Robin N. Perutz, Ph.D - Publications

Affiliations: 
Chemistry University of York, York, England, United Kingdom 
Area:
Organometallic chemistry; Photochemistry
Website:
http://www.york.ac.uk/chemistry/staff/academic/o-s/rperutz/

199 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Beweries T, Buchmeiser MR, Bugden FE, Champness NR, Chanbasha B, Costas M, Echeverria J, Eisenstein O, Ferguson C, Goodall JC, Gramage-Doria R, Greenhalgh M, Gyton M, Ham R, Kennepohl P, ... ... Perutz RN, et al. Make - underpinning concepts of the synthesis of systems where non-covalent interactions are important: general discussion. Faraday Discussions. PMID 37486614 DOI: 10.1039/d3fd90012f  0.502
2023 Altus KM, Beweries T, Champness NR, Duhme-Klair A, Eisenstein O, Ham R, Hatcher LE, Herres-Pawlis S, Johnson CL, Kennepohl P, Linnebank PR, Liu WC, Macgregor SA, Mahmudov KT, Martín-Fernández C, ... ... Perutz RN, et al. Measure - understanding of structural and electronic changes occurring within the relevant timescale of catalytic systems: general discussion. Faraday Discussions. PMID 37436132 DOI: 10.1039/d3fd90016a  0.512
2023 Beweries T, Buchmeiser MR, Champness NR, Costas M, Duhme-Klair A, Echeverría J, Eisenstein O, Ferguson CTJ, Goodall JC, Gramage-Doria R, Gyton M, Ham R, Herres-Pawlis S, Johnson CL, Kennepohl P, ... ... Perutz RN, et al. Manipulate - techniques to manipulate the surroundings of a synthetic catalyst to control activity and selectivity: general discussion. Faraday Discussions. PMID 37436131 DOI: 10.1039/d3fd90013d  0.504
2023 Thangavadivale VG, Tendera L, Bertermann R, Radius U, Beweries T, Perutz RN. Solution and solid-state studies of hydrogen and halogen bonding with N-heterocyclic carbene supported nickel(II) fluoride complexes. Faraday Discussions. PMID 37097153 DOI: 10.1039/d2fd00171c  0.6
2022 Turner JJ, George MW, Poliakoff M, Perutz RN. Photochemistry of transition metal carbonyls. Chemical Society Reviews. PMID 35708003 DOI: 10.1039/d1cs00826a  0.449
2021 Perutz RN, Sabo-Etienne S, Weller AS. Metathesis by partner interchange in σ-bond ligands: expanding applications of the σ-CAM mechanism. Angewandte Chemie (International Ed. in English). PMID 34694734 DOI: 10.1002/anie.202111462  0.582
2020 Walaijai K, Cavill SA, Whitwood AC, Douthwaite RE, Perutz RN. Electrocatalytic Proton Reduction by a Cobalt(III) Hydride Complex with Phosphinopyridine PN Ligands. Inorganic Chemistry. PMID 33275426 DOI: 10.1021/acs.inorgchem.0c02505  0.306
2019 Aoki Y, Bauer M, Braun T, Cadge J, Davies D, Durand DJ, Eisenstein O, Ess D, Fairlamb I, Fey N, Gallarati S, George M, Greaves M, Halse M, Hamilton A, ... ... Perutz R, et al. Physical methods for mechanistic understanding: general discussion. Faraday Discussions. PMID 31755887 DOI: 10.1039/C9Fd90070E  0.376
2019 Aoki Y, Braun T, Davies D, Eisenstein O, Fairlamb I, Fey N, George M, Goult C, Hamilton A, Huang Z, Ishii Y, Jakoobi M, Kuwata S, Lloyd-Jones G, Love J, ... ... Perutz R, et al. Understanding unusual element-element bond formation and activation: general discussion. Faraday Discussions. PMID 31755882 DOI: 10.1039/C9Fd90071C  0.423
2019 Aoki Y, Bauer M, Braun T, Cadge JA, Clarke GE, Durand DJ, Eisenstein O, Gallarati S, Greaves M, Harvey J, Haynes A, Hintermair U, Hulme AN, Ishii Y, Jakoobi M, ... ... Perutz R, et al. Mechanistic insight into organic and industrial transformations: general discussion. Faraday Discussions. PMID 31754665 DOI: 10.1039/C9Fd90072A  0.374
2019 Halse ME, Procacci B, Perutz RN, Duckett SB. Towards measuring reactivity on micro-to-millisecond timescales with laser pump, NMR probe spectroscopy. Faraday Discussions. PMID 31508642 DOI: 10.1039/C9Fd00039A  0.553
2019 Dickinson DP, Evans SW, Grellier M, Kendall H, Perutz RN, Procacci B, Sabo-Etienne S, Smart KA, Whitwood AC. Photochemical Oxidative Addition of Germane and Diphenylgermane to Ruthenium Dihydride Complexes Organometallics. 38: 626-637. DOI: 10.1021/Acs.Organomet.8B00770  0.635
2018 Thangavadivale V, Aguiar PM, Jasim NA, Pike SJ, Smith DA, Whitwood AC, Brammer L, Perutz RN. Self-complementary nickel halides enable multifaceted comparisons of intermolecular halogen bonds: fluoride ligands other halides. Chemical Science. 9: 3767-3781. PMID 29780509 DOI: 10.1039/C8Sc00890F  0.377
2018 Procacci B, Duckett SB, George MW, Hanson-Heine MWD, Horvath R, Perutz RN, Sun X, Vuong KQ, Welch JA. Competing Pathways in the Photochemistry of Ru(H)2(CO)(PPh3)3 Organometallics. 37: 855-868. DOI: 10.1021/Acs.Organomet.7B00802  0.622
2017 Poliakoff M, Perutz R. Tribute to Daedalus: Fertile mind that led to unexpected places. Nature. 549: 31. PMID 28880290 DOI: 10.1038/549031D  0.422
2017 Eisenstein O, Milani J, Perutz RN. Selectivity of C-H Activation and Competition between C-H and C-F Bond Activation at Fluorocarbons. Chemical Reviews. PMID 28653537 DOI: 10.1021/Acs.Chemrev.7B00163  0.408
2017 Halse ME, Procacci B, Henshaw SL, Perutz RN, Duckett SB. Coherent evolution of parahydrogen induced polarisation using laser pump, NMR probe spectroscopy: Theoretical framework and experimental observation. Journal of Magnetic Resonance (San Diego, Calif. : 1997). 278: 25-38. PMID 28347906 DOI: 10.1016/J.Jmr.2017.03.005  0.566
2016 Procacci B, Aguiar PM, Halse ME, Perutz RN, Duckett SB. Photochemical pump and NMR probe to monitor the formation and kinetics of hyperpolarized metal dihydrides. Chemical Science. 7: 7087-7093. PMID 28451144 DOI: 10.1039/C6Sc01956K  0.614
2016 Ortuño MA, Jasim NA, Whitwood AC, Lledós A, Perutz RN. Platinum(0)-mediated C-O bond activation of ethers via an SN2 mechanism. Dalton Transactions (Cambridge, England : 2003). PMID 27748779 DOI: 10.1039/C6Dt03241A  0.373
2016 Ducrot AB, Coulson BA, Perutz RN, Duhme-Klair AK. Light-Induced Activation of a Molybdenum Oxotransferase Model within a Ru(II)-Mo(VI) Dyad. Inorganic Chemistry. PMID 27690401 DOI: 10.1021/Acs.Inorgchem.6B01485  0.346
2016 Perutz RN, Procacci B. Photochemistry of Transition Metal Hydrides. Chemical Reviews. PMID 27380829 DOI: 10.1021/Acs.Chemrev.6B00204  0.435
2015 Windle CD, George MW, Perutz RN, Summers PA, Sun XZ, Whitwood AC. Comparison of rhenium-porphyrin dyads for CO photoreduction: photocatalytic studies and charge separation dynamics studied by time-resolved IR spectroscopy. Chemical Science. 6: 6847-6864. PMID 29861927 DOI: 10.1039/C5Sc02099A  0.361
2015 Torres O, Calladine JA, Duckett SB, George MW, Perutz RN. Detection of σ-alkane complexes of manganese by NMR and IR spectroscopy in solution: (η(5)-C5H5)Mn(CO)2(ethane) and (η(5)-C5H5)Mn(CO)2(isopentane). Chemical Science. 6: 418-424. PMID 28936300 DOI: 10.1039/C4Sc02869D  0.633
2015 Smith DA, Beweries T, Blasius C, Jasim N, Nazir R, Nazir S, Robertson CC, Whitwood AC, Hunter CA, Brammer L, Perutz RN. The Contrasting Character of Early and Late Transition Metal Fluorides as Hydrogen Bond Acceptors. Journal of the American Chemical Society. 137: 11820-31. PMID 26302048 DOI: 10.1021/Jacs.5B07509  0.619
2015 Procacci B, Jiao Y, Evans ME, Jones WD, Perutz RN, Whitwood AC. Activation of B-H, Si-H, and C-F bonds with Tp'Rh(PMe3) complexes: kinetics, mechanism, and selectivity. Journal of the American Chemical Society. 137: 1258-72. PMID 25547430 DOI: 10.1021/Ja5113172  0.595
2015 Torres O, Calladine JA, Duckett SB, George MW, Perutz RN. Detection of σ-alkane complexes of manganese by NMR and IR spectroscopy in solution: (η5-C5H5)Mn(CO)2(ethane) and (η5-C5H5)Mn(CO)2(isopentane) Chemical Science. 6: 418-424. DOI: 10.1039/c4sc02869d  0.533
2015 Milani J, Pridmore NE, Whitwood AC, Fairlamb IJS, Perutz RN. The Role of Fluorine Substituents in the Regioselectivity of Intramolecular C-H Bond Functionalization of Benzylamines at Palladium(II) Organometallics. 34: 4376-4386. DOI: 10.1021/Acs.Organomet.5B00608  0.348
2015 Smart KA, Mothes-Martin E, Vendier L, Perutz RN, Grellier M, Sabo-Etienne S. A Ruthenium Dihydrogen Germylene Complex and the Catalytic Synthesis of Digermoxane Organometallics. 34: 4158-4163. DOI: 10.1021/Acs.Organomet.5B00570  0.655
2015 Ducrot A, Scattergood B, Coulson B, Perutz RN, Duhme-Klair AK. Electronic fine-tuning of oxygen atom transfer reactivity of cis-dioxomolybdenum(VI) complexes with thiosemicarbazone ligands European Journal of Inorganic Chemistry. DOI: 10.1002/Ejic.201500059  0.335
2014 Torres O, Procacci B, Halse ME, Adams RW, Blazina D, Duckett SB, Eguillor B, Green RA, Perutz RN, Williamson DC. Photochemical pump and NMR probe: chemically created NMR coherence on a microsecond time scale. Journal of the American Chemical Society. 136: 10124-31. PMID 24945724 DOI: 10.1021/Ja504732U  0.727
2014 Procacci B, Blagg RJ, Perutz RN, Rendón N, Whitwood AC. Photochemical Reactions of Fluorinated Pyridines at Half-Sandwich Rhodium Complexes: Competing Pathways of Reaction. Organometallics. 33: 45-52. PMID 24563575 DOI: 10.1021/Om400552R  0.755
2014 Jasim NA, Perutz RN, Procacci B, Whitwood AC. Oxidative addition of ether O-methyl bonds at a Pt(0) centre. Chemical Communications (Cambridge, England). 50: 3914-7. PMID 24549146 DOI: 10.1039/C4Cc00853G  0.341
2014 Smith DA, Brammer L, Hunter CA, Perutz RN. Metal hydrides form halogen bonds: measurement of energetics of binding. Journal of the American Chemical Society. 136: 1288-91. PMID 24380577 DOI: 10.1021/Ja4121499  0.385
2014 Robertson CC, Perutz RN, Brammer L, Hunter CA. A solvent-resistant halogen bond Chemical Science. 5: 4179-4183. DOI: 10.1039/C4Sc01746C  0.38
2014 Nova A, Taylor DJ, Blacker AJ, Duckett SB, Perutz RN, Eisenstein O. Computational studies explain the importance of two different substituents on the chelating bis(amido) ligand for transfer hydrogenation by bifunctional Cp*Rh(III) catalysts Organometallics. 33: 3433-3442. DOI: 10.1021/Om500356E  0.583
2012 Windle CD, Câmpian MV, Duhme-Klair AK, Gibson EA, Perutz RN, Schneider J. CO2 photoreduction with long-wavelength light: dyads and monomers of zinc porphyrin and rhenium bipyridine. Chemical Communications (Cambridge, England). 48: 8189-91. PMID 22785349 DOI: 10.1039/C2Cc33308B  0.545
2012 Câmpian MV, Perutz RN, Procacci B, Thatcher RJ, Torres O, Whitwood AC. Selective photochemistry at stereogenic metal and ligand centers of cis-[Ru(diphosphine)2(H)2]: preparative, NMR, solid state, and laser flash studies. Journal of the American Chemical Society. 134: 3480-97. PMID 22276646 DOI: 10.1021/Ja210568T  0.374
2012 Guihaumé J, Halbert S, Eisenstein O, Perutz RN. Hydrofluoroarylation of alkynes with Ni catalysts. C-H activation via ligand-to-ligand hydrogen transfer, an alternative to oxidative addition Organometallics. 31: 1300-1314. DOI: 10.1021/Om2005673  0.417
2011 Schneider J, Vuong KQ, Calladine JA, Sun XZ, Whitwood AC, George MW, Perutz RN. Photochemistry and photophysics of a Pd(II) metalloporphyrin: Re(I) tricarbonyl bipyridine molecular dyad and its activity toward the photoreduction of CO2 to CO. Inorganic Chemistry. 50: 11877-89. PMID 22043811 DOI: 10.1021/Ic200243Y  0.351
2011 Beweries T, Brammer L, Jasim NA, McGrady JE, Perutz RN, Whitwood AC. Energetics of halogen bonding of group 10 metal fluoride complexes. Journal of the American Chemical Society. 133: 14338-48. PMID 21851113 DOI: 10.1021/Ja203320Y  0.65
2011 Clot E, Eisenstein O, Jasim N, Macgregor SA, McGrady JE, Perutz RN. C-F and C-H bond activation of fluorobenzenes and fluoropyridines at transition metal centers: how fluorine tips the scales. Accounts of Chemical Research. 44: 333-48. PMID 21410234 DOI: 10.1021/Ar100136X  0.405
2011 Calladine JA, Duckett SB, George MW, Matthews SL, Perutz RN, Torres O, Vuong KQ. Manganese alkane complexes: an IR and NMR spectroscopic investigation. Journal of the American Chemical Society. 133: 2303-10. PMID 21280655 DOI: 10.1021/Ja110451K  0.626
2011 Corden VA, Duhme-Klair AK, Hostachy S, Perutz RN, Reddig N, Becker HC, Hammarström L. Spectroscopic and structural investigations reveal the signaling mechanism of a luminescent molybdate sensor. Inorganic Chemistry. 50: 1105-15. PMID 21218777 DOI: 10.1021/Ic1019422  0.363
2011 Girotti R, Romerosa A, Mañas S, Serrano-Ruiz M, Perutz R. Photo-aquation of cis-[RuCl2(mPTA)4](CF 3SO3)4 in water (mPTA = N-methyl-1,3,5-triaza- 7-phosphaadamantane) Dalton Transactions. 40: 828-836. DOI: 10.1039/C0Dt00885K  0.38
2010 Guihaumé J, Clot E, Eisenstein O, Perutz RN. Importance of palladium-carbon bond energies in direct arylation of polyfluorinated benzenes. Dalton Transactions (Cambridge, England : 2003). 39: 10510-9. PMID 20931129 DOI: 10.1039/C0Dt00296H  0.397
2010 Calladine JA, Torres O, Anstey M, Ball GE, Bergman RG, Curley J, Duckett SB, George MW, Gilson AI, Lawes DJ, Perutz RN, Sun XZ, Vollhardt KPC. Photoinduced N2 loss as a route to long-lived organometallic alkane complexes: A time-resolved IR and NMR study Chemical Science. 1: 622-630. DOI: 10.1039/C0Sc00311E  0.618
2010 Gibson EA, Duhme-Klair AK, Perutz RN. Design and synthesis of water soluble (metallo)porphyrins with pendant arms: Studies of binding to xanthine oxidase New Journal of Chemistry. 34: 1125-1134. DOI: 10.1039/B9Nj00736A  0.544
2010 Nova A, Reinhold M, Perutz RN, MacGregor SA, McGrady JE. Selective activation of the ortho C?F bond in pentafluoropyridine by zerovalent nickel: Reaction via a metallophosphorane intermediate stabilized by neighboring group assistance from the pyridyl nitrogen Organometallics. 29: 1824-1831. DOI: 10.1021/Om100064Z  0.371
2010 Dransfield TA, Nazir R, Perutz RN, Whitwood AC. Liquid injection field desorption/ionization of transition metal fluoride complexes Journal of Fluorine Chemistry. 131: 1213-1217. DOI: 10.1016/J.Jfluchem.2010.05.008  0.367
2010 CRONIN L, NICASIO MC, PERUTZ RN, PETERS RG, RODDICK DM, WHITTLESEY MK. ChemInform Abstract: Laser Flash Photolysis and Matrix Isolation Studies of Ru(R2PCH2CH2PR2) 2H2 (R: C2H5, C6H5, C2F5): Control of Oxidative Addition Rates by Phosphine Substituents Cheminform. 27: no-no. DOI: 10.1002/chin.199607074  0.584
2009 Blacker AJ, Clot E, Duckett SB, Eisenstein O, Grace J, Nova A, Perutz RN, Taylor DJ, Whitwood AC. Synthesis and structure of "16-electron" rhodium(III) catalysts fortransfer hydrogenation of a cyclic imine: mechanistic implications. Chemical Communications (Cambridge, England). 6801-3. PMID 19885484 DOI: 10.1039/B912943J  0.581
2009 Clot E, Mégret C, Eisenstein O, Perutz RN. Exceptional sensitivity of metal-aryl bond energies to ortho-fluorine substituents: influence of the metal, the coordination sphere, and the spectator ligands on M-C/H-C bond energy correlations. Journal of the American Chemical Society. 131: 7817-27. PMID 19453181 DOI: 10.1021/Ja901640M  0.408
2009 Godoy F, Klahn AH, Oelckers B, Garland MT, Ibáñez A, Perutz RN. Synthesis, reactivity and molecular structure of phosphino tetramethyl cyclopentadienyl complex (eta5: eta1-C5Me4CH2PPh2)Re(CO)2. Dalton Transactions (Cambridge, England : 2003). 3044-51. PMID 19352533 DOI: 10.1039/B820751H  0.435
2009 Girotti R, Romerosa A, Mañas S, Serrano-Ruiz M, Perutz RN. Visible-light photoisomerization and photoaquation of trans-[Ru(1,3,5-triaza-7-phosphaadamantane)4Cl2] in organic solvent and water. Inorganic Chemistry. 48: 3692-8. PMID 19320468 DOI: 10.1021/Ic802284J  0.368
2009 Duckett SB, George MW, Jina OS, Matthews SL, Perutz RN, Sun XZ, Vuong KQ. A systematic approach to the generation of long-lived metal alkane complexes: combined IR and NMR study of (Tp)Re(CO)2(cyclopentane). Chemical Communications (Cambridge, England). 1401-3. PMID 19259601 DOI: 10.1039/B819671K  0.585
2009 Blacker AJ, Duckett SB, Grace J, Perutz RN, Whitwood AC. Reactivity, structures, and NMR spectroscopy of half-sandwich pentamethylcyclopentadienyl rhodium amido complexes relevant to transfer hydrogenation Organometallics. 28: 1435-1446. DOI: 10.1021/Om8009969  0.555
2008 Nova A, Erhardt S, Jasim NA, Perutz RN, Macgregor SA, McGrady JE, Whitwood AC. Competing C-F activation pathways in the reaction of Pt(0) with fluoropyridines: phosphine-assistance versus oxidative addition. Journal of the American Chemical Society. 130: 15499-511. PMID 18950168 DOI: 10.1021/Ja8046238  0.349
2008 Gabrielsson A, Lindsay Smith JR, Perutz RN. Remote site photosubstitution in metalloporphyrin-rhenium tricarbonylbipyridine assemblies: photo-reactions of molecules with very short lived excited states. Dalton Transactions (Cambridge, England : 2003). 4259-69. PMID 18682865 DOI: 10.1039/B806267F  0.364
2008 Libri S, Jasim NA, Perutz RN, Brammer L. Metal fluorides form strong hydrogen bonds and halogen bonds: measuring interaction enthalpies and entropies in solution. Journal of the American Chemical Society. 130: 7842-4. PMID 18507375 DOI: 10.1021/Ja8020318  0.343
2008 Câmpian MV, Clot E, Eisenstein O, Helmstedt U, Jasim N, Perutz RN, Whitwood AC, Williamson D. Stereochemical nonrigidity of a chiral rhodium boryl hydride complex: a sigma-borane complex as transition state for isomerization. Journal of the American Chemical Society. 130: 4375-85. PMID 18327937 DOI: 10.1021/Ja077357O  0.431
2007 Lindup RJ, Marder TB, Perutz RN, Whitwood AC. Sequential C-F activation and borylation of fluoropyridines via intermediate Rh(I) fluoropyridyl complexes: a multinuclear NMR investigation. Chemical Communications (Cambridge, England). 3664-6. PMID 17728887 DOI: 10.1039/B707840D  0.347
2007 Ampt KA, Duckett SB, Perutz RN. Low temperature in situ UV irradiation of [(eta 5-C5H5)Co(C2H4)2] in the NMR probe: formation of Co(III) silyl hydride complexes. Dalton Transactions (Cambridge, England : 2003). 2993-6. PMID 17622415 DOI: 10.1039/B705290A  0.633
2007 Perutz RN, Sabo-Etienne S. The sigma-CAM Mechanism: sigma complexes as the basis of sigma-bond metathesis at late-transition-metal centers. Angewandte Chemie (International Ed. in English). 46: 2578-92. PMID 17380532 DOI: 10.1002/Anie.200603224  0.641
2007 Perutz RN, Sabo-Etienne S. The σ-CAM Mechanism: σ Complexes as the Basis of σ-Bond Metathesis at Late-Transition-Metal Centers Cheminform. 38. DOI: 10.1002/chin.200726207  0.545
2006 Clot E, Mégret C, Eisenstein O, Perutz RN. Validation of the M-C/H-C bond enthalpy relationship through application of density functional theory. Journal of the American Chemical Society. 128: 8350-7. PMID 16787100 DOI: 10.1021/Ja061803A  0.365
2006 Ampt KA, Burling S, Donald SM, Douglas S, Duckett SB, Macgregor SA, Perutz RN, Whittlesey MK. Photochemical isomerization of N-heterocyclic carbene ruthenium hydride complexes: in situ photolysis, parahydrogen, and computational studies. Journal of the American Chemical Society. 128: 7452-3. PMID 16756294 DOI: 10.1021/Ja0622397  0.734
2006 Mkhalid IA, Coventry DN, Albesa-Jove D, Batsanov AS, Howard JA, Perutz RN, Marder TB. Ir-catalyzed borylation of C-H bonds in N-containing heterocycles: regioselectivity in the synthesis of heteroaryl boronate esters. Angewandte Chemie (International Ed. in English). 45: 489-91. PMID 16323236 DOI: 10.1002/Anie.200503047  0.389
2006 Câmpian MV, Harris JL, Jasim N, Perutz RN, Marder TB, Whitwood AC. Comparisons of photoinduced oxidative addition of B-H, B-B, and Si-H bonds at rhodium(η5-cyclopentadienyl)phosphine centers Organometallics. 25: 5093-5104. DOI: 10.1021/Om060500M  0.422
2005 Burling S, Elliott PI, Jasim NA, Lindup RJ, McKenna J, Perutz RN, Archibald SJ, Whitwood AC. C-F Bond activation at Ni(0) and simple reactions of square planar Ni(II) fluoride complexes. Dalton Transactions (Cambridge, England : 2003). 3686-95. PMID 16258621 DOI: 10.1039/B510052F  0.329
2005 Coventry DN, Batsanov AS, Goeta AE, Howard JA, Marder TB, Perutz RN. Selective Ir-catalysed borylation of polycyclic aromatic hydrocarbons: structures of naphthalene-2,6-bis(boronate), pyrene-2,7-bis(boronate) and perylene-2,5,8,11-tetra(boronate) esters. Chemical Communications (Cambridge, England). 2172-4. PMID 15846437 DOI: 10.1039/B501778E  0.388
2004 Duckett SB, Galvez-Lopez MD, Perutz RN, Schott D. Direct reaction of photogenerated diarylcarbenes at square-planar rhodium(I). Dalton Transactions (Cambridge, England : 2003). 2746-9. PMID 15514761 DOI: 10.1039/B407735K  0.61
2004 Ampt KA, Duckett SB, Perutz RN. Photochemical reactions of (eta 5-cyclopentadienyl)bis(t-butylacrylate) rhodium with silanes: dynamics of isomer interconversion via Rh(eta 2-silane) species. Dalton Transactions (Cambridge, England : 2003). 3331-7. PMID 15483718 DOI: 10.1039/B410257F  0.603
2004 Schott D, Callaghan P, Dunne J, Duckett SB, Godard C, Goicoechea JM, Harvey JN, Lowe JP, Mawby RJ, Müller G, Perutz RN, Poli R, Whittlesey MK. The reaction of M(CO)3(Ph2PCH2CH2PPh2)(M = Fe, Ru) with parahydrogen: probing the electronic structure of reaction intermediates and the internal rearrangement mechanism for the dihydride products. Dalton Transactions (Cambridge, England : 2003). 3218-24. PMID 15483704 DOI: 10.1039/B407457B  0.782
2004 Lam WH, Lam KC, Lin Z, Shimada S, Perutz RN, Marder TB. Theoretical study of reaction pathways for the rhodium phosphine-catalysed borylation of C-H bonds with pinacolborane. Dalton Transactions (Cambridge, England : 2003). 1556-62. PMID 15252604 DOI: 10.1039/B402632B  0.456
2004 Reinhold M, McGrady JE, Perutz RN. A comparison of C-F and C-H bond activation by zerovalent ni and pt: a density functional study. Journal of the American Chemical Society. 126: 5268-76. PMID 15099111 DOI: 10.1021/Ja0396908  0.413
2004 Callaghan PL, Fernández-Pacheco R, Jasim N, Lachaize S, Marder TB, Perutz RN, Rivalta E, Sabo-Etienne S. Photochemical oxidative addition of B-H bonds at ruthenium and rhodium. Chemical Communications (Cambridge, England). 242-3. PMID 14737569 DOI: 10.1039/B312246H  0.645
2004 Montiel-Palma V, Pattison DI, Perutz RN, Turner C. Photochemistry of Ru(etp)(CO)H2 (etp = PhP(CH2CH 2PPh2)2): Fast oxidative addition and coordination following exclusive dihydrogen loss Organometallics. 23: 4034-4039. DOI: 10.1021/Om049729X  0.741
2004 Chan D, Duckett SB, Heath SL, Khazal IG, Perutz RN, Sabo-Etienne S, Timmins PL. Platinum bis(tricyclohexylphosphine) silyl hydride complexes Organometallics. 23: 5744-5756. DOI: 10.1021/Om049549N  0.712
2004 Jasim NA, Perutz RN, Whitwood AC, Braun T, Izundu J, Neumann B, Rothfeld S, Stammler HG. Contrasting reactivity of fluoropyridines at palladium and platinum: C-F oxidative addition at palladium, P-C and C-F activation at platinum Organometallics. 23: 6140-6149. DOI: 10.1021/Om049448P  0.522
2003 Godard C, Duckett SB, Parsons S, Perutz RN. Dipyridylketone binding and subsequent C-C bond insertion reactions at cyclopentadienylrhodium. Chemical Communications (Cambridge, England). 2332-3. PMID 14518900 DOI: 10.1039/B306877C  0.59
2003 Clot E, Besora M, Maseras F, Mégret C, Eisenstein O, Oelckers B, Perutz RN. Bond energy M-C/H-C correlations: dual theoretical and experimental approach to the sensitivity of M-C bond strength to substituents. Chemical Communications (Cambridge, England). 490-1. PMID 12638964 DOI: 10.1039/B210036N  0.381
2003 Clot E, Oelckers B, Klahn AH, Eisenstein O, Perutz RN. cis–trans Isomerisation of CpRe(CO)2(H)(ArF)(ArF= C6FnH5−n; n= 0–5) is the rate determining step in C–H activation of fluoroarenes: a DFT study Dalton Transactions. 4065-4074. DOI: 10.1039/B305064E  0.404
2003 Jasim NA, Perutz RN, Archibald SJ. Replacement of [RuH2(PMe3)4] by [RuH 2(PEt3)4] switches reaction products: Synthesis of fluoride-bridged diruthenium complexes Dalton Transactions. 2184-2187. DOI: 10.1039/B301582C  0.36
2002 Godard C, Callaghan P, Cunningham JL, Duckett SB, Lohman JA, Perutz RN. NMR characterisation of unstable solvent and dihydride complexes generated at low temperature by in-situ UV irradiation. Chemical Communications (Cambridge, England). 2836-7. PMID 12478771 DOI: 10.1039/B208007A  0.575
2002 Braun T, Perutz RN. Routes to fluorinated organic derivatives by nickel mediated C-F activation of heteroaromatics. Chemical Communications (Cambridge, England). 2749-57. PMID 12478732 DOI: 10.1039/B206154F  0.481
2002 Gabrielsson A, Hartl F, Smith JR, Perutz RN. Photo-induced ligand substitution at a remote site via electron transfer in a porphyrin-appended rhenium carbonyl supermolecule. Chemical Communications (Cambridge, England). 950-1. PMID 12123063 DOI: 10.1039/B200127F  0.307
2002 Archibald SJ, Foxon SP, Freeman JD, Hobson JE, Perutz RN, Walton PH. Preparation of cationic cobalt phenoxide and ethoxide complexes and their reversible reaction with carbon dioxide Journal of the Chemical Society, Dalton Transactions. 2797-2799. DOI: 10.1039/B204560E  0.344
2002 Aspley CJ, Lindsay Smith JR, Perutz RN, Pursche D. Synthesis and photochemistry of free base and zinc tetraaryl porphyrins mono-substituted with tungsten pentacarbonyl via a pyridine linker Journal of the Chemical Society, Dalton Transactions. 170-180. DOI: 10.1039/B108562J  0.348
2002 Atheaux I, Delpech F, Donnadieu B, Sabo-Etienne S, Chaudret B, Hussein K, Barthelat JC, Braun T, Duckett SB, Perutz RN. Exchange processes in complexes with two ruthenium (η2-silane) linkages: Role of the secondary interactions between silicon and hydrogen atoms Organometallics. 21: 5347-5357. DOI: 10.1021/Om0206148  0.794
2001 Braun T, Perutz RN, Sladek MI. Catalytic C-F activation of polyfluorinated pyridines by nickel-mediated cross-coupling reactions. Chemical Communications (Cambridge, England). 2254-5. PMID 12240137 DOI: 10.1039/B106646C  0.475
2001 Carbó JJ, Eisenstein O, Higgitt CL, Klahn AH, Maseras F, Oelckers B, Perutz RN. The reaction of the unsaturated rhenium fragment {Re(η5-C5Me5)-(CO)2} with 1,4-difluorobenzene. Thermal intramolecular conversion of a rhenium (difluorophenyl)(hydride) to Re(η2-C6H4F2) and a [1,4]-metallotropic shift Journal of the Chemical Society, Dalton Transactions. 1452-1461. DOI: 10.1039/B101101O  0.322
2001 Jasim NA, Perutz RN, Foxon SP, Walton PH. Synthesis, characterisation and reactivity of ruthenium bis-bifluoride, ruthenium hydride bifluoride and ruthenium hydride fluoride complexes Journal of the Chemical Society, Dalton Transactions. 1676-1685. DOI: 10.1039/B101007G  0.442
2001 Braun T, Cronin L, Higgitt CL, McGrady JE, Perutz RN, Reinhold M. Coordination and oxidative addition of octafluoronaphthalene at a nickel centre: Isolation of an intermediate in C-F bond activation New Journal of Chemistry. 25: 19-21. DOI: 10.1039/B006368L  0.514
2000 Lewis JD, Perutz RN, Moore JN. Proton-controlled photoisomerization: Rhenium(I) tricarbonyl bipyridine linked to amine or azacrown ether groups by a styryl pyridine bridging ligand Chemical Communications. 1865-1866. DOI: 10.1039/B005889K  0.334
2000 Archibald SJ, Braun T, Gaunt JA, Hobson JE, Perutz RN. Chemistry of nickel tetrafluoropyridyl derivatives: Their versatile behaviour with Brønsted acids and the Lewis acid BF3 Journal of the Chemical Society, Dalton Transactions. 2013-2018. DOI: 10.1039/B002333G  0.492
2000 Montiel-Palma V, Perutz RN, George MW, Jina OS, Sabo-Etienne S. Two photochemical pathways in competition: matrix isolation, time-resolved and NMR studies of cis-[Ru(PMe3)4(H)2] Chemical Communications. 1175-1176. DOI: 10.1039/B002297G  0.637
2000 Cronin L, Higgitt CL, Perutz RN. Structure and dynamic exchange in rhodium η2-naphthalene and rhodium η2-phenanthrene complexes: Quantitative NOESY and EXSY studies Organometallics. 19: 672-683. DOI: 10.1021/Om9908377  0.419
2000 Jasim NA, Perutz RN. Hydrogen bonding in transition metal complexes: Synthesis, dynamics, and reactivity of platinum hydride bifluoride complexes Journal of the American Chemical Society. 122: 8685-8693. DOI: 10.1021/Ja0010913  0.458
2000 Montiel-Palma V, Perutz RN, George MW, Jina OS, Sabo-Etienne S. Two photochemical pathways in competition: Matrix isolation, time- resolved and NMR studies of cis-[Ru(PMe3)4(H)2] Chemical Communications. 1175-1176.  0.754
1999 Braun T, Foxon SP, Perutz RN, Walton PH. Nickel-Assisted Carbon-Fluorine Bond Activation of 2,4,6-Trifluoropyrimidine: Synthesis of New Pyrimidine and Pyrimidinone Derivatives. Angewandte Chemie (International Ed. in English). 38: 3326-3329. PMID 10602185 DOI: 10.1002/(Sici)1521-3773(19991115)38:22<3326::Aid-Anie3326>3.0.Co;2-7  0.512
1999 Colombo MG, George MW, Moore JN, Pattison DI, Perutz RN, Virrels IG, Ye T. Ultrafast Photodissociation of Hydrogen From Ru(PPh3)3(CO)(H)2: A Time-Resolved Infrared Study Laser Chemistry. 19: 283-285. DOI: 10.1155/1999/91069  0.411
1999 Abbott LC, Arnold CJ, Gordon KC, Hester RE, Moore JN, Perutz RN, Ye TQ. Time-resolved infrared spectroscopy of binuclear rhenium (I) polypyridyl complexes in solution Laser Chemistry. 19: 279-282. DOI: 10.1155/1999/43782  0.36
1999 Aspley CJ, Smith JRL, Perutz RN. Systematic synthesis and photochemistry of tetraaryl porphyrins mono-substituted with a transition metal carbonyl: characterisation of a zinc porphyrin–rhenium carbonyl complex† Journal of the Chemical Society-Dalton Transactions. 2269-2272. DOI: 10.1039/A903779I  0.306
1999 Godoy F, Higgitt CL, Klahn AH, Oelckers B, Parsons S, Perutz RN. Photochemical reactions of [Re(η5-C5R5)(CO)3] (R = H or Me) with partially fluorinated benzenes: C-H and C-F activation Journal of the Chemical Society - Dalton Transactions. 2039-2047. DOI: 10.1039/A902573A  0.39
1999 Aspley CJ, Boxwell C, Buil ML, Higgitt CL, Long C, Perutz RN. A new combination of donor and acceptor: bis(η6-benzene)chromium and hexafluorobenzene form a charge-transfer stacked crystal Chemical Communications. 1027-1028. DOI: 10.1039/A900919A  0.345
1999 Braun T, Parsons S, Perutz RN, Voith M. Reactivity of a Nickel Fluoride Complex: Preparation of New Tetrafluoropyridyl Derivatives Organometallics. 18: 1710-1716. DOI: 10.1021/Om980935C  0.494
1998 Perutz RN. Metal dihydride complexes: Photochemical mechanisms for reductive elimination Pure and Applied Chemistry. 70: 2211-2220. DOI: 10.1351/Pac199870112211  0.469
1998 Heaton SN, Partridge MG, Perutz RN, Parsons SJ, Zimmermann F. Photochemical displacement of co-ordinated ethene from [Rh(η5-C5H5)(PPh3)(C 2H4)] Journal of the Chemical Society - Dalton Transactions. 2515-2520. DOI: 10.1039/A803048K  0.409
1998 Klahn AH, Oelckers B, Godoy F, Garland MT, Vega A, Perutz RN, Higgitt CL. Synthesis and reactions of the rhenium fulvene complexes [Re(η6-C5Me4CH2)(CO) 2(C6F4R)] (R = F or CF3): Products derived from initial C-F activation Journal of the Chemical Society - Dalton Transactions. 3079-3086. DOI: 10.1039/A802899K  0.405
1998 Chan D, Cronin L, Duckett SB, Hupfield P, Perutz RN. Synthesis, structure and reactivity of N,O-metallacyclic (dicarbonyldiazene) platinum complexes New Journal of Chemistry. 22: 511-516. DOI: 10.1039/A709198B  0.583
1998 Chan D, Cronin L, Duckett SB, Hupfield P, Perutz RN. Synthesis, structure and reactivity of N,O-metallacyclic (dicarbonyldiazene) platinum complexes New Journal of Chemistry. 22: 511-516. DOI: 10.1039/A709198B  0.472
1998 Macgregor SA, Eisenstein O, Whittlesey MK, Perutz RN. A theoretical study of [M(PH3)4] (M = Ru or Fe), models for the highly reactive d8 intermediates [M(dmpe)2] (dmpe = Me2PCH2CH2PMe2). Zero activation energies for addition of CO and oxidative addition of H2 Journal of the Chemical Society - Dalton Transactions. 291-300. DOI: 10.1039/A706081E  0.586
1998 Nicasio MC, Perutz RN, Tekkaya A. Photochemistry of Os(dmpe)2 H2: Matrix, transient solution, and NMR studies of 16-Electron Os(dmpe)2 (dmpe = Me2PCH2CH2PMe2) Organometallics. 17: 5557-5564. DOI: 10.1021/Om9806141  0.43
1998 Abbott LC, Arnold CJ, Ye TQ, Gordon KC, Perutz RN, Hester RE, Moore JN. Ultrafast time-resolved UV-visible and infrared absorption spectroscopy of binuclear rhenium(I) polypyridyl complexes in solution Journal of Physical Chemistry A. 102: 1252-1260. DOI: 10.1021/Jp972526K  0.345
1998 Bosque R, Clot E, Fantacci S, Maseras F, Eisenstein O, Perutz RN, Renkema KB, Caulton KG. Inertness of the Aryl−F Bond toward Oxidative Addition to Osmium and Rhodium Complexes:  Thermodynamic or Kinetic Origin? Journal of the American Chemical Society. 120: 12634-12640. DOI: 10.1021/Ja9824573  0.348
1997 Colombo M, George MW, Moore JN, Pattison DI, Perutz RN, Virrels IG, Ye T. Ultrafast Reductive Elimination Of Hydrogen From A Metal Carbonyl Dihydride Complex; A Study By Time-Resolved Ir And Visible Spectroscopy Journal of the Chemical Society-Dalton Transactions. 2857-2860. DOI: 10.1039/A704484D  0.434
1997 Higgitt CL, Klahn AH, Moore MH, Oelckers B, Partridge MG, Perutz RN. Structure and dynamics of the η2-hexafluorobenzene complexes [Re(η5-C5H4R)(CO)2(η 2-C6F6)] (R = H or Me) and [Rh(η5-C5Me5)(PMe3)(η 2-C6F6)] Journal of the Chemical Society - Dalton Transactions. 1269-1280. DOI: 10.1039/A608135E  0.411
1997 Whittlesey MK, Perutz RN, Greener B, Moore MH. Synthesis, molecular structure and NMR spectroscopy of a transition-metal bifluoride complex: Formation via C-F activation or reaction with Et3N·3HF Chemical Communications. 187-188. DOI: 10.1039/A606598H  0.688
1997 Cronin L, Higgitt CL, Karch R, Perutz RN. Rapid intermolecular carbon-fluorine bond activation of pentafluoropyridine at nickel(0): Comparative reactivity of fluorinated arene and fluorinated pyridine derivatives Organometallics. 16: 4920-4928. DOI: 10.1021/Om9705160  0.361
1997 Bianchini C, Casares JA, Osman R, Pattison DI, Peruzzini M, Perutz RN, Zanobini F. C-H bond cleavage in thiophenes by [P(CH2CH2PPh2)3Ru]. UV flash kinetic spectroscopy discloses the ruthenium-thiophene adduct which precedes C-H insertion Organometallics. 16: 4611-4619. DOI: 10.1021/Om9703898  0.397
1997 Nicasio MC, Perutz RN, Walton PH. Transient photochemistry, matrix isolation, and molecular structure of cis-Ru(dmpm)2H2 (dmpm = Me2PCH2PMe2) Organometallics. 16: 1410-1417. DOI: 10.1021/Om961018E  0.364
1997 Whittlesey MK, Perutz RN, Virrels IG, George MW. Low-Temperature-Matrix and Room-Temperature-Solution Photochemistry of Ru(CO)3(dmpe) (dmpe = Me2PCH2CH2PMe2)† Organometallics. 16: 268-274. DOI: 10.1021/Om960683K  0.634
1997 Osman R, Pattison DI, Perutz RN, Bianchini C, Casares JA, Peruzzini M. Photochemistry of M(PP3)H2 (M = Ru, Os; PP3 = P(CH2CH2PPh2)3): Preparative, NMR, and time-resolved studies Journal of the American Chemical Society. 119: 8459-8473. DOI: 10.1021/Ja963797W  0.456
1996 Ballhorn M, Partridge MG, Perutz RN, Whittlesey MK. Photochemical intermolecular C-H and C-F insertion of rhodium into pentafluoroanisole to generate a metallacycle; conversion to a cyclic carbene complex Chemical Communications. 961-962. DOI: 10.1039/Cc9960000961  0.641
1996 Whittlesey MK, Perutz RN, Moore MH. Facile intermolecular aromatic C-F bond activation reactions of [Ru(dmpe)2H2] (dmpe = Me2PCH2CH2PMe2) Chemical Communications. 787-788. DOI: 10.1039/Cc9960000787  0.678
1996 Whittlesey MK, Perutz RN, Moore MH. Facile insertion of CO2 into the Ru-H bonds of Ru(dmpe)2H2 (dmpe = Me2PCH2CH2PMe2): Identification of three ruthenium formate complexes Organometallics. 15: 5166-5169. DOI: 10.1021/Om960588B  0.652
1996 Brown SSD, Heaton SN, Moore MH, Perutz RN, Wilson G. Synthesis and photoisomerization of divinyltetramethyldisiloxane and divinyltetramethyldisilazane complexes of (η5O5R5)Rh (R = H, Me). Crystal and molecular structure of (η5-C5Me5)Rh[η4-(CH 2=CH)Me2SiOSiMe2(CH=CH2)] Organometallics. 15: 1392-1404. DOI: 10.1021/Om950826N  0.445
1996 Arnold CJ, Ye TQ, Perutz RN, Hester RE, Moore JN. An ultrafast time-resolved UV /visible absorption study of the UV photochemistry of [(η5-C5H5)Fe(CO)2]2 Chemical Physics Letters. 248: 464-469. DOI: 10.1016/0009-2614(95)01343-1  0.33
1995 Selmeczy AD, Jones WD, Osman R, Perutz R. Substituent Effects on Reductive Elimination from Disubstituted Aryl Hydride Complexes: Mechanistic and Thermodynamic Considerations Organometallics. 14: 5677-5685. DOI: 10.1021/Om00012A038  0.615
1995 Mawby RJ, Perutz RN, Whittlesey MK. Matrix Photochemistry of Ru(CO)2(PMe3)2H2 and Ru(CO)3(PMe3)2: Formation of Ru(CO)2(PMe3)2.cntdot. .cntdot. .cntdot.S (S = Ar, CH4, Xe) Organometallics. 14: 3268-3274. DOI: 10.1021/Om00007A030  0.632
1995 Cronin L, Nicasio MC, Perutz RN, Peters RG, Roddick DM, Whittlesey MK. Laser flash photolysis and matrix isolation studies of Ru[R2PCH2CH2PR2]2H 2 (R = C2H5, C6H5, C2F5): Control of oxidative addition rates by phosphine substituents Journal of the American Chemical Society. 117: 10047-10054. DOI: 10.1021/Ja00145A016  0.622
1995 Cronin L, Nicasio MC, Perutz RN, Peters RG, Roddick DM, Whittlesey MK. Laser Flash Photolysis and Matrix Isolation Studies of Ru[R2PCH2CH2PR2]2H2 (R = C2H5, C6H5, C2F5): Control of Oxidative Addition Rates by Phosphine Substituents Journal of the American Chemical Society. 117: 10047-10054. DOI: 10.1021/ja00145a016  0.583
1995 Brough SA, Hall C, McCamley A, Perutz RN, Stahl S, Wecker U, Werner H. Photochemistry of Os(η6-arene) complexes in low-temperature matrices: an infrared spectroscopic study of CH bond activation Journal of Organometallic Chemistry. 504: 33-46. DOI: 10.1016/0022-328X(95)05609-S  0.544
1994 Partridge MG, McCamley A, Perutz RN. Photochemical generation of 16-electron [Rh(η5)-C5H5)-(PMe3)] and [Ir(η5-C5H5)(PMe3)] in low-temperature matrices: Evidence for methane activation Journal of the Chemical Society, Dalton Transactions. 3519-3526. DOI: 10.1039/Dt9940003519  0.402
1994 Hall C, Harris JL, Killey A, Maddox TP, Palmer S, Perutz RN, Rooney AD, Goff SEJ, Kazarian SG, Poliakoff M. Charge-transfer interactions between sulfur dioxide and group 8 half-sandwich complexes Journal of the Chemical Society, Dalton Transactions. 3515-3517. DOI: 10.1039/Dt9940003515  0.551
1994 Osman R, Pattison DI, Perutz RN, Bianchini C, Peruzzini M. Pulsed laser photolysis of Os(pp3)H2 [pp3 = P(CH2CH2PPh2)3]: Kinetic selectivity for reaction with methane Journal of the Chemical Society, Chemical Communications. 513-514. DOI: 10.1039/C39940000513  0.4
1994 Selmeczy AD, Jones WD, Partridge MG, Perutz RN. Selectivity in the activation of fluorinated aromatic hydrocarbons by rhodium complexes [(C5H5)Rh(PMe3)] and [(C5Me5)Rh(PMe3)] Organometallics. 13: 522-532. DOI: 10.1021/Om00014A025  0.511
1994 Osman R, Perutz RN, Rooney AD, Langley AJ. Picosecond photolysis of a metal dihydride: Rapid reductive elimination of dihydrogen from Ru(dmpe)2H2 (dmpe = (CH3)2PCH2CH2P(CH3) 2) Journal of Physical Chemistry. 98: 3562-3563. DOI: 10.1021/J100065A002  0.432
1993 Blom R, Rankin DWH, Robertson HE, Perutz RN. The molecular structure of (η5-cyclopentadienyl)-bis(ethene)rhodium determined by gas-phase electron diffraction Journal of the Chemical Society, Dalton Transactions. 1983-1986. DOI: 10.1039/Dt9930001983  0.362
1993 Bell TW, Brough SA, Partridge MG, Perutz RN, Rooney AD. Competition between intramolecular and intermolecular carbon-hydrogen bond activation in iridium ethene complexes Organometallics. 12: 2933-2941. DOI: 10.1021/Om00032A014  0.404
1993 Whittlesey MK, Mawby RJ, Osman R, Perutz RN, Field LD, Wilkinson MP, George MW. Transient and matrix photochemistry of Fe(dmpe)2H2 (dmpe = Me2PCH2CH2Me2): dynamics of C-H and H-H activation Journal of the American Chemical Society. 115: 8627-8637. DOI: 10.1021/Ja00072A016  0.642
1993 Chin RM, Dong L, Duckett SB, Partridge MG, Jones WD, Perutz RN. Control of .eta.2-coordination vs. carbon-hydrogen bond activation by rhodium: the role of aromatic resonance energies Journal of the American Chemical Society. 115: 7685-7695. DOI: 10.1021/Ja00070A012  0.641
1993 Belt ST, Helliwell M, Jones WD, Partridge MG, Perutz RN. .eta.2-Coordination and carbon-fluorine activation of hexafluorobenzene by cyclopentadienylrhodium and -iridium complexes Journal of the American Chemical Society. 115: 1429-1440. DOI: 10.1021/Ja00057A028  0.55
1993 Chin RM, Dong L, Duckett SB, Partridge MG, Jones WD, Perutz RN. Control of η2-coordination vs C-H bond activation by rhodium: The role of aromatic resonance energies Journal of the American Chemical Society. 115: 7685-7695.  0.528
1992 Klahn AH, Moore MH, Perutz RN. Intermolecular C-F and intramolecular C-H activation reaction of [Re(η5-C5Me5)(CO)3] with hexafluorobenzene: Crystal and molecular structure of [Re(η6- C5Me4CH2)(CO)2(C6F 5)] Journal of the Chemical Society, Chemical Communications. 1699-1701. DOI: 10.1039/C39920001699  0.418
1992 Bell TW, Helliwell M, Partridge MG, Perutz RN. Sequential displacement of coordinated ethene by hexafluorobenzene: crystal structures of .eta.2- and .eta.4-hexafluorobenzene complexes of iridium Organometallics. 11: 1911-1918. DOI: 10.1021/Om00041A025  0.305
1992 Duckett SB, Perutz RN. Mechanism of homogeneous hydrosilation of alkenes by (.eta.5-cyclopentadienyl)rhodium Organometallics. 11: 90-98. DOI: 10.1021/Om00037A022  0.513
1992 Hall C, Jones WD, Mawby RJ, Osman R, Perutz RN, Whittlesey MK. Matrix isolation and transient photochemistry of ruthenium complex Ru(dmpe)2H2: characterization and reactivity of Ru(dmpe)2 (dmpe = Me2PCH2CH2PMe2) Journal of the American Chemical Society. 114: 7425-7435. DOI: 10.1021/Ja00045A014  0.722
1992 Brookhart M, Chandler W, Kessler RJ, Liu Y, Pienta NJ, Santini CC, Hall C, Perutz RN, Timney JA. Matrix isolation and transient absorption studies of [bis[bis(pentafluoroethyl)phosphino]ethane]tetracarbonylchromium: intermolecular alkane complexes and intramolecular F-coordination Journal of the American Chemical Society. 114: 3802-3815. DOI: 10.1021/Ja00036A032  0.372
1992 Duckett SB, Perutz RN. Mechanism of homogeneous hydrosilation of alkenes by (η5-cyclopentadienyl)rhodium Organometallics. 11: 90-98.  0.49
1992 Brookhart M, Chandler W, Kessler RJ, Liu Y, Pienta NJ, Santini CC, Hall C, Perutz RN, Timney JA. Matrix isolation and transient absorption studies of (bis(bis(pentafluoroethyl)phosphino)ethane)tetracarbonyl-chromium: Intermolecular alkane complexes and intramolecular F-coordination Journal of the American Chemical Society. 114: 3802-3815.  0.738
1991 Cloke FGN, Khan K, Perutz RN. η-Arene complexes of scandium(0) and scandium(II) Journal of the Chemical Society, Chemical Communications. 1372-1373. DOI: 10.1039/C39910001372  0.351
1991 Belt ST, Dong L, Duckett SB, Jones WD, Partridge MG, Perutz RN. Control of η2-arene coordination and C-H bond activation by cyclopentadienyl complexes of rhodium Journal of the Chemical Society, Chemical Communications. 266-269. DOI: 10.1039/C39910000266  0.701
1991 Jones WD, Partridge MG, Perutz RN. Sequential arene coordination and C-F insertion in the reactions of (η5-pentamethylcyclopentadienyl)rhodium complexes with hexafluorobenzene Journal of the Chemical Society, Chemical Communications. 264-266. DOI: 10.1039/C39910000264  0.57
1991 Duckett SB, Perutz RN. Thermal and photochemical reactions of rhodium(trialkylsilyl)hydride complexes: NMR and bonding of poly(silyl)(hydride) complexes Journal of the Chemical Society, Chemical Communications. 28-31. DOI: 10.1039/C39910000028  0.642
1991 McCamley A, Perutz RN. Resonance Raman spectroscopy of matrix-isolated bis(.eta.6-arene)vanadium complexes The Journal of Physical Chemistry. 95: 2738-2744. DOI: 10.1021/J100160A023  0.321
1991 Perutz RN, Hill JN, McCamley A. Laser spectroscopy of open-shell sandwich complexes Coordination Chemistry Reviews. 111: 111-116. DOI: 10.1016/0010-8545(91)84015-W  0.359
1990 Perutz RN, Belt ST, McCamley A, Whittlesey MK. C—H activation by organometallics: The role of matrix isolation studies Pure and Applied Chemistry. 62: 1539-1545. DOI: 10.1351/Pac199062081539  0.628
1990 Perutz RN. Photochemical C—H bond activation; NMR, matrix and laser kinetic studies Pure and Applied Chemistry. 62: 1103-1106. DOI: 10.1351/Pac199062061103  0.43
1990 Bell TW, Haddleton DM, McCamley A, Partridge MG, Perutz RN, Willner H. Photochemical isomerization of metal ethene to metal vinyl hydride complexes: A matrix-isolation and solution NMR study Journal of the American Chemical Society. 112: 9212-9226. DOI: 10.1021/Ja00181A025  0.586
1990 Bell SEJ, Hill JN, McCamley A, Perutz RN. Laser-induced fluorescence of reactive metallocenes (.eta.5-C5H5)2M (M = Re, W, Mo) and (.eta.5-C5Me5)2Re The Journal of Physical Chemistry. 94: 3876-3878. DOI: 10.1021/J100373A004  0.319
1990 MCCAMLEY A, PERUTZ RN, STAHL S, WERNER H. ChemInform Abstract: Inter- and Intramolecular Photochemical C-H Activation with (η6-Arene)(carbonyl)osmium Complexes in Matrices and in Solution. Cheminform. 21. DOI: 10.1002/chin.199010277  0.473
1989 Howdle SM, Grebenik P, Perutz RN, Poliakoff M. The synthesis and spectroscopic identification of [(η5- C5H5)Re(N2)3] and [(η5-C5H5)Re(CO)(N2) 2] in supercritical xenon at room temperature and in N2 matrices at 20 K Journal of the Chemical Society, Chemical Communications. 1517-1519. DOI: 10.1039/C39890001517  0.497
1989 Belt ST, Duckett SB, Helliwell M, Perutz RN. Activation and η2-co-ordination of arenes: Crystal and molecular structure of an (η2-hexafluorobenzene)rhodium complex Journal of the Chemical Society, Chemical Communications. 928-930. DOI: 10.1039/C39890000928  0.621
1989 Belt ST, Duckett SB, Haddleton DM, Perutz RN. Photochemical substitution of ethene and hydrogen/deuterium exchange in (.eta.5-cyclopentadienyl)bis(ethene)rhodium Organometallics. 8: 748-759. DOI: 10.1021/Om00105A027  0.637
1989 Belt ST, Grevels FW, Klotzbücher WE, McCamley A, Perutz RN. Intermediates in the time-resolved and matrix photochemistry of (η5-cyclopentadienyl)rhodium complexes: Roles of alkane activation and rhodium-rhodium bond formation Journal of the American Chemical Society®. 111: 8373-8382. DOI: 10.1021/Ja00204A008  0.347
1989 McCamley A, Perutz RN, Stahl S, Werner H. Inter- and intramolecular photochemical C-H activation in matrices and in solution with (η6-arene)(carbonyl)osmium complexes Angewandte Chemie - International Edition in English. 28: 1690-1692. DOI: 10.1002/Anie.198916901  0.541
1989 McCamley A, Perutz RN, Stahl S, Werner H. Inter‐ und intramolekulare photochemische C‐H‐Aktivierung mit Aren(carbonyl)osmium‐Komplexen in Matrix und in Lösung Angewandte Chemie. 101: 1721-1723. DOI: 10.1002/Ange.19891011225  0.398
1989 Belt ST, Duckett SB, Haddleton DM, Perutz RN. Photochemical substitution of ethene and H/D exchange in (η5-cyclopentadienyl)bis(ethene)rhodium Organometallics. 8: 748-759.  0.531
1988 Duckett SB, Haddleton DM, Jackson SA, Perutz RN, Poliakoff M, Upmacis RK. Photochemical oxidative addition reactions of (.eta.5-cyclopentadienyl)bis(ethene)rhodium with dihydrogen and trialkylsilanes: formation and isolation of rhodium(III) and rhodium(V) hydrides Organometallics. 7: 1526-1532. DOI: 10.1021/Om00097A013  0.706
1988 Bandy JA, Cloke FGN, Copper G, Day JP, Girling RB, Graham RG, Green JC, Grinter R, Perutz RN. Decamethylrhenocene, (.eta.5-C5Me5)2Re Journal of the American Chemical Society. 110: 5039-5050. DOI: 10.1021/Ja00223A023  0.312
1988 Haddleton DM, McCamley A, Perutz RN. Matrix photochemistry of (η5-cyclopentadienyl)bis(ethene)rhodium and (η5-cyclopentadienyl)(ethene)carbonylrhodium: A test-bed for intermediates in C-H activation Journal of the American Chemical Society. 110: 1810-1817. DOI: 10.1021/Ja00214A025  0.554
1988 Duckett SB, Haddleton DM, Jackson SA, Perutz RN, Poliakoff M, Upmacis RK. Photochemical oxidative addition reactions of (η5-cyclopentadienyl)bis(ethene)rhodium with dihydrogen and trialkylsilanes: Formation and isolation of rhodium(III) and rhodium(V) hydrides Organometallics. 7: 1526-1532.  0.502
1987 Belt ST, Haddleton DM, Perutz RN, Smith BPH, Dixon AJ. Transient photochemistry of (η5-cyclopentadienyl)bis(ethene) rhodium Journal of the Chemical Society, Chemical Communications. 1347-1349. DOI: 10.1039/C39870001347  0.538
1986 Haddleton DM, Perutz RN. Photochemical activation of ethene C-H bonds of (η5-C 5H5)Ir(C2H4)2 in low-temperature matrices and in solution Journal of the Chemical Society, Chemical Communications. 1734-1736. DOI: 10.1039/C39860001734  0.585
1986 Girling RB, Grebenik P, Perutz RN. Vibrational spectra of terminal metal hydrides: Solution and matrix-isolation studies of [(η-C5H5)2MHn]x+ (M = Re, Mo, W, Nb, Ta; n = 1-3; x = 0, 1) Inorganic Chemistry. 25: 31-36. DOI: 10.1021/Ic00221A010  0.328
1986 Haddleton DM, Perutz RN, Jackson SA, Upmacis RK, Poliakoff M. Photochemical generation and reactions of rhodium (η5-cyclopentadienyl) (ethene) (dinitrogen) in liquid xenon Journal of Organometallic Chemistry. 311: C15-C20. DOI: 10.1016/0022-328X(86)80242-X  0.664
1985 Haddleton DM, Perutz RN. Solution and matrix photochemistry of (η-cyclopentadienyl)bis(ethene) rhodium Journal of the Chemical Society, Chemical Communications. 1372-1374. DOI: 10.1039/C39850001372  0.551
1985 Baynham RFG, Chetwynd-Talbot J, Grebenik P, Perutz RN, Powell MHA. Photochemistry of M(η5-C5H5)2(H)CO and M(η5-C5H5)2H3 (M = Nb, Ta) in low-temperature matrices Journal of Organometallic Chemistry. 284: 229-242. DOI: 10.1016/0022-328X(85)87214-4  0.461
1984 Bandy JA, Berry A, Green MLH, Perutz RN, Prout K, Verpeaux JN. Synthesis of anionic sandwich compounds: [Ti(η-C6H5R)2]- and the crystal structure of [K(18-crown-6)(μ-H)Mo(η-C5H5)2] Journal of the Chemical Society - Series Chemical Communications. 729-731. DOI: 10.1039/C39840000729  0.402
1984 Perutz RN, Scaiano JC. Transient spectroscopy and kinetics of monomeric molybdenocene Mo(η-C5H5)2 in solution Journal of the Chemical Society, Chemical Communications. 457-458. DOI: 10.1039/C39840000457  0.395
1984 De Los Angeles Paz-Sandoval M, Powell P, Drew MGB, Perutz RN. Diene and dienyl complexes of transition elements. 8. Addition and substitution reactions of pentadienyltricarbonylmanganese with phosphines, phosphites, and carbon monoxide Organometallics. 3: 1026-1033. DOI: 10.1021/Om00085A011  0.395
1984 Cloke FGN, Fyne PJ, Gibson VC, Green MLH, Ledoux MJ, Perutz RN, Dix A, Gourdon A, Prout K. Synthesis, crystal structures and some reactions of zero-valent tris[bis-1,2-(dimethylphosphino)ethane] derivatives of chromium, molybdenum, tungsten, vanadium, niobium and tantalum Journal of Organometallic Chemistry. 277: 61-73. DOI: 10.1016/0022-328X(84)80680-4  0.347
1984 Cox PA, Grebenik P, Perutz RN, Graham RG, Grinter R. Rhenocene: Magnetic circular dichroism and laser-induced fluorescence in nitrogen matrices Chemical Physics Letters. 108: 415-419. DOI: 10.1016/0009-2614(84)85170-2  0.307
1983 Chetwynd-Talbot J, Grebenik P, Perutz RN, Powell MHA. Photochemical studies of rhenium .eta.-cyclopentadienyl complexes in matrixes and in solution: detection of rhenocene and mechanisms of hydrogen transfer Inorganic Chemistry. 14: 1675-1684. DOI: 10.1021/Ic00153A024  0.322
1982 Chetwynd-Talbot J, Grebenik P, Perutz RN. Photochemical reactions of M(.eta.-C5H5)2Ln (M = W, Mo, Cr, V) in low-temperature matrixes. Detection of tungstenocene and molybdenocene Inorganic Chemistry. 13: 3647-3657. DOI: 10.1021/Ic00140A013  0.32
1981 Chetwynd-Talbot J, Grebenik P, Perutz RN. Photochemistry of [(η-C5H5)2ReH] and [(η-C5H5)(η2-C5H 6)Re(CO)2,] in low temperature matrices: Hydrogen loss and hydrogen migration Journal of the Chemical Society, Chemical Communications. 452-454. DOI: 10.1039/C39810000452  0.342
1979 Grebenik P, Downs AJ, Green MLH, Perutz RN. Infrared spectroscopic evidence for photochemical generation of the metallocenes [(η-C5H5)2M] (M = Mo or W) in low-temperature matrices Journal of the Chemical Society, Chemical Communications. 742-744. DOI: 10.1039/C39790000742  0.354
1978 Perutz RN. Matrix photolysis of trimethylazidosilane: Silicon-hydrogen bond formation Journal of the Chemical Society, Chemical Communications. 762-763. DOI: 10.1039/C39780000762  0.366
1978 Burdett JK, Grzybowski JM, Perutz RN, Poliakoff M, Turner JJ, Turner RF. Photolysis and spectroscopy with polarized light: key to the photochemistry of pentacarbonylchromium and related species Inorganic Chemistry. 17: 147-154. DOI: 10.1021/Ic50179A028  0.601
1978 BURDETT JK, GRZYBOWSKI JM, PERUTZ RN, POLIAKOFF M, TURNER JJ, TURNER RF. ChemInform Abstract: PHOTOLYSIS AND SPECTROSCOPY WITH POLARIZED LIGHT- KEY TO THE PHOTOCHEMISTRY OF PENTACARBONYLCHROMIUM AND RELATED SPECIES Chemischer Informationsdienst. 9. DOI: 10.1002/Chin.197815299  0.604
1978 Burdett JK, Grzybowski JM, Perutz RN, Poliakoff M, Turner JJ, Turner RF. Photolysis and spectroscopy with polarized light: Key to the photochemistry of Cr(CO)5 and related species Inorganic Chemistry. 17: 147-154.  0.455
1977 Turner JJ, Burdett JK, Perutz RN, Poliakoff M. Matrix Photochemistry of Metal Carbonyls Pure and Applied Chemistry. 49: 271-285. DOI: 10.1351/Pac197749030271  0.626
1976 Burdett JK, Perutz RN, Poliakoff M, Turner JJ. Vibrational frequency shifts for isotopes of hexacarbonylchromium Inorganic Chemistry. 15: 1245-1245. DOI: 10.1021/Ic50159A061  0.612
1976 Burdett JK, Perutz RN, Poliakoff M, Turner JJ. Vibrational frequency shifts for isotopes of hexacarbonylchromium [2] Inorganic Chemistry. 15: 1245.  0.435
1975 Burdett JK, Graham MA, Perutz RN, Poliakoff M, Rest AJ, Turner JJ, Turner RF. Photochemistry of the group 6 hexacarbonyls in low-temperature matrices. V. Two routes to square pyramidal matrix isolated chromium pentacarbonyl Journal of the American Chemical Society. 97: 4805-4808. DOI: 10.1021/Ja00850A003  0.605
1975 Burdett JK, Perutz RN, Poliakoff M, Turner JJ. Polarized photochemistry and photo-orientation of pentacarbonylchromium in low-temperature matrices Journal of the Chemical Society, Chemical Communications. 157-159. DOI: 10.1002/Chin.197523406  0.597
1973 Cotton FA, Edwards WT, Rauch FC, Graham MA, Perutz RN, Turner JJ. An approach to direct evaluation of PI bonding in metal carbonyls Journal of Coordination Chemistry. 2: 247-250. DOI: 10.1080/00958977308072983  0.478
1972 Graham MA, Perutz RN, Poliakoff M, Turner JJ. Intermediates in chromium carbonyl photochemistry Journal of Organometallic Chemistry. 34. DOI: 10.1016/S0022-328X(00)88270-4  0.508
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