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Nathaniel K. Szymczak - Publications

Affiliations: 
Chemistry University of Michigan, Ann Arbor, Ann Arbor, MI 
Area:
synthetic transition-metal based inorganic chemistry targeted toward the development of new catalytic transformations for energy recycling and delivery with minimal energy input
Website:
https://www.chem.lsa.umich.edu/chem/faculty/facultyDetail.php?Uniqname=nszym
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64 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Beagan DM, Kiernicki JJ, Zeller M, Szymczak NK. A Bidentate Ligand Featuring Ditopic Lewis Acids in the Second Sphere for Selective Substrate Capture and Activation. Angewandte Chemie (International Ed. in English). PMID 36720708 DOI: 10.1002/anie.202218907  0.758
2022 Wang B, Seo CSG, Zhang C, Chu J, Szymczak NK. A Borane Lewis Acid in the Secondary Coordination Sphere of a Ni(II) Imido Imparts Distinct C-H Activation Selectivity. Journal of the American Chemical Society. PMID 35973127 DOI: 10.1021/jacs.2c06662  0.788
2022 Norwine EE, Kiernicki JJ, Zeller M, Szymczak NK. Distinct Reactivity Modes of a Copper Hydride Enabled by an Intramolecular Lewis Acid. Journal of the American Chemical Society. PMID 35960993 DOI: 10.1021/jacs.2c02937  0.737
2022 Nasrallah DJ, Zehnder TE, Ludwig JR, Steigerwald DC, Kiernicki JJ, Szymczak NK, Schindler CS. Hydrazone and Oxime Olefination via Ruthenium Alkylidenes. Angewandte Chemie (International Ed. in English). e202112101. PMID 35275430 DOI: 10.1002/anie.202112101  0.705
2021 Kiernicki JJ, Norwine EE, Zeller M, Szymczak NK. Substrate Specific Metal-Ligand Cooperative Binding: Considerations for Weak Intramolecular Lewis Acid/Base Pairs. Inorganic Chemistry. PMID 34242009 DOI: 10.1021/acs.inorgchem.1c01382  0.738
2020 Wilson JR, Zeller M, Szymczak NK. Hydrogen-bonded nickel(I) complexes. Chemical Communications (Cambridge, England). PMID 33346759 DOI: 10.1039/d0cc07216h  0.369
2020 Kiernicki JJ, Norwine EE, Lovasz MA, Zeller M, Szymczak NK. Mobility of Lewis acids within the secondary coordination sphere: toward a model for cooperative substrate binding. Chemical Communications (Cambridge, England). PMID 33016291 DOI: 10.1039/d0cc05121g  0.73
2020 Kiernicki JJ, Zeller M, Szymczak NK. Examining the Generality of Metal-Ligand Cooperativity Across a Series of First-Row Transition Metals: Capture, Bond Activation, and Stabilization. Inorganic Chemistry. 59: 9279-9286. PMID 32551605 DOI: 10.1021/Acs.Inorgchem.0C01163  0.779
2020 Shanahan JP, Mullis DM, Zeller M, Szymczak NK. Reductively Stable Hydrogen-Bonding Ligands Featuring Appended CF-H Units. Journal of the American Chemical Society. PMID 32352797 DOI: 10.1021/Jacs.0C01718  0.481
2020 Shanahan JP, Szymczak NK. Lewis Acid Effects on Calculated Ligand Electronic Parameters Organometallics. DOI: 10.1021/Acs.Organomet.0C00407  0.372
2019 Kiernicki JJ, Norwine EE, Zeller M, Szymczak NK. Tetrahedral iron featuring an appended Lewis acid: distinct pathways for the reduction of hydroxylamine and hydrazine. Chemical Communications (Cambridge, England). PMID 31528878 DOI: 10.1039/C9Cc05720J  0.765
2019 Kiernicki JJ, Shanahan JP, Zeller M, Szymczak NK. Tuning ligand field strength with pendent Lewis acids: access to high spin iron hydrides. Chemical Science. 10: 5539-5545. PMID 31293738 DOI: 10.1039/C9Sc00561G  0.771
2019 Shanahan JP, Szymczak NK. Hydrogen Bonding to a Dinitrogen Complex at Room Temperature: Impacts on N Activation. Journal of the American Chemical Society. PMID 31083988 DOI: 10.1021/Jacs.9B02288  0.455
2019 Hale LVA, Sikes NM, Szymczak NK. Reductive C-C Coupling from α,β-Unsaturated Nitriles by Intercepting Keteniminates. Angewandte Chemie (International Ed. in English). PMID 31016843 DOI: 10.1002/Anie.201904530  0.346
2019 Geri JB, Aguilera EY, Szymczak NK. Difluoromethane as a precursor to difluoromethyl borates. Chemical Communications (Cambridge, England). PMID 30969308 DOI: 10.1039/C9Cc01565E  0.351
2019 Kiernicki JJ, Zeller M, Szymczak NK. Requirements for Lewis Acid-Mediated Capture and N-N Bond Cleavage of Hydrazine at Iron. Inorganic Chemistry. PMID 30628782 DOI: 10.1021/Acs.Inorgchem.8B02433  0.764
2018 Dahl EW, Kiernicki JJ, Zeller M, Szymczak NK. Hydrogen Bonds Dictate O Capture and Release within a Zinc Tripod. Journal of the American Chemical Society. PMID 30074788 DOI: 10.1021/Jacs.8B04266  0.749
2018 Geri JB, Ciatti JL, Szymczak NK. Charge effects regulate reversible CO reduction catalysis. Chemical Communications (Cambridge, England). PMID 29943782 DOI: 10.1039/C8Cc04370A  0.395
2018 Hale LVA, Szymczak NK. Hydrogen Transfer Catalysis beyond the Primary Coordination Sphere Acs Catalysis. 8: 6446-6461. DOI: 10.1021/Acscatal.7B04216  0.361
2017 Dahl EW, Dong HT, Szymczak NK. Phenylamino derivatives of tris(2-pyridylmethyl)amine: hydrogen-bonded peroxodicopper complexes. Chemical Communications (Cambridge, England). PMID 29242872 DOI: 10.1039/C7Cc08619A  0.46
2017 Kiernicki JJ, Zeller M, Szymczak NK. Hydrazine Capture and N-N Bond Cleavage at Iron Enabled by Flexible Appended Lewis Acids. Journal of the American Chemical Society. PMID 29227655 DOI: 10.1021/Jacs.7B11465  0.782
2017 Geri JB, Wade Wolfe MM, Szymczak NK. Borazine-CF3- Adducts for Rapid, Room Temperature, and Broad Scope Trifluoromethylation. Angewandte Chemie (International Ed. in English). PMID 29205733 DOI: 10.1002/Anie.201711316  0.353
2017 Tseng KT, Kampf JW, Szymczak NK. Correction to "Modular Attachment of Appended Boron Lewis Acids to a Ruthenium Pincer Catalyst: Metal-Ligand Cooperativity Enables Selective Alkyne Hydrogenation". Journal of the American Chemical Society. 139: 18122. PMID 29172476 DOI: 10.1021/jacs.7b09662  0.315
2017 Geri JB, Szymczak NK. Recyclable Trifluoromethylation Reagents from Fluoroform. Journal of the American Chemical Society. PMID 28703573 DOI: 10.1021/Jacs.7B05408  0.349
2017 Geri JB, Shanahan JP, Szymczak NK. Testing the Push-Pull Hypothesis: Lewis Acid Augmented N2 Activation at Iron. Journal of the American Chemical Society. PMID 28414226 DOI: 10.1021/Jacs.7B01982  0.428
2017 Dahl EW, Louis-Goff T, Szymczak NK. Second sphere ligand modifications enable a recyclable catalyst for oxidant-free alcohol oxidation to carboxylates. Chemical Communications (Cambridge, England). PMID 28154846 DOI: 10.1039/C6Cc10206A  0.311
2016 Hale LV, Szymczak NK. Stereoretentive Deuteration of α-Chiral Amines with D2O. Journal of the American Chemical Society. PMID 27709928 DOI: 10.1021/Jacs.6B07879  0.376
2016 Tseng KT, Kampf JW, Szymczak NK. Modular Attachment of Appended Boron Lewis Acids to a Ruthenium Pincer Catalyst: Metal-Ligand Cooperativity Enables Selective Alkyne Hydrogenation. Journal of the American Chemical Society. PMID 27472301 DOI: 10.1021/Jacs.6B03972  0.429
2016 Dahl EW, Szymczak NK. Hydrogen Bonds Dictate the Coordination Geometry of Copper: Characterization of a Square-Planar Copper(I) Complex. Angewandte Chemie (International Ed. in English). PMID 26822857 DOI: 10.1002/Anie.201511527  0.435
2016 Tseng KT, Lin S, Kampf JW, Szymczak NK. Upgrading ethanol to 1-butanol with a homogeneous air-stable ruthenium catalyst. Chemical Communications (Cambridge, England). PMID 26758387 DOI: 10.1039/C5Cc09913G  0.337
2016 Hale LVA, Malakar T, Tseng KNT, Zimmerman PM, Paul A, Szymczak NK. The Mechanism of Acceptorless Amine Double Dehydrogenation by N,N,N-Amide Ruthenium(II) Hydrides: A Combined Experimental and Computational Study Acs Catalysis. 6: 4799-4813. DOI: 10.1021/Acscatal.6B01465  0.466
2016 Moore CM, Bark B, Szymczak NK. Simple Ligand Modifications with Pendent OH Groups Dramatically Impact the Activity and Selectivity of Ruthenium Catalysts for Transfer Hydrogenation: The Importance of Alkali Metals Acs Catalysis. 6: 1981-1990. DOI: 10.1021/Acscatal.6B00229  0.384
2016 McCrory CCL, Szymczak NK, Peters JC. Evaluating Activity for Hydrogen-Evolving Cobalt and Nickel Complexes at Elevated Pressures of Hydrogen and Carbon Monoxide Electrocatalysis. 7: 87-96. DOI: 10.1007/S12678-015-0281-Y  0.569
2015 Carter TJ, Heiden ZM, Szymczak NK. Discovery of low energy pathways to metal-mediated B 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 1111111111111111111111111111111111 1111111111111111111111111111111111 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 1111111111111111111111111111111111 1111111111111111111111111111111111 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 N bond reduction guided by computation and experiment. Chemical Science. 6: 7258-7266. PMID 28757986 DOI: 10.1039/C5Sc02348C  0.47
2015 Moore CM, Szymczak NK. Nitrite reduction by copper through ligand-mediated proton and electron transfer. Chemical Science. 6: 3373-3377. PMID 28706701 DOI: 10.1039/C5Sc00720H  0.378
2015 Geri JB, Szymczak NK. A Proton-Switchable Bifunctional Ruthenium Complex That Catalyzes Nitrile Hydroboration. Journal of the American Chemical Society. 137: 12808-14. PMID 26425797 DOI: 10.1021/Jacs.5B08406  0.492
2015 Moore CM, Dahl EW, Szymczak NK. Beyond H₂: exploiting 2-hydroxypyridine as a design element from [Fe]-hydrogenase for energy-relevant catalysis. Current Opinion in Chemical Biology. 25: 9-17. PMID 25528204 DOI: 10.1016/J.Cbpa.2014.11.021  0.381
2015 Moore CM, Szymczak NK. Redox-induced fluoride ligand dissociation stabilized by intramolecular hydrogen bonding. Chemical Communications (Cambridge, England). 51: 5490-2. PMID 25322967 DOI: 10.1039/C4Cc06832G  0.386
2015 Tseng KNT, Kampf JW, Szymczak NK. Regulation of Iron-Catalyzed Olefin Hydroboration by Ligand Modifications at a Remote Site Acs Catalysis. 5: 411-415. DOI: 10.1021/Cs501820W  0.464
2015 Tseng KNT, Kampf JW, Szymczak NK. Mechanism of N,N,N-Amide Ruthenium(II) Hydride Mediated Acceptorless Alcohol Dehydrogenation: Inner-Sphere β-H Elimination versus Outer-Sphere Bifunctional Metal-Ligand Cooperativity Acs Catalysis. 5: 5468-5485. DOI: 10.1021/Acscatal.5B00952  0.404
2015 Bayram E, Linehan JC, Fulton JL, Szymczak NK, Finke RG. Determination of the dominant catalyst derived from the classic [RhCp∗Cl2]2 precatalyst system: Is it single-metal Rh1Cp∗-based, subnanometer Rh4 cluster-based, or Rh(0) n nanoparticle-based cyclohexene hydrogenation catalysis at room temperature and mild pressures? Acs Catalysis. 5: 3876-3886. DOI: 10.1021/Acscatal.5B00315  0.365
2014 Moore CM, Quist DA, Kampf JW, Szymczak NK. A 3-fold-symmetric ligand based on 2-hydroxypyridine: regulation of ligand binding by hydrogen bonding. Inorganic Chemistry. 53: 3278-80. PMID 24654846 DOI: 10.1021/Ic5003594  0.408
2014 Tseng KNT, Szymczak NK. Dehydrogenative Oxidation of Primary Amines to Nitriles Synlett. DOI: 10.1055/S-0034-1378543  0.405
2014 Carter TJ, Wang JY, Szymczak NK. Manganese-mediated hydride delivery to a borazine by stepwise reduction and protonation Organometallics. 33: 1540-1543. DOI: 10.1021/Om500157M  0.43
2013 Tseng KN, Rizzi AM, Szymczak NK. Oxidant-free conversion of primary amines to nitriles. Journal of the American Chemical Society. 135: 16352-5. PMID 24144014 DOI: 10.1021/Ja409223A  0.378
2013 Tutusaus O, Ni C, Szymczak NK. A transition metal Lewis acid/base triad system for cooperative substrate binding. Journal of the American Chemical Society. 135: 3403-6. PMID 23421523 DOI: 10.1021/Ja400962H  0.768
2013 Moore CM, Szymczak NK. 6,6'-Dihydroxy terpyridine: a proton-responsive bifunctional ligand and its application in catalytic transfer hydrogenation of ketones. Chemical Communications (Cambridge, England). 49: 400-2. PMID 23192306 DOI: 10.1039/C2Cc36927C  0.469
2012 Carter TJ, Kampf JW, Szymczak NK. Reduction of borazines mediated by low-valent chromium species. Angewandte Chemie (International Ed. in English). 51: 13168-72. PMID 23161604 DOI: 10.1002/Anie.201206668  0.389
2012 Moore CM, Szymczak NK. A tris(2-quinolylmethyl)amine scaffold that promotes hydrogen bonding within the secondary coordination sphere. Dalton Transactions (Cambridge, England : 2003). 41: 7886-9. PMID 22610281 DOI: 10.1039/C2Dt30406F  0.421
2011 Szymczak NK, Zakharov LN, Tyler DR. Bis{1,2-bis-[bis-(3-meth-oxy-prop-yl)phosphan-yl]ethane-κP,P'}dichlorido-osmium(II). Acta Crystallographica. Section E, Structure Reports Online. 67: m1808. PMID 22199590 DOI: 10.1107/S1600536811048926  0.576
2011 Bayram E, Linehan JC, Fulton JL, Roberts JA, Szymczak NK, Smurthwaite TD, Özkar S, Balasubramanian M, Finke RG. Is it homogeneous or heterogeneous catalysis derived from [RhCp*Cl2]2? In operando XAFS, kinetic, and crucial kinetic poisoning evidence for subnanometer Rh4 cluster-based benzene hydrogenation catalysis. Journal of the American Chemical Society. 133: 18889-902. PMID 22035197 DOI: 10.1021/Ja2073438  0.39
2011 Neiner D, Karkamkar A, Bowden M, Joon Choi Y, Luedtke A, Holladay J, Fisher A, Szymczak N, Autrey T. Kinetic and thermodynamic investigation of hydrogen release from ethane 1,2-di-amineborane Energy and Environmental Science. 4: 4187-4193. DOI: 10.1039/C1Ee01884A  0.303
2009 Szymczak NK, Berben LA, Peters JC. Redox rich dicobalt macrocycles as templates for multi-electron transformations. Chemical Communications (Cambridge, England). 6729-31. PMID 19885460 DOI: 10.1039/B913946J  0.667
2009 Szymczak NK, Braden DA, Crossland JL, Turov Y, Zakharov LN, Tyler DR. Aqueous coordination chemistry of H2: why is coordinated H2 inert to substitution by water in trans-Ru(P2)2(H2)H+-type complexes (P2 = a chelating phosphine)? Inorganic Chemistry. 48: 2976-84. PMID 19253994 DOI: 10.1021/Ic801884X  0.779
2009 Yelle RB, Crossland JL, Szymczak NK, Tyler DR. Theoretical studies of N2 reduction to ammonia in Fe(dmpe)2N2. Inorganic Chemistry. 48: 861-71. PMID 19166364 DOI: 10.1021/Ic800930T  0.708
2008 Shaw WJ, Linehan JC, Szymczak NK, Heldebrant DJ, Yonker C, Camaioni DM, Baker RT, Autrey T. In situ multinuclear NMR spectroscopic studies of the thermal decomposition of ammonia borane in solution. Angewandte Chemie (International Ed. in English). 47: 7493-6. PMID 18756572 DOI: 10.1002/Anie.200802100  0.312
2008 Szymczak NK, Tyler DR. Aspects of dihydrogen coordination chemistry relevant to reactivity in aqueous solution Coordination Chemistry Reviews. 252: 212-230. DOI: 10.1016/J.Ccr.2007.06.007  0.627
2007 Fulton JL, Linehan JC, Autrey T, Balasubramanian M, Chen Y, Szymczak NK. When is a nanoparticle a cluster? An operando EXAFS study of amine borane dehydrocoupling by Rh(4-6) clusters. Journal of the American Chemical Society. 129: 11936-49. PMID 17824610 DOI: 10.1021/Ja073331L  0.356
2007 Gilbertson JD, Szymczak NK, Crossland JL, Miller WK, Lyon DK, Foxman BM, Davis J, Tyler DR. Coordination chemistry of H2 and N2 in aqueous solution. Reactivity and mechanistic studies using trans-FeII(P2)2X2)-type complexes (P2 = a chelating, water-solubilizing phosphine). Inorganic Chemistry. 46: 1205-14. PMID 17256842 DOI: 10.1021/Ic061570O  0.802
2006 Szymczak NK, Zakharov LN, Tyler DR. Solution chemistry of a water-soluble eta2-H2 ruthenium complex: evidence for coordinated H2 acting as a hydrogen bond donor. Journal of the American Chemical Society. 128: 15830-5. PMID 17147394 DOI: 10.1021/Ja065532F  0.635
2006 Szymczak NK, Oelkers AB, Tyler DR. Detection of hydrogen bonding in solution: a 2H nuclear magnetic resonance method based on rotational motion of a donor/acceptor complex. Physical Chemistry Chemical Physics : Pccp. 8: 4002-8. PMID 17028690 DOI: 10.1039/B608147A  0.755
2005 Gilbertson JD, Szymczak NK, Tyler DR. Reduction of N2 to ammonia and hydrazine utilizing H2 as the reductant. Journal of the American Chemical Society. 127: 10184-5. PMID 16028926 DOI: 10.1021/Ja053030G  0.753
2004 Szymczak NK, Han F, Tyler DR. Arrested chloride abstraction from trans-RuCl2(DMeOPrPE)2 with TlPF6; formation of a 1-D coordination polymer having unusual octahedral coordination around thallium(I). Dalton Transactions (Cambridge, England : 2003). 3941-2. PMID 15558117 DOI: 10.1039/B415259J  0.526
2004 Gilbertson JD, Szymczak NK, Tyler DR. H2 activation in aqueous solution: formation of trans-[Fe(DMeOPrPE)2H(H2)]+ via the heterolysis of H2 in water. Inorganic Chemistry. 43: 3341-3. PMID 15154795 DOI: 10.1021/Ic0498642  0.739
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