| Year |
Citation |
Score |
| 2024 |
Phearman AS, Bullock RM. Synthesis and Reactivity of Fe(II) Complexes Containing Cis Ammonia Ligands. Inorganic Chemistry. 63: 2024-2033. PMID 38230973 DOI: 10.1021/acs.inorgchem.3c03757 |
0.368 |
|
| 2022 |
Tran BL, Erickson JD, Speelman AL, Bullock RM. Mechanistic Studies of Carbonyl Allylation Mediated by (NHC)CuH: Isoprene Insertion, Allylation, and β-Hydride Elimination. Inorganic Chemistry. 62: 342-352. PMID 36525336 DOI: 10.1021/acs.inorgchem.2c03402 |
0.304 |
|
| 2022 |
Dunn PL, Barona M, Johnson SI, Raugei S, Bullock RM. Hydrogen Atom Abstraction from an Os(NH) Complex Generates an Os(NH) Complex: Experimental and Computational Analysis of the N-H Bond Dissociation Free Energies and Reactivity. Inorganic Chemistry. PMID 36121917 DOI: 10.1021/acs.inorgchem.2c00708 |
0.725 |
|
| 2022 |
Cook BJ, Barona M, Johnson SI, Raugei S, Bullock RM. Weakening the N-H Bonds of NH Ligands: Triple Hydrogen-Atom Abstraction to Form a Chromium(V) Nitride. Inorganic Chemistry. PMID 35829761 DOI: 10.1021/acs.inorgchem.2c01115 |
0.379 |
|
| 2022 |
Wiedner ES, Appel AM, Raugei S, Shaw WJ, Bullock RM. Molecular Catalysts with Diphosphine Ligands Containing Pendant Amines. Chemical Reviews. PMID 35640056 DOI: 10.1021/acs.chemrev.1c01001 |
0.334 |
|
| 2020 |
Fantuzzi F, Nascimento MAC, Ginovska B, Bullock RM, Raugei S. Splitting of multiple hydrogen molecules by bioinspired diniobium metal complexes: a DFT study. Dalton Transactions (Cambridge, England : 2003). 50: 840-849. PMID 33237062 DOI: 10.1039/d0dt03411h |
0.347 |
|
| 2020 |
Dunn PL, Cook BJ, Johnson SI, Appel AM, Bullock RM. Oxidation of Ammonia with Molecular Complexes. Journal of the American Chemical Society. PMID 32977718 DOI: 10.1021/jacs.0c08269 |
0.721 |
|
| 2020 |
Bullock RM, Chen JG, Gagliardi L, Chirik PJ, Farha OK, Hendon CH, Jones CW, Keith JA, Klosin J, Minteer SD, Morris RH, Radosevich AT, Rauchfuss TB, Strotman NA, Vojvodic A, et al. Using nature's blueprint to expand catalysis with Earth-abundant metals. Science (New York, N.Y.). 369. PMID 32792370 DOI: 10.1126/Science.Abc3183 |
0.711 |
|
| 2020 |
Tran BL, Neisen BD, Speelman AL, Gunasekara T, Wiedner E, Bullock RM. Mechanistic Studies on the Insertion of Carbonyl Substrates into Cu-H: Different Rate-Limiting Steps as a Function of Electrophilicity. Angewandte Chemie (International Ed. in English). PMID 32022415 DOI: 10.1002/Anie.201916406 |
0.779 |
|
| 2020 |
Dunn P, Johnson SI, Kaminsky W, Bullock RM. Diversion of Catalytic C-N Bond Formation to Catalytic Oxidation of NH3 Through Modification of the Hydrogen Atom Abstractor. Journal of the American Chemical Society. PMID 32009401 DOI: 10.1021/Jacs.9B13706 |
0.736 |
|
| 2020 |
Zhang S, Li H, Appel AM, Hall MB, Bullock RM. Controlling P–C/C–H Bond Cleavage in Nickel Bis(diphosphine) Complexes: Reactivity Scope, Mechanism, and Computations Organometallics. DOI: 10.1021/Acs.Organomet.0C00388 |
0.427 |
|
| 2019 |
Cook BJ, Johnson SI, Chambers GM, Kaminsky W, Bullock RM. Triple hydrogen atom abstraction from Mn-NH complexes results in cyclophosphazenium cations. Chemical Communications (Cambridge, England). PMID 31691686 DOI: 10.1039/C9Cc06915A |
0.465 |
|
| 2019 |
Shan B, Brennaman MK, Troian-Gautier L, Liu Y, Nayak A, Klug CM, Li TT, Bullock RM, Meyer TJ. A Silicon-Based Heterojunction Integrated with a Molecular Excited State in a Water-Splitting Tandem Cell. Journal of the American Chemical Society. PMID 31244171 DOI: 10.1021/Jacs.9B04238 |
0.332 |
|
| 2019 |
Bhattacharya P, Heiden ZM, Chambers GM, Johnson SI, Bullock RM, Mock MT. Catalytic Ammonia Oxidation to Dinitrogen by Hydrogen Atom Abstraction. Angewandte Chemie (International Ed. in English). PMID 31115120 DOI: 10.1002/Anie.201903221 |
0.76 |
|
| 2019 |
Johnson SI, Heins SP, Klug CM, Wiedner ES, Bullock RM, Raugei S. Design and reactivity of pentapyridyl metal complexes for ammonia oxidation. Chemical Communications (Cambridge, England). PMID 30977481 DOI: 10.1039/C9Cc01249D |
0.444 |
|
| 2019 |
Chambers GM, Johnson SI, Raugei S, Bullock RM. Anion control of tautomeric equilibria: Fe-H N-H influenced by NH···F hydrogen bonding. Chemical Science. 10: 1410-1418. PMID 30842818 DOI: 10.1039/C8Sc04239J |
0.443 |
|
| 2019 |
Prokopchuk DE, Chambers GM, Walter ED, Mock MT, Bullock RM. H2 Binding, Splitting, and Net Hydrogen Atom Transfer at a Paramagnetic Iron Complex. Journal of the American Chemical Society. PMID 30669844 DOI: 10.1021/Jacs.8B12823 |
0.817 |
|
| 2019 |
Tran BL, Fulton JL, Linehan JC, Balasubramanian M, Lercher JA, Bullock RM. Operando XAFS Studies on Rh(CAAC)-Catalyzed Arene Hydrogenation Acs Catalysis. 9: 4106-4114. DOI: 10.1021/Acscatal.8B04929 |
0.39 |
|
| 2019 |
Bhattacharya P, Heiden ZM, Chambers GM, Johnson SI, Bullock RM, Mock MT. Frontispiece: Catalytic Ammonia Oxidation to Dinitrogen by Hydrogen Atom Abstraction Angewandte Chemie International Edition. 58. DOI: 10.1002/Anie.201983461 |
0.698 |
|
| 2018 |
Chambers GM, Wiedner ES, Bullock RM. H2 Oxidation Electrocatalysis Enabled by Metal-to-Metal Hydrogen Atom Transfer: A Homolytic Approach to a Heterolytic Reaction. Angewandte Chemie (International Ed. in English). PMID 30117247 DOI: 10.1002/Anie.201807510 |
0.482 |
|
| 2018 |
Chen JG, Crooks RM, Seefeldt LC, Bren KL, Bullock RM, Darensbourg MY, Holland PL, Hoffman B, Janik MJ, Jones AK, Kanatzidis MG, King P, Lancaster KM, Lymar SV, Pfromm P, et al. Beyond fossil fuel-driven nitrogen transformations. Science (New York, N.Y.). 360. PMID 29798857 DOI: 10.1126/Science.Aar6611 |
0.486 |
|
| 2018 |
Kendall AJ, Johnson SI, Bullock RM, Mock MT. Catalytic Silylation of N2 and Synthesis of NH3 and N2H4 by Net Hydrogen Atom Transfer Reactions using a Chromium P4 Macrocycle. Journal of the American Chemical Society. PMID 29384664 DOI: 10.1021/Jacs.7B11132 |
0.744 |
|
| 2018 |
Tran BL, Fulton JL, Linehan JC, Lercher JA, Bullock RM. Rh(CAAC)-Catalyzed Arene Hydrogenation: Evidence for Nanocatalysis and Sterically Controlled Site-Selective Hydrogenation Acs Catalysis. 8: 8441-8449. DOI: 10.1021/Acscatal.8B02589 |
0.395 |
|
| 2018 |
Klug CM, Cardenas AJP, Bullock RM, O’Hagan M, Wiedner ES. Reversing the Tradeoff between Rate and Overpotential in Molecular Electrocatalysts for H2 Production Acs Catalysis. 8: 3286-3296. DOI: 10.1021/Acscatal.7B04379 |
0.393 |
|
| 2017 |
Wang D, Sheridan MV, Shan B, Farnum BH, Marquard SL, Sherman BD, Eberhart MS, Nayak A, Dares C, Das A, Bullock RM, Meyer TJ. Layer-by-Layer Molecular Assemblies for Dye-Sensitized Pho-toelectrosynthesis Cells Prepared by Atomic Layer Deposi-tion. Journal of the American Chemical Society. PMID 28810743 DOI: 10.1021/Jacs.7B07216 |
0.746 |
|
| 2017 |
Bullock RM, Chambers GM. Frustration across the periodic table: heterolytic cleavage of dihydrogen by metal complexes. Philosophical Transactions. Series a, Mathematical, Physical, and Engineering Sciences. 375. PMID 28739961 DOI: 10.1098/Rsta.2017.0002 |
0.362 |
|
| 2017 |
Prokopchuk DE, Wiedner ES, Walter ED, Popescu CV, Piro NA, Kassel WS, Bullock RM, Mock MT. Catalytic N2 Reduction into Silylamines and Thermodynamics of N2 Binding at Square Planar Fe. Journal of the American Chemical Society. PMID 28613896 DOI: 10.1021/Jacs.7B04552 |
0.792 |
|
| 2017 |
Zhang S, Appel AM, Bullock RM. Reversible Heterolytic Cleavage of the H-H Bond by Molybdenum Complexes: Controlling the Dynamics of Exchange Between Proton and Hydride. Journal of the American Chemical Society. PMID 28467854 DOI: 10.1021/Jacs.7B03053 |
0.489 |
|
| 2017 |
Bhattacharya P, Heiden ZM, Wiedner ES, Raugei S, Piro NA, Kassel WS, Bullock RM, Mock MT. Ammonia Oxidation by Abstraction of Three Hydrogen Atoms from a Mo-NH3 Complex. Journal of the American Chemical Society. PMID 28166403 DOI: 10.1021/Jacs.7B00002 |
0.768 |
|
| 2017 |
Klug CM, O’Hagan M, Bullock RM, Appel AM, Wiedner ES. Impact of Weak Agostic Interactions in Nickel Electrocatalysts for Hydrogen Oxidation Organometallics. 36: 2275-2284. DOI: 10.1021/Acs.Organomet.7B00103 |
0.486 |
|
| 2016 |
Cardenas AJ, Ginovska B, Kumar N, Hou J, Raugei S, Helm ML, Appel AM, Bullock RM, O'Hagan M. Controlling Proton Delivery through Catalyst Structural Dynamics. Angewandte Chemie (International Ed. in English). PMID 27677094 DOI: 10.1002/Anie.201607460 |
0.422 |
|
| 2016 |
Wiedner ES, Chambers MB, Pitman CL, Bullock RM, Miller AJ, Appel AM. Thermodynamic Hydricity of Transition Metal Hydrides. Chemical Reviews. PMID 27483171 DOI: 10.1021/Acs.Chemrev.6B00168 |
0.42 |
|
| 2016 |
Egbert JD, O'Hagan M, Wiedner ES, Bullock RM, Piro NA, Kassel WS, Mock MT. Putting chromium on the map for N2 reduction: production of hydrazine and ammonia. A study of cis-M(N2)2 (M = Cr, Mo, W) bis(diphosphine) complexes. Chemical Communications (Cambridge, England). PMID 27331373 DOI: 10.1039/C6Cc03449G |
0.714 |
|
| 2016 |
Wiedner ES, Bullock RM. Electrochemical Detection of Transient Cobalt Hydride Intermediates of Electrocatalytic Hydrogen Production. Journal of the American Chemical Society. PMID 27300721 DOI: 10.1021/Jacs.6B04779 |
0.5 |
|
| 2016 |
Bligaard T, Bullock RM, Campbell CT, Chen JG, Gates BC, Gorte RJ, Jones CW, Jones WD, Kitchin JR, Scott SL. Toward Benchmarking in Catalysis Science: Best Practices, Challenges, and Opportunities Acs Catalysis. 6: 2590-2602. DOI: 10.1021/Acscatal.6B00183 |
0.478 |
|
| 2015 |
Darmon JM, Kumar N, Hulley EB, Weiss CJ, Raugei S, Bullock RM, Helm ML. Increasing the rate of hydrogen oxidation without increasing the overpotential: a bio-inspired iron molecular electrocatalyst with an outer coordination sphere proton relay. Chemical Science. 6: 2737-2745. PMID 29142678 DOI: 10.1039/C5Sc00398A |
0.49 |
|
| 2015 |
Raugei S, Helm ML, Hammes-Schiffer S, Appel AM, O'Hagan M, Wiedner ES, Bullock RM. Experimental and Computational Mechanistic Studies Guiding the Rational Design of Molecular Electrocatalysts for Production and Oxidation of Hydrogen. Inorganic Chemistry. PMID 26653114 DOI: 10.1021/Acs.Inorgchem.5B02262 |
0.487 |
|
| 2015 |
Bullock RM, Helm ML. Molecular Electrocatalysts for Oxidation of Hydrogen Using Earth-Abundant Metals: Shoving Protons Around with Proton Relays. Accounts of Chemical Research. PMID 26079983 DOI: 10.1021/Acs.Accounts.5B00069 |
0.548 |
|
| 2015 |
Zhang S, Bullock RM. Molybdenum Hydride and Dihydride Complexes Bearing Diphosphine Ligands with a Pendant Amine: Formation of Complexes with Bound Amines. Inorganic Chemistry. 54: 6397-409. PMID 26054002 DOI: 10.1021/Acs.Inorgchem.5B00728 |
0.469 |
|
| 2015 |
Ho MH, O'Hagan M, Dupuis M, DuBois DL, Bullock RM, Shaw WJ, Raugei S. Water-assisted proton delivery and removal in bio-inspired hydrogen production catalysts. Dalton Transactions (Cambridge, England : 2003). 44: 10969-79. PMID 25999141 DOI: 10.1039/C5Dt00782H |
0.645 |
|
| 2015 |
Mock MT, Pierpont AW, Egbert JD, O'Hagan M, Chen S, Bullock RM, Dougherty WG, Kassel WS, Rousseau R. Protonation studies of a mono-dinitrogen complex of chromium supported by a 12-membered phosphorus macrocycle containing pendant amines. Inorganic Chemistry. 54: 4827-39. PMID 25933172 DOI: 10.1021/Acs.Inorgchem.5B00351 |
0.744 |
|
| 2015 |
Das AK, Engelhard MH, Lense S, Roberts JA, Bullock RM. Covalent attachment of diphosphine ligands to glassy carbon electrodes via Cu-catalyzed alkyne-azide cycloaddition. Metallation with Ni(ii). Dalton Transactions (Cambridge, England : 2003). 44: 12225-33. PMID 25811536 DOI: 10.1039/C5Dt00162E |
0.372 |
|
| 2015 |
Raugei S, DuBois DL, Rousseau R, Chen S, Ho MH, Bullock RM, Dupuis M. Toward molecular catalysts by computer. Accounts of Chemical Research. 48: 248-55. PMID 25574854 DOI: 10.1021/Ar500342G |
0.544 |
|
| 2015 |
Liu T, Liao Q, O'Hagan M, Hulley EB, DuBois DL, Bullock RM. Iron Complexes Bearing Diphosphine Ligands with Positioned Pendant Amines as Electrocatalysts for the Oxidation of H2 Organometallics. 34: 2747-2764. DOI: 10.1021/Om501289F |
0.724 |
|
| 2015 |
Brown HJS, Wiese S, Roberts JAS, Bullock RM, Helm ML. Electrocatalytic hydrogen production by [Ni(7PPh 2NH)2]2+: Removing the Distinction between endo- and exo-protonation sites Acs Catalysis. 5: 2116-2123. DOI: 10.1021/Cs502132Y |
0.478 |
|
| 2015 |
Hulley EB, Kumar N, Raugei S, Bullock RM. Manganese-Based Molecular Electrocatalysts for Oxidation of Hydrogen Acs Catalysis. 5: 6838-6847. DOI: 10.1021/Acscatal.5B01751 |
0.427 |
|
| 2015 |
Ho MH, Rousseau R, Roberts JAS, Wiedner ES, Dupuis M, Dubois DL, Bullock RM, Raugei S. Ab Initio-Based Kinetic Modeling for the Design of Molecular Catalysts: The Case of H2 Production Electrocatalysts Acs Catalysis. 5: 5436-5452. DOI: 10.1021/Acscatal.5B01152 |
0.554 |
|
| 2015 |
Labios LA, Weiss CJ, Egbert JD, Lense S, Bullock RM, Dougherty WG, Kassel WS, Mock MT. Synthesis and Protonation studies of molybdenum(0) bis(dinitrogen) complexes supported by diphosphine ligands containing pendant amines Zeitschrift Fur Anorganische Und Allgemeine Chemie. 641: 105-117. DOI: 10.1002/Zaac.201400119 |
0.781 |
|
| 2014 |
Das AK, Engelhard MH, Bullock RM, Roberts JA. A hydrogen-evolving Ni(P2N2)2 electrocatalyst covalently attached to a glassy carbon electrode: preparation, characterization, and catalysis. comparisons with the homogeneous analogue. Inorganic Chemistry. 53: 6875-85. PMID 24971843 DOI: 10.1021/Ic500701A |
0.362 |
|
| 2014 |
Liu T, Wang X, Hoffmann C, DuBois DL, Bullock RM. Heterolytic cleavage of hydrogen by an iron hydrogenase model: an Fe-Hâ‹…â‹…â‹…H-N dihydrogen bond characterized by neutron diffraction. Angewandte Chemie (International Ed. in English). 53: 5300-4. PMID 24757087 DOI: 10.1002/Anie.201402090 |
0.73 |
|
| 2014 |
Lewandowska-Andralojc A, Grills DC, Zhang J, Bullock RM, Miyazawa A, Kawanishi Y, Fujita E. Kinetic and mechanistic studies of carbon-to-metal hydrogen atom transfer involving Os-centered radicals: evidence for tunneling. Journal of the American Chemical Society. 136: 3572-8. PMID 24498925 DOI: 10.1021/Ja4123076 |
0.362 |
|
| 2014 |
Bullock RM, Appel AM, Helm ML. Production of hydrogen by electrocatalysis: making the H-H bond by combining protons and hydrides. Chemical Communications (Cambridge, England). 50: 3125-43. PMID 24448464 DOI: 10.1039/C3Cc46135A |
0.52 |
|
| 2014 |
Das P, Ho MH, O'Hagan M, Shaw WJ, Bullock RM, Raugei S, Helm ML. Controlling proton movement: electrocatalytic oxidation of hydrogen by a nickel(II) complex containing proton relays in the second and outer coordination spheres. Dalton Transactions (Cambridge, England : 2003). 43: 2744-54. PMID 24306451 DOI: 10.1039/C3Dt53074D |
0.522 |
|
| 2014 |
Wang X, Liu T, Bullock RM, Hoffmann C. Heterolytic Cleavage of H2 Revealed by Neutron Single Crystal Diffraction Acta Crystallographica Section a Foundations and Advances. 70: C922-C922. DOI: 10.1107/S2053273314090779 |
0.672 |
|
| 2014 |
Hulley EB, Helm ML, Bullock RM. Heterolytic cleavage of H2 by bifunctional manganese(i) complexes: Impact of ligand dynamics, electrophilicity, and base positioning Chemical Science. 5: 4729-4741. DOI: 10.1039/C4Sc01801J |
0.475 |
|
| 2014 |
Hou J, Fang M, Cardenas AJP, Shaw WJ, Helm ML, Bullock RM, Roberts JAS, O'Hagan M. Electrocatalytic H2 production with a turnover frequency >107 s-1: The medium provides an increase in rate but not overpotential Energy and Environmental Science. 7: 4013-4017. DOI: 10.1039/C4Ee01899K |
0.426 |
|
| 2014 |
Liu T, Dubois MR, Dubois DL, Bullock RM. Electrochemical oxidation of H2 catalyzed by ruthenium hydride complexes bearing P2N2 ligands with pendant amines as proton relays Energy and Environmental Science. 7: 3630-3639. DOI: 10.1039/C4Ee01262C |
0.731 |
|
| 2014 |
Bullock RM, Appel AM, Helm ML. Production of hydrogen by electrocatalysis: Making the H-H bond by combining protons and hydrides Chemical Communications. 50: 3125-3143. DOI: 10.1039/c3cc46135a |
0.32 |
|
| 2014 |
Fang M, Wiedner ES, Dougherty WG, Kassel WS, Liu T, Dubois DL, Bullock RM. Cobalt complexes containing pendant amines in the second coordination sphere as electrocatalysts for H2 production Organometallics. 33: 5820-5833. DOI: 10.1021/Om5004607 |
0.723 |
|
| 2014 |
Weiss CJ, Egbert JD, Chen S, Helm ML, Bullock RM, Mock MT. Protonation studies of a tungsten dinitrogen complex supported by a diphosphine ligand containing a pendant amine Organometallics. 33: 2189-2200. DOI: 10.1021/Om401127V |
0.763 |
|
| 2014 |
Heiden ZM, Chen S, Labios LA, Bullock RM, Walter ED, Tyson EL, Mock MT. Proton and electron additions to Iron(II) dinitrogen complexes containing pendant amines Organometallics. 33: 1333-1336. DOI: 10.1021/Om401089D |
0.764 |
|
| 2014 |
Darmon JM, Raugei S, Liu T, Hulley EB, Weiss CJ, Bullock RM, Helm ML. Iron complexes for the electrocatalytic oxidation of hydrogen: Tuning primary and secondary coordination spheres Acs Catalysis. 4: 1246-1260. DOI: 10.1021/Cs500290W |
0.663 |
|
| 2014 |
Chen S, Ho MH, Bullock RM, Dubois DL, Dupuis M, Rousseau R, Raugei S. Computing free energy landscapes: Application to Ni-based electrocatalysts with pendant amines for H2 production and oxidation Acs Catalysis. 4: 229-242. DOI: 10.1021/Cs401104W |
0.696 |
|
| 2013 |
Ho MH, Raugei S, Rousseau R, Dupuis M, Bullock RM. Evaluation of the Role of Water in the H2 Bond Formation by Ni(II)-Based Electrocatalysts. Journal of Chemical Theory and Computation. 9: 3505-14. PMID 26584107 DOI: 10.1021/Ct400396S |
0.447 |
|
| 2013 |
Bullock RM. Chemistry. Abundant metals give precious hydrogenation performance. Science (New York, N.Y.). 342: 1054-5. PMID 24288322 DOI: 10.1126/Science.1247240 |
0.38 |
|
| 2013 |
Wiedner ES, Appel AM, DuBois DL, Bullock RM. Thermochemical and mechanistic studies of electrocatalytic hydrogen production by cobalt complexes containing pendant amines. Inorganic Chemistry. 52: 14391-403. PMID 24261463 DOI: 10.1021/Ic4025475 |
0.609 |
|
| 2013 |
Das AK, Engelhard MH, Liu F, Bullock RM, Roberts JAS. The electrode as organolithium reagent: Catalyst-free covalent attachment of electrochemically active species to an azide-terminated glassy carbon electrode surface Inorganic Chemistry. 52: 13674-13684. PMID 24228741 DOI: 10.1021/Ic402247N |
0.31 |
|
| 2013 |
Wiedner ES, Roberts JA, Dougherty WG, Kassel WS, DuBois DL, Bullock RM. Synthesis and electrochemical studies of cobalt(III) monohydride complexes containing pendant amines. Inorganic Chemistry. 52: 9975-88. PMID 23945020 DOI: 10.1021/Ic401232G |
0.577 |
|
| 2013 |
van der Eide EF, Yang P, Bullock RM. Isolation of two agostic isomers of an organometallic cation: different structures and colors. Angewandte Chemie (International Ed. in English). 52: 10190-4. PMID 23897712 DOI: 10.1002/Anie.201305032 |
0.3 |
|
| 2013 |
Hulley EB, Welch KD, Appel AM, DuBois DL, Bullock RM. Rapid, reversible heterolytic cleavage of bound H2. Journal of the American Chemical Society. 135: 11736-9. PMID 23889300 DOI: 10.1021/Ja405755J |
0.637 |
|
| 2013 |
Mock MT, Chen S, O'Hagan M, Rousseau R, Dougherty WG, Kassel WS, Bullock RM. Dinitrogen reduction by a chromium(0) complex supported by a 16-membered phosphorus macrocycle. Journal of the American Chemical Society. 135: 11493-6. PMID 23865433 DOI: 10.1021/Ja405668U |
0.732 |
|
| 2013 |
Yang JY, Smith SE, Liu T, Dougherty WG, Hoffert WA, Kassel WS, Rakowski DuBois M, DuBois DL, Bullock RM. Two pathways for electrocatalytic oxidation of hydrogen by a nickel bis(diphosphine) complex with pendant amines in the second coordination sphere. Journal of the American Chemical Society. 135: 9700-12. PMID 23631473 DOI: 10.1021/Ja400705A |
0.734 |
|
| 2013 |
Heiden ZM, Chen S, Mock MT, Dougherty WG, Kassel WS, Rousseau R, Bullock RM. Protonation of ferrous dinitrogen complexes containing a diphosphine ligand with a pendent amine. Inorganic Chemistry. 52: 4026-39. PMID 23506204 DOI: 10.1021/Ic4000704 |
0.741 |
|
| 2013 |
Roberts JA, Bullock RM. Direct determination of equilibrium potentials for hydrogen oxidation/production by open circuit potential measurements in acetonitrile. Inorganic Chemistry. 52: 3823-35. PMID 23488870 DOI: 10.1021/Ic302461Q |
0.362 |
|
| 2013 |
Liu T, Dubois DL, Bullock RM. An iron complex with pendent amines as a molecular electrocatalyst for oxidation of hydrogen. Nature Chemistry. 5: 228-233. PMID 23422565 DOI: 10.1038/Nchem.1571 |
0.712 |
|
| 2013 |
Stewart MP, Ho MH, Wiese S, Lindstrom ML, Thogerson CE, Raugei S, Bullock RM, Helm ML. High catalytic rates for hydrogen production using nickel electrocatalysts with seven-membered cyclic diphosphine ligands containing one pendant amine. Journal of the American Chemical Society. 135: 6033-46. PMID 23384205 DOI: 10.1021/Ja400181A |
0.481 |
|
| 2013 |
van der Eide EF, Helm ML, Walter ED, Bullock RM. Structural and spectroscopic characterization of 17- and 18-electron piano-stool complexes of chromium. Thermochemical analyses of weak Cr-H bonds. Inorganic Chemistry. 52: 1591-603. PMID 23343354 DOI: 10.1021/Ic302460Y |
0.46 |
|
| 2013 |
Franz JA, O'Hagan M, Ho MH, Liu T, Helm ML, Lense S, Dubois DL, Shaw WJ, Appel AM, Raugei S, Bullock RM. Conformational dynamics and proton relay positioning in nickel catalysts for hydrogen production and oxidation Organometallics. 32: 7034-7042. DOI: 10.1021/Om400695W |
0.734 |
|
| 2013 |
Heiden ZM, Chen S, Mock MT, Dougherty WG, Kassel WS, Rousseau R, Bullock RM. Protonation of ferrous dinitrogen complexes containing a diphosphine ligand with a pendent amine Inorganic Chemistry. 52: 4026-4039. DOI: 10.1021/ic4000704 |
0.706 |
|
| 2013 |
Wiese S, Kilgore UJ, Ho MH, Raugei S, Dubois DL, Bullock RM, Helm ML. Hydrogen production using nickel electrocatalysts with pendant amines: Ligand effects on rates and overpotentials Acs Catalysis. 3: 2527-2535. DOI: 10.1021/Cs400638F |
0.631 |
|
| 2012 |
O'Hagan M, Ho MH, Yang JY, Appel AM, Rakowski DuBois M, Raugei S, Shaw WJ, DuBois DL, Bullock RM. Proton delivery and removal in [Ni(P(R)2N(R')2)2]2+ hydrogen production and oxidation catalysts. Journal of the American Chemical Society. 134: 19409-24. PMID 23072436 DOI: 10.1021/Ja307413X |
0.644 |
|
| 2012 |
van der Eide EF, Yang P, Walter ED, Liu T, Bullock RM. Dinuclear metalloradicals featuring unsupported metal-metal bonds. Angewandte Chemie (International Ed. in English). 51: 8361-4. PMID 22821475 DOI: 10.1002/Anie.201203531 |
0.551 |
|
| 2012 |
Pool DH, Stewart MP, O'Hagan M, Shaw WJ, Roberts JA, Bullock RM, DuBois DL. Acidic ionic liquid/water solution as both medium and proton source for electrocatalytic H2 evolution by [Ni(P2N2)2]2+ complexes. Proceedings of the National Academy of Sciences of the United States of America. 109: 15634-9. PMID 22685211 DOI: 10.1073/Pnas.1120208109 |
0.61 |
|
| 2012 |
Raugei S, Chen S, Ho MH, Ginovska-Pangovska B, Rousseau RJ, Dupuis M, DuBois DL, Bullock RM. The role of pendant amines in the breaking and forming of molecular hydrogen catalyzed by nickel complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 6493-506. PMID 22532421 DOI: 10.1002/Chem.201103346 |
0.624 |
|
| 2012 |
Liu T, Chen S, O'Hagan MJ, Rakowski DuBois M, Bullock RM, DuBois DL. Synthesis, characterization, and reactivity of Fe complexes containing cyclic diazadiphosphine ligands: the role of the pendant base in heterolytic cleavage of H2. Journal of the American Chemical Society. 134: 6257-72. PMID 22394350 DOI: 10.1021/Ja211193J |
0.721 |
|
| 2012 |
Weiss CJ, Groves AN, Mock MT, Dougherty WG, Kassel WS, Helm ML, DuBois DL, Bullock RM. Synthesis and reactivity of molybdenum and tungsten bis(dinitrogen) complexes supported by diphosphine chelates containing pendant amines. Dalton Transactions (Cambridge, England : 2003). 41: 4517-29. PMID 22344347 DOI: 10.1039/C2Dt12224C |
0.771 |
|
| 2012 |
Smith SE, Yang JY, DuBois DL, Bullock RM. Reversible electrocatalytic production and oxidation of hydrogen at low overpotentials by a functional hydrogenase mimic. Angewandte Chemie (International Ed. in English). 51: 3152-5. PMID 22334352 DOI: 10.1002/Anie.201108461 |
0.617 |
|
| 2012 |
Van Der Eide EF, Liu T, Camaioni DM, Walter ED, Bullock RM. Facile thermal W-W bond homolysis in the N-heterocyclic carbene containing tungsten dimer [CpW(CO) 2(IMe)] 2 Organometallics. 31: 1775-1789. DOI: 10.1021/Om201162G |
0.617 |
|
| 2012 |
Wiedner ES, Yang JY, Chen S, Raugei S, Dougherty WG, Kassel WS, Helm ML, Bullock RM, DuBois MR, DuBois DL. Stabilization of nickel complexes with Ni 0H-N bonding interactions using sterically demanding cyclic diphosphine ligands Organometallics. 31: 144-156. DOI: 10.1021/Om200709Z |
0.658 |
|
| 2012 |
Wiese S, Kilgore UJ, Dubois DL, Bullock RM. [Ni(P Me 2N Ph 2) 2] (BF 4) 2 as an electrocatalyst for H 2 production Acs Catalysis. 2: 720-727. DOI: 10.1021/Cs300019H |
0.658 |
|
| 2012 |
Raugei S, Chen S, Ho M, Ginovska-Pangovska B, Rousseau RJ, Dupuis M, DuBois DL, Bullock RM. Inside Cover: The Role of Pendant Amines in the Breaking and Forming of Molecular Hydrogen Catalyzed by Nickel Complexes (Chem. Eur. J. 21/2012) Chemistry - a European Journal. 18: 6402-6402. DOI: 10.1002/Chem.201290084 |
0.419 |
|
| 2011 |
Kilgore UJ, Stewart MP, Helm ML, Dougherty WG, Kassel WS, DuBois MR, DuBois DL, Bullock RM. Studies of a series of [Ni(P(R)2N(Ph)2)2(CH3CN)]2+ complexes as electrocatalysts for H2 production: substituent variation at the phosphorus atom of the P2N2 ligand. Inorganic Chemistry. 50: 10908-18. PMID 21999814 DOI: 10.1021/Ic201461A |
0.625 |
|
| 2011 |
Mock MT, Chen S, Rousseau R, O'Hagan MJ, Dougherty WG, Kassel WS, DuBois DL, Bullock RM. A rare terminal dinitrogen complex of chromium. Chemical Communications (Cambridge, England). 47: 12212-4. PMID 21993453 DOI: 10.1039/C1Cc15430C |
0.771 |
|
| 2011 |
Helm ML, Stewart MP, Bullock RM, DuBois MR, DuBois DL. A synthetic nickel electrocatalyst with a turnover frequency above 100,000 s⁻¹ for H₂ production. Science (New York, N.Y.). 333: 863-6. PMID 21836012 DOI: 10.1126/Science.1205864 |
0.625 |
|
| 2011 |
Roberts JA, Franz JA, van der Eide EF, Walter ED, Petersen JL, DuBois DL, Bullock RM. Comproportionation of cationic and anionic tungsten complexes having an N-heterocyclic carbene ligand to give the isolable 17-electron tungsten radical CpW(CO)2(IMes)(•). Journal of the American Chemical Society. 133: 14593-603. PMID 21786753 DOI: 10.1021/Ja202754E |
0.676 |
|
| 2011 |
Roberts JA, Appel AM, DuBois DL, Bullock RM. Comprehensive thermochemistry of W-H bonding in the metal hydrides CpW(CO)2(IMes)H, [CpW(CO)2(IMes)H](•+), and [CpW(CO)2(IMes)(H)2]+. Influence of an N-heterocyclic carbene ligand on metal hydride bond energies. Journal of the American Chemical Society. 133: 14604-13. PMID 21780811 DOI: 10.1021/Ja202830W |
0.645 |
|
| 2011 |
O'Hagan M, Shaw WJ, Raugei S, Chen S, Yang JY, Kilgore UJ, DuBois DL, Bullock RM. Moving protons with pendant amines: proton mobility in a nickel catalyst for oxidation of hydrogen. Journal of the American Chemical Society. 133: 14301-12. PMID 21595478 DOI: 10.1021/Ja201838X |
0.652 |
|
| 2011 |
Dupuis M, Chen S, Raugei S, DuBois DL, Bullock RM. Comment on "New insights in the electrocatalytic proton reduction and hydrogen oxidation by bioinspired catalysts: a DFT investigation". The Journal of Physical Chemistry. A. 115: 4861-5. PMID 21504191 DOI: 10.1021/Jp111479Z |
0.625 |
|
| 2011 |
Kilgore UJ, Roberts JA, Pool DH, Appel AM, Stewart MP, DuBois MR, Dougherty WG, Kassel WS, Bullock RM, DuBois DL. [Ni(P(Ph)2N(C6H4X)2)2]2+ complexes as electrocatalysts for H2 production: effect of substituents, acids, and water on catalytic rates. Journal of the American Chemical Society. 133: 5861-72. PMID 21438562 DOI: 10.1021/Ja109755F |
0.617 |
|
| 2011 |
Yang JY, Bullock RM, DuBois MR, DuBois DL. Fast and efficient molecular electrocatalysts for H2 production: Using hydrogenase enzymes as guides Mrs Bulletin. 36: 39-47. DOI: 10.1557/Mrs.2010.8 |
0.574 |
|
| 2011 |
Chen S, Rousseau R, Raugei S, Dupuis M, DuBois DL, Bullock RM. Comprehensive thermodynamics of nickel hydride bis(diphosphine) complexes: A predictive model through computations Organometallics. 30: 6108-6118. DOI: 10.1021/Om200645X |
0.631 |
|
| 2011 |
Roberts JAS, Dubois DL, Bullock RM. Experimental and digital simulation studies of the electrochemical oxidation of the metal anion [CpW(CO)2(IMes)]- and the 17-electron metal radical CpW(CO)2(IMes)•. Kinetics and thermodynamics of capture and release of MeCN by a metal radical and a metal cation Organometallics. 30: 4555-4563. DOI: 10.1021/Om2002816 |
0.542 |
|
| 2011 |
Appel AM, Pool DH, O'Hagan M, Shaw WJ, Yang JY, Rakowski Dubois M, Dubois DL, Bullock RM. [Ni(PPh 2NBn 2) 2(CH3CN)]2+ as an electrocatalyst for H 2 production: Dependence on acid strength and isomer distribution Acs Catalysis. 1: 777-785. DOI: 10.1021/Cs2000939 |
0.563 |
|
| 2011 |
Raugei S, Chen S, Ho M, Rousseau R, Dupuis M, Dubois DL, Bullock RM. Ni(II) complexes for hydrogen oxidation and hydrogen production: An ab-initio molecular dynamics investigation Acs National Meeting Book of Abstracts. |
0.532 |
|
| 2011 |
Yang J, Smith SE, O'Hagan M, Kilgore UJ, Dubois MR, Bullock RM, Dubois DL. Molecular nickel diphosphine electrocatalysts for hydrogen oxidation and production: The function of proton relays in the secondary coordination sphere Acs National Meeting Book of Abstracts. |
0.523 |
|
| 2011 |
Bullock RM, Yang JY, Roberts JAS, Kilgore UJ, Helm ML, Smith SE, Stewart MP, Dubois DL. Nickel(II) electrocatalysts with pendant amines as proton relays for production of hydrogen and oxidation of hydrogen Acs National Meeting Book of Abstracts. |
0.52 |
|
| 2011 |
Bullock RM, Yang JY, Roberts JAS, Kilgore UJ, Wiedner ES, Liu T, Dubois DL. Nickel and cobalt catalysts for production of H2 and oxidation of H2: Shoving protons around with pendant amines Acs National Meeting Book of Abstracts. |
0.577 |
|
| 2011 |
Mock MT, Groves AN, Weiss CJ, Chen S, Rousseau R, Dubois DL, Bullock RM. Group 6 dinitrogen complexes supported by diphosphine ligands containing proton relays: Toward the reduction of dinitrogen to ammonia Acs National Meeting Book of Abstracts. |
0.747 |
|
| 2011 |
Yang JY, O'Hagan M, Shaw W, Appel A, Smith S, Bullock RM, DuBois MR, DuBois DL. Role of proton relays in molecular electrocatalysts for hydrogen oxidation and production Acs National Meeting Book of Abstracts. |
0.498 |
|
| 2010 |
Chen S, Raugei S, Rousseau R, Dupuis M, Bullock RM. Homogeneous Ni catalysts for H2 oxidation and production: an assessment of theoretical methods, from density functional theory to post Hartree-Fock correlated wave-function theory. The Journal of Physical Chemistry. A. 114: 12716-24. PMID 21070021 DOI: 10.1021/Jp106800N |
0.391 |
|
| 2010 |
Yang JY, Chen S, Dougherty WG, Kassel WS, Bullock RM, DuBois DL, Raugei S, Rousseau R, Dupuis M, Rakowski DuBois M. Hydrogen oxidation catalysis by a nickel diphosphine complex with pendant tert-butyl amines. Chemical Communications (Cambridge, England). 46: 8618-20. PMID 20938535 DOI: 10.1039/C0Cc03246H |
0.655 |
|
| 2010 |
Yang JY, Bullock RM, Dougherty WG, Kassel WS, Twamley B, DuBois DL, Rakowski DuBois M. Reduction of oxygen catalyzed by nickel diphosphine complexes with positioned pendant amines. Dalton Transactions (Cambridge, England : 2003). 39: 3001-10. PMID 20221533 DOI: 10.1039/B921245K |
0.589 |
|
| 2010 |
Fagan PJ, Voges MH, Bullock RM. Catalytic Ionic Hydrogenation of Ketones by {[Cp*Ru(CO)2]2(μ-H)}+ Organometallics. 29: 1045-1048. DOI: 10.1021/Om901005K |
0.464 |
|
| 2010 |
Welch KD, Dougherty WG, Kassel WS, Dubois DL, Bullock RM. Synthesis, structures, and reactions of manganese complexes containing diphosphine ligands with pendant amines Organometallics. 29: 4532-4540. DOI: 10.1021/Om100668E |
0.637 |
|
| 2010 |
Wiedner ES, Yang JY, Dougherty WG, Kassel WS, Bullock RM, Dubois MR, Dubois DL. Comparison of cobalt and nickel complexes with sterically demanding cyclic diphosphine ligands: Electrocatalytic H2 production by [Co(P tBu 2NPh 2)(CH3CN) 3](BF4)2 Organometallics. 29: 5390-5401. DOI: 10.1021/Om100395R |
0.644 |
|
| 2010 |
Dubois DL, Dubois MCR, Bullock RM. Modular approach to molecular electrocatalysts for H2 production and oxidation Acs National Meeting Book of Abstracts. |
0.504 |
|
| 2010 |
Bullock RM, Yang JY, Wiedner ES, Welch KD, Dubois DL. Molecular catalysts for oxidation of hydrogen and production of hydrogen: Shoving protons around with pendant amines Acs National Meeting Book of Abstracts. |
0.52 |
|
| 2010 |
Rakowski-DuBois M, Dubois D, Bullock RM. Nickel catalysts for hydrogen oxidation and production containing diphosphine ligands with pendant amine bases Acs National Meeting Book of Abstracts. |
0.546 |
|
| 2009 |
Ghosh P, Fagan PJ, Marshall WJ, Hauptman E, Bullock RM. Synthesis of ruthenium carbonyl complexes with phosphine or substituted Cp ligands, and their activity in the catalytic deoxygenation of 1,2-propanediol. Inorganic Chemistry. 48: 6490-500. PMID 19548688 DOI: 10.1021/Ic900413Y |
0.689 |
|
| 2009 |
Yang JY, Bullock RM, Shaw WJ, Twamley B, Fraze K, DuBois MR, DuBois DL. Mechanistic insights into catalytic h(2) oxidation by ni complexes containing a diphosphine ligand with a positioned amine base. Journal of the American Chemical Society. 131: 5935-45. PMID 19341269 DOI: 10.1021/Ja900483X |
0.68 |
|
| 2009 |
Schlaf M, Ghosh P, Fagan P, Hauptman E, Bullock RM. Catalytic Deoxygenation of 1,2-Propanediol to Given-Propanol Advanced Synthesis & Catalysis. 351: 789-800. DOI: 10.1002/Adsc.200800685 |
0.706 |
|
| 2008 |
Jacobsen GM, Yang JY, Twamley B, Wilson AD, Bullock RM, Rakowski Dubois M, Dubois DL. Hydrogen production using cobalt-based molecular catalysts containing a proton relay in the second coordination sphere Energy and Environmental Science. 1: 167-174. DOI: 10.1039/B805309J |
0.629 |
|
| 2008 |
Cheng TY, Szalda DJ, Hanson JC, Muckerman JT, Bullock RM. Four-electron-donor hemilabile η3-PPh3 ligand that binds through a C=C bond rather than an agostic C-H interaction, and displacement of the C=C by methyl iodide or water Organometallics. 27: 3785-3795. DOI: 10.1021/Om800401D |
0.433 |
|
| 2007 |
Bullock RM. An iron catalyst for ketone hydrogenations under mild conditions. Angewandte Chemie (International Ed. in English). 46: 7360-3. PMID 17847139 DOI: 10.1002/Anie.200703053 |
0.384 |
|
| 2007 |
Wu F, Dioumaev VK, Szalda DJ, Hanson J, Bullock RM. A tungsten complex with a bidentate, hemilabile N-heterocyclic carbene ligand, facile displacement of the weakly bound W-(C=C) bond, and the vulnerability of the NHC ligand toward catalyst deactivation during ketone hydrogenation Organometallics. 26: 5079-5090. DOI: 10.1021/Om700694E |
0.524 |
|
| 2007 |
Egbert JD, Bullock RM, Heinekey DM. Cationic dihydrogen/dihydride complexes of osmium: Structure and dynamics Organometallics. 26: 2291-2295. DOI: 10.1021/Om0700718 |
0.458 |
|
| 2006 |
Cheng TY, Szalda DJ, Zhang J, Bullock RM. Synthesis and structure of CpMo(CO)(dppe)H and its oxidation by Ph3C+. Inorganic Chemistry. 45: 4712-20. PMID 16749835 DOI: 10.1021/Ic060111K |
0.476 |
|
| 2005 |
Zhang J, Grills DC, Huang KW, Fujita E, Bullock RM. Carbon-to-metal hydrogen atom transfer: direct observation using time-resolved infrared spectroscopy. Journal of the American Chemical Society. 127: 15684-5. PMID 16277493 DOI: 10.1021/Ja0555724 |
0.4 |
|
| 2005 |
Kimmich BFM, Fagan PJ, Hauptman E, Marshall WJ, Bullock RM. Molybdenum carbonyl complexes in the solvent-free catalytic hydrogenation of ketones Organometallics. 24: 6220-6229. DOI: 10.1021/Om050564H |
0.47 |
|
| 2004 |
Bullock RM. Catalytic ionic hydrogenations. Chemistry (Weinheim An Der Bergstrasse, Germany). 10: 2366-74. PMID 15146510 DOI: 10.1002/Chem.200305639 |
0.413 |
|
| 2004 |
Kimmich BF, Fagan PJ, Hauptman E, Bullock RM. Solvent-free ketone hydrogenations catalyzed by molybdenum complexes. Chemical Communications (Cambridge, England). 1014-5. PMID 15069521 DOI: 10.1039/B401760A |
0.376 |
|
| 2003 |
Dioumaev VK, Bullock RM. A recyclable catalyst that precipitates at the end of the reaction. Nature. 424: 530-2. PMID 12891351 DOI: 10.1038/Nature01856 |
0.31 |
|
| 2003 |
Dioumaev VK, Szalda DJ, Hanson J, Franz JA, Bullock RM. An N-heterocyclic carbene as a bidentate hemilabile ligand: A synchrotron X-ray diffraction and density functional theory study Chemical Communications. 9: 1670-1671. DOI: 10.1039/B303762B |
0.393 |
|
| 2002 |
Voges MH, Bullock RM. Catalytic ionic hydrogenations of ketones using molybdenum and tungsten complexes Journal of the Chemical Society, Dalton Transactions. 759-770. DOI: 10.1039/B107754F |
0.468 |
|
| 2002 |
Cheng TY, Bullock RM. Hydride transfer from (η5-C5Me5)(CO)2MH (M = Fe, Ru, Os) to trityl cation: Different products from different metals and the kinetics of hydride transfer Organometallics. 21: 2325-2331. DOI: 10.1021/Om020012O |
0.345 |
|
| 2002 |
Kimmich BFM, Bullock RM. Protonation of (PCP)PtH to give a dihydrogen complex Organometallics. 21: 1504-1507. DOI: 10.1021/Om0108651 |
0.469 |
|
| 2002 |
Kimmich BF, Marshall WJ, Fagan PJ, Hauptman E, Bullock R. Palladium complexes with PCP ligands. Inorganica Chimica Acta. 330: 52-58. DOI: 10.1016/S0020-1693(01)00736-8 |
0.401 |
|
| 2001 |
Schlaf M, Ghosh P, Fagan PJ, Hauptman E, Bullock RM. Metal-Catalyzed Selective Deoxygenation of Diols to Alcohols. Angewandte Chemie (International Ed. in English). 40: 3887-3890. PMID 29712139 DOI: 10.1002/1521-3773(20011015)40:20<3887::Aid-Anie3887>3.0.Co;2-Q |
0.646 |
|
| 2001 |
Schlaf M, Ghosh P, Fagan PJ, Hauptman E, Bullock RM. Metal-Catalyzed Selective Deoxygenation of Diols to Alcohols We thank the U.S. Department of Energy, Office of Science, Laboratory Technology Research Program for support. Research at Brookhaven National Laboratory was carried out under contract DE-AC02-98CH10886 with the U.S. Department of Energy and was additionally supported by its Division of Chemical Sciences, Office of Basic Energy Sciences. We thank Dupont Central Research and Development for additional funding. M.S. thanks the NSERC (Canada) for a postdoctoral fellowship. Angewandte Chemie (International Ed. in English). 40: 3887-3890. PMID 11668564 DOI: 10.1002/1521-3773(20011015)40:20<3887::AID-ANIE3887>3.0.CO;2-Q |
0.485 |
|
| 2001 |
Song JS, Szalda DJ, Bullock RM. Alcohol complexes of tungsten prepared by ionic hydrogenations of ketones Organometallics. 20: 3337-3346. DOI: 10.1021/Om010222L |
0.413 |
|
| 2001 |
Cabelli DE, Shafiq F, Creutz C, Bullock RM. Pulse radiolysis studies of water-soluble tungsten hydride complexes: One-electron reduction of metal hydrides and hydrogen atom transfer reactions Organometallics. 20: 3729-3737. DOI: 10.1021/Om0102089 |
0.358 |
|
| 2000 |
Shafiq F, Szalda DJ, Creutz C, Bullock RM. Water-Soluble Tungsten Hydrides: Synthesis, Structures, and Reactions of (C5H4CO2H)(CO)3WH and Related Complexes Organometallics. 19: 824-833. DOI: 10.1021/Om990778X |
0.411 |
|
| 2000 |
Bullock RM, Voges MH. Homogeneous catalysis with inexpensive metals: Ionic hydrogenation of ketones with molybdenum and tungsten catalysts Journal of the American Chemical Society. 122: 12594-12595. DOI: 10.1021/Ja0010599 |
0.36 |
|
| 1999 |
Cheng TY, Szalda DJ, Bullock RM. An uncommon bonding mode of a familiar ligand: a molybdenum complex with a four-electron donor chelating η3-PPh3 ligand, and its structural determination using synchrotron radiation Chemical Communications. 1999: 1629-1630. DOI: 10.1039/A905092B |
0.373 |
|
| 1999 |
Cheng TY, Bullock RM. Isotope effects on hydride transfer reactions from transition metal hydrides to trityl cation. An inverse isotope effect for a hydride transfer Journal of the American Chemical Society. 121: 3150-3155. DOI: 10.1021/Ja983448X |
0.347 |
|
| 1998 |
Cheng TY, Brunschwig BS, Bullock RM. Hydride transfer reactions of transition metal hydrides: Kinetic hydricity of metal carbonyl hydrides Journal of the American Chemical Society. 120: 13121-13137. DOI: 10.1021/Ja9820036 |
0.379 |
|
| 1998 |
Abramov YA, Brammer L, Klooster WT, Bullock RM. Experimental Charge Density and Neutron Structural Study ofcis-HMn(CO)4PPh3: Comprehensive Analysis of Chemical Bonding and Evidence for a C−H···H−Mn Hydrogen Bond Inorganic Chemistry. 37: 6317-6328. DOI: 10.1021/Ic9809660 |
0.32 |
|
| 1996 |
Bullock RM, Song J, Szalda DJ. Protonation of Metal Hydrides by Strong Acids. Formation of an Equilibrium Mixture of Dihydride and Dihydrogen Complexes from Protonation of Cp*Os(CO)2H. Structural Characterization of [CpW(CO)2(PMe3)(H)2]+OTf− Organometallics. 15: 2504-2516. DOI: 10.1021/Om950976Y |
0.458 |
|
| 1995 |
Luan L, Song J, Bullock RM. Ionic Hydrogenation of Alkynes by HOTf and Cp(CO)3WH The Journal of Organic Chemistry. 60: 7170-7176. DOI: 10.1021/Jo00127A023 |
0.392 |
|
| 1994 |
Bullock RM, Song J. Ionic Hydrogenations of Hindered Olefins at Low Temperature. Hydride Transfer Reactions of Transition Metal Hydrides Journal of the American Chemical Society. 116: 8602-8612. DOI: 10.1021/Ja00098A021 |
0.353 |
|
| 1993 |
Lichtenberger DL, Renshaw SK, Bullock RM. Metal-acetylide bonding in (.eta.5-C5H5)Fe(CO)2C.tplbond.CR compounds. Measures of metal-d.pi.-acetylide-.pi. interactions from photoelectron spectroscopy Journal of the American Chemical Society. 115: 3276-3285. DOI: 10.1021/Ja00061A028 |
0.393 |
|
| 1993 |
Brammer L, Zhao D, Bullock RM, McMullan RK. X-ray and neutron diffraction studies of tricarbonyl(.eta.-pentamethylcyclopentadienyl)hydridomolybdenum at 163 K Inorganic Chemistry. 32: 4819-4824. DOI: 10.1021/Ic00074A027 |
0.353 |
|
| 1992 |
Brammer L, McCann MC, Bullock RM, McMullan RK, Sherwood P. Et3NH+Co(CO)4-: hydrogen-bonded adduct or simple ion pair? Single-crystal neutron diffraction study at 15 K Organometallics. 11: 2339-2341. DOI: 10.1021/Om00043A009 |
0.413 |
|
| 1992 |
Lemke FR, Szalda DJ, Bullock RM. Insertion of isocyanides into the carbon-zirconium bond of ruthenium/zirconium dimetalloalkenes. Spectroscopic and structural comparisons of the .eta.2-iminoacyl complexes Cp(PMe3)2RuCH:CRC(NBu-tert)ZrClCp2 (R = H vs. R = Me) and kinetics of isomerization of a thermodynamically unstable .eta.2-iminoacyl complex Organometallics. 11: 876-884. DOI: 10.1021/Om00038A056 |
0.318 |
|
| 1992 |
Bullock RM, Brammer L, Schultz AJ, Albinati A, Koetzle TF. Low-temperature neutron diffraction study of HMn2Re(CO)14 and studies of a metal metal exchange equilibrium that converts HMn2Re(CO)14 into HMnRe2(CO)14 Journal of the American Chemical Society. 114: 5125-5130. DOI: 10.1021/Ja00039A025 |
0.301 |
|
| 1992 |
Bullock RM, Rappoli BJ. Formation of a manganese alkyl complex as an intermediate in the ring-opening hydroformylation of α-cyclopropylstyrene by HMn(CO)5 Journal of Organometallic Chemistry. 429: 345-368. DOI: 10.1016/0022-328X(92)83184-J |
0.4 |
|
| 1992 |
Song JS, Szalda DJ, Bullock RM, Lawrie CJC, Rodkin MA, Norton JR. Hydride transfer by hydrido transition-metal complexes. Ionic hydrogenation of aldehydes and ketones, and structural characterization of an alcohol complex Angewandte Chemie (International Edition in English). 31: 1233-1235. DOI: 10.1002/Anie.199212331 |
0.591 |
|
| 1992 |
Song J, Szalda DJ, Bullock RM, Lawrie CJC, Rodkin MA, Norton JR. Hydridübertragung durch Hydridokomplexe, ionische Hydrierung von Aldehyden und Ketonen sowie Struktur eines Alkoholkomplexes Angewandte Chemie. 104: 1280-1282. DOI: 10.1002/Ange.19921040944 |
0.463 |
|
| 1991 |
Bullock RM. Metal-Hydrogen Bond Cleavage Reactions of Transition Metal Hydrides: Hydrogen Atom, Hydride, and Proton Transfer Reactions Comments On Inorganic Chemistry. 12: 1-33. DOI: 10.1080/02603599108018617 |
0.423 |
|
| 1991 |
Lemke FR, Szalda DJ, Bullock RM. Ruthenium/zirconium complexes containing C2 bridges with bond orders of 3, 2, and 1. Synthesis and structures of Cp(PMe3)2RuCHnCHnZrClCp2 (n = 0, 1, 2) Journal of the American Chemical Society. 113: 8466-8477. DOI: 10.1021/Ja00022A039 |
0.397 |
|
| 1991 |
Bullock RM, Rappoli BJ. Preparation and reactions of Mn2(CO)9(.eta.1-aldehyde) complexes Journal of the American Chemical Society. 113: 1659-1669. DOI: 10.1021/Ja00005A033 |
0.334 |
|
| 1991 |
Albinati A, Bullock RM, Rappoli BJ, Koetzle TF. X-ray diffraction study of pentacarbonyl(μ-hydrido)(nonacarbonyldimanganese)rhenium, HMn2Re(CO)14 Inorganic Chemistry. 30: 1414-1417. DOI: 10.1021/Ic00006A048 |
0.357 |
|
| 1990 |
Bullock RM, Samsel EG. Hydrogen atom transfer reactions of transition-metal hydrides. Kinetics and mechanism of the hydrogenation of .alpha.-cyclopropylstyrene by metal carbonyl hydrides Journal of the American Chemical Society. 112: 6886-6898. DOI: 10.1021/Ja00175A024 |
0.392 |
|
| 1990 |
Bullock RM, Lemke FR, Szalda DJ. Complexes containing a C2 bridge between an electron-rich metal and an electron-deficient metal. An agostic interaction in a RuCH2CH2Zr moiety Journal of the American Chemical Society. 112: 3244-3245. DOI: 10.1021/Ja00164A073 |
0.409 |
|
| 1989 |
Bullock RM, Rappoli BJ. Ionic hydrogenations using transition metal hydrides. Rapid hydrogenation of hindered alkenes at low temperature Journal of the Chemical Society, Chemical Communications. 1447-1448. DOI: 10.1039/C39890001447 |
0.41 |
|
| 1989 |
Anson CE, Johnson BFG, Lewis J, Powell DB, Sheppard N, Bhattacharyya AK, Bender BR, Bullock RM, Hembre RT, Norton JR. [Os2(CO)8(μ2-η2-C 2H4)] as a vibrational model for 1,2-di-σ chemisorbed ethylene on metal surfaces Journal of the Chemical Society, Chemical Communications. 703-705. DOI: 10.1039/C39890000703 |
0.574 |
|
| 1989 |
Bullock RM, Rappoli BJ, Samsel EG, Rheingold AL. Ring-opening hydroformylation of α-cyclopropylstyrene by HMn(CO) <inf>5</inf>, and structure of a novel Mn<inf>2</inf>(CO)<inf>9</inf>(η <sup>1</sup>-aldehyde) complex Journal of the Chemical Society, Chemical Communications. 261-263. DOI: 10.1039/C39890000261 |
0.368 |
|
| 1989 |
Bullock RM. Rearrangement of a metal (η<sup>2</sup>-alkyne) complex to a metal vinylidene and subsequent reaction of the metal vinylidene to regenerate the alkyne Journal of the Chemical Society, Chemical Communications. 165-167. DOI: 10.1039/C39890000165 |
0.382 |
|
| 1989 |
Bullock RM, Headford CEL, Hennessy KM, Kegley SE, Norton JR. Intramolecular hydrogen exchange among the coordinated methane fragments of Cp2W(H)CH3. Evidence for the formation of a .sigma. complex of methane prior to elimination Journal of the American Chemical Society. 111: 3897-3908. DOI: 10.1021/JA00193A022 |
0.338 |
|
| 1989 |
Bullock RM, Headford CEL, Hennessy KM, Kegley SE, Norton JR. Intramolecular hydrogen exchange among the coordinated methane fragments of Cp2W(H)CH3. Evidence for the formation of a σ complex of methane prior to elimination Journal of the American Chemical Society. 111: 3897-3908. DOI: 10.1021/Ja00193A022 |
0.636 |
|
| 1989 |
Bullock RM, Ricci JS, Szalda DJ. Hydroformylation of the C triple bond C bond of (C sub 5 H sub 5 )(PMe sub 3 ) sub 2 Ru-C triple bond C-CH sub 3 by HRe(CO) sub 5 to give an. eta. sup 1 -aldehyde complex of rhenium Journal of the American Chemical Society. 111: 2741-2743. DOI: 10.1021/Ja00189A072 |
0.347 |
|
| 1988 |
Bullock RM, Hembre RT, Norton JR. Synthesis of Os2(CO)8(μ-CHCH3) from a geminal ditriflate and its reversible carbonylation to a ketene-bridged diosmacycle Journal of the American Chemical Society. 110: 7868-7870. DOI: 10.1021/Ja00231A043 |
0.575 |
|
| 1987 |
Bullock RM. Proton transfer from metal hydrides to metal alkynyl complexes. Remarkable carbon basicity of (C5H5)(PMe3)2RuC.tplbond.CCMe3 Journal of the American Chemical Society. 109: 8087-8089. DOI: 10.1021/Ja00260A025 |
0.383 |
|
| 1987 |
Bullock RM, Samsel EG. Hydrogen atom transfer reactions of transition-metal hydrides. Utilization of a radical rearrangement in the determination of hydrogen atom transfer rates Journal of the American Chemical Society. 109: 6542-6544. DOI: 10.1021/Ja00255A067 |
0.363 |
|
| 1987 |
Bullock RM, Casey CP. Heterobimetallic compounds linked by heterodifunctional ligands Accounts of Chemical Research. 20: 167-173. DOI: 10.1021/Ar00137A002 |
0.487 |
|
| 1985 |
Bullock RM, Headford CEL, Kegley SE, Norton JR. Hydrogen exchange between the methyl and hydride ligands of dicyclopentadienylhydridomethyltungsten prior to methane elimination Journal of the American Chemical Society. 107: 727-729. DOI: 10.1021/Ja00289A048 |
0.6 |
|
| 1984 |
Casey CP, Bullock RM. Photochemical hydrogenolysis of the phosphorus-cyclopentadienyl bond of [cyclic] (CO)4MnMo(CO)3[.eta.5-C5H4P(C6H4Me-p)2] and formation of the phosphido-bridged metal hydride complex (CO)4Mn[.mu.-P(C6H4Me-p)2](.mu.-H)Mo(CO)2(C5H5) Organometallics. 3: 1100-1104. DOI: 10.1021/Om00085A023 |
0.582 |
|
| 1983 |
Casey CP, Bullock RM, Nief F. Synthesis of molybdenum-rhodium and molybdenum-iridium compounds linked by a heterodifunctional ligand and formation of molybdenum-iridium dihydrides by reaction with molecular hydrogen Journal of the American Chemical Society. 105: 7574-7580. DOI: 10.1021/Ja00364A019 |
0.551 |
|
| 1983 |
Casey CP, Bullock RM. Protonation of metalmetal bonds in heterobimetallic compounds linked by a heterodifunctional ligand Journal of Organometallic Chemistry. 251: 245-248. DOI: 10.1016/S0022-328X(00)99507-X |
0.535 |
|
| 1982 |
Casey CP, Bullock RM, Fultz WC, Rheingold AL. Heterobimetallic compounds linked by heterodifunctional ligands: synthesis and x-ray crystal structure of (CO)4MnMo(CO)3(.eta.5-C5H4PPh2) Organometallics. 1: 1591-1596. DOI: 10.1021/Om00072A008 |
0.479 |
|
| 1981 |
Casey CP, Bullock RM. Fluxional behavior of (CO)4Fe(u-AsMe2)Mo(CO)2(C5H5) Journal of Organometallic Chemistry. 218. DOI: 10.1016/S0022-328X(00)81015-3 |
0.468 |
|
| 1980 |
Walsh JL, Bullock RM, Meyer TJ. Alkyl nitrite complexes of ruthenium prepared by acid-base chemistry at the bound nitrosyl group Inorganic Chemistry. 19: 865-869. DOI: 10.1021/Ic50206A015 |
0.339 |
|
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