Streib WE. Mo2(OCH2tBu)6(Cp)Na(DME). Preparation, structure, and solution behavior Canadian Journal of Chemistry. 74: 2386-2391. DOI: 10.1139/V96-266  0.382
1996 Chisholm MH. Ditungsten hexaalkoxides: templates for organometallic chemistry and catalysis Journal of the Chemical Society-Dalton Transactions. 1781-1791. DOI: 10.1039/Dt9960001781  0.383
1996 Cayton RH, Chacon ST, Chisholm MH, Folting K, Moodley KG. The Tungsten−Tungsten Triple Bond. 20.1Synthesis and Characterization of Cyclooctatetraenyltetrakis(dimethylamido)ditungsten Organometallics. 15: 992-997. DOI: 10.1021/Om9508748  0.353
1996 Budzichowski TA, Chisholm MH, Folting K, Streib WE, Scheer M. Tetranuclear Phosphinidine, Phosphide, Arsenide, and Oxide Anionic Clusters of Molybdenum and Tungsten Supported by Neopentoxide Ligands:  Na(18-crown-6)[M4(μ3-PSiMe3)(OCH2tBu)11], K(18-crown-6)[M4(μ3-E)(OCH2tBu)10] (E = P, As), K(18-crown-6)2[Mo4(μ3-O)(OCH2tBu)11]‡ Inorganic Chemistry. 35: 3659-3666. DOI: 10.1021/Ic951292L  0.446
1996 Chisholm MH, Christou G, Folting K, Huffman JC, James CA, Samuels JA, Wesemann JL, Woodruff WH. Solution Studies of Ru2(O2CR)4n+Complexes (n= 0, 1; O2CR = Octanoate, Crotonate, Dimethylacrylate, Benzoate,p-Toluate) and Solid-State Structures of Ru2(O2C-p-tolyl)4(THF)2, [Ru2(O2C-p-tolyl)4(THF)2]+[BF4]-, and Ru2(O2C-p-tolyl)4(CH3CN)2:  Investigations of the Axial Ligation of the Ru2Core Inorganic Chemistry. 35: 3643-3658. DOI: 10.1021/Ic950860U  0.399
1996 Baxter DV, Chisholm MH, Gama GJ, DiStasi VF, Hector AL, Parkin IP. Molecular routes to metal carbides, nitrides, and oxides. 2. Studies of the ammonolysis of metal dialkylamides and hexamethyldisilylamides Chemistry of Materials. 8: 1222-1228. DOI: 10.1021/Cm950499+  0.394
1996 Chisholm MH, Hoffman DM, Northius JM, Huffman JC. Further studies of the reactions involving ethyne and M2(OBut)6, where M = Mo and W. Polyacetylene formation versus formation of ethyne adducts and C - C coupled products Polyhedron. 16: 839-847. DOI: 10.1016/S0277-5387(96)00332-4  0.449
1996 Budzichowski TA, Chisholm MH, Folting K, Kramer KS. Mo2(O)(OCH2tBu)4(PMe3)4. Preparation and characterization of a partial hydrolysis product of Mo2(OCH2tBu)6 Polyhedron. 15: 3085-3091. DOI: 10.1016/0277-5387(96)00004-6  0.473
1996 Chisholm MH, Folting K, Moodley KG, Wesemann JE. Further comments on the lability of M2(O2CR)4 complexes and structural characterization of [Bu4nN]2+[Rh8(O2CBut)16(O2CMe)2(toluene)2]2− Polyhedron. 15: 1903-1905. DOI: 10.1016/0277-5387(95)00533-1  0.345
1996 Chisholm MH, Huffman JC, Iyer SS, Lynn MA. Nitro-substituted benzoates of dimolybdenum: the Mo24+ δ to ligand charge transfer band Inorganica Chimica Acta. 243: 283-293. DOI: 10.1016/0020-1693(96)04918-3  0.711
1996 Budzichowski TA, Chisholm MH, Folting K. Substrate Uptake and Activation by Dimolybdenum and Ditungsten Hexaalkoxides–Factors Influencing the Cleavage of C–X Multiple Bonds in the Reactions Between [Mo2(OR)6] (R tBu or CH2tBu) and Ar2CS, Et2NCN, and P(nBu)3 Chemistry - a European Journal. 2: 110-117. DOI: 10.1002/Chem.19960020119  0.452
1995 Chisholm MH. The emerging chemistry of polynuclear metal hydrido alkoxides: H x M y (OR) z Chemical Society Reviews. 24: 79. DOI: 10.1039/Cs9952400079  0.355
1995 Scheer M, Schuster K, Budzichowski TA, Chisholm MH, Streib WE. Is it possible to stabilise complexes with a tungsten–phosphorus triple bond? Journal of the Chemical Society, Chemical Communications. 1671-1672. DOI: 10.1039/C39950001671  0.434
1995 Caulton KG, Chisholm MH, Doherty S, Folting K. Preparation and Structures of Arylmolybdenum(6+) Nitrido Compounds: (2,4,6-Me3C6H2)3Mo.tplbond.N and (2-Me2NCH2C6H4)2(tBuO)Mo.tplbond.N Organometallics. 14: 2585-2588. DOI: 10.1021/Om00005A066  0.326
1995 Budzichowski TA, Chisholm MH, Folting K, Huffman JC, Streib WE. Dimetal Hepta- and Octaalkoxide Anions of Molybdenum and Tungsten, M2(OR)7- and M2(OR)82- (M.tplbond.M). Preparation, Structures, Oxidation, and a Study of the Thermal Decomposition of W2(OR)7- to Give W2(H)(O)(OR)6- Where R = tBu and iPr Journal of the American Chemical Society. 117: 7428-7440. DOI: 10.1021/Ja00133A016  0.364
1995 Pinkas J, Huffman JC, Chisholm MH, Caulton KG. Origin of Different Coordination Polyhedra for Cu[CF3C(O)CHC(O)CF3]2L (L = H2O, NH3) Inorganic Chemistry. 34: 5314-5318. DOI: 10.1021/Ic00125A034  0.318
1995 Pinkas J, Huffman JC, Baxter DV, Chisholm MH, Caulton KG. Mechanistic Role of H2O and the Ligand in the Chemical Vapor Deposition of Cu, Cu2O, CuO, and Cu3N from Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato)copper(II) Chemistry of Materials. 7: 1589-1596. DOI: 10.1021/Cm00056A028  0.329
1995 Baxter DV, Chisholm MH, DiStasi VF, Haubrich ST. Molecular routes for the synthesis of metal carbides, nitrides, and oxides. 1. Studies of the thermal decomposition of M2(OR)6 and M2(CH2Ph)2(OR)4 compounds where M = Mo and W Chemistry of Materials. 7: 84-92. DOI: 10.1021/Cm00049A014  0.381
1995 Budzichowski TA, Chisholm MH, Folting K, Fromhold MG, Streib WE. Metathetic reactions involving ditungsten hexapivalate. Preparation and structures of W2(O2CtBu)2(OtBu) 2(NiPr2)2, W2(O2CtBu)4(Ni Pr2)2, W2(O2CtBu)2 (OtBu)... Inorganica Chimica Acta. 235: 339-347. DOI: 10.1016/0020-1693(95)90075-H  0.414
1995 Chisholm MH, Kramer KS, Streib WE. [W4(O)2)(O-i-Pr)8]2 an unusual octanuclear oxo-alkoxide cluster of tungsten Journal of Cluster Science. 6: 135-145. DOI: 10.1007/Bf01175841  0.337
1995 Chisholm MH, Kramer KS, Streib WE. Complexes with Polar WW Multiple Bonds:[W2(OiPr)4L(dmpe)2](L=(H)2, CO) and[W2(O)4(μ-O){W(CO)(dmpe)2}2] Angewandte Chemie International Edition in English. 34: 891-893. DOI: 10.1002/Anie.199508911  0.34
1995 Chisholm MH, Folting-Streib K, Tiedtke DB, Lemoigno F, Eisenstein O. Solid-State and Solution Structures of[{NW(OC(CH3)2CF3)3}3] and Factors Favoring the Metathesis of CN and WW Triple Bonds in Reactions Involving Organic Nitriles and Ditungsten Hexaalkoxides Angewandte Chemie International Edition in English. 34: 110-112. DOI: 10.1002/Anie.199501101  0.331
1995 Chisholm MH, Kramer KS, Streib WE. Komplexe mit polaren W-W-Mehrfachbindungen: [W2(OiPr)4L(dmpe)2] (L = (H)2, CO) und [W2(O)4(μ-O){W(CO)(dmpe)2}2] Angewandte Chemie. 107: 977-979. DOI: 10.1002/Ange.19951070812  0.302
1994 Chisholm MH, Haubrich ST, Martin JD, Streib WE. Stepwise activation of σ-thienyl ligands at di-tungsten centres Journal of the Chemical Society, Chemical Communications. 683-684. DOI: 10.1039/C39940000683  0.582
1994 Baxter DV, Cayton RH, Chisholm MH, Huffman JC, Putilina EF, Tagg SL, Wesemann JL, Zwanziger JW, Darrington FD. Multiple bonds between metal atoms in ordered assemblies. 2. Quadruple bonds in the mesomorphic state Journal of the American Chemical Society. 116: 4551-4566. DOI: 10.1021/Ja00090A003  0.326
1994 Budzichowski TA, Chisholm MH, Strieb WE. Direct observation of the conversion of a tertiary butoxide ligand to hydrido-oxo ligands with the liberation of isobutylene at a ditungsten center Journal of the American Chemical Society. 116: 389-390. DOI: 10.1021/Ja00080A052  0.33
1994 Budzichowski TA, Chisholm MH. Coordination chemistry of complexes with metalmetal multiple bonds: Reversible coordination of cyanide ion by dimolybdenum and ditungsten hexaalkoxides Polyhedron. 13: 2035-2042. DOI: 10.1016/S0277-5387(00)83486-5  0.331
1994 Chisholm MH, Putilina EF, Folting K, Streib WE. Attempts to prepare W2(?-diketonate)4(M4-M) complexes by reductiye elimination fromd 3 -d 3 ditungsten complexes. Preparation and structures of W2 R 2(NMe2)2 (Bu t -acac)2 and W2 R 2(OPr i )2 (Bu t -acac)2 compounds, whereR = Et, Ph, CH2Ph, and BC i Journal of Cluster Science. 5: 67-82. DOI: 10.1007/Bf01165492  0.415
1993 Chisholm MH, Cook CM, Huffman JC, Streib WE. Ene-yne couplings at a ditungsten center to give alkylidyne hydrido complexes supported by siloxide ligands Organometallics. 12: 2677-2685. DOI: 10.1021/Om00031A043  0.331
1993 Chisholm MH, Cook CM, Huffman JC, Martin JD. Carbon-carbon coupling of a .mu.-ethynyl ligand with an isocyanide at a ditungsten center. Preparation and structure of W2(.mu.-CCCNHXyl)(OSiMe2But)5(CNXyl)4, where Xyl = 2,6-Me2C6H3 Organometallics. 12: 2354-2359. DOI: 10.1021/Om00030A051  0.504
1993 Chisholm MH, Huffman JC, Kramer KS, Streib WE. Mo4(H)3(O-Bu-tert)7(HNMe2): a novel hydrido cluster of molybdenum Journal of the American Chemical Society. 115: 9866-9867. DOI: 10.1021/Ja00074A090  0.328
1993 Schulz H, Folting K, Huffman JC, Streib WE, Chisholm MH. Studies of mono substituted compounds of formula M2(NMe2)5X (M.tplbond.M), where M = molybdenum and tungsten and X = iodine, alkyl, aryl, and diphenylphosphido, and the bridged-1,1'-ferrocenyl complex W2(NMe2)(.mu.-(C5H4)2Fe) Inorganic Chemistry. 32: 6056-6066. DOI: 10.1021/Ic00078A025  0.393
1993 Rothfuss H, Barry JT, Huffman JC, Caulton KG, Chisholm MH. Two isomers of trichlorotris(dimethylphenylphosphine)tungsten and their potential for equilibration with W2Cl6(PMe2Ph)n Inorganic Chemistry. 32: 4573-4577. DOI: 10.1021/Ic00073A018  0.325
1993 Chisholm MH, Folting K, Huffman JC, Putilina EF, Streib WE, Tatz RJ. Quadruple bonds between molybdenum atoms supported by alkoxide ligands Inorganic Chemistry. 32: 3771-3780. DOI: 10.1021/Ic00069A038  0.449
1993 Caulton KG, Chisholm MH, Drake SR, Folting K, Huffman JC, Streib WE. Triangular phenoxide aggregates of calcium, strontium, and barium: a comparison Inorganic Chemistry. 32: 1970-1976. DOI: 10.1021/Ic00062A016  0.365
1993 Caulton KG, Chisholm MH, Drake SR, Folting K, Huffman JC. Synthesis and structural characterization of the alkaline earth aryloxide aggregates H2Ba8(.mu.5-O)2(OPh)14(HMPA)6 and H2Sr6Ba2(.mu.5-O)2(OPh)14(HMPA)6. A new structural type displaying metal ion site selectivity Inorganic Chemistry. 32: 816-820. DOI: 10.1021/Ic00058A011  0.352
1993 Budzichowski TA, Chisholm MH, Martin JD, Huffman JC, Moodley KG, Streib WE. Two new structural types for d3-d3 dimers of molybdenum and tungsten: [K(18-crown-6)]+[Mo2(OCH2But)7]- and [W2{P(c-hexyl)2}3(OCH2But)3{HP(c-hexyl)2}] Polyhedron. 12: 343-345. DOI: 10.1016/S0277-5387(00)81733-7  0.599
1993 Chisholm MH, Gama GJ, Parkin IP. Synthesis and characterization of M2(EPh3)2(NMe2)4 compounds (E = C, Si, Ge, Sn; M = Mo, W) Polyhedron. 12: 961-965. DOI: 10.1016/S0277-5387(00)81554-5  0.377
1993 Cayton RH, Chisholm MH, Putilina EF, Folting K. Covalenty linked molybdenum-molybdenum quadruple bonds. Dioxypyridazine dianion and 2-imidazolinethionate as bridges between dimolybdenum fragments Polyhedron. 12: 2627-2633. DOI: 10.1016/S0277-5387(00)80090-X  0.463
1993 Budzichowski TA, Chisholm MH, Huffman JC, S. Kramer K, U. Fromhold M. Cationic d3-d3 dinuclear compounds of tungsten: [W2(O2CBut)5]+X−, where X−=BF4− and CF3SO3− Inorganica Chimica Acta. 213: 141-146. DOI: 10.1016/S0020-1693(00)83824-4  0.414
1993 Chisholm MH, Folting K, Haubrich ST, Martin JD. Triple bonds between tungsten atoms with ancillary dimesitylboroalkoxide ligands. Preparations, properties and structures of W2(NMe2)4[OB(Mes)2]2 and W2(OBut)4[OB(Mes)2]2 Inorganica Chimica Acta. 213: 17-24. DOI: 10.1016/S0020-1693(00)83809-8  0.612
1993 Scheer M, Becker U, Huffman JC, Chisholm MH. Px ligands with a maximum of electron-donating ability Journal of Organometallic Chemistry. 461: C1-C3. DOI: 10.1016/0022-328X(93)83299-B  0.331
1993 Barry JT, Chacon ST, Chisholm MH, Folting K, Martin JD. [Et3PH][W4O3Cl7(PEt3)3]. A 12-electron tetrahedral tungsten cluster with an interesting arrangement of ligands Journal of Cluster Science. 4: 259-269. DOI: 10.1007/Bf00703742  0.562
1993 Chisholm MH, Johnston V, Martin JD, Lobkovsky E, Huffman JC. A tetranuclear tungsten carbido alkoxide cluster with a hydride ligand: W4(μ-C)(NMe)(OCH2But)11(H) Journal of Cluster Science. 4: 105-117. DOI: 10.1007/Bf00702712  0.587
1993 Chisholm MH, Cook CM, Huffman JC, Martin JD. Carbon-carbon coupling of a μ-ethynyl ligand with an isocyanide at a ditungsten center. Preparation and structure of W2(μ-CCCNHXyl)(OSiMe2BUt) 5(CNXyl)4, where Xyl = 2,6-Me2C6H3 Organometallics. 12: 2354-2359.  0.45
1992 Chisholm MH, Folting K, Huffman JC, Kramer KS, Tatz RJ. Direct observation of ligand migration in the reversible addition of trimethylphosphine to 1,2-Mo2(CH2Ph)2(OPr-iso)4 and structural characterization of (Me3P)(PhCH2)2(iso-PrO)Mo.tplbond.Mo(OPr-iso)3 and 1,2-Mo2(CH2Ph)2(OPr-iso)4(dmpm), where dmpm = bis(dimethylphosphino)methane Organometallics. 11: 4029-4036. DOI: 10.1021/Om00060A018  0.379
1992 Chisholm MH, Jansen RM, Huffman JC. Attempted preparation of a dimetallabenzyne. Preparation and crystal structure of W2(.mu.-C3Ph3)(.mu.-CPh)(NMe2)4 (M-M) Organometallics. 11: 2305-2307. DOI: 10.1021/Om00042A054  0.353
1992 Caulton KG, Cayton RH, Chisholm MH, Huffman JC, Lobkovsky EB, Xue Z. Structure and bonding of (.mu.-dicarbido)hexa-tert-butoxyditungsten, (tert-BuO)3W.tplbond.CC.tplbond.W(O-tert-Bu)3 Organometallics. 11: 321-326. DOI: 10.1021/Om00037A055  0.562
1992 Chacon ST, Chisholm MH, Eisenstein O, Huffman JC. Metal alkoxides. Models for metal oxides. 18. Structure, bonding and dynamic behavior of bis(.eta.2-ethylene)hexakis(neopentoxy)ditungsten. Studies of the reversible addition of carbon-carbon double bonds to a tungsten-tungsten triple bond Journal of the American Chemical Society. 114: 8497-8509. DOI: 10.1021/Ja00048A022  0.39
1992 Chisholm MH, Hammond CE, Johnston VJ, Streib WE, Huffman JC. Metal alkoxides: models for metal oxides. 17. Reductive cleavage of carbon monoxide to carbide and oxide by ditungsten and tetratungsten alkoxides. Crystal and molecular structures of W4(.mu.4-C)(OCH2-c-Pen)14, W4(.mu.4-C)(O)(OCH2-tert-Bu)12 and W4(.mu.4-C)(O)(O-i-Pr)12 Journal of the American Chemical Society. 114: 7056-7065. DOI: 10.1021/Ja00044A016  0.327
1992 Chisholm MH, Kramer KS, Streib WE. W6(H)5(O-Pr-iso)13. A polynuclear-polyhydride tungsten complex supported exclusively by alkoxide ligands Journal of the American Chemical Society. 114: 3571-3573. DOI: 10.1021/Ja00035A071  0.358
1992 Chisholm MH, Cook CM, Folting K. A new structural type for an electron-precise, six-electron triangular metal cluster: W3O2(O-tert-Bu)8 Journal of the American Chemical Society. 114: 2721-2722. DOI: 10.1021/Ja00033A057  0.303
1992 Chisholm MH, Huffman JC, Lucas EA, Sousa A, Streib WE. On the nature of the olefination reaction involving ditungsten hexaalkoxides and aldehydes or ketones Journal of the American Chemical Society. 114: 2710-2712. DOI: 10.1021/Ja00033A051  0.327
1992 Buhro WE, Chisholm MH, Folting K, Huffman JC, Martin JD, Streib WE. The tungsten-tungsten triple bond. 17.1 mixed amido-phosphido compounds of formula M2(PR2)2(NMe2)4. Comparisons of amido and phosphido ligation and bridged and unbridged isomers Journal of the American Chemical Society. 114: 557-570. DOI: 10.1021/Ja00028A024  0.717
1992 Chisholm MH, Kramer KS, Martin JD, Huffman JC, Lobkovsky EB, Streib WE. The tungsten-tungsten triple bond. 19. Preparation and characterization of W2 6+-containing compounds supported by amide/alkoxide and trifluoromethanesulfonate ligands Inorganic Chemistry. 31: 4469-4474. DOI: 10.1021/Ic00048A007  0.599
1992 Chisholm MH, Johnston VJ, Streib WE. Reactions of the 12-electron alkoxide-supported tungsten clusters W4(OR)12 (R = CH2-iso-Pr, cyclopentylmethyl) with isocyanides, nitriles, nitric oxide, and alkynes. Comparison with the reactivity of W2(OR)6 compounds Inorganic Chemistry. 31: 4081-4083. DOI: 10.1021/Ic00046A018  0.376
1992 Drake SR, Streib WE, Folting K, Chisholm MH, Caulton KG. Dinuclear barium alkoxides and siloxides displaying variable coordination numbers and asymmetric dispositions of ligands Inorganic Chemistry. 31: 3205-3210. DOI: 10.1021/Ic00041A008  0.389
1992 Cayton RH, Chisholm MH, Putilina EF, Folting K, Huffman JC, Moodley KG. Synthesis and substitution reactions of dinuclear molybdenum complexes containing Mo-Mo quadruple bonds and labile solvent ligands Inorganic Chemistry. 31: 2928-2934. DOI: 10.1021/Ic00039A048  0.409
1992 Chisholm MH, Folting K, Putilina EF. Tetrakis(.beta.-diketonate)dimolybdenum complexes. Preparations, properties, and solid-state and molecular structure of tetrakis(2,2,6,6-tetramethyl-3,5-heptanedionato)dimolybdenum Inorganic Chemistry. 31: 1510-1513. DOI: 10.1021/Ic00034A036  0.31
1992 Chisholm MH, Budzichowski TA, Feher FJ, Ziller JW. Tungsten-containing polyhedral oligosilasesquioxanes: synthesis, structure and reactivity of (c-C6H11)7Si7O9(O3W[NMe2]3) Polyhedron. 11: 1575-1579. DOI: 10.1016/S0277-5387(00)83709-2  0.43
1992 Cayton RH, Chisholm MH, Hampden-Smith MJ, Huffman JC, Moodley KG. The tungsten-tungsten triple bond18. Bridging and terminal allyl ligands in complexes of the formula W2(R)2(NMe2)4, where R C3H5 and C4H7 Polyhedron. 11: 3197-3210. DOI: 10.1016/S0277-5387(00)83663-3  0.742
1992 Chisholm MH, Cook CM, Folting K, Streib WE. Oxygen atom transfer in the reaction between hexakis(dimethyl-tert-butylsiloxy)ditungsten and nitric oxide. A remarkable difference in the reactivity of the tungsten-tungsten triple bond as a function of the attendant ligands: ButO versus ButMe2SiO Inorganica Chimica Acta. 198: 63-77. DOI: 10.1016/S0020-1693(00)92347-8  0.459
1992 Chisholm MH, Yang Y, Lobkovsky E, Huffman JC. Synthesis and crystal and molecular structure of Mo4O(OCH2But)10(py): A 12-electron butterfly cluster Journal of Cluster Science. 3: 151-165. DOI: 10.1007/Bf00702880  0.409
1992 Chacon ST, Chisholm MH, Cook CM, Hampden-Smith MJ, Streib WE. New Routes to Alkylidyne-Bridged Ditungsten Compounds Supported by Alkoxide or Siloxide Ligands by the Activation of Ethylene Angewandte Chemie International Edition in English. 31: 462-464. DOI: 10.1002/Anie.199204621  0.364
1991 Chisholm MH. Developing the reactivity of multiple bonds between metal atoms: inorganic functional groups Pure and Applied Chemistry. 63: 665-680. DOI: 10.1351/Pac199163050665  0.365
1991 Chisholm MH, Cook CM, Huffman JC, Streib WE. Hexakis(tert-butyldimethylsiloxy)ditungsten and its reaction with ethyne. Hydrogen atom transfer reactions involving bridging ethynyl, ethyne, vinyl and ethylidyne ligands. Crystal structures of [W2(OSiBu tMe2)6], [W2(OSiBu tMe2)6(μ-C2H2)(C 5H5N)] and.. Journal of the Chemical Society, Dalton Transactions. 929-937. DOI: 10.1039/Dt9910000929  0.455
1991 Chisholm MH, Parkin IP, Folting K, Lubkovsky EB, Streib WE. Diolates of dimolybdenum and ditungsten (MM) with seven-, eight- and nine-membered rings Journal of the Chemical Society, Chemical Communications. 1673-1675. DOI: 10.1039/C39910001673  0.431
1991 Chisholm MH, Lucas EA, Sousa AC, Huffman JC, Folting K, Lobkovsky EB, Streib WE. Reduction of α,β-unsaturated ketones and aldehydes by tungsten-tungsten triple bonds: Formation of 1,2 and 1,4 adducts as opposed to C=O cleavage Journal of the Chemical Society, Chemical Communications. 847-849. DOI: 10.1039/C39910000847  0.36
1991 Chisholm MH, Huffman JC, Lucas EA, Lubkovsky EB. Addition of 1,3-butadiene to a metal-metal triple bond. Preparation and structure of tungsten complex W2(OCH2-tert-Bu)6(py)(C4H6) Organometallics. 10: 3424-3425. DOI: 10.1021/Om00056A006  0.383
1991 Chisholm MH, Folting K, Huffman JC, Lucas EA. Cycloalkyne ligands formed by the coupling of polymethylene-bridged alkylidynes: LnM.tplbond.C(CH2)nC.tplbond.MLn .fwdarw. L2nM2[.mu.-C2(CH2)n] Organometallics. 10: 535-537. DOI: 10.1021/Om00049A005  0.369
1991 Cayton RH, Chisholm MH, Huffman JC, Lobkovsky EB. Metal-metal multiple bonds in ordered assemblies. 1. Tetranuclear molybdenum and tungsten carboxylates involving covalently linked metal-metal quadruple bonds. Molecular models for subunits of one-dimensional stiff-chain polymers Journal of the American Chemical Society. 113: 8709-8724. DOI: 10.1021/Ja00023A019  0.309
1991 Caulton KG, Chisholm MH, Streib WE, Xue Z. Direct observation of .alpha.-hydrogen transfer from alkyl to alkylidyne ligands in (Me3CCH2)3W:CSiMe3. Kinetic and mechanistic studies of alkyl-alkylidyne exchange Journal of the American Chemical Society. 113: 6082-6090. DOI: 10.1021/Ja00016A024  0.537
1991 Budzichowski TA, Chacon ST, Chisholm MH, Feher FJ, Streib W. Dimolybdenum and ditungsten derivatives of the trisilanol, [(c-C6H11)7Si7O9(OH)3]: [(c-C6H11)7Si7O12]2Mo2 (M.tplbond.M) and [(c-C6H11)7Si7O12]2W2(.mu.-H)(O-tert-Bu) Journal of the American Chemical Society. 113: 689-691. DOI: 10.1021/Ja00002A056  0.337
1991 Chacon ST, Chisholm MH, Folting K, Hampden-Smith MJ, Huffman JC. Cyclopentoxyditungsten compounds and crystal and molecular structures and dynamic solution behavior of W2(.mu.-H)(O-cyclo-C5H9)7(HNMe2) Inorganic Chemistry. 30: 3122-3125. DOI: 10.1021/Ic00016A006  0.301
1991 Caulton KG, Chisholm MH, Drake SR, Folting K. Synthesis and molecular structure of a mononuclear barium aryloxide-ethanolamine complex, Ba(2,6-tert-Bu2C6H3O)2(HOCH2CH2NMe2)4.cntdot.2C7H8, exhibiting extensive hydrogen bonding Inorganic Chemistry. 30: 1500-1503. DOI: 10.1021/Ic00007A015  0.418
1991 Cayton RH, Chisholm MH. Are internal flips of M-M multiple bonds within cubic or octahedral ligand fields symmetry allowed? Inorganic Chemistry. 30: 1422-1425. DOI: 10.1021/Ic00006A051  0.384
1991 Cayton RH, Chisholm MH, Davidson ER, DiStasi VF, Du P, Huffman JC. Crystal and molecular structure of hexakis(tert-butoxo)dialuminum. Comments on the extent of M-O .pi. bonding in Group 6 and Group 13 alkoxides Inorganic Chemistry. 30: 1020-1024. DOI: 10.1021/Ic00005A027  0.348
1991 Casas JM, Cayton RH, Chisholm MH. Comments on the substitutional lability of the dimetal carboxylates of molybdenum and rhodium. Effects of M-M MO configuration Inorganic Chemistry. 30: 358-360. DOI: 10.1021/Ic00003A002  0.357
1991 Xue Z, Caulton KG, Chisholm MH. Low-pressure chemical vapor deposition of tungsten carbide (WC) thin films Chemistry of Materials. 3: 384-386. DOI: 10.1021/Cm00015A004  0.445
1991 Baxter DV, Chisholm MH, DiStasi VF, Klang JA. M2(OR)6 compounds (M = Al, Mo, W; R = t-Bu, cy-Hex) as single-source precursors. Studies of thermolysis under he flow Chemistry of Materials. 3: 221-222. DOI: 10.1021/Cm00014A006  0.368
1991 Chisholm M, Parkin I, Huffman J, Lobkovsky E, Folting K. The preparation and characterization of M2(OEPh3)2(NMe2)4,where M = Mo and W and E = C and Si. The x-ray crystal structures of gauche-W2(OCPh3)2(NMe2)4, anti-Mo2(OCPh3)2(NMe2)4 and anti-W2(OSiPh3)2(NMe2)4 Polyhedron. 10: 2839-2846. DOI: 10.1016/S0277-5387(00)86188-4  0.437
1991 Chisholm MH, Parkin IP, Streib WE, Folting KS. Mixed alkoxide-anilide d3-d3 dimers of molybdenum and tungsten. The X-ray crystal structures of M2(OBut)4(HNPh)2(H2NPh)2 (M = Mo, W) Polyhedron. 10: 2309-2316. DOI: 10.1016/S0277-5387(00)86155-0  0.448
1991 Chisholm MH, Drake SR, Naiini AA, Streib WE. The synthesis and characterization of volatile lithium alkoxides, and the single crystal X-ray structure of [LiOCMe2Ph]6 Polyhedron. 10: 805-810. DOI: 10.1016/S0277-5387(00)86112-4  0.322
1991 Chisholm M, Parkin I, Huffman J. The synthesis, characterization and X-ray structure of anti-W2(GePh3)2(NMe2)4 Polyhedron. 10: 1215-1219. DOI: 10.1016/S0277-5387(00)86097-0  0.372
1991 Casas JM, Chisholm MH, Sicilia MV, Streib WE. Imino-ether complexes of platinum: cis-[PtCl2(NHC(OR)Me)2] and [PtCl4(NHC(OR)Me)2], where R = Me, Et and Pri. Preparation, characterization and X-ray structure for [PtCl4(NHC(OPri)Me)2]2 Polyhedron. 10: 1573-1578. DOI: 10.1016/S0277-5387(00)86083-0  0.436
1991 Chisholm MH, Huffman JC, Wesemann JL. Synthesis and X-ray crystal structures of [Me2NH2]+[Al(OSiMe3)4]− and Al2(OSiMe3)6 Polyhedron. 10: 1367-1372. DOI: 10.1016/S0277-5387(00)81270-X  0.331
1991 Chisholm MH, Drake SR, Naiini AA, Streib WE. Synthesis and X-ray crystal structures of the one-dimensional ribbon chains [MOBut·ButOH]∞ and the cubane species [MOBut]4 (M = K and Rb) Polyhedron. 10: 337-345. DOI: 10.1016/S0277-5387(00)80154-0  0.372
1990 Caulton KG, Chisholm MH, Drake SR, Huffman JC. Preparation, crystal and molecular structure of a hydrocarbon soluble, volatile oxo-alkoxide of barium: H4Ba6(μ6-O) (OCH2CH2OCH3)14 Journal of the Chemical Society, Chemical Communications. 1498-1499. DOI: 10.1039/C39900001498  0.379
1990 Caulton KG, Chisholm MH, Drake SR, Folting K. Synthesis and structural characterization of the first examples of molecular aggregates of barium supported by aryloxide and alkoxide ligands: [HBa5(O)(OPh)9(thf)8] and [H3Ba 6(O)(OBut)11(OCEt2CH 2O)(thf)3] (thf=tetrahydrofuran) Journal of the Chemical Society, Chemical Communications. 1349-1351. DOI: 10.1039/C39900001349  0.359
1990 Chisholm MH, Parkin IP, Huffman JC, Streib WB. Triple bonds between molybdenum and tungsten atoms supported by selenolate ligands: M2(SeAr)6 and M2(OPri)2(SeAr)4(Ar = mesityl) Journal of the Chemical Society, Chemical Communications. 920-921. DOI: 10.1039/C39900000920  0.42
1990 Chisholm MH, Folting K, Klang JA. Reaction between benzophenone and ditungsten hexaalkoxides. Molecular structure and reactivity of W(OCH2-tert-Bu)4(py)(.eta.2-OCPh2) Organometallics. 9: 607-613. DOI: 10.1021/Om00117A013  0.359
1990 Chisholm MH, Folting K, Klang JA. Reductive cleavage of ketonic carbon-oxygen bonds in the reactions between ketones and ditungsten hexaalkoxides. Structural characterization of a ditungsten .mu.-propylidene derivative Organometallics. 9: 602-606. DOI: 10.1021/Om00117A012  0.403
1990 Chisholm MH, Huffman JC, Klang JA. A convenient synthesis of trialkylalkylidyne tungsten (6+) compounds and the X-ray crystal structure of (Me3CCH2)3WCPh(py) Polyhedron. 9: 1271-1276. DOI: 10.1016/S0277-5387(00)86763-7  0.353
1990 Chisholm MH, Huffman JC, Parkin IP, Streib WE. Preparation and characterization of M2(SeAr′)6 and mixed ligand M2(OR)2(SeAr′)4 species (M = Mo, W) Polyhedron. 9: 2941-2952. DOI: 10.1016/S0277-5387(00)84205-9  0.425
1990 Chisholm MH, Hammond CE, Huffman JC, Martin JD. Twelve-electron tetranuclear tungsten alkoxide clusters are not tetrahedral. Preparation, structure and bonding in W4(O)(OPri)10 and W4(O)(Cl)(OPri)9. Comparisons with the bonding in carbonyl clusters Polyhedron. 9: 1829-1841. DOI: 10.1016/S0277-5387(00)83995-9  0.583
1990 Chisholm MH, Hammond CE, Huffman JC, Johnston VJ. Structural characterization of a tetranuclear tungsten carbide cluster formed by the reductive cleavage of carbon monoxide: W4(μ4-C)(OCH2-c-C5H9)14 Journal of Organometallic Chemistry. 394: c16-c20. DOI: 10.1016/0022-328X(90)87272-F  0.347
1990 Chisholm MH, Folting K, Johnston VJ, Hammond CE. A tricarbonyl, tetranuclear tungsten cluster supported by alkoxide ligands: W4(OCH2Pri)12(η2,μ4-CO)(CO)2 Journal of Organometallic Chemistry. 394: 265-274. DOI: 10.1016/0022-328X(90)87237-8  0.439
1990 Chisholm MH. Organometallic chemistry of d3–d3 dimolybdenum and ditungsten Journal of Organometallic Chemistry. 400: 235-253. DOI: 10.1016/0022-328X(90)83015-C  0.301
1990 Cayton RH, Chisholm MH, Darrington FD. Multiple Bonds Between Metal Atoms in Ordered Assemblies: Liquid Crystals Containing MoMo Quadruple Bonds Angewandte Chemie International Edition in English. 29: 1481-1483. DOI: 10.1002/Anie.199014811  0.309
1990 Cayton RH, Chacon ST, Chisholm MH, Huffman JC. How Do Two CC Double Bonds Add to One MM Triple Bond? Structure and Bonding in Bis(η2-ethylene)hexakis(neopentoxy)ditungsten Angewandte Chemie International Edition in English. 29: 1026-1028. DOI: 10.1002/Anie.199010261  0.33
1990 Caulton KG, Chisholm MH, Drake SR, Streib WE. [Ba3(OSiPh3)6(THF)] · 0.5 THF — Synthese und Struktur eines dreikernigen Bariumsiloxids mit niedrig koordiniertem Barium Angewandte Chemie. 102: 1492-1493. DOI: 10.1002/Ange.19901021236  0.324
1989 Chisholm MH. Carbon-carbon and carbon-hydrogen bond activation at ditungsten centers supported by alkoxide ligands Pure and Applied Chemistry. 61: 1707-1714. DOI: 10.1351/Pac198961101707  0.443
1989 Chisholm MH, Ho D, Huffman JC, Marchant NS. Reactions between certain trialkoxytungsten alkylidyne complexes and carbon monoxide. Competitive carbon-carbon bond formation leading to alkyne or ketenyl complexes Organometallics. 8: 1626-1636. DOI: 10.1021/Om00109A009  0.328
1989 Chisholm MH, Heppert JA, Huffman JC, Ontiveros CD. 1,3-Ditungstacyclobutadienes. 4. 1:1 Diphenyldiazomethane adducts W2(.mu.-CSiMe3)2X4.cntdot.(N2CPh2). A comparison of the effects of the supporting ligands, X = (trimethylsilyl)methyl versus isopropoxyl Organometallics. 8: 976-982. DOI: 10.1021/Om00106A018  0.308
1989 Chisholm MH, Folting K, Huffman JC, Klang JA, Streib WE. Metal alkoxides: models for metal oxides. 14. Carbonylation of an ethylidyne-capped tritungsten alkoxide cluster to form W3(.mu.-CMe)(OCHMe2)9(CO)2: preparation, properties, and structure Organometallics. 8: 89-93. DOI: 10.1021/Om00103A011  0.312
1989 Chisholm MH, Eichhorn BW, Huffman JC. Tungsten-carbon, carbon-carbon and carbon-hydrogen bond activations in the chemistry of W2R2(OR')4(W.tplbond.W) complexes. 3. Competitive .alpha.-hydrogen versus .beta.-hydrogen eliminations and ethylene-to-acetylene hydrogen transfers Organometallics. 8: 80-89. DOI: 10.1021/Om00103A010  0.523
1989 Chisholm MH, Eichhorn BW, Huffman JC. Tungsten-carbon, carbon-hydrogen, and carbon-carbon bond activation in the chemistry of 1,2-W2R2(OR')4(W.tplbond.W) complexes. 2. Metal-carbon bond homolysis and competitive alkane and dihydrogen eliminations in double .alpha.-hydrogen activation processes Organometallics. 8: 67-79. DOI: 10.1021/Om00103A009  0.53
1989 Chisholm MH, Eichhorn BW, Folting K, Huffman JC. Tungsten-carbon, carbon-hydrogen, and carbon-carbon bond activation in the chemistry of 1,2-W2R2(OR')4(W.tplbond.W) complexes. 1. Alkyne-promoted metal-to-metal alkyl migrations, W.tplbond.W/C.tplbond.C bond metathesis, and metallacyclopropene formation Organometallics. 8: 49-66. DOI: 10.1021/Om00103A008  0.558
1989 Cayton RH, Chisholm MH. Electronic coupling between covalently linked metal-metal quadruple bonds of molybdenum and tungsten Journal of the American Chemical Society. 111: 8921-8923. DOI: 10.1021/Ja00206A027  0.423
1989 Buhro WE, Chisholm MH, Martin JD, Huffman JC, Folting K, Streib WE. Reactions involving carbon dioxide and mixed amido-phosphido dinuclear compounds. M2(NMe2)4(PR2)2(M.tplbond.M), where M = Mo and W. Comparative study of the insertion of carbon dioxide into metal-nitrogen and metal-phosphorus bonds Journal of the American Chemical Society. 111: 8149-8156. DOI: 10.1021/Ja00203A014  0.682
1989 Chisholm MH, Folting K, Hammond CE, Hampden-Smith MJ, Moodley KG. Metal alkoxides: models for metal oxides. 16. Synthesis and characterization of a new class of homoleptic 12-electron molybdenum and tungsten alkoxide clusters of formula M4(OR)12: structural characterization of Mo4(OCH2-c-Bu)12.cntdot.(HOCH2-c-Bu) Journal of the American Chemical Society. 111: 5300-5312. DOI: 10.1021/Ja00196A040  0.369
1989 Chisholm MH, Huffman JC, Hampden-Smith MJ. Metal alkoxides. Models for metal oxides. 15. Carbon-carbon and carbon hydrogen bond activation in the reactions between ethylene and ditungsten hexaalkoxides: W2(OCH2-t-Bu)6(.eta.2-C2H4)2, W2(OR)6(CH2)4(.eta.2-C2H4), and W2(OR)6(.mu.-CCH2CH2CH2) (where R = Ch2-t-Bu, i-Pr, c-C5H9, and c-C6H11). Preparations, properties, structures, and reaction mechanisms Journal of the American Chemical Society. 111: 5284-5299. DOI: 10.1021/Ja00196A039  0.338
1989 Cayton RH, Chisholm MH, Clark DL, Hammond CE. Molybdenum tetrahydroxiden+ (n = 0, 2), tetrahedral or square-planar? The dn-d10-n hole formalism for .pi.-donor and .pi.-acceptor ligand fields Journal of the American Chemical Society. 111: 2751-2755. DOI: 10.1021/Ja00190A001  0.462
1989 Chisholm MH, Clark DL, Hampden-Smith MJ. Hexaisopropoxyditungsten and dodecaisopropoxytetratungsten: W2(O-i-Pr)6 and W4(O-i-Pr)12. 2. Studies of cluster dynamics and the equilibrium between the 12-electron cluster and two metal-metal triple bonds. A symmetry-allowed [.pi.s2 + .pi.s2] cycloaddition reaction and comparisons with the chemistry of cyclobutadiene Journal of the American Chemical Society. 111: 574-586. DOI: 10.1021/Ja00184A027  0.495
1989 Chisholm MH, Hammond CE, Huffman JC. Double bonds between molybdenum atoms supported by dimethylamido ligands: Mo2(NMe2)4(OR)4 compounds, where R  4- methylcyclohexyl and diisopropylmethyl Polyhedron. 8: 129-131. DOI: 10.1016/S0277-5387(00)86393-7  0.386
1989 Chisholm MH, Huffman JC, Koh J. A diiron-ditungsten cluster supported by carbonyl and alkoxide ligands: Fe2W2(OPri)6(CO)5(py) Polyhedron. 8: 127-128. DOI: 10.1016/S0277-5387(00)86392-5  0.376
1989 Chisholm MH, Folting K, Huffman JC, Koh J. Oxidative addition of 1,4-diisopropyl-1,4-diazabutadiene to hexakisisopropoxydimolybdenum (MM). Mo2(Opri)6(PriNCHCHNPri and Mo2(OPri)5(PriNCHCHNPri)2 Polyhedron. 8: 123-125. DOI: 10.1016/S0277-5387(00)86391-3  0.414
1989 Chisholm MH, Hammond CE, Huffman JC. Preparation and characterization of mixed amido-phosphido compounds of molybdenum(IV). A comparison of π-donating ligands in Mo(NMe2)4, Mo(PCy2)4 and [Mo(NMe2)2(PPh2)2] based on X-ray studies Polyhedron. 8: 1419-1423. DOI: 10.1016/S0277-5387(00)86255-5  0.469
1989 CHISHOLM MH, CLARK DL, HAMPDEN-SMITH MJ, HOFFMAN DM. ChemInform Abstract: Alkoxide Clusters of Molybdenum and Tungsten as Templates for Organometallic Chemistry: Comparison with Carbonyl Clusters of the Later Transition Elements Cheminform. 20. DOI: 10.1002/chin.198928356  0.326
1989 CHISHOLM MH, CLARK DL, HAMPDEN-SMITH MJ. ChemInform Abstract: Hexaisopropoxyditungsten and Dodecaisopropoxytetratungsten: W2(O-iPr)6 and W4(O-iPr)12. Part 2. Studies of Cluster Dynamics and the Equilibrium Between the 12-Electron Cluster and Two Metal-Metal Triple Bonds. A Symmetry-Allowed (π2 s Cheminform. 20. DOI: 10.1002/chin.198918056  0.414
1989 Chisholm MH, Folting K, Hammond CE, Huffman JC, Martin JD. Comments on the Molecular Structure and Bonding In [W4Cl(O)(OiPr)9] and [W4(O)(OiPr)10]. Analogies with Tetranuclear Carbonyl Clusters Angewandte Chemie International Edition in English. 28: 1368-1370. DOI: 10.1002/Anie.198913681  0.509
1989 Chisholm MH, Clark DL, Hampden-Smith MJ, Hoffman DH. Alkoxide Clusters of Molybdenum and Tungsten as Templates for Organometallic Chemistry: Comparison with Carbonyl Clusters of the Later Transition Elements Angewandte Chemie International Edition in English. 28: 432-444. DOI: 10.1002/Anie.198904321  0.563
1989 Chisholm MH, Folting K, Hammond CE, Huffman JC, Martin JD. Anmerkungen zu Molekülstruktur und Bindungsverhältnissen in [W4Cl(O)(OiPr)9] und [W4(O)(OiPr)10]; Analogien mit vierkernigen Carbonylclustern Angewandte Chemie. 101: 1399-1400. DOI: 10.1002/Ange.19891011020  0.47
1989 Chisholm MH, Clark DL, Hampden-Smith MJ, Hoffman DM. Organometallchemie mit Molybdän- und Wolframalkoxidclustern; Vergleich mit Carbonylclustern der späten Übergangsmetalle Angewandte Chemie. 101: 446-458. DOI: 10.1002/Ange.19891010406  0.518
1989 Chisholm MH, Eichhorn BW, Huffman JC. Tungsten-carbon, carbon-hydrogen, and carbon-carbon bond activation in the chemistry of 1,2-W2R2(OR′)4(Wu=W) complexes. 2. Metal-carbon bond homolysis and competitive alkane and dihydrogen eliminations in double α-hydrogen activation processes Organometallics. 8: 67-79.  0.471
1989 Buhro WE, Chisholm MH, Martin JD, Huffman JC, Folting K, Streib WE. Reactions involving carbon dioxide and mixed amido-phosphido dinuclear compounds: M2(NMe2)4(PR2) 2(M≡M), where M = Mo and W. Comparative study of the insertion of carbon dioxide into metal-nitrogen and metal-phosphorus bonds Journal of the American Chemical Society. 111: 8149-8156.  0.669
1988 Chisholm MH, Folting K, Huffman JC, Klang JA. W3(O-i-Pr)9(Cl)2(.mu.3-CMe). An unexpected mode of .mu.3-ethylidyne bonding and dynamic solution behavior Organometallics. 7: 1033-1036. DOI: 10.1021/Om00095A004  0.327
1988 Buhro WE, Chisholm MH, Folting K, Huffman JC, Martin JD, Streib WE. Unbridged and bridged isomers of W2(PCy2)2(NMe2)4: Preparations, characterizations, and comments on thermodynamic and activation parameters for the closing of phosphido bridges in d3-d3 dinuclear compounds Journal of the American Chemical Society. 110: 6563-6565. DOI: 10.1021/Ja00227A047  0.654
1988 Chisholm MH, Hampden-Smith MJ, Huffman JC, Moodley KG. Diallyl- and bis(2-methylallyl)tetrakis(dimethylamino)ditungsten: W2(.mu.-.eta.3-C3H5)2(NMe2)4 and W2(.mu.1-C4H7)2(NMe2)4 (M.tplbond.M). Comments on ligand-metal .pi.-interactions at (W.tplbond.W)6+ centers Journal of the American Chemical Society. 110: 4070-4071. DOI: 10.1021/Ja00220A074  0.407
1988 Chisholm MH, Folting K, Hammond CE, Hampden-Smith MJ. A new class of homoleptic 12-electron molybdenum and tungsten alkoxide clusters of formula [M4(OR)12] Journal of the American Chemical Society. 110: 3314-3315. DOI: 10.1021/Ja00218A059  0.362
1988 Bursten BE, Chisholm MH, Clark DL. Electronic structure and bonding in halide- and alkoxide-supported tetranuclear molybdenum clusters Inorganic Chemistry. 27: 2084-2096. DOI: 10.1021/Ic00285A016  0.464
1988 Chisholm MH, Clark DL, Errington RJ, Folting K, Huffman JC. Tetranuclear halide-alkoxide clusters of molybdenum formed by the coupling of M-M triple-bonded dinuclear compounds. Synthesis, characterization, and molecular structures of Mo4F2(O-iso-Pr)10, Mo4X3(O-iso-Pr)9, and Mo4X4(O-iso-Pr)8 (X = chloride, bromide, iodide) Inorganic Chemistry. 27: 2071-2084. DOI: 10.1021/Ic00285A015  0.539
1988 Blatchford TP, Chisholm MH, Huffman JC. Reactions of metal-metal multiple bonds. 15. Reactions of M2(OR)6(M.ident.M) compounds (M = molybdenum, cobalt) with 9,10-phenanthrenequinone and tetrachloro-1,2-benzoquinone Inorganic Chemistry. 27: 2059-2070. DOI: 10.1021/Ic00285A014  0.39
1988 Chisholm MH, Ontiveros CD. 1,3-ditungstacyclobutadienesIII. A comparison of the influence of the supporting ligands, PriO versus Me3SiCH2, on the reactivity of the M2(μ-CR)2 core toward alkynes Polyhedron. 7: 1015-1021. DOI: 10.1016/S0277-5387(00)86321-4  0.399
1988 Chisholm MH, Huffman JC, Marchant NS. A study of the reaction between Mo2(OCH2CMe3)6(μ-η1,η2-NCNR2) compounds (R = Me and Et) and 2-butyne Polyhedron. 7: 919-930. DOI: 10.1016/S0277-5387(00)86312-3  0.472
1988 Chisholm MH, Conroy BK, Clark DL, Huffman JC. Metal alkoxides: models for metal oxides—XIII. NMR spectroscopic and theoretical investigations into the reduction of alkynes bonded to hexaalkoxides of dimolybdenum and ditungsten Polyhedron. 7: 903-918. DOI: 10.1016/S0277-5387(00)86311-1  0.606
1988 Chisholm MH, Hammond CE, Huffman JC. Tetrakisdimethylamidozirconium and its dimethylamido lithium adduct: Structures of [zr(nme2)4]2 and zr(nme2)6li2(thf)2 Polyhedron. 7: 2515-2520. DOI: 10.1016/S0277-5387(00)83867-X  0.377
1988 Chisholm MH, Hampden-Smith MJ, Huffman JC, Martin JD, Stahl KA, Moodley KG. The tungsten-tungsten triple bondXVI. Bis(cyclopentadienyl)- and bis(indenyl)tetradimethylamidoditungsten (WW) Polyhedron. 7: 1991-1999. DOI: 10.1016/S0277-5387(00)80714-7  0.791
1988 Chisholm MH, Hammond CE, Huffman JC. Mo(NMe2)6Li2(THF)2 Polyhedron. 7: 399-400. DOI: 10.1016/S0277-5387(00)80489-1  0.343
1988 Chisholm MH, Eichhorn BW, Folting K, Huffman JC. The tungsten-tungsten triple bond. XV. Synthesis, structure and reactivity of 1,2-W2[CH(SiMe3)2]2(NMe 2)4: the remarkable inertness of a sterically-encumbered tungsten-amido complex Inorganica Chimica Acta. 144: 193-199. DOI: 10.1016/S0020-1693(00)86285-4  0.643
1988 CHISHOLM MH, CLARK DL, ERRINGTON RJ, FOLTING K, HUFFMAN JC. ChemInform Abstract: Reactions of Metal-Metal Multiple Bonds. Part 16. Tetranuclear Halide-Alkoxide Clusters of Molybdenum Formed by the Coupling of M-M Triple-Bonded Dinuclear Compounds. Synthesis, Characterization, and Molecular Structures of Mo4F2(O-iP Cheminform. 19. DOI: 10.1002/chin.198841273  0.511
1988 CHISHOLM MH, CLARK DL, FOLTING K, HUFFMAN JC, HAMPDEN-SMITH MJ. ChemInform Abstract: Hexaisopropoxyditungsten and Dodecaisopropoxytetratungsten: W2(O-iPr)6 and W4(O-iPr)12. Part 1. Preparation, Structure, and Bonding. The First Example of a Metal-Metal Triple Bond and Its 12-Electron Cluster. Analogies with Ethyne and Cheminform. 19. DOI: 10.1002/chin.198813284  0.444
1988 Bursten BE, Chisholm MH, Clark DL. Electronic structure and bonding in halide- and alkoxide-supported tetranuclear molybdenum clusters Inorganic Chemistry. 27: 2084-2096.  0.578
1987 Chisholm MH, Clark DL. Evaluating the Role of π-Donor Ligands in Transition Metal Chemistry. Applications of Fenske-Hall Molecular Orbital Calculations and Mulliken Population Analyses Comments On Inorganic Chemistry. 6: 23-40. DOI: 10.1080/02603598708081851  0.568
1987 Buhro WE, Chisholm MH, Folting K, Eichhorn BW, Huffman JC. The first example of a d3-d3 dinuclear compound containing four-co-ordinate metal atoms sharing a pair of bridging ligands: [(ButO)2W(μ-PPh2)]2 Journal of the Chemical Society, Chemical Communications. 845-847. DOI: 10.1039/C39870000845  0.726
1987 Chisholm MH, Eichhorn BW, Huffman JC. W2(n-Pr)2(.eta.2-C2Me2)2(O-iso-Pr)4, W2(.mu.-C2Me2)2(O-iso-Pr)4, and W4(.mu.-CEt)2(.mu.-C2Me2)2(.eta.2-C2Me2)2(O-iso-Pr)6. Competitive .alpha.- and .beta.-carbon-hydrogen activation pathways at a dimetal center Organometallics. 6: 2264-2265. DOI: 10.1021/Om00153A046  0.537
1987 Chisholm MH, Clark DL, Ho D, Huffman JC. Monoisocyanide adducts of ditungsten hexaalkoxides. Synthetic, structural, and theoretical investigations into the nature of C.tplbond.N bond order reduction Organometallics. 6: 1532-1542. DOI: 10.1021/Om00150A028  0.481
1987 Chisholm MH, Clark DL, Huffman JC, Smith CA. Metal alkoxides - Models for metal oxides. 12. The first molecular carbido cluster of tungsten, W4(C)(NMe)(OCHMe2)12 and carbon-13 NMR spectroscopic evidence for a related oxo-carbido cluster, W4(C)(O)(OCHMe2)12, formed in the stepwise reductive cleavage of carbon monoxide by lower valent tungsten alkoxides Organometallics. 6: 1280-1291. DOI: 10.1021/Om00149A026  0.492
1987 Chisholm MH, Huffman JC, Marchant NS. Preparation, structure, and bonding of Mo2(OCH2CMe3)6(.mu.-.eta.1,.eta.2-NCNMe2) Organometallics. 6: 1073-1080. DOI: 10.1021/Om00148A027  0.359
1987 Chisholm MH, Heppert JA, Kober EM, Lichtenberger DL. 1,3-Ditungstacyclobutadienes. 2. Synthesis of alkoxide derivatives of W2(.mu.-CSiMe3)2(CH2SiMe3)4 and investigations of the electronic structures of the M2(.mu.-CSiMe3)2 core as a function of dn-dn interactions (n = 0, M = Ta; n = 1, M = W; n = 2, M = Re) Organometallics. 6: 1065-1073. DOI: 10.1021/Om00148A026  0.349
1987 Chisholm MH, Hammond CE, Huffman JC. Mo3[C(O)NMe2]6(CO)6(HNMe2)2. An unexpected product formed in the carbonylation of Mo(NMe2)4 displaying three distinct modes of carbamoyl molybdenum bonding Organometallics. 6: 210-211. DOI: 10.1021/Om00144A048  0.327
1987 Chisholm MH, Clark DL, Folting K, Huffman JC, Hampden-Smith M. Hexaisopropoxyditungsten and dodecaisopropoxytetratungsten: W2(O-i-Pr)6 and W4(O-i-Pr)12. 1. Preparation, structure, and bonding. The first example of a metal-metal triple bond and its 12-electron cluster. Analogies with ethyne and cyclobutadiene Journal of the American Chemical Society. 109: 7750-7761. DOI: 10.1021/Ja00259A025  0.513
1987 Chisholm MH, Clark DL, Huffman JC, Van der Sluys WG. The tungsten-tungsten triple bond. 14. Factors influencing triple bonds between tungsten atoms having valence molecular orbital configurations of .sigma.2.pi.4 and .pi.4.delta.2 and preparation and characterization of bis(neopentyl)bis(acetato)bis(diethyldithiocarbamato)ditungsten Journal of the American Chemical Society. 109: 6817-6825. DOI: 10.1021/Ja00256A039  0.512
1987 Chisholm MH, Clark DL, Huffman JC, Van der Sluys WG, Kober EM, Lichtenberger DL, Bursten BE. The tungsten-tungsten triple bond. 13. Bisalkyl tetracarboxylates of dimolybdenum and ditungsten. Triple bonds between metal atoms with the valence molecular orbital description .pi.4.delta.2 Journal of the American Chemical Society. 109: 6796-6816. DOI: 10.1021/Ja00256A038  0.49
1987 Chisholm MH, Hampden-Smith M. Carbon-hydrogen bond activation and carbon-carbon bond formation in the reaction between ethylene and hexaisopropoxyditungsten Journal of the American Chemical Society. 109: 5871-5872. DOI: 10.1021/Ja00253A061  0.344
1987 Blau RJ, Chisholm MH, Folting K, Wang RJ. Reactions of ditungsten hexaalkoxides with alkynylplatinum(II) complexes: formation of heterometallic dicarbido complexes in competition with products derived from alkyne metathesis Journal of the American Chemical Society. 109: 4552-4560. DOI: 10.1021/Ja00249A018  0.33
1987 Chisholm MH, Folting K, Eichhorn BW, Huffman JC. The first hydrocarbyl trinuclear and tetranuclear clusters of tungsten: W3O(CH2Ph)(O-i-Pr)9 and W3O(R)2(O-i-Pr)8 where R = CH2Ph, Ph, and W4(p-tolyl)2(O-i-Pr)10 Journal of the American Chemical Society. 109: 3146-3147. DOI: 10.1021/Ja00244A048  0.512
1987 Chisholm MH, Huffman JC, Van Der Sluys WG. An unbridged triple bond uniting d6 Mo(0) and d2 Mo(IV) atoms: bis[bis(dimethylphosphino)ethane]tetraisopropoxodimolybdenum Journal of the American Chemical Society. 109: 2514-2515. DOI: 10.1021/Ja00242A047  0.315
1987 Buhro WE, Chisholm MH, Folting K, Huffman JC. Comparison of the relative .pi.-donor abilities of amido and phosphido ligands. 1,2-Bis(di-tert-butylphosphido)tetrakis(dimethylamido)dimolybdenum and -ditungsten: 1,2-M2(P(tert-Bu)2)2(NMe2)4(M.tplbond.M) Journal of the American Chemical Society. 109: 905-906. DOI: 10.1021/Ja00237A049  0.606
1987 Chisholm MH, Eichhorn BW, Folting K, Huffman JC, Ontiveros CD, Streib WE, Van der Sluys WG. Preparation and characterization of sodium heptachloropentakis(THF)ditungstate(1-). A synthetically useful precursor for X3W.tplbond.WX3 compounds where X = CH2-tert-Bu, NMe2 and O-tert-Bu Inorganic Chemistry. 26: 3182-3186. DOI: 10.1021/Ic00266A024  0.544
1987 Buhro WE, Chisholm MH, Folting K, Huffman JC. Phosphinecarboxylate ligands formed by the insertion of carbon dioxide into metal-phosphido bonds. Preparation and structural characterization of tetrakis(di-tert-butylphosphinecarboxylato)dimolybdenum [6] Inorganic Chemistry. 26: 3087-3088. DOI: 10.1021/Ic00266A006  0.61
1987 Blatchford TP, Chisholm MH, Huffman JC. Tris(N,N'-dimethylethylenediaminato)dimolybdenum and tris(N,N'-dimethylethylenediaminato)ditungsten. A comparison of eclipsed and staggered triple bonds, .sigma.2.pi.4, between molybdenum and tungsten atoms in X3M.ident.MX3 compounds Inorganic Chemistry. 26: 1920-1925. DOI: 10.1021/Ic00259A022  0.377
1987 Chisholm MH, Conroy BK, Eichhorn BW, Folting K, Hoffman DM, Huffman JC, Marchant NS. Reactions involving alkynes and tungsten-tungsten triple bonds supported by alkoxide ligands Polyhedron. 6: 783-792. DOI: 10.1016/S0277-5387(00)86884-9  0.621
1987 Chisholm M, Clark D, Kober E, Van Der Sluys W. Electronic absorption spectra of M2L6 compounds containing metal-metal triple bonds of σ2π4 configuration Polyhedron. 6: 723-727. DOI: 10.1016/S0277-5387(00)86880-1  0.568
1987 Chisholm M. Recent advances in the chemistry of metal-metal multiple bonds Polyhedron. 6: v. DOI: 10.1016/S0277-5387(00)86872-2  0.305
1987 Chisholm MH, Folting K, Hampden-Smith M, Smith CA. Preparation and characterization of hexacyclohexoxido- and trispinacolato-ditungsten (MM). A comparison of staggered and eclipsed ethane-like O3WWO3 units Polyhedron. 6: 1747-1755. DOI: 10.1016/S0277-5387(00)86546-8  0.757
1987 Chisholm MH, Ho DM, Huffman JC, Van Der Sluys WG. A reaction converting a w-w triple bond to a double bond: tetrakis-diethyldithiophosphate-disulfide-ditungsten, preparation and characterization Polyhedron. 6: 1115-1123. DOI: 10.1016/S0277-5387(00)80964-X  0.46
1987 Chisholm M, Huffman J, Pasterczyk J. Synthesis and reactivity of compounds of formula W(S)(OR)4 Polyhedron. 6: 1551-1557. DOI: 10.1016/S0277-5387(00)80839-6  0.432
1987 Blatchford TP, Chisholm MH, Huffman JC. Diamagnetic anisotropy of MM bonded molecules for MMo or W: how much π is there and how do we slice it? Polyhedron. 6: 1677-1680. DOI: 10.1016/S0277-5387(00)80770-6  0.371
1987 Buhro WE, Chisholm MH. Organometallic Chemistry of Molybdenum and Tungsten Supported by Alkoxide Ligands Advances in Organometallic Chemistry. 27: 311-369. DOI: 10.1016/S0065-3055(08)60030-1  0.64
1987 Chisholm MH, Huffman JC, Pasterczyk JW. (η3-P3)W(OCH2But)3(HNMe2) formed by cleavage of the WW bond in the reaction between W2(OCH2But)6(HNMe2)2 and P4 Inorganica Chimica Acta. 133: 17-18. DOI: 10.1016/S0020-1693(00)84361-3  0.311
1987 Chisholm MH. A molecular model for the reductive cleavage of carbon monoxide to carbide and oxide on reduced metal oxides Journal of Organometallic Chemistry. 334: 77-84. DOI: 10.1016/0022-328X(87)80039-6  0.428
1987 CHISHOLM MH, HAMPDEN-SMITH M. ChemInform Abstract: Coordination of Ethylene to a Complex with M-M Triple Bonding: Bis(η2-ethylene)hexakis(neopentyloxy)ditungsten. Cheminform. 18. DOI: 10.1002/CHIN.198749282  0.311
1987 CHISHOLM MH, CLARK DL, FOLTING K, HUFFMAN JC. ChemInform Abstract: The First Observation of the Equilibrium 2 MM ⇄ M4 (M: Transition Metal); Synthesis and Structure of Hexaisopropoxyditungsten and Its Dimer. Cheminform. 18. DOI: 10.1002/chin.198712291  0.449
1987 Chisholm MH, Hammond CE, Hampden-Smith M, Huffmann JC, Van Der Sluys WG. Preparation and Structure of[Mo4(OMe)2(OiPr)10]; Comments on Why[W2(OiPr)6] Dimerizes, Whereas[Mo2(OiPr)6] Does Not Angewandte Chemie International Edition in English. 26: 904-906. DOI: 10.1002/Anie.198709041  0.348
1987 Chisholm MH, Hampden-Smith M. Olefinic CC Double Bond Coordination to a MM Triple Bond: Bis(η2-ethylene)hexakis(neopentyloxy)ditungsten Angewandte Chemie International Edition in English. 26: 903-904. DOI: 10.1002/Anie.198709031  0.355
1987 Chisholm MH, Hampden-Smith M. Koordination von Ethylen an einen Komplex mit M-M-Dreifachbindung: Bis(η2-ethylen)hexakis(neopentyloxy)diwolfram Angewandte Chemie. 99: 936-937. DOI: 10.1002/Ange.19870990923  0.351
1987 Chisholm MH, Clark DL, Huffman JC, Van Der Sluys WG, Kober EM, Lichtenberger DL, Bursten BE. The tungsten-tungsten triple bond. 13. Bisalkyl tetracarboxylates of dimolybdenum and ditungsten. Triple bonds between metal atoms with the valence molecular orbital description π4δ2 Journal of the American Chemical Society. 109: 6796-6816.  0.596
1987 Chisholm MH, Eichhorn BW, Folting K, Huffman JC, Ontiveros CD, Streib WE, Van Der Sluys WG. Preparation and characterization of NaW2Cl7(THF)5. A synthetically useful precursor for X3W = WX3 compounds where X = CH2-t-Bu, NMe2, and O-t-Bu Inorganic Chemistry. 26: 3182-3186.  0.526
1987 Buhro WE, Chisholm MH, Folting K, Huffman JC. Comparison of the relative π-donor abilities of amido and phosphide ligands. 1,2-bis(di-tert-butylphosphido)tetrakis(dimethylamido)-dimolybdenum and -ditungsten: 1,2-M2(P(t-Bu)2)2(NMe2) 4(M≡M) Journal of the American Chemical Society. 109: 905-906.  0.58
1986 Chisholm MH, Hammond CE, Ho D, Huffman JC. Carbon-nitrogen bond formation in the reaction between tetrakis(dimethylamido)molybdenum(IV) and 2,6-dimethylphenyl isocyanide. Preparation and characterization of the first homoleptic metallaamidine complex: Mo(.eta.2-Me2NC:NC6H3Me3-2,6)4. Journal of the American Chemical Society. 108: 7860-1. PMID 22283313 DOI: 10.1021/Ja00284A075  0.353
1986 Chisholm MH, Conroy BK, Folting K, Hoffman DM, Huffman JC. Alkyne adducts of ditungsten hexaneopentoxide and alkylidyne-capped tritungsten compounds supported by neopentoxide ligands Organometallics. 5: 2457-2465. DOI: 10.1021/Om00143A009  0.333
1986 Ahmed KJ, Chisholm MH, Folting K, Huffman JC. Alkyne adducts of mixed chloro-dimethylamido ditungsten compounds Organometallics. 5: 2171-2181. DOI: 10.1021/Om00142A002  0.382
1986 Blower PJ, Chisholm MH, Clark DL, Eichhorn BW. Electronic structure and bonding in monocarbonyl adducts of dimolybdenum and ditungsten hexaalkoxides: a theoretical and spectroscopic investigation into the mechanism of metal-metal and carbon-oxygen bond order reduction Organometallics. 5: 2125-2138. DOI: 10.1021/Om00141A033  0.347
1986 Chisholm MH, Eichhorn BW, Folting K, Huffman JC, Tatz RJ. Metal alkoxides - models for metal oxides. 11. Synthesis and properties of mixed alkyl/aryl/benzyl alkoxides of formula 1,2-W2R2(OR')4 and W2R(OR')5(M.tplbond.M) Organometallics. 5: 1599-1606. DOI: 10.1021/Om00139A015  0.591
1986 Chisholm MH, Tatz RJ. Metal alkoxides - models for metal oxides. 10. Synthesis and properties of alkyl alkoxides of formula 1,2-Mo2R2(OR')4 and Mo2R(OR')5 (M.tplbond.M) Organometallics. 5: 1590-1598. DOI: 10.1021/Om00139A014  0.347
1986 Chisholm MH, Folting K, Huffman JC, Marchant NS. An unexpected carbon-carbon bond formation in the reaction between Mo2(ONp)6(.mu.-NCNEt2) and 2-butyne Organometallics. 5: 602-603. DOI: 10.1021/Om00134A040  0.331
1986 Ahmed KJ, Chisholm MH. Carbonyl adducts of dichlorotetrakis(dimethylamido)ditungsten and insertion of carbon monoxide into a tungsten-amido bond Organometallics. 5: 185-189. DOI: 10.1021/Om00133A001  0.348
1986 Ahmed KJ, Chisholm MH, Folting K, Huffman JC. Study of the formation of a .sigma.,.pi.-vinyl ligand by hydrogen atom transfer from a coordinated dimethylamide to a perpendicularly bonded ethyne ligand. Preparation and characterization of (PMe2Ph)Cl2W(.mu.-NMe2)(.mu.-.eta.1,.eta.2-CHCH2)(.mu.-.eta.2,.eta.1-CH2NMe)WCl(NMe2)(PMe2Ph) Journal of the American Chemical Society. 108: 989-999. DOI: 10.1021/Ja00265A025  0.382
1986 Chisholm MH, Huffman JC, Smith CA. Metal alkoxides-models for metal oxides. 9. Hydridoditungsten alkoxides: W2(H)(O-iso-Pr)8Na.cntdot.diglyme and W2(H)(I)(OCH2-tert-Bu)6(H2NMe). Further investigations of the reaction between W2(NMe2)6(M.tplbond.M) and iso-PrOH leading to W4(H)2(O-iso-Pr)14 Journal of the American Chemical Society. 108: 222-230. DOI: 10.1021/Ja00262A007  0.366
1986 Chan DMT, Chisholm MH, Folting K, Huffman JC, Marchant NS. Trialkoxynitridomolybdenum compounds: (RO)3Mo.ident.N. Preparation, structures (R = tert-Bu and iso-Pr), and comparisons with a tungsten analog (R = tert-Bu) Inorganic Chemistry. 25: 4170-4174. DOI: 10.1021/Ic00243A023  0.419
1986 Chisholm MH, Chiu HT, Huffman JC, Wang RJ. The tungsten-tungsten triple bond. 12. Bis(1,3-diaryltriazenido)bis(dimethylamido)diethylditungsten (M.tplbond.M) compounds Inorganic Chemistry. 25: 1092-1096. DOI: 10.1021/Ic00228A008  0.376
1986 Chisholm MH. Interconverting multiple bonds between molybdenum and tungsten atoms: oxidative-additions and reductive-eliminations from dinuclear centers Polyhedron. 5: 25-30. DOI: 10.1016/S0277-5387(00)84880-9  0.435
1986 Chisholm M, Chiu H, Huffman J. Unexpected products formed by the addition of halogens [X2 (= I2 or Br2)] to W2(O2CBut)4 (MM): The x=ray crystal structures of [W2(O2CBut)5·2ButCONMe2]+[W2I4(O2CBut)2]− and W2Br2(O2CBut)3·2THF Polyhedron. 5: 1377-1380. DOI: 10.1016/S0277-5387(00)83132-0  0.371
1986 Chisholm MH, Heppert JA. Chemistry of 1,3-Ditungstacyclobutadienes Advances in Organometallic Chemistry. 26: 97-124. DOI: 10.1016/S0065-3055(08)60004-0  0.479
1986 Chisholm MH, Huffman JC, van der Sluys W. Synthesis and characterization of bis(neopentyl)-tetrakis(acetato)dimolybdenum. A notably short metal-metal distance for a d3-d3 dinuclear compound containing a M-M triple bond of valence molecular orbital configuration π4 δ2 Inorganica Chimica Acta. 116: L13-L14. DOI: 10.1016/S0020-1693(00)84603-4  0.414
1986 CHISHOLM MH, CHIU HT, HUFFMAN JC, WANG RJ. ChemInform Abstract: Tungsten - Tungsten Triple Bond. Part 12. Bis(1,3-diaryltriazenido)bis(dimethylamido)diethylditungsten (M ≡ M) Compounds. Chemischer Informationsdienst. 17. DOI: 10.1002/chin.198633249  0.314
1986 CHISHOLM MH, HEPPERT JA, HOFFMAN DM, HUFFMAN JC. ChemInform Abstract: The Tungsten-Tungsten Triple Bond. Part 10. Ditungsten Hexapivalate. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198604270  0.311
1986 Chisholm MH, Clark DL, Folting K, Huffman JC. The First Observation of the Equilibrium 2 M?M ? M4 (M = Transition Metal); Synthesis and Structure of Hexaisopropoxyditungsten and Its Dimer Angewandte Chemie International Edition in English. 25: 1014-1015. DOI: 10.1002/Anie.198610141  0.507
1986 Chisholm MH, Conroy BK, Huffman JC, Marchant NS. Evidence for Equilibria betweenμ-Alkyne and Alkylidyne Complexes of Tungsten Alkoxides:[W2(OR)6(μ-C2R′2)] ? 2[(RO)3W≡ CR′] Angewandte Chemie International Edition in English. 25: 446-447. DOI: 10.1002/Anie.198604461  0.352
1986 Chisholm MH, Clark DL, Folting K, Huffmann JC. Eine Beobachtung der Gleichgewichtsreaktion 2 MM⇄ M4(M=Übergangsmetall); Synthese und Struktur von Hexaisopropoxydiwolfram und seinem Dimer Angewandte Chemie. 98: 1021-1023. DOI: 10.1002/Ange.19860981125  0.537
1986 Chisholm MH, Conroy BK, Huffman JC, Marchant NS. Hinweise auf ein Gleichgewicht zwischen μ-Alkin-und Alkylidin-Komplexen von Wolframalkoxiden: [W2(OR)6(μ-C2R′2)] ⇋ 2[(RO)3WCR′] Angewandte Chemie. 98: 448-449. DOI: 10.1002/Ange.19860980512  0.307
1986 Chisholm MH, Eichhorn BW, Folting K, Huffman JC, Tatz RJ. Metal alkoxides - Models for metal oxides. 11. Synthesis and properties of mixed alkyl/aryl/benzyl alkoxides of formula 1,2-W2R2(OR′)4 and W2R(OR′)5(M≡M) Organometallics. 5: 1599-1606.  0.478
1986 Blower PJ, Chisholm MH, Clark DL, Eichhorn BW. Electronic structure and bonding in monocarbonyl adducts of dimolybdenum and ditungsten hexaalkoxides: A theoretical and spectroscopic investigation into the mechanism of M-M and C-O bond order reduction Organometallics. 5: 2125-2138.  0.639
1985 Chisholm MH, Hoffman DM, Huffman JC. Reactions involving the triple bond in dimolybdenum and ditungsten hexa-alkoxides and C-C, C-N, and C-O triple bonds Chemical Society Reviews. 14: 69-91. DOI: 10.1039/Cs9851400069  0.305
1985 Chisholm MH, Heppert JA, Huffman JC, Streib WE. Attack of isocyanide and carbon monoxide on a bridging alkylidyne ligand at a ditungsten centre. Cleavage of the C-N and C-O triple bonds with respective formation of tungsten-imido and -oxo groups and concomitant addition of the carbon atom to the bridging alkylidyne carbon yielding a bridging σ-W1,η2-W2 alkynyl ligand Journal of the Chemical Society, Chemical Communications. 1771-1773. DOI: 10.1039/C39850001771  0.416
1985 Chisholm MH, Folting K, Heppert JA, Streib WE. Attack by allenes on a bridging alkylidyne ligand at a ditungsten centre: formation of a bridging allyl-η3-W1,σ-W2-alkylidene ligand Journal of the Chemical Society, Chemical Communications. 1755-1757. DOI: 10.1039/C39850001755  0.384
1985 Blau RJ, Chisholm MH, Folting K, Wang RJ. Synthesis, X-ray crystal structure, and n.m.r. studies of trans-bis(dimethylpheylphosphine)bis[{dicarbido(4–)σ-Pt,σ-W1, η2-W2}-pentakis(t-butoxy)ditingsten(MM)]platinum(II) Journal of the Chemical Society, Chemical Communications. 1582-1584. DOI: 10.1039/C39850001582  0.411
1985 Chisholm MH, Heppert JA, Huffman JC, Thornton P. Paramagnetic 1,3-dimetallacyclobutadienes of tungsten(VI): -2,4-bis(trimethylsilyl)-1,3-dihalogeno-l,1,3,3-tetrakis(trimethylsilylmethyl)-1,3-ditungstacyclobutadienes Journal of the Chemical Society, Chemical Communications. 1466-1467. DOI: 10.1039/C39850001466  0.365
1985 Chisholm MH, Eichhorn BW, Huffman JC. Reaction between bis(Benzyl)tetraisopropoxyditungsten(W≡W) and but-2-yne: W2(CH2Ph)2(OPri)4(η2-c2Me2)2 and w2(h)(OPri)4(μ-CPh)(μ-c4Me4). a terminal metal hydride with a1H N.M.R. resonance 20 p.p.m. downfield of Me4Si Journal of the Chemical Society - Series Chemical Communications. 861-862. DOI: 10.1039/C39850000861  0.615
1985 Ahmed KJ, Chisholm MH, Folting K, Huffman JC. W2Cl3(NMe2)3(PMe2Ph)2 and its reaction with ethyne to give (PMe2Ph)Cl2W(µ-NMe2)(µ-σ,η2–CHCH2)(µ-η2,σ-CH2NMe)WCl(NMe2)(PMe2Ph): a compound containing an azadimetallabicyclobutane core and a σ,π-vinyl ligand Journal of the Chemical Society, Chemical Communications. 152-153. DOI: 10.1039/C39850000152  0.397
1985 Ahmed KJ, Chisholm MH, Huffman JC. The molybdenum-molybdenum triple bond. 16. Bis[(trimethylsilyl)methylidene]tetrakis(trimethylphosphine)dibromodimolybdenum(M.tplbond.M). An example of a nonbridged dinuclear bis(carbene) complex Organometallics. 4: 1168-1174. DOI: 10.1021/Om00126A005  0.378
1985 Chisholm MH, Hoffman DM, Huffman JC. Metal alkoxides: models for metal oxides. 8. Monocarbonyl adducts of ditungsten hexaalkoxides (M.tplbond.M) (RO = t-BuO, i-PrO and t-BuCH2O) and the dimer [W2(O-i-Pr)6(.mu.-CO)]2 Organometallics. 4: 986-993. DOI: 10.1021/Om00125A005  0.38
1985 Braydich MD, Bursten BE, Chisholm MH, Clark DL. Comparative studies on the electronic structures of tetraformatoditungsten and dimethyltetraformatoditungsten by the relativistic X.alpha.-SW method: a d3-d3 metal dimer with a quadruple metal-metal bond Journal of the American Chemical Society. 107: 4459-4465. DOI: 10.1021/Ja00301A015  0.314
1985 Ahmed KJ, Chisholm MH, Folting K, Huffman JC. The tungsten-tungsten triple bond. 11. Ligand redistribution reactions involving chloride and dimethylamide ligands at dimolybdenum and ditungsten (M.tplbond.M) centers induced by added tertiary phosphines. Preparations and characterizations of W2Cl2(NMe2)4(Me2PCH2PMe2), W2Cl3(NMe2)3(PMe2Ph)2, and W2Cl4(NMe2)2(PMe2Ph)2 Inorganic Chemistry. 24: 4039-4044. DOI: 10.1021/Ic00218A017  0.425
1985 Chisholm MH, Folting K, Huffman JC, Kober EM. Reactions of metal-metal multiple bonds. 14. Synthesis and characterization of triangulo-W3 and -Mo2W oxo-capped alkoxide clusters. Conproportionation of M-M triple bonds and .sigma.2.pi.4 and d0 metal-oxo groups: M.tplbond.M + M.tplbond.O .fwdarw. M3(.mu.3-O) Inorganic Chemistry. 24: 241-245. DOI: 10.1021/Ic00196A027  0.406
1985 Chisholm MH, Folting K, Huffman JC, Koh J. A diphosphide adduct of ditungsten-hexaisopropoxide: X-ray crystal structure of W2(OPri)6(py)(μ-P2) Polyhedron. 4: 893-895. DOI: 10.1016/S0277-5387(00)87042-4  0.387
1985 Chisholm MH, Corning JF, Folting K, Huffman JC. Triple bonds between molybdenum and tungsten atoms supported by thiolate ligands: (RS)3MM(SR)3 Polyhedron. 4: 383-390. DOI: 10.1016/S0277-5387(00)86996-X  0.451
1985 Chisholm MH, Kober EM, Ironmonger DJ, Thornton P. Bis(2,2′-bipyridyl)diisopropoxomolybdenum(II): A spin-state equilibrium for a complex of a second-row transition element Polyhedron. 4: 1869-1874. DOI: 10.1016/S0277-5387(00)86703-0  0.329
1985 Chetcuti MJ, Chisholm MH, Chiu HT, Huffman JC. 1,2-dimetallacyclo-1,2-hexyne compounds of molybdenum and tungsten Polyhedron. 4: 1213-1217. DOI: 10.1016/S0277-5387(00)84107-8  0.696
1985 Chisholm MH, Clark DL, Huffman JC. The molybdenum-molybdenum triple bond—XVII. Syntheses, spectroscopic and structural characterizations of Mo4F4(O—t-Bu)8 and Mo2F2(O—t-Bu)4(PMe3)2 (MoMo) Polyhedron. 4: 1203-1211. DOI: 10.1016/S0277-5387(00)84106-6  0.561
1985 Chisholm MH, Folting K, Huffman JC, Leonelli J, Marchant NS, Smith CA, Taylor LCE. Tetranuclear carbidotungsten and nitridomolybdenum clusters supported by alkoxide ligands: W4(C)(OCHMe2)12(NMe) and Mo4(N)2(OCHMe2)12 Journal of the American Chemical Society. 107: 3722-3724. DOI: 10.1002/Chin.198540275  0.309
1985 Braydich MD, Bursten BE, Chisholm MH, Clark DL. Comparative studies on the electronic structures of W2(O2CH)4 and W2(O2CH)4(CH3)2 by the relativistic Xα-SW method: A d3-d3 metal dimer with a quadruple metal-metal bond? Journal of the American Chemical Society. 107: 4459-4465.  0.603
1984 Blatchford TP, Chisholm MH, Folting K, Huffman JC. Dioxododecaisopropoxytetratungsten. Oxygen atom abstraction from acetone in reactions with hexaisopropoxyditungsten (WW) Journal of the Chemical Society, Chemical Communications. 1295-1296. DOI: 10.1039/C39840001295  0.353
1984 Chisholm MH, Hoffman DM, Huffman JC. Metal alkoxides - models for metal oxides. 6. The linking of alkyne and nitrile fragments at ditungsten centers. Preparation and characterization of W2(O-tert-Bu)6(CHCHC(Ph)N), W2(O-iso-Pr)7(CH2CHC(Ph)N), W2(OCH2-tert-Bu)6(N(CMe)4N)(py), and W2(O-iso-Pr)7(NHC(Me)CHCHC(Me)N) Journal of the American Chemical Society. 106: 6815-6826. DOI: 10.1021/Ja00334A057  0.314
1984 Chisholm MH, Hoffman DM, Huffman JC. Metal alkoxides models for metal oxides. 5. Coupling of alkyne ligands in reactions involving ditungsten hexaalkoxides: an alternative to the metathesis reaction M.tplbond.M + C.tplbond.C- .fwdarw. 2M.tplbond.C Journal of the American Chemical Society. 106: 6806-6815. DOI: 10.1021/Ja00334A056  0.38
1984 Chisholm MH, Folting K, Hoffman DM, Huffman JC. Metal alkoxides: models for metal oxides. 4. Alkyne adducts of ditungsten hexaalkoxides and evidence for an equilibrium between dimetallatetrahedrane and methylidynemetal complexes: W2(.mu.-C2H2) .dblharw. 2W.tplbond.CH Journal of the American Chemical Society. 106: 6794-6805. DOI: 10.1021/Ja00334A055  0.329
1984 Chisholm MH, Hoffman DM, Huffman JC, Van der Sluys WG, Russo S. Bis(benzyl)- and bis(neopentyl)tetra(propionato)ditungsten (M .tplbond. M). Axial ligation and unprecedentedly short tungsten-tungsten distances for the RW .tplbond. WR unit Journal of the American Chemical Society. 106: 5386-5388. DOI: 10.1021/Ja00330A078  0.372
1984 Chisholm MH, Huffmann JC, Tatz RJ. Dimolybdenum compound (iso-PrO)3Mo.tplbond.Mo(CH2Ph)2(O-iso-Pr)(PMe3): the first example of a compound containing a triple bond uniting three- and four-coordinate molybdenum atoms and the observation of phosphine-promoted, reversible benzyl-alkoxy migrations at the (M.tplbond.M)6+ center Journal of the American Chemical Society. 106: 5385-5386. DOI: 10.1021/Ja00330A077  0.446
1984 Chisholm MH, Heppert JA, Huffman JC. Molecular structure and dynamic solution behavior of the bridging 1,3-dimetallaallyl ligand in (Me3SiCH2)4W2(.mu.-CSiMe3)(.mu.-C3R2SiMe3) compounds (R = hydrogen, methyl, or phenyl) formed by insertion of alkynes into a bridging (.mu.2) ligand Journal of the American Chemical Society. 106: 1151-1153. DOI: 10.1021/Ja00316A075  0.392
1984 Chisholm MH, Cotton FA, Folting K, Huffman JC, Ratermann AL, Shamshoum ES. Insertion reactions of hexaalkoxydimolybdenum and -ditungsten compounds with organic isocyanates. Syntheses and structures of W2(OCMe3)4[N(C6H5)C(O)OCMe3]2 and Mo2(O-i-Pr)4[N(C6H5)C(O)O-i-Pr] Inorganic Chemistry. 23: 4423-4427. DOI: 10.1021/Ic00194A005  0.345
1984 Chisholm MH, Chiu HT, Folting K, Huffman JC. The molybdenum-molybdenum triple bond. 15. Compounds with chains of metal atoms having M-M single and triple bonds: M2(M'(M'Me3)3)2(NMe2)4 (M.tplbond.M) where M = Mo and W and M' = Si and Sn Inorganic Chemistry. 23: 4097-4102. DOI: 10.1021/Ic00192A052  0.387
1984 Chisholm MH, Hoffman DM, Huffman JC. A new structure type for a 6-electron triangulo tungsten cluster: W3(.mu.3-CMe)(.mu.-O-iso-Pr)3(O-iso-Pr)6 Inorganic Chemistry. 23: 3683-3684. DOI: 10.1021/Ic00191A001  0.32
1984 Chisholm MH, Folting K, Huffman JC, Ratermann AL. Reactions of metal-metal multiple bonds. 13. Reactions of diazoalkanes with hexaalkoxides of dimolybdenum and ditungsten (M.tplbond.M). Preparation and characterization of Mo2(O-iso-Pr)6(N2CPh2)2(py), W2(O-tert-Bu)6(N2C(p-tol)2)2, and Mo(O-tert-Bu)4(N2CPh2) Inorganic Chemistry. 23: 2303-2311. DOI: 10.1021/Ic00183A019  0.356
1984 Chisholm MH, Huffman JC, Ratermann AL, Smith C. Reactions of metal-metal multiple bonds. 12. Reactions of organic halides (chloride, bromide, iodide) with hexaalkoxydimolybdenum and -ditungsten (M.tplbond.M) compounds. Preparation and characterization of hexaneopentoxydibromo(pyridine)dimolybdenum (M:M) Inorganic Chemistry. 23: 1596-1599. DOI: 10.1021/Ic00179A028  0.438
1984 Chisholm MH, Corning JF, Folting K, Huffman JC, Ratermann AL, Rothwell IP, Streib WE. Reactions of metal-metal multiple bonds. 11. A comparison of the reactivity of M2(OR)6 (M.tplbond.M) and M2(OR)4(R'COCHCOR')2 (M.tplbond.M) compounds (M = Mo, W) with the .pi.-acid ligands CO, RC.tplbond.CR and RNC Inorganic Chemistry. 23: 1037-1042. DOI: 10.1021/Ic00176A008  0.597
1984 Chisholm MH, Folting K, Huffman JC, Kirkpatrick CC. Reactions of metal-metal multiple bonds. 10. Reactions of Mo2(OR)6 (M.tplbond.M) and [Mo(OR)4]x compounds with molecular oxygen. Preparation and characterization of oxo alkoxides of molybdenum: MoO2(OR)2, MoO2(OR)2(bpy), MoO(OR)4, Mo3O(OR)10, Mo4O8(OR)4(py)4, and Mo6O10(OR)12 Inorganic Chemistry. 23: 1021-1037. DOI: 10.1021/Ic00176A007  0.453
1984 Chisholm MH, Corning JF, Huffman JC. The molybdenum-molybdenum triple bond. 14. Preparation and characterization of mixed alkoxy-thiolate compounds of formula Mo2(OR)2(SAr)4 (M.tplbond.M) Inorganic Chemistry. 23: 754-757. DOI: 10.1021/Ic00174A023  0.422
1984 Chisholm MH, Folting K, Huffman JC, Ratermann AL. The molybdenum-molybdenum triple bond. 13. Preparations and characterization of bis(.beta.-diketonato)tetraalkoxydimolybdenum and -ditungsten compounds Inorganic Chemistry. 23: 613-618. DOI: 10.1021/Ic00173A025  0.346
1984 Chisholm M, Chiu H, Huffman J. A general synthesis for ditungsten tetracarboxylates. Preparation of WW quadruple bonds by reductive-elimination (alkyl group disproportionation) from 1,2-diethyl compounds with WW triple bonds Polyhedron. 3: 759-760. DOI: 10.1016/S0277-5387(00)88019-5  0.39
1984 Chisholm MH, Folting K, Huffman JC, Marchant NS. Notable features in the molecular structure of W2(OCH2-t-Bu)6(NCNMe2)3: Three different modes of bonding for NCNMe2(2-) ligands Polyhedron. 3: 1033-1035. DOI: 10.1016/S0277-5387(00)84665-3  0.421
1984 Chisholm MH, Heppert JA, Huffman JC. Octahedral Mo6 clusters supported by methoxide ligands Polyhedron. 3: 475-478. DOI: 10.1016/S0277-5387(00)84521-0  0.402
1984 CHISHOLM MH, HUFFMAN JC, TATZ RJ. ChemInform Abstract: DIMOLYBDENUM COMPOUND (ISO-PRO)3MOMO(CH2PH)2(O-ISO-PR)(PME3): THE FIRST EXAMPLE OF A COMPOUND CONTAINING A TRIPLE BOND UNITING THREE- AND FOUR-COORDINATE MOLYBDENUM ATOMS AND THE OBSERVATION OF PHOSPHINE-PROMOTED, REVERSIBLE BENZYL-A Chemischer Informationsdienst. 15. DOI: 10.1002/Chin.198451287  0.392
1984 Chisholm MH, Connor JA, Huffman JC, Kober EM, Overton C. Characterization of bis(2,2'-bipyridine) and bis(1,10-phenanthroline) derivatives of molybdenum and tungsten carbonyls. Crystal and molecular structure of cis-dicarbonylbis(2,2'-bipyridine)molybdenum(0) Inorganic Chemistry. 23: 2298-2303. DOI: 10.1002/Chin.198443296  0.33
1984 CHISHOLM MH, CORNING JF, FOLTING K, HUFFMAN JC, RATERMANN AL, ROTHWELL IP, STREIB WE. ChemInform Abstract: REACTIONS OF METAL-METAL MULTIPLE BONDS. 11. A COMPARISON OF THE REACTIVITY OF M2(OR)6 (MM) AND M2(OR)4(R′COCHCOR′)2 (MM) COMPOUNDS (M = MO, W) WITH THE Π-ACID LIGANDS CO, RCCR AND RNC Chemischer Informationsdienst. 15. DOI: 10.1002/Chin.198429269  0.579
1984 CHISHOLM MH, COTTON FA, FANG A, KOBER EM. ChemInform Abstract: THEORETICAL AND EXPERIMENTAL STUDIES OF THE ELECTRONIC STRUCTURE OF THE MO3(μ3-O)(μ3-OR)(μ-OR)3(OR)6 TYPE OF TRIANGULAR METAL ATOM CLUSTER COMPOUND Chemischer Informationsdienst. 15. DOI: 10.1002/Chin.198425054  0.376
1984 CHISHOLM MH, FOLTING K, HUFFMAN JC, TATZ RJ. ChemInform Abstract: QUADRUPLE BONDS BETWEEN MOLYBDENUM ATOMS SUPPORTED BY ALKOXIDE LIGANDS. STRUCTURAL EFFECTS AND REACTIVITY PATTERNS Chemischer Informationsdienst. 15. DOI: 10.1002/Chin.198421270  0.332
1983 Chisholm MH, Folting K, Hoffman DM, Huffman JC, Leonelli J. The remarkable role of steric factors in the reactions of alkynes (HCCH and MeCCMe)with ditungsten hexa-alkoxides: crystal and molecular structures of W2(OPri)6(py)2(µ-C2H2), W2(OCH2But)6(py)2(µ-C2Me2), and W2(OPri)6(µ-C4R4)(C2R2), where R = H and Me (py = pyridine) Journal of the Chemical Society, Chemical Communications. 589-591. DOI: 10.1039/C39830000589  0.406
1983 Chisholm M, Huffman J, Rothwell I, Bradley P, Kress N, Woodruff W. Additions and Corrections - Bis(2,2'-bipyridyl)diisopropoxymolybdenum(II), Structural and Spectroscopic Evidence for Molybdenum-to-Bipyridyl π* Bonding Journal of the American Chemical Society. 105: 7210-7210. DOI: 10.1021/Ja00362A603  0.586
1983 Chisholm MH, Huffman JC, Marchant NL. Reactions of M-M triple bonds with carbon-nitrogen triple bonds: adduct formation (M = molybdenum) and metathesis (M = tungsten) as seen in the reactions between dimethylcyanamide and hexaalkoxides of dimolybdenum and ditungsten Journal of the American Chemical Society. 105: 6162-6163. DOI: 10.1021/Ja00357A038  0.383
1983 Chisholm MH, Corning JF, Huffman JC. Hexakis(2,4,6-trimethylbenzenethiolato)dimolybdenum (Mo2(SC6H2Me3)6). The first example of a compound containing a molybdenum-molybdenum triple bond supported by six mercaptido ligands Journal of the American Chemical Society. 105: 5924-5925. DOI: 10.1021/Ja00356A040  0.389
1983 Chisholm MH, Huffman JC, Tatz RJ. .beta.-Hydrogen effects in alkylalkoxides of dimolybdenum (M.tplbond.M) Journal of the American Chemical Society. 105: 2075-2077. DOI: 10.1021/Ja00345A073  0.306
1983 Chetcuti MJ, Chisholm MH, Folting K, Haitko DA, Huffman JC, Janos J. 1,2-Dibenzyl- and 1,2-diaryltetrakis(dimethylamido)dimolybdenum and -ditungsten compounds: M2R2(NMe2)4 (M.tplbond.M). Structural effects of Me2N-to-M .pi. bonding Journal of the American Chemical Society. 105: 1163-1170. DOI: 10.1021/Ja00343A015  0.661
1983 Chetcuti MJ, Chisholm MH, Chiu HT, Huffman JC. Incorporating metal-metal multiple bonds into heterometallic chains: bis[tris(trimethylstanyl)tin]tetrakis(dimethylamido)dimolybdenum and -ditungsten and related compounds Journal of the American Chemical Society. 105: 1060-1061. DOI: 10.1021/Ja00342A072  0.652
1983 Chetcuti MJ, Chisholm MH, Huffman JC, Leonelli J. Oxidative-additions to (W.tplbond.W)6+ centers: the influence of Lewis base association reactions Journal of the American Chemical Society. 105: 292-293. DOI: 10.1021/Ja00340A025  0.605
1983 Chisholm MH, Huffman JC, Ratermann AL. Reactions of metal-metal multiple bonds. 9. .alpha.-Diketone adducts of ditungsten hexaalkoxides: W2(OR)6(O2C2R'2)2 (M-M) Inorganic Chemistry. 22: 4100-4105. DOI: 10.1021/Ic00168A055  0.369
1983 Chisholm MH, Hoffman DM, Huffman JC. Isoelectronic molecules with triple bonds to metal atoms (M = Mo, W): crystal and molecular structures of tri-tert-butoxytungsten ethylidyne and nitride Inorganic Chemistry. 22: 2903-2906. DOI: 10.1021/Ic00162A028  0.338
1983 Chisholm MH, Huffman JC, Kirkpatrick CC. Reactions of Mo2(OR)6 (M.tplbond.M) compounds (R = iso-Pr and tert-Bu) with benzoyl peroxide Inorganic Chemistry. 22: 1704-1707. DOI: 10.1021/Ic00154A002  0.389
1983 Chisholm MH, Corning JF, Huffman JC. The molybdenum-molybdenum triple bond. 12. Preparation and characterization of bis(tert-butyl mercaptido)tetrakis(dimethylamido)dimolybdenum(M.tplbond.M) Inorganic Chemistry. 22: 38-40. DOI: 10.1021/Ic00143A010  0.4
1983 Chisholm MH. Metal-metal bonds and metal-carbon bonds in the chemistry of molybdenum and tungsten alkoxides Polyhedron. 2: 681-722. DOI: 10.1016/S0277-5387(00)87197-1  0.385
1983 CHISHOLM MH, CORNING JF, HUFFMAN JC. ChemInform Abstract: HEXAKIS(2,4,6-TRIMETHYLBENZENETHIOLATO)DIMOLYBDENUM (MO2(SC6H2ME3)6). THE FIRST EXAMPLE OF A COMPOUND CONTAINING A MOLYBDENUM-MOLYBDENUM TRIPLE BOND SUPPORTED BY SIX MERCAPTIDO LIGANDS Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198350244  0.318
1983 CHETCUTI MJ, CHISHOLM MH, FOLTING K, HAITKO DA, HUFFMAN JC, JANOS J. ChemInform Abstract: 1,2-DIBENZYL- AND 1,2-DIARYLTETRAKIS(DIMETHYLAMIDO)DIMOLYBDENUM AND -DITUNGSTEN COMPOUNDS: M2R2(NME2)4 (MM). STRUCTURAL EFFECTS OF ME2N-TO-M Π BONDING Chemischer Informationsdienst. 14. DOI: 10.1002/Chin.198325312  0.669
1983 CHISHOLM MH, CORNING JF, HUFFMAN JC. ChemInform Abstract: THE MOLYBDENUM-MOLYBDENUM TRIPLE BOND. 12. PREPARATION AND CHARACTERIZATION OF BIS(TERT-BUTYL MERCAPTIDO)TETRAKIS(DIMETHYLAMIDO)DIMOLYBDENUM(MM) Chemischer Informationsdienst. 14. DOI: 10.1002/Chin.198315283  0.387
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