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John M. Brown - Publications

Affiliations: 
Chemistry University of Oxford, Oxford, United Kingdom 
Area:
enantioselective synthesis
Website:
http://research.chem.ox.ac.uk/john-brown.aspx
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Year Citation  Score
2020 Ibba F, Pupo G, Thompson AL, Brown JM, Claridge TDW, Gouverneur V. Impact of Multiple Hydrogen Bonds with Fluoride on Catalysis: Insight from NMR Spectroscopy. Journal of the American Chemical Society. PMID 33166450 DOI: 10.1021/jacs.0c09832  0.526
2019 Pupo G, Vicini AC, Ascough DMH, Ibba F, Christensen KE, Thompson AL, Brown JM, Paton RS, Gouverneur V. Hydrogen Bonding Phase-Transfer Catalysis with Potassium Fluoride: Enantioselective Synthesis of β-Fluoroamines. Journal of the American Chemical Society. PMID 30689372 DOI: 10.1021/Jacs.8B12568  0.575
2019 Brown JM. Ronald Charles David Breslow. 14 March 193125 October 2017 Biographical Memoirs of Fellows of the Royal Society. 66: 53-77. DOI: 10.1098/Rsbm.2018.0039  0.309
2018 Pupo G, Ibba F, Ascough DMH, Vicini AC, Ricci P, Christensen KE, Pfeifer L, Morphy JR, Brown JM, Paton RS, Gouverneur V. Asymmetric nucleophilic fluorination under hydrogen bonding phase-transfer catalysis. Science (New York, N.Y.). 360: 638-642. PMID 29748281 DOI: 10.1126/Science.Aar7941  0.569
2017 Rauf W, Brown JM. Mechanisms for C(sp(2))-Si activation of aryltrimethylsilyl groups in palladium-catalysed couplings. Organic & Biomolecular Chemistry. PMID 28926074 DOI: 10.1039/C7Ob01675A  0.749
2016 Pfeifer L, Engle KM, Pidgeon GW, Sparkes HA, Thompson AL, Brown JM, Gouverneur VE. Hydrogen-Bonded Homoleptic Fluoride-Diarylurea Complexes: Structure, Reactivity and Coordinating Power. Journal of the American Chemical Society. PMID 27608274 DOI: 10.1021/Jacs.6B07501  0.736
2016 Rauf W, Brown JM. Palladium-catalysed directed C-H activation by anilides and ureas; water participation in a general base mechanism. Organic & Biomolecular Chemistry. PMID 27184358 DOI: 10.1039/C6Ob00897F  0.753
2015 Engle KM, Pfeifer L, Pidgeon GW, Giuffredi GT, Thompson AL, Paton RS, Brown JM, Gouverneur V. Coordination diversity in hydrogen-bonded homoleptic fluoride-alcohol complexes modulates reactivity. Chemical Science. 6: 5293-5302. PMID 29449931 DOI: 10.1039/C5Sc01812A  0.696
2015 Pubill-Ulldemolins C, Fernánez E, Bo C, Brown JM. Origins of observed reactivity and specificity in the addition of B2Cl4 and analogues to unsaturated compounds. Organic & Biomolecular Chemistry. 13: 9619-28. PMID 26260922 DOI: 10.1039/C5Ob01280E  0.357
2014 Fernández E, Guiry PJ, Connole KP, Brown JM. Quinap and congeners: atropos PN ligands for asymmetric catalysis. The Journal of Organic Chemistry. 79: 5391-400. PMID 24806741 DOI: 10.1021/Jo500512S  0.612
2014 Emer E, Pfeifer L, Brown JM, Gouverneur V. cis-Specific hydrofluorination of alkenylarenes under palladium catalysis through an ionic pathway. Angewandte Chemie (International Ed. in English). 53: 4181-5. PMID 24644083 DOI: 10.1002/Anie.201310056  0.776
2014 Kurbangalieva A, Carmichael D, Hii KK, Jutand A, Brown JM. Oxidative addition to palladium(0) diphosphine complexes: observations of mechanistic complexity with iodobenzene as reactant. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 1116-25. PMID 24375651 DOI: 10.1002/Chem.201301937  0.458
2014 Brown JM, Pfaltz A, Van Santen RA. Mechanistic studies in catalysis Catalysis Science and Technology. 4: 3408. DOI: 10.1039/C4Cy90040E  0.51
2014 Brown JM. Rhodium asymmetric hydrogenation observed during its exponential growth phase Organometallics. 33: 5912-5923. DOI: 10.1021/Om500780C  0.355
2013 Rauf W, Brown JM. Reactive intermediates in catalytic alkenylation; pathways for Mizoroki-Heck, oxidative Heck and Fujiwara-Moritani reactions. Chemical Communications (Cambridge, England). 49: 8430-40. PMID 23949625 DOI: 10.1039/C3Cc44842H  0.757
2013 Carroll MP, Guiry PJ, Brown JM. Meta-analysis in asymmetric catalysis. Influence of chelate geometry on the roles of PN chelating ligands. Organic & Biomolecular Chemistry. 11: 4591-601. PMID 23636132 DOI: 10.1039/C3Ob40360B  0.626
2013 Raskatov JA, Thompson AL, Cowley AR, Claridge TDW, Brown JM. Chiral recognition in contact ion-pairs; Observation, characterization and analysis Chemical Science. 4: 3140-3147. DOI: 10.1039/C3Sc51096D  0.675
2013 Benedetto E, Tredwell M, Hollingworth C, Khotavivattana T, Brown JM, Gouverneur V. Regio- and stereoretentive synthesis of branched, linear (E)- and (Z)-allyl fluorides from allyl carbonates under Ir-catalysis Chemical Science. 4: 89-96. DOI: 10.1039/C2Sc21789A  0.555
2012 Paton RS, Brown JM. Dinuclear palladium complexes--precursors or catalysts? Angewandte Chemie (International Ed. in English). 51: 10448-50. PMID 22968902 DOI: 10.1002/Anie.201205417  0.389
2012 Blessley G, Holden P, Walker M, Brown JM, Gouverneur V. Palladium-catalyzed substitution and cross-coupling of benzylic fluorides. Organic Letters. 14: 2754-7. PMID 22594918 DOI: 10.1021/Ol300977F  0.551
2012 Gosiewska S, Raskatov JA, Shintani R, Hayashi T, Brown JM. The origins of enantioselectivity in Rh-diene complex catalysed arylation of cyclohex-2-enones. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 80-4. PMID 22161767 DOI: 10.1002/Chem.201102421  0.696
2012 Benedetto E, Keita M, Tredwell M, Hollingworth C, Brown JM, Gouverneur V. Platinum-catalyzed substitution of allylic fluorides Organometallics. 31: 1408-1416. DOI: 10.1021/Om201029M  0.563
2011 Hollingworth C, Hazari A, Hopkinson MN, Tredwell M, Benedetto E, Huiban M, Gee AD, Brown JM, Gouverneur V. Palladium-catalyzed allylic fluorination. Angewandte Chemie (International Ed. in English). 50: 2613-7. PMID 21370349 DOI: 10.1002/Anie.201007307  0.544
2011 Raskatov JA, Brown JM, Thompson AL. Chiral selection in the formation of borates from racemic binaphthols and related diols Crystengcomm. 13: 2923-2929. DOI: 10.1107/S0108767311080998  0.659
2011 Thompson AL, Raskatov JA, Brown JM. Chiral selection in the formation of borates from racemic binaphthols and related diols Acta Crystallographica Section a Foundations of Crystallography. 67: C753-C754. DOI: 10.1107/S0108767311080998  0.633
2010 Quaranta M, Gehring T, Odell B, Brown JM, Blackmond DG. Unusual inverse temperature dependence on reaction rate in the asymmetric autocatalytic alkylation of pyrimidyl aldehydes. Journal of the American Chemical Society. 132: 15104-7. PMID 20942400 DOI: 10.1021/Ja103204W  0.326
2010 Rauf W, Thompson AL, Brown JM. Anilide activation of adjacent C-H bonds in the palladium-catalysed Fujiwara-Moritani reaction. Dalton Transactions (Cambridge, England : 2003). 39: 10414-21. PMID 20936231 DOI: 10.1039/C0Dt00378F  0.763
2010 Fanton G, Coles NM, Cowley AR, Flemming JP, Brown JM. Observation Of 2,7-Disubstitution In Palladium Catalysed Directed C-H Activation Of Indoles Heterocycles. 80: 895-901. DOI: 10.3987/Com-09-S(S)117  0.343
2010 Rauf W, Hazari A, Gouverneur V, Brown JM. Catalytic activation of hydrogen, silicon, and fluorine by transition-metal complexes Pure and Applied Chemistry. 82: 1415-1428. DOI: 10.1351/Pac-Con-09-10-37  0.789
2010 Raskatov JA, Thompson AL, Brown JM. Asymmetric catalysis with 7-ring chelate diphosphines: DIOP, BINAP and conformational mobility Tetrahedron Asymmetry. 21: 1737-1744. DOI: 10.1016/J.Tetasy.2010.04.030  0.676
2010 Brown JM, Rose M, Knight FI, Wienand A. Ruthenium diphosphine complexes for catalysis; a general synthesis and direct comparisons with rhodium complexes Recueil Des Travaux Chimiques Des Pays-Bas. 114: 242-251. DOI: 10.1002/Recl.19951140419  0.385
2009 Brown JM, Gouverneur V. Transition-metal-mediated reactions for C(sp2)-F bond construction: the state of play. Angewandte Chemie (International Ed. in English). 48: 8610-4. PMID 19827068 DOI: 10.1002/Anie.200902121  0.543
2009 Rauf W, Thompson AL, Brown JM. Comparative catalytic C-H vs. C-Si activation of arenes with Pd complexes directed by urea or amide groups. Chemical Communications (Cambridge, England). 3874-6. PMID 19662237 DOI: 10.1039/B905717J  0.733
2009 Hübers HW, Evenson KM, Hill C, Brown JM. The rotational spectrum of the NH+ radical in its X 2Pi and a 4Sigma- states. The Journal of Chemical Physics. 131: 034311. PMID 19624201 DOI: 10.1063/1.3160964  0.327
2009 Ma T, Butler C, Brown JM, Linton C, Steimle TC. Optical Zeeman spectroscopy of ytterbium monofluoride, YbF. The Journal of Physical Chemistry. A. 113: 8038-44. PMID 19555112 DOI: 10.1021/Jp903596G  0.592
2009 Halfen DT, Ziurys LM, Brown JM. Fine structure and hyperfine perturbations in the pure rotational spectrum of the VCl radical in its X 5Delta(r) state. The Journal of Chemical Physics. 130: 164301. PMID 19405573 DOI: 10.1063/1.3108538  0.34
2009 Jackson M, Zink LR, Towle JP, Riley N, Brown JM. The rotational spectrum of the FeD radical in its X (4)Delta state, measured by far-infrared laser magnetic resonance. The Journal of Chemical Physics. 130: 154311. PMID 19388750 DOI: 10.1063/1.3117182  0.324
2009 Hazari A, Gouverneur V, Brown JM. Palladium-catalyzed substitution of allylic fluorides. Angewandte Chemie (International Ed. in English). 48: 1296-9. PMID 19142916 DOI: 10.1002/Anie.200804310  0.553
2009 Rauf W, Brown JM. Catalytic Amide-Directed Palladadesilylation-Alkenylation Synlett. 2009: 3103-3106. DOI: 10.1055/S-0029-1218339  0.758
2009 Daniels DSB, Brown JM, Gayral M, Xu Y, Stewart MI. Disubstituted Benzenes fromAcyclic Precursors by a [5+1] Annulation Synlett. 2009: 1387-1390. DOI: 10.1055/S-0029-1217162  0.301
2009 Brown JM, Müller HSP. The rotational spectrum of the SH+ radical in its X3Σ− state Journal of Molecular Spectroscopy. 255: 68-71. DOI: 10.1016/J.Jms.2009.02.017  0.303
2009 Brown J, Gouverneur V. Übergangsmetall-vermittelte Reaktionen zum Aufbau von Csp2-F-Bindungen Angewandte Chemie. 121: 8762-8766. DOI: 10.1002/Ange.200902121  0.467
2009 Nguyen B, Brown JM. Stereoselectivity in the Rhodium‐Catalysed Reductions of Non‐Conjugated Dienes Advanced Synthesis & Catalysis. 351: 1333-1343. DOI: 10.1002/Adsc.200900013  0.353
2008 Punniyamurthy T, Mayr M, Dorofeev AS, Bataille CJ, Gosiewska S, Nguyen B, Cowley AR, Brown JM. Enantiomerically pure bicyclo[3.3.1]nona-2,6-diene as the sole source of enantioselectivity in BIPHEP-Rh asymmetric hydrogenation. Chemical Communications (Cambridge, England). 5092-4. PMID 18956032 DOI: 10.1039/B807669C  0.339
2008 Rauf W, Brown JM. Catalytic amide-mediated methyl transfer from silanes to alkenes in Fujiwara-Moritani oxidative coupling. Angewandte Chemie (International Ed. in English). 47: 4228-30. PMID 18431728 DOI: 10.1002/Anie.200800815  0.727
2008 Flemming JP, Berry MB, Brown JM. Sequential ortho-lithiations; the sulfoxide group as a relay to enable meta-substitution. Organic & Biomolecular Chemistry. 6: 1215-21. PMID 18362961 DOI: 10.1039/B716954J  0.312
2008 Harrison JJ, Brown JM, Chen J, Steimle TC, Sears TJ. The Zeeman effect on lines in the (1,0) band of the F4Δ- X4Δ transition of the FeH radical Astrophysical Journal. 679: 854-861. DOI: 10.1086/587169  0.586
2008 Mayr M, Bataille CJR, Gosiewska S, Raskatov JA, Brown JM. Synthesis and rhodium complexation of enantiomerically enriched bicyclo[3.3.1]nona-2,6-diene Tetrahedron Asymmetry. 19: 1328-1332. DOI: 10.1016/J.Tetasy.2008.05.009  0.682
2008 Müller HS, Löblein K, Hübner H, Hüttner W, Brown JM. The rotational spectrum of the NF2 free radical: Determination of molecular structure Journal of Molecular Spectroscopy. 251: 185-193. DOI: 10.1016/J.Jms.2008.02.014  0.305
2007 Harrison JJ, Brown JM, Flory MA, Sheridan PM, McLamarrah SK, Ziurys LM. The rotational spectrum of CoF in all three spin-orbit components of the X3Phi i state. The Journal of Chemical Physics. 127: 194308. PMID 18035884 DOI: 10.1063/1.2789427  0.307
2007 Hodges PJ, Ross AJ, Crozet P, Salami H, Brown JM. On the spin-orbit splitting of CuCl2 in its 2 Pi g ground state. The Journal of Chemical Physics. 127: 024309. PMID 17640130 DOI: 10.1063/1.2747239  0.301
2007 Han J, Hu S, Chen H, Utkin Y, Brown JM, Curl RF. Jet-cooled infrared spectrum of methoxy in the CH stretching region. Physical Chemistry Chemical Physics : Pccp. 9: 3725-34. PMID 17622407 DOI: 10.1039/B700502D  0.761
2007 Espino G, Kurbangalieva A, Brown JM. Aryl bromide/triflate selectivities reveal mechanistic divergence in palladium-catalysed couplings; the Suzuki-Miyaura anomaly. Chemical Communications (Cambridge, England). 1742-4. PMID 17457427 DOI: 10.1039/B701517H  0.3
2007 Espino G, Brown JM, Cowley AR. trans-Bromido[4,5-difluoro-2-(trifluoromethylsulfonyloxy)phenyl-κC1]bis(triphenylphosphine-κP)palladium(II) Acta Crystallographica Section E Structure Reports Online. 63: m2047-m2048. DOI: 10.1107/S1600536807031492  0.314
2007 Robinson A, Brown J, Flores-Mijangos J, Zink L, Jackson M. Spectroscopic study of the 14NH radical in vibrationally excited levels of the X3Σ− state by far infrared laser magnetic resonance Molecular Physics. 105: 639-662. DOI: 10.1080/00268970601162085  0.318
2007 Knochel P, Cheemala M, Gayral M, Brown J, Rossen K. New Paracyclophane Phosphine for Highly Enantioselective Ruthenium-Catalyzed Hydrogenation of Prochiral Ketones Synthesis. 2007: 3877-3885. DOI: 10.1055/S-2007-990917  0.341
2007 Gengler JJ, Steimle TC, Harrison JJ, Brown JM. An analysis of the rotational, fine and hyperfine effects in the (0, 0) band of the A7Π-X7Σ+ transition of manganese monohydride, MnH Journal of Molecular Spectroscopy. 241: 192-199. DOI: 10.1016/J.Jms.2006.12.010  0.581
2007 Barnes MP, Brown JM. Vibrational and rotational analyses of bands between 636 and 660 nm in the red system of CuCl2 Journal of Molecular Spectroscopy. 241: 200-219. DOI: 10.1016/J.Jms.2006.12.007  0.307
2006 Brown JM, Körsgen H, Beaton SP, Evenson KM. The rotational and fine-structure spectrum of FeH, studied by far-infrared laser magnetic resonance. The Journal of Chemical Physics. 124: 234309. PMID 16821920 DOI: 10.1063/1.2198843  0.327
2006 Hodges PJ, Brown JM, Varberg TD. The ultraviolet spectrum of the CoCl2 radical, studied at vibrational and rotational resolution. The Journal of Chemical Physics. 124: 204302. PMID 16774327 DOI: 10.1063/1.2188937  0.319
2006 Steimle TC, Chen J, Harrison JJ, Brown JM. A molecular-beam optical Stark study of lines in the (1,0) band of the F4delta(7/2)-X4delta(7/2) transition of iron monohydride, FeH. The Journal of Chemical Physics. 124: 184307. PMID 16709106 DOI: 10.1063/1.2194551  0.586
2006 Chen J, Gengler J, Steimle TC, Brown JM. Optical Zeeman spectroscopy of calcium monohydride Physical Review a - Atomic, Molecular, and Optical Physics. 73. DOI: 10.1103/Physreva.73.012502  0.582
2006 Gillett DA, Cooksy AL, Brown JM. Infrared laser magnetic resonance spectroscopy of the ν3 fundamental and associated hot bands of the NCO free radical Journal of Molecular Spectroscopy. 239: 190-200. DOI: 10.1016/J.Jms.2006.07.005  0.341
2006 Hodges PJ, Brown JM, Ashworth SH. Rotational and vibrational structure in the 288 nm band system of the FeCl2 radical Journal of Molecular Spectroscopy. 237: 205-217. DOI: 10.1016/J.Jms.2006.03.014  0.327
2005 Black A, Brown JM, Pichon C. Regiochemical control of the catalytic asymmetric hydroboration of 1,2-diarylalkenes. Chemical Communications (Cambridge, England). 5284-6. PMID 16244729 DOI: 10.1039/B508292G  0.32
2005 Carmichael D, Ricard L, Seeboth N, Brown JM, Claridge TD, Odell B. Synthesis, structure and dynamics of methoxynaphthalene-substituted phospha-ruthenocenes and -ferrocenes. Dalton Transactions (Cambridge, England : 2003). 2173-81. PMID 15957060 DOI: 10.1039/B418926D  0.306
2005 Capito E, Brown JM, Ricci A. Directed palladation: fine tuning permits the catalytic 2-alkenylation of indoles. Chemical Communications (Cambridge, England). 1854-6. PMID 15795765 DOI: 10.1039/B417035K  0.3
2005 Virgo WL, Steimle TC, Brown JM. Optical zeeman spectroscopy of the (0, 0) bands of the B 3Π-X3 Δ and A 3Φ-X 3Δ transitions of titanium monoxide, TiO Astrophysical Journal. 628: 567-573. DOI: 10.1086/431282  0.597
2005 Flores-Mijangos J, Ganser H, Brown JM. The infrared spectrum of the AsD radical in its X3Σ− state, recorded by laser magnetic resonance Journal of Molecular Spectroscopy. 232: 167-173. DOI: 10.1016/J.Jms.2005.04.001  0.351
2005 Farrington EJ, Barnard CFJ, Rowsell E, Brown JM. Ruthenium Complex-Catalysed Heck Reactions of Areneboronic Acids; Mechanism, Synthesis and Halide Tolerance Advanced Synthesis & Catalysis. 347: 185-195. DOI: 10.1002/Adsc.200404231  0.353
2004 Balfour WJ, Brown JM, Wallace L. Electronic spectra of iron monohydride in the infrared near 1.35 and 1.58 microm. The Journal of Chemical Physics. 121: 7735-42. PMID 15485234 DOI: 10.1063/1.1797731  0.324
2004 Deeth RJ, Smith A, Brown JM. Electronic control of the regiochemistry in palladium-phosphine catalyzed intermolecular Heck reactions. Journal of the American Chemical Society. 126: 7144-51. PMID 15174886 DOI: 10.1021/Ja0315098  0.359
2004 Gridnev ID, Brown JM. Asymmetric autocatalysis: novel structures, novel mechanism? Proceedings of the National Academy of Sciences of the United States of America. 101: 5727-31. PMID 15060283 DOI: 10.1073/Pnas.0308178101  0.33
2004 Pichon C, Odell B, Brown JM. A direct meta-lithiation route to 1,3-disubstituted ferrocenes. Chemical Communications (Cambridge, England). 598-9. PMID 14973626 DOI: 10.1039/B314641C  0.309
2004 Allen MD, Evenson KM, Brown JM. Part of the far-infrared laser magnetic resonance spectrum of the HF + free radical Journal of Molecular Spectroscopy. 227: 13-22. DOI: 10.1016/J.Jms.2004.05.001  0.335
2004 Flores-Mijangos J, Brown JM, Matsushima F, Odashima H, Takagi K, Zink LR, Evenson KM. The far-infrared spectrum of the 14NH radical in its X 3Σ - state Journal of Molecular Spectroscopy. 225: 189-195. DOI: 10.1016/J.Jms.2004.02.026  0.314
2004 Davidson SA, Evenson KM, Brown JM. The far-infrared laser magnetic resonance spectrum of the 13CH radical Journal of Molecular Spectroscopy. 223: 20-30. DOI: 10.1016/J.Jms.2003.09.002  0.305
2004 Virgo WL, Steimle TC, Aucoin LE, Brown JM. The permanent electric dipole moments of ruthenium monocarbide in the 3Π and 3Δ states Chemical Physics Letters. 391: 75-80. DOI: 10.1016/J.Cplett.2004.04.088  0.58
2004 Hii K, Claridge T, Giernoth R, Brown J. Conformationally Restricted Arene Intermediates in the Intermolecular Heck Arylation of Vinylarenes Advanced Synthesis & Catalysis. 346: 983-988. DOI: 10.1002/Adsc.200404072  0.785
2003 Gridnev ID, Serafimov JM, Quiney H, Brown JM. Reflections on spontaneous asymmetric synthesis by amplifying autocatalysis. Organic & Biomolecular Chemistry. 1: 3811-9. PMID 14649913 DOI: 10.1039/B307382N  0.335
2003 Steimle TC, Virgo WL, Brown JM. Permanent electric dipole moments and hyperfine interaction in ruthenium monocarbide, RuC Journal of Chemical Physics. 118: 2620-2625. DOI: 10.1063/1.1534586  0.563
2003 Lim CW, Tissot O, Mattison A, Hooper MW, Brown JM, Cowley AR, Hulmes DI, Blacker AJ. Practical preparation and resolution of 1-(2′-diphenylphosphino-1′-naphthyl)isoquinoline: A useful ligand for catalytic asymmetric synthesis Organic Process Research and Development. 7: 379-384. DOI: 10.1021/Op034007N  0.314
2003 Bedford RB, Hazelwood SL, Limmert ME, Brown JM, Ramdeehul S, Cowley AR, Coles SJ, Hursthouse MB. The Role of Ligand Transformations on the Performance of Phosphite- and Phosphinite-Based Palladium Catalysts in the Suzuki Reaction Organometallics. 22: 1364-1371. DOI: 10.1021/Om020941F  0.346
2003 Korostylev A, Gridnev I, Brown JM. Mechanistic and synthetic aspects of hydroboration with a simple atropisomeric ligand prepared from 1-(1′-(isoquinolyl)-2-naphthol Journal of Organometallic Chemistry. 680: 329-334. DOI: 10.1016/S0022-328X(03)00602-8  0.344
2003 Wienkoop M, Urban W, Towle JP, Brown JM, Evenson KM. Studies of the mid- and far-infrared laser magnetic resonance spectra of the CD radical: Information on vibrationally excited levels Journal of Molecular Spectroscopy. 218: 85-94. DOI: 10.1016/S0022-2852(02)00064-4  0.302
2003 Brown JM, Evans PL, James AP. Directed Homogeneous Hydrogenation: Methyl anti‐3‐Hydroxy‐2‐Methylpentanoate Organic Syntheses. 64-64. DOI: 10.1002/0471264180.Os068.09  0.309
2002 Galardon E, Ramdeehul S, Brown JM, Cowley A, Hii KK, Jutand A. Profound steric control of reactivity in aryl halide addition to bisphosphane palladium(0) complexes. Angewandte Chemie (International Ed. in English). 41: 1760-3. PMID 19750708 DOI: 10.1002/1521-3773(20020517)41:10<1760::Aid-Anie1760>3.0.Co;2-3  0.422
2002 Sheridan PM, Xin J, Ziurys LM, Beaton SA, Kermode SM, Brown JM. The pure rotational spectrum of NaC in its X 4Σ- state: Observation and interpretation Journal of Chemical Physics. 116: 5544-5550. DOI: 10.1063/1.1457441  0.336
2002 Kermode SM, Brown JM. Identification of New Low-Lying Electronic States of the FeF Radical Journal of Molecular Spectroscopy. 213: 158-169. DOI: 10.1006/Jmsp.2002.8564  0.336
2002 Maeda K, Farrington EJ, Galardon E, John BD, Brown JM. Competing Regiochemical Pathways in the Heck Arylation of 1,2‐Dihydronaphthalene Advanced Synthesis & Catalysis. 344: 104-109. DOI: 10.1002/1615-4169(200201)344:1<104::Aid-Adsc104>3.0.Co;2-V  0.338
2001 Tamassia F, Kermode SM, Brown JM. A Study of the (2-0) Overtone Bands of the FO, BrO, and IO Free Radicals by Laser Magnetic Resonance. Journal of Molecular Spectroscopy. 205: 92-101. PMID 11148112 DOI: 10.1006/Jmsp.2000.8240  0.316
2001 Adams NJ, Bargon J, Brown JM, Farrington EJ, Galardon E, Giernoth R, Heinrich H, John BD, Maeda K. Interplay of synthesis and mechanism in asymmetric homogeneous catalysis Pure and Applied Chemistry. 73: 343-346. DOI: 10.1351/Pac200173020343  0.777
2001 Breed PG, Ramsden JA, Brown JM. Scope and limitations of ruthenium-catalyzed metathesis of simple polymer-bound alkenes Canadian Journal of Chemistry. 79: 1049-1057. DOI: 10.1139/V01-045  0.313
2001 Jones WE, Sun F, Curl RF, Allen MD, Evenson KM, Brown JM. Far-infrared LMR spectroscopic investigation of the quasi-linear molecule DCCN: The v5(1 0) transition Canadian Journal of Physics. 79: 389-408. DOI: 10.1139/P00-069  0.329
2001 WILSON C, BROWN JM. The FeH radical: rotational assignment of the a6A Δ(ν = 2) and b6II (ν = 1) levels Molecular Physics. 99: 1549-1561. DOI: 10.1080/00268970110062620  0.303
2001 Heinrich H, Giernoth R, Bargon J, Brown JM. Observation of a stable cis-diphosphine solvate rhodium dihydride derived from PHANEPHOS Chemical Communications. 1296-1297. DOI: 10.1039/B102316K  0.752
2001 Tucker SC, Brown JM, Oakes J, Thornthwaite D. Resolution and coupling of 1-(2′-hydroxy-1′-naphthyl)isoquinolines Tetrahedron. 57: 2545-2554. DOI: 10.1016/S0040-4020(01)00064-3  0.301
2001 Wilson C, Brown JM. Evidence for a Strong Intercombination Transition in FeH at around 510 nm Journal of Molecular Spectroscopy. 209: 192-197. DOI: 10.1006/Jmsp.2001.8395  0.309
2001 Allen MD, Evenson KM, Brown JM. High-resolution spectroscopic measurements of the v5 bending vibration-rotation band of HCCN in its X̃3Σ- state at 129 cm-1 Journal of Molecular Spectroscopy. 209: 143-164. DOI: 10.1006/Jmsp.2001.8387  0.324
2001 Brown JM, Giernoth R. ChemInform Abstract: New Mechanistic Aspects of the Asymmetric Homogeneous Hydrogenation of Alkenes Cheminform. 32: no-no. DOI: 10.1002/chin.200119273  0.302
2001 Hii KK, Claridge TDW, Brown JM, Smith A, Deeth RJ. The intermolecular asymmetric Heck reaction: Mechanistic and computational studies Helvetica Chimica Acta. 84: 3043-3056. DOI: 10.1002/1522-2675(20011017)84:10<3043::Aid-Hlca3043>3.0.Co;2-V  0.439
2000 Price DW, Drew MG, Hii KK, Brown JM. The Chatt-Dewar-Duncanson model revisited: X-ray, DFT and NMR studies of rhodium-alkene binding--deviations from structural ideality. Chemistry (Weinheim An Der Bergstrasse, Germany). 6: 4587-96. PMID 11192092 DOI: 10.1002/1521-3765(20001215)6:24<4587::Aid-Chem4587>3.0.Co;2-6  0.441
2000 Fernandez E, Maeda K, Hooper MW, Brown JM. Catalytic asymmetric hydroboration/amination and alkylamination with rhodium complexes of 1,1'-(2-diarylphosphino-1-naphthyl)isoquinoline Chemistry (Weinheim An Der Bergstrasse, Germany). 6: 1840-6. PMID 10845644 DOI: 10.1002/(Sici)1521-3765(20000515)6:10<1840::Aid-Chem1840>3.0.Co;2-6  0.359
2000 Brown JM, Leppard SJ, Oakes J, Thornthwaite D. Diastereoselectivity in scalemic tartrate/titanium epoxidations Chirality. 12: 496-504. PMID 10824177 DOI: 10.1002/(Sici)1520-636X(2000)12:5/6<496::Aid-Chir35>3.0.Co;2-Y  0.305
2000 Allen MD, Evenson KM, Gillett DA, Brown JM. Far-Infrared Laser Magnetic Resonance Spectroscopic Study of the nu(2) Bending Fundamental of the CCN Radical in Its &Xtilde;(2)Pi(r) State. Journal of Molecular Spectroscopy. 201: 18-29. PMID 10753607 DOI: 10.1006/Jmsp.2000.8075  0.335
2000 Hughes RA, Brown JM, Evenson KM. Rotational Spectrum of the AsH(2) Radical in Its Ground State, Studied by Far-Infrared Laser Magnetic Resonance. Journal of Molecular Spectroscopy. 200: 210-228. PMID 10708534 DOI: 10.1006/Jmsp.1999.8037  0.339
2000 Braddock DC, Brown JM. Catalytic and Stoichiometric Lewis Acid Participation in Aldehyde Ene Cyclisations Collection of Czechoslovak Chemical Communications. 65: 741-756. DOI: 10.1135/Cccc20000741  0.413
2000 Tamassia F, Brown JM, Saito S. The detection of the free radical FO (X 2Π3/2) by submillimeter-wave spectroscopy Journal of Chemical Physics. 112: 5523-5526. DOI: 10.1063/1.481184  0.321
2000 Giernoth R, Heinrich H, Adams NJ, Deeth RJ, Bargon J, Brown JM. PHIP detection of a transient rhodium dihydride intermediate in the homogeneous hydrogenation of dehydroamino acids Journal of the American Chemical Society. 122: 12381-12382. DOI: 10.1021/Ja002516O  0.746
2000 Braddock DC, Brown JM. Asymmetric synthesis and Lewis acid mediated type II carbonyl ene cyclisations of (R)-2-isopropyl-5-methylhex-5-enal Tetrahedron-Asymmetry. 11: 3591-3607. DOI: 10.1016/S0957-4166(00)00316-5  0.393
1999 Whitham CJ, Jackson RJ, Brown JM. Rotational Spectra of Conformers and Isotopomers of 1-Hydroxynaphthalene Journal of Molecular Spectroscopy. 195: 172-176. PMID 10191162 DOI: 10.1006/Jmsp.1999.7808  0.318
1999 Tamassia F, Brown JM, Evenson KM. Fine-structure spectrum of the FO radical, observed by far-infrared laser magnetic resonance Journal of Chemical Physics. 110: 7273-7286. DOI: 10.1063/1.478630  0.31
1999 Körsgen H, Urban W, Brown JM. The infrared spectrum of FeH2, studied in the gas phase by laser magnetic resonance Journal of Chemical Physics. 110: 3861-3869. DOI: 10.1063/1.478240  0.315
1999 Carmichael D, Doucet H, Brown JM. Hybrid P-chiral diphosphines for asymmetric hydrogenation Chemical Communications. 261-262. DOI: 10.1039/A808711C  0.327
1999 Gaumont A, Brown JM, Hursthouse MB, Coles SJ. Isolation Of The Reactive Intermediate In Palladium-Catalysed Coupling Of Secondary Phosphine-Boranes With Aryl Halides Chemical Communications. 63-64. DOI: 10.1039/A807830K  0.309
1999 Jutand A, Hii KK, Thornton-Pett M, Brown JM. Factors affecting the oxidative addition of aryl electrophiles to 1,1′-bis(diphenylphosphino)ferrocenepalladium(η2-methyl acrylate), an isolable Pd[0] alkene complex Organometallics. 18: 5367-5374. DOI: 10.1021/Om9906417  0.435
1999 Jutand A, Hii KK(, Thornton-Pett M, Brown JM. Factors Affecting the Oxidative Addition of Aryl Electrophiles to 1,1‘-Bis(diphenylphosphino)ferrocenepalladium(η2-methyl acrylate), an Isolable Pd[0] Alkene Complex Organometallics. 18: 5367-5374. DOI: 10.1021/om9906417  0.285
1999 Doucet H, Fernandez E, Layzell TP, Brown JM. The Scope of Catalytic Asymmetric Hydroboration/Oxidation with Rhodium Complexes of 1,1′-(2-Diarylphosphino-1-naphthyl)isoquinolines Chemistry: a European Journal. 5: 1320-1330. DOI: 10.1002/(Sici)1521-3765(19990401)5:4<1320::Aid-Chem1320>3.0.Co;2-#  0.311
1998 Braddock DC, Hii KKM, Brown JM. Models for the Carbonyl-ene Cyclization Reaction: Open and Closed Transition States. Angewandte Chemie (International Ed. in English). 37: 1720-1723. PMID 29711498 DOI: 10.1002/(Sici)1521-3773(19980703)37:12<1720::Aid-Anie1720>3.0.Co;2-W  0.424
1998 Ashworth SH, Brown JM. Dispersed Fluorescence from the 460-nm Band System of NiCl2: Observation of a New, Low-Lying Electronic State. Journal of Molecular Spectroscopy. 191: 276-285. PMID 9753562 DOI: 10.1006/Jmsp.1998.7639  0.3
1998 Mürtz P, Zink LR, Evenson KM, Brown JM. Measurement of high-frequency rotational transitions of H2O+ in its ground state by far-infrared laser magnetic resonance (LMR) spectroscopy Journal of Chemical Physics. 109: 9744-9752. DOI: 10.1063/1.477644  0.336
1998 Farrington E, Franchini MC, Brown JM. Diastereoselective homogeneous hydrogenations without direction by substituents Chemical Communications. 277-278. DOI: 10.1039/A707025J  0.325
1998 Deeth RJ, Smith A, Hii KKM, Brown JM. The Heck olefination reaction; a DFT study of the elimination pathway Tetrahedron Letters. 39: 3229-3232. DOI: 10.1016/S0040-4039(98)00398-0  0.413
1998 Braddock DC, Hii KK(, Brown JM. Modelle für die Carbonyl-En-Cyclisierung: offene und geschlossene Übergangszustände Angewandte Chemie. 110: 1798-1801. DOI: 10.1002/(Sici)1521-3757(19980619)110:12<1798::Aid-Ange1798>3.0.Co;2-A  0.332
1997 Beaton SA, Brown JM. Laser Excitation Spectroscopy of the A 3 Piu -X ; 3 Sigmag - Transition of the NCN Radical Journal of Molecular Spectroscopy. 183: 347-359. PMID 9252305 DOI: 10.1006/Jmsp.1997.7286  0.311
1997 Körsgen H, Evenson KM, Brown JM. The bending vibration of FeD2 at 226 cm−1, detected by far-infrared laser magnetic resonance spectroscopy Journal of Chemical Physics. 107: 1025-1027. DOI: 10.1063/1.474432  0.31
1997 Goodridge DM, Carter RT, Brown JM, Steimle TC. Rotational analysis and assignment of the green band system of FeH to the e 6Π–a 6Δ transition The Journal of Chemical Physics. 106: 4823-4831. DOI: 10.1063/1.473531  0.598
1997 Steimle T, Marr AJ, Beaton SA, Brown JM. Molecular Beam Optical Zeeman Spectroscopy Of Iridium Mononitride Journal of Chemical Physics. 106: 2073-2077. DOI: 10.1063/1.473141  0.578
1997 Doucet H, Brown JM. Synthesis of 1′-(2-(diarylphosphino)1-naphthyl)isoquinolines; variation of the aryl substituent Tetrahedron-Asymmetry. 8: 3775-3784. DOI: 10.1016/S0957-4166(97)00556-9  0.356
1997 Brown JM, Golding BT, Barton DHR. An appreciation of Arthur Birch, 1915–1995 Tetrahedron. 53. DOI: 10.1016/S0040-4020(97)89737-2  0.315
1997 Knight FI, Brown JM, Lazzari D, Ricci A, Blacker AJ. Electrophilic amination of catecholboronate esters formed in the asymmetric hydroboration of vinylarenes Tetrahedron. 53: 11411-11424. DOI: 10.1016/S0040-4020(97)00722-9  0.303
1997 Claridge TDW, Long JM, Brown JM, Hibbs D, Hursthouse MB. Synthesis of 1-methyl-2-diphenylphosphino-3-(1'-isoquinolyl)indole; an easily racemised ligand giving insights into catalytic asymmetric allylation Tetrahedron. 53: 4035-4050. DOI: 10.1016/S0040-4020(97)00016-1  0.353
1997 Brown JM, Laing JCP. Nucleophilic displacement routes to P-chiral phosphines; The introduction of sterically encumbered groups Journal of Organometallic Chemistry. 529: 435-444. DOI: 10.1016/S0022-328X(96)06660-0  0.347
1997 Lakin NM, Varberg TD, Brown JM. The Detection of Lines in the Microwave Spectrum of Indium Hydroxide, InOH, and Its Isotopomers Journal of Molecular Spectroscopy. 183: 34-41. DOI: 10.1006/Jmsp.1996.7237  0.327
1997 Hii KK, Claridge TDW, Brown JM. Intermediates in the Intermolecular, Asymmetric Heck Arylation of Dihydrofurans Angewandte Chemie International Edition in English. 36: 984-987. DOI: 10.1002/Anie.199709841  0.458
1997 Hii KK, Claridge TDW, Brown JM. Zwischenstufen in der intramolekularen asymmetrischen Heck-Arylierung von Dihydrofuranen Angewandte Chemie. 109: 1033-1036. DOI: 10.1002/Ange.19971090925  0.333
1996 Körsgen H, Mürtz P, Lipus K, Urban W, Towle JP, Brown JM. The identification of the FeH2 radical in the gas phase by infrared spectroscopy Journal of Chemical Physics. 104: 4859-4861. DOI: 10.1063/1.471180  0.331
1996 Ashworth SH, Grieman FJ, Brown JM. Rotational analysis of bands in the 460 nm system of nickel dichloride produced in a free‐jet expansion: Determination of the structure and electronic ground state of nickel dichloride Journal of Chemical Physics. 104: 48-63. DOI: 10.1063/1.470875  0.313
1996 Brown JM, Hughes GD. Competing nickel-catalysed dimerisation and degenerate isomerisation of propene Inorganica Chimica Acta. 252: 229-237. DOI: 10.1016/S0020-1693(96)05317-0  0.319
1996 Berens U, Brown JM, Long J, Selke R. Synthesis and resolution of 2,2'-bis-diphenylphosphino [3,3']biindolyl ; a new atropisomeric ligand for transition metal catalysis Tetrahedron-Asymmetry. 7: 285-292. DOI: 10.1016/0957-4166(95)00447-5  0.329
1996 Allen MD, Ziurys LM, Brown JM. The millimeter-wave spectrum of FeO in its X5Δi state (v = 0): A study of all five spin components Chemical Physics Letters. 257: 130-136. DOI: 10.1016/0009-2614(96)00521-0  0.321
1996 Hensel KD, Brown JM. The ν3Band of the NCN Radical, Studied by LMR Journal of Molecular Spectroscopy. 180: 170-174. DOI: 10.1006/Jmsp.1996.0238  0.325
1996 Fink EH, Setzer KD, Ramsay DA, Towle JP, Brown JM. High-Resolution Study of theX21 →X10+Fine-Structure Transition of BiF☆ Journal of Molecular Spectroscopy. 178: 143-156. DOI: 10.1006/Jmsp.1996.0168  0.312
1996 Beaton SA, Ito Y, Brown JM. Laser Excitation Spectroscopy of theÃ3Πu–X3Σ−gTransition of the NCN Radical Journal of Molecular Spectroscopy. 178: 99-107. DOI: 10.1006/Jmsp.1996.0162  0.302
1996 Brown JM, Hii KK. Characterization of Reactive Intermediates in Palladium-Catalyzed Arylation of Methyl Acrylate(Heck Reaction) Angewandte Chemie International Edition in English. 35: 657-659. DOI: 10.1002/Anie.199606571  0.427
1995 Hensel KD, Hughes RA, Brown JM. IR spectrum of the AsH radical in its X3Σ–state, recorded by laser magnetic resonance Journal of the Chemical Society, Faraday Transactions. 91: 2999-3004. DOI: 10.1039/Ft9959102999  0.318
1995 Ramsden JA, Claridge TDW, Brown JM. Structure and dynamics of intermediates in asymmetric hydrogenation by rhodium complexes of (2-methoxyphenyl)-P-phenyl-P-(2′-diphenylphosphino)ethylphosphine Journal of the Chemical Society, Chemical Communications. 2469-2471. DOI: 10.1039/C39950002469  0.349
1995 Alcock NW, Hulmes DI, Brown JM. Contrasting behaviour of related palladium complex-derived resolving agents. 8-H conformational locking of the 1-naphthyl side-chain Journal of the Chemical Society, Chemical Communications. 395-397. DOI: 10.1039/C39950000395  0.305
1995 Brown JM, Perez-Torrente JJ, Alcock NW. Restricted Rotation about the Metal-Aryl Bond in Platinum-Aryl Complexes of Chiral Diphosphines Organometallics. 14: 1195-1203. DOI: 10.1021/Om00003A021  0.341
1995 Brown JM, Perez-Torrente JJ, Alcock NW, Clase HJ. Stable Arylpalladium Iodides and Reactive Arylpalladium Trifluoromethanesulfonates in the Intramolecular Heck Reaction Organometallics. 14: 207-213. DOI: 10.1021/Om00001A032  0.314
1995 Valk J, Claridge TD, Brown JM, Hibbs D, Hursthouse MB. Synthesis and chemistry of a new P-N chelating ligand; (R) and (S)-6-(2′-diphenylphosphino-1′-naphthyl)phenanthridine Tetrahedron: Asymmetry. 6: 2597-2610. DOI: 10.1016/0957-4166(95)00341-L  0.329
1995 Valk JM, Whitlock GA, Layzell TP, Brown JM. Catalytic asymmetric hydroboration with heterotopic P-N ligands: Trends in enantioselectivity with increased steric demand Tetrahedron: Asymmetry. 6: 2593-2596. DOI: 10.1016/0957-4166(95)00340-U  0.313
1995 Brown JM, Guiry PJ, Christopher J, Laing P, Hursthouse MB, Abdul Malik KM. Steric and electronic requirements of amide and ester groups in benzylidenemalonates Tetrahedron. 51: 7423-7434. DOI: 10.1016/0040-4020(95)00368-I  0.61
1995 Ashworth SH, Evenson KM, Brown JM. Identification and Analysis of the Far-Infrared Laser Magnetic Resonance Spectrum of the HS2 Radical Journal of Molecular Spectroscopy. 172: 282-295. DOI: 10.1006/Jmsp.1995.1176  0.332
1994 Gillett DA, Brown JM. The laser magnetic resonance spectrum of the ν1 band of the CCN radical in its state Canadian Journal of Physics. 72: 1001-1006. DOI: 10.1139/P94-131  0.303
1994 Brown JM, Varberg TD, Evenson KM, Cooksy AL. The fine-structure intervals of (N-14)+ by far-infrared laser magnetic resonance The Astrophysical Journal. 428. DOI: 10.1086/187387  0.301
1994 Lakin NM, Brown JM, Beattie IR, Jones PJ. The identification of InOH in the gas phase and determination of its geometric structure The Journal of Chemical Physics. 100: 8546-8549. DOI: 10.1063/1.466756  0.319
1994 Varberg TD, Evenson KM, Brown JM. Detection of OH+ in its a 1Δ state by far infrared laser magnetic resonance The Journal of Chemical Physics. 100: 2487-2491. DOI: 10.1063/1.466497  0.336
1994 Smith VCM, Aplin RT, Brown JM, Hursthouse MB, Karalulov AI, Malik KMA, Cooley NA. Scope of the C-S Insertion Reaction of Thiazolium Salts with Platinum(0) Diphosphine Complexes Journal of the American Chemical Society. 116: 5180-5189. DOI: 10.1021/Ja00091A023  0.326
1994 Brown JM, Lloyd-Jones GC. Vinylborane Formation in Rhodium-Catalyzed Hydroboration of Vinylarenes. Mechanism versus Borane Structure and Relationship to Silation Journal of the American Chemical Society. 116: 866-878. DOI: 10.1021/Ja00082A006  0.614
1994 Ramsden JA, Brown JM, Hursthouse MB, Karalulov AI. A chelating diphosphine with a single stereogenic phosphorus atom; RP or SP-(2-methoxyphenyl)-P-phenyl-P-(2′-diphenylphosphino)ethylphosphine Tetrahedron-Asymmetry. 5: 2033-2044. DOI: 10.1016/S0957-4166(00)86279-5  0.34
1994 Brown JM, Hulmes DI, Guiry PJ. Mechanistic and synthetic studies in catalytic allylic alkylation with palladium complexes of 1-(2-diphenylphosphino-1-naphthyl)isoquinoline Tetrahedron. 50: 4493-4506. DOI: 10.1016/S0040-4020(01)89381-9  0.628
1994 Brown JM, Guiry PJ, Price DW, Hursthouse MB, Karalulov S. Chirality and the metal-alkene bond; distortions in the solution and solid-state structures of η2Ethene rhodium bis-oxazolinylmethane complexes Tetrahedron: Asymmetry. 5: 561-564. DOI: 10.1016/0957-4166(94)80018-9  0.622
1994 Brown JM, Guiry PJ. Bite angle dependence of the rate of reductive elimination from diphosphine palladium complexes Inorganica Chimica Acta. 220: 249-259. DOI: 10.1016/0020-1693(94)03876-7  0.608
1994 Beaton SP, Evenson KM, Brown JM. Rotational Spectroscopy of the CoH Radical in Its Ground 3Φ State by Far-Infrared Laser Magnetic Resonance: Determination of Molecular Parameters Journal of Molecular Spectroscopy. 164: 395-415. DOI: 10.1006/Jmsp.1994.1084  0.341
1994 Gillett DA, Towle JP, Islam M, Brown JM. The Infrared Spectrum of Isotopomers of the TeH Radical, Observed by CO Laser Magnetic Resonance Journal of Molecular Spectroscopy. 163: 459-482. DOI: 10.1006/Jmsp.1994.1040  0.33
1993 Brown JM, Beaton SP, Evenson KM. Rotational frequencies of transition metal hydrides for astrophysical searches in the far-infrared Astrophysical Journal. 414: L125-L127. DOI: 10.1086/187012  0.305
1993 Lipus K, Urban W, Evenson KM, Brown JM. Laser magnetic resonance spectroscopy of the NiD radical in the far- and mid-infrared Molecular Physics. 79: 571-587. DOI: 10.1080/00268979300101461  0.331
1993 Towle JP, Brown JM. The infrared spectrum of the GeH radical Molecular Physics. 78: 249-261. DOI: 10.1080/00268979300100211  0.324
1993 Carter RT, Steimle TC, Brown JM. The identification of a 6Φ–X 4Δ intercombination system in the FeH radical at 448 nm The Journal of Chemical Physics. 99: 3166-3173. DOI: 10.1063/1.465177  0.588
1993 Carey JV, Barker MD, Brown JM, Russell MJH. Preparation of enantiomerically pure phosphine oxides by nucleophilic displacement chemistry using oxazaphospholidines Journal of the Chemical Society-Perkin Transactions 1. 831-839. DOI: 10.1039/P19930000831  0.34
1993 Barnes MP, Carter RT, Lakin NM, Brown JM. Observation and analysis of rotational and nuclear hyperfine structure in bands of the red system of copper dichloride Journal of the Chemical Society, Faraday Transactions. 89: 3205-3215. DOI: 10.1039/Ft9938903205  0.329
1993 Brown JM, Hulmes DI, Layzell TP. Effective asymmetric hydroboration catalysed by a rhodium complex of 1-(2-diphenylphosphino-1-naphthyl)isoquinoline Journal of the Chemical Society, Chemical Communications. 1673-1674. DOI: 10.1039/C39930001673  0.328
1993 Braddock DC, Brown JM, Guiry PJ. Stereochemistry of the catalysed Diels–Alder reaction between cyclopentadiene and dimethyl monothionofumarate; soft versus hard Lewis acids Journal of the Chemical Society, Chemical Communications. 1244-1246. DOI: 10.1039/C39930001244  0.585
1993 Leitner W, Brown JM, Brunner H. Asymmetric catalysis. 80. Mechanistic aspects of the rhodium-catalyzed enantioselective transfer hydrogenation of .alpha.,.beta.-unsaturated carboxylic acids using formic acid/triethylamine (5:2) as the hydrogen source Journal of the American Chemical Society. 115: 152-159. DOI: 10.1021/Ja00054A021  0.676
1993 Alcock NW, Brown JM, Hulmes DI. Synthesis and resolution of 1-(2-diphenylphosphino-1-naphthyl)isoquinoline; a PN chelating ligand for asymmetric catalysis. Tetrahedron-Asymmetry. 4: 743-756. DOI: 10.1016/S0957-4166(00)80183-4  0.329
1993 Brown JM, Lloyd-Jones GC, Layzell TP. Reversible dimerisation of ephedrine-derived oxazaborolidines Tetrahedron: Asymmetry. 4: 2151-2154. DOI: 10.1016/S0957-4166(00)80063-4  0.549
1993 Armstrong SK, Brown JM, Burk MJ. The stereochemistry of enamide intermediates in DuPHOS-Rh(I) catalysed asymmetric hydrogenation Tetrahedron Letters. 34: 879-882. DOI: 10.1016/0040-4039(93)89038-R  0.363
1992 Brown J, Derome A, Hughes G, Monaghan P. Homogeneous Hydrogenation With Iridium Complexes. Evidence for Polyhydride Intermediates in the Reduction of α-Pinene Australian Journal of Chemistry. 45: 143-153. DOI: 10.1071/Ch9920143  0.347
1992 Brown JM, Pearson M, Jastrzebski JTBH, Koten Gv. Intramolecular facilitation of aryl-transfer from tin in palladium-catalysed cross-coupling Journal of the Chemical Society, Chemical Communications. 2: 1440-1441. DOI: 10.1039/C39920001440  0.308
1992 Brown JM, Lloyd-Jones GC. Vinylborane formation in rhodium-catalysed hydroborations; ligand-free homogeneous catalysis Journal of the Chemical Society, Chemical Communications. 710-712. DOI: 10.1039/C39920000710  0.443
1992 Ando D, Bevan C, Brown JM, Price DW. Contrasting pathways for the directed homogeneous hydrogenation of vinyl sulfoxides and vinyl sulfones Journal of the Chemical Society, Chemical Communications. 592-594. DOI: 10.1039/C39920000592  0.324
1992 Brown JM, Leppard SW, Lloyd-Jones GC. A rapid assay for the enantiomeric purity of secondary alcohols using 4S,5R-4-methyl,5-phenyl-1,3,2-oxazaborolidine (ephedrineborane). Tetrahedron: Asymmetry. 3: 261-266. DOI: 10.1016/S0957-4166(00)80205-0  0.58
1991 Petri M, Simon U, Zimmermann W, Urban W, Towle JP, Brown JM. Infrared diode laser spectroscopy of the ground state of geH (X 2Π) Molecular Physics. 72: 315-319. DOI: 10.1080/00268979100100241  0.329
1991 Calhorda MJ, Brown JM, Cooley NA. The carbon-carbon bond-forming step in catalytic cross-coupling: migration or elimination? Organometallics. 10: 1431-1438. DOI: 10.1021/Om00051A039  0.37
1991 Alcock NW, Brown JM, Rose M, Wienand A. A Simple General Route To Chelate Diphosphine Ruthenium (Ii) Complexes Tetrahedron-Asymmetry. 2: 47-50. DOI: 10.1016/S0957-4166(00)82156-4  0.337
1991 Brown JM, Brunner H, Leitner W, Rose M. Enantioselective catalytic transfer hydrogenation of α,β-unsaturated carboxylic acids with formates catalyzed by novel ruthenium phosphine complexes Tetrahedron: Asymmetry. 2: 331-334. DOI: 10.1016/S0957-4166(00)82111-4  0.689
1991 Nelis T, Beaton SP, Evenson KM, Brown JM. A determination of the molecular parameters for NiH in its 2Δ ground state by laser magnetic resonance Journal of Molecular Spectroscopy. 148: 462-478. DOI: 10.1016/0022-2852(91)90402-V  0.339
1991 Corkery SM, Brown JM, Beaton SP, Evenson KM. Molecular parameters of chromium hydride in its X6Σ+ state determined by far-infrared laser magnetic resonance spectroscopy Journal of Molecular Spectroscopy. 149: 257-273. DOI: 10.1016/0022-2852(91)90158-7  0.332
1991 Brown JM, Radford H, Sears TJ. Avoided crossings in the far-infrared laser magnetic resonance spectrum of HCO Journal of Molecular Spectroscopy. 148: 20-37. DOI: 10.1016/0022-2852(91)90031-5  0.321
1991 Zink LR, Grieman FJ, Brown JM, Gilson TR, Beattie IR. Vibrational structure in the laser excitation spectrum of nickel dichloride at 360 nm Journal of Molecular Spectroscopy. 146: 225-237. DOI: 10.1016/0022-2852(91)90001-Q  0.302
1991 Ashworth SH, Brown JM. The electric dipole moments of SeH and GeH in their ground 2Π states Chemical Physics Letters. 182: 73-80. DOI: 10.1016/0009-2614(91)80106-8  0.31
1991 Brown JM, Maddox PJ. Iridium complexes of dehydroamino acids: The kinetic resolution of racemic diphosphines and their application in catalytic asymmetric hydrogenation Chirality. 3: 345-354. DOI: 10.1002/Chir.530030421  0.392
1990 Towle JP, Brown JM, Lipus K, Bachem E, Urban W. The infrared spectrum of the FeH radical by laser magnetic resonance Molecular Physics. 79: 835-845. DOI: 10.1080/00268979300101661  0.304
1990 Steimle TC, Nachman DF, Shirley JE, Fletcher DA, Brown JM. The microwave spectrum of NiH Molecular Physics. 69: 923-932. DOI: 10.1080/00268979000100691  0.596
1990 Fletcher DA, Carter RT, Brown JM, Steimle TC. The green system of FeH recorded at ambient temperatures Journal of Chemical Physics. 93: 9192-9193. DOI: 10.1063/1.459209  0.533
1990 Nelis T, Brown JM, Evenson KM. The rotational spectrum of the CH radical in its a 4Σ - state, studied by far-infrared laser magnetic resonance The Journal of Chemical Physics. 92: 4067-4076. DOI: 10.1063/1.457768  0.326
1990 Brown JM, Cooley NA. Mapping the reaction pathway in palladium-catalyzed cross-coupling reactions Organometallics. 9: 353-359. DOI: 10.1021/Om00116A010  0.322
1990 Brown JM, Lloyd-Jones GC. Catalytic asymmetric hydroboration with oxazaborolidines Tetrahedron: Asymmetry. 1: 869-872. DOI: 10.1016/S0957-4166(00)82276-4  0.607
1990 Brown JM, Carey JV, Russell MJ. The nucleophilic displacement route to homochiral arylphosphine oxides Tetrahedron. 46: 4877-4886. DOI: 10.1016/S0040-4020(01)85600-3  0.306
1990 Fink EH, Setzer KD, Ramsay DA, Vervloet M, Brown JM. High-resolution study of the A 1−X 0+ emission system of bismuth hydride Journal of Molecular Spectroscopy. 142: 108-116. DOI: 10.1016/0022-2852(90)90294-Z  0.309
1989 Alcock NW, Brown JM, James AP. Structure of the rhodium complex of a reactant in directed hydrogenation Acta Crystallographica Section C-Crystal Structure Communications. 45: 734-736. DOI: 10.1107/S0108270188012880  0.327
1989 Burghardt I, Zink LR, Fletcher DA, Brown JM, Beattie IR. Nuclear hyperflne structure in the electronic spectrum of CuCI Molecular Physics. 67: 1401-1417. DOI: 10.1080/00268978900101891  0.327
1989 Brown JM, Cooley NA, Price DW. Arylation of alkenyl bromides catalysed by platinum complexes Journal of the Chemical Society, Chemical Communications. 458-460. DOI: 10.1039/C39890000458  0.32
1989 Brown JM, Davies SG. Chemical asymmetric synthesis Nature. 342: 631-636. DOI: 10.1038/342631A0  0.42
1989 Baker KV, Brown JM, Cooley NA, Hughes GD, Taylor RJ. Reactive intermediates in asymmetric cross-coupling catalysed by palladium P-N chelates Journal of Organometallic Chemistry. 370: 397-406. DOI: 10.1016/0022-328X(89)87301-2  0.344
1989 Bressan M, Morvillo A, Brown JM. Mono- and bi-nuclear complexes of the rigid bidentate ligand 2-ethylthio-5-diphenylphosphinofuran Journal of Organometallic Chemistry. 361: 249-254. DOI: 10.1016/0022-328X(89)85389-6  0.317
1989 Steimle TC, Nachman DF, Fletcher DA, Brown JM. The permanent electric dipole moment of CH in its A2Δ state Journal of Molecular Spectroscopy. 138: 222-229. DOI: 10.1016/0022-2852(89)90112-4  0.575
1988 Brown JM, Cooley NA. Transient and Stable Intermediates in Cross-Coupling Reactions Philosophical Transactions of the Royal Society A. 326: 587-594. DOI: 10.1098/Rsta.1988.0110  0.359
1988 Steimle TC, Chang W, Nachman DF, Brown JM. Electronic properties of CuS: Experimental determination of the magnetic hyperfine interactions and permanent electric dipole moment Journal of Chemical Physics. 89: 7172-7179. DOI: 10.1063/1.455295  0.568
1988 Brown JM, Cooley NA. Observation of stable and transient intermediates in palladium complex-catalysed cross-coupling reactions Journal of the Chemical Society, Chemical Communications. 1345-1347. DOI: 10.1039/C39880001345  0.336
1988 Brown JM, Phillip EL. Structure and reactivity in asymmetric hydrogenation ; a molecular graphics analysis Tetrahedron. 44: 4905-4916. DOI: 10.1016/S0040-4020(01)86195-0  0.358
1988 Birtwistle DH, Brown JM, Foxton MW. Diastereoselectivity in the intramolecular diels-alder reaction of dienylpropynoates Tetrahedron. 44: 7309-7318. DOI: 10.1016/S0040-4020(01)86103-2  0.373
1988 Comben ER, Brown JM. The high-lying rotational energy levels of the OH radical in the ν = 0 level of the X 2Π state Chemical Physics. 119: 443-454. DOI: 10.1016/0301-0104(88)87203-3  0.306
1988 Alcock NW, Brown JM, Evans PL. Phosphinosulphoxide rhodium complexes. Synthesis, crystal structure, and catalytic chemistry of [(2,3,5,6-η)-bicyclo[2.2.1]-hepta-2,5-diene][P,O-diphenyl(phenylsulphinylmethyl)-phosphine]rhodium(I) trifluoromethanesulphonate and asymmetric analogues Journal of Organometallic Chemistry. 356: 233-247. DOI: 10.1016/0022-328X(88)83094-8  0.368
1988 Brown JM, Evenson KM. The far-infrared laser magnetic resonance spectrum of vibrationally excited C2H Journal of Molecular Spectroscopy. 131: 161-171. DOI: 10.1016/0022-2852(88)90115-4  0.329
1987 Woodward DR, Fletcher DA, Brown JM. Dispersed fluorescence studies of the NCO radical: Fermi resonance between the (100) and (020) levels of the (formula presented) state Molecular Physics. 62: 517-536. DOI: 10.1080/00268978700102381  0.307
1987 Seebass W, Werner J, Urban W, Comben ER, Brown JM. The infrared spectrum of five isotopic forms of the SiH radical by laser magnetic resonance Molecular Physics. 62: 161-174. DOI: 10.1080/00268978700102121  0.332
1987 Brown JM, Uehara H. A study of the vibration–rotation and fine structure energy levels of the NSe radical by laser magnetic resonance Journal of Chemical Physics. 87: 880-884. DOI: 10.1063/1.453705  0.331
1987 Brown JM, Kent AG. Structural characterisation in solution of intermediates in rhodium-catalysed hydroformylation and their interconversion pathways Journal of the Chemical Society-Perkin Transactions 1. 11: 1597-1607. DOI: 10.1039/P29870001597  0.37
1987 Brown JM, Evans PL, Lucy AR. Stereochemistry of intermediates in homogeneous hydrogenation catalysed by tristriphenylphosphinerhodium chloride, employing nuclear magnetic resonance magnetisation transfer Journal of the Chemical Society-Perkin Transactions 1. 1589-1596. DOI: 10.1039/P29870001589  0.384
1987 Brown JM, Chaloner PA, Morris GA. The catalytic resting state of asymmetric homogeneous hydrogenation. Exchange processes delineated by nuclear magnetic resonance saturation-transfer (DANTE) techniques Journal of the Chemical Society-Perkin Transactions 1. 11: 1583-1588. DOI: 10.1039/P29870001583  0.382
1987 Brown JM, Dayrit FM, Sinou D. Chiral ligands for organometallic catalysis containing two dioxolane rings Journal of the Chemical Society-Perkin Transactions 1. 91-95. DOI: 10.1039/P29870000091  0.308
1987 Brown JM, Maddox PJ. Hydrogen transfer and C-H activation in a dihydroiridium amido-alkene complex Journal of the Chemical Society, Chemical Communications. 1278-1280. DOI: 10.1039/C39870001278  0.331
1987 Brown JM, Maddox PJ. Solution structures of iridium alkyl hydrides pertaining to asymmetric hydrogenation Journal of the Chemical Society, Chemical Communications. 1276-1278. DOI: 10.1039/C39870001276  0.323
1987 Brown JM, James AP. Stereoselective homogeneous hydrogenation of 3-substituted itaconate esters Journal of the Chemical Society, Chemical Communications. 181-182. DOI: 10.1039/C39870000181  0.305
1987 Brown JM, James AP, Prior LM. Kinetic resolution in the directed hydrogenation of N-substituted -(aminoalkyl) acrylates, precursors of optically active -amino acids. Tetrahedron Letters. 28: 2179-2182. DOI: 10.1016/S0040-4039(00)96075-1  0.31
1987 Leopold KR, Evenson KM, Comben ER, Brown JM. The far-infrared Laser Magnetic Resonance spectrum of the 17OH radical: Determination of nuclear hyperfine parameters Journal of Molecular Spectroscopy. 122: 440-454. DOI: 10.1016/0022-2852(87)90018-X  0.306
1987 Brown JM. Directed Homogeneous Hydrogenation [New Synthetic Methods (65)] Angewandte Chemie. 26: 190-203. DOI: 10.1002/Anie.198701901  0.346
1986 Brown JM, Zink LR, Jennings DA, Evenson KM, Hinz A. Laboratory measurement of the rotational spectrum of the OH radical with tunable far-infrared research The Astrophysical Journal. 307: 410. DOI: 10.1086/164427  0.301
1986 Comben ER, Brown JM, Steimle TC, Leopold KR, Evenson KM. The microwave and far-infrared spectra of the O-(18)H radical The Astrophysical Journal. 305: 513. DOI: 10.1086/164263  0.591
1986 Saykally RJ, Evenson KM, Comben ER, Brown JM. Measurement of the rotational spectrum of carbon monoxide in its metastable a3Π state by laser magnetic resonance Molecular Physics. 58: 735-743. DOI: 10.1080/00268978600101541  0.311
1986 Leopold KR, Evenson KM, Brown JM. Far infrared laser magnetic resonance detection of NH and ND (a 1Δ) The Journal of Chemical Physics. 85: 324-330. DOI: 10.1063/1.451659  0.321
1986 Steimle TC, Woodward DR, Brown JM. The lambda‐doubling spectrum of 13CH, studied by microwave optical double resonance Journal of Chemical Physics. 85: 1276-1282. DOI: 10.1063/1.451265  0.584
1986 Alcock NW, Brown JM, Maddox PJ. Substrate-induced kinetic resolution of racemic biphosphines in situ for homogeneous catalysis Journal of the Chemical Society, Chemical Communications. 1532-1534. DOI: 10.1039/C39860001532  0.341
1986 Brown JM, Cutting I, Evans PL, Maddox PJ. Factors affecting stereochemical control in directed homogeneous hydrogenation of α-hydroxyalkylacrylates Tetrahedron Letters. 27: 3307-3310. DOI: 10.1016/S0040-4039(00)84783-8  0.341
1986 Brown JM, Cook SJ, Khan R. Hydroformylation catalysed by rhodium complexes of trehalose-derived ligands aa and ββ-tredip; a highly recioselective route to α-methylarylpropionaldehydes Tetrahedron. 42: 5105-5109. DOI: 10.1016/S0040-4020(01)88063-7  0.301
1986 Brown JM, Cook SJ, Kent AG. Flexible cis- or trans- chelating biphosphine ligands derived from - or - trehalose Tetrahedron. 42: 5097-5104. DOI: 10.1016/S0040-4020(01)88062-5  0.305
1986 Brown JM, Lucy AR. trans-bis(diphenylphosphine)cyclopropane; a ligand selective for binuclear complexation with ca. 4.5 Å intermetallic separation Journal of Organometallic Chemistry. 314: 241-246. DOI: 10.1016/0022-328X(86)80367-9  0.333
1986 Brown JM, Schubert JE, Saykally RJ, Evenson KM. The far-infrared laser magnetic resonance spectrum of the CF radical and determination of ground state parameters Journal of Molecular Spectroscopy. 120: 421-434. DOI: 10.1016/0022-2852(86)90015-9  0.329
1985 Steimle TC, Woodward DR, Brown JM. Laboratory observations of the 3.3 gigahertz transitions in (C-12)H and (C-13)H The Astrophysical Journal. 294: L59. DOI: 10.1086/184509  0.576
1985 Werner J, Seebass W, Koch M, Curl RF, Urban W, Brown JM. An observation of the v 1 rotation-vibration band of the NCO radical by laser magnetic resonance spectroscopy Molecular Physics. 56: 453-461. DOI: 10.1080/00268978500102441  0.312
1985 Brown JM, Evenson KM, Sears TJ. Infrared and far-infrared laser magnetic resonance spectroscopy of the GeH radical: Determination of ground state parameters The Journal of Chemical Physics. 83: 3275-3284. DOI: 10.1063/1.449186  0.353
1985 Steimle T, Brown JM. On the lambda‐doubling spectrum of carbon monoxide in its a 3Π state Journal of Chemical Physics. 82: 1618-1619. DOI: 10.1063/1.448392  0.359
1985 Alcock NW, Brown JM, Derome AE, Lucy AR. Iridium analogues of catalytic intermediates in asymmetric hydrogenation Journal of the Chemical Society, Chemical Communications. 575-578. DOI: 10.1039/C39850000575  0.337
1985 Brown JM, Derome AE, Hall SA. Nature of the catalytic cycle in iridium-complex catalysed hydrogenation of unsaturated alcohols Tetrahedron. 41: 4647-4656. DOI: 10.1016/S0040-4020(01)82360-7  0.337
1985 Brown JM, Hall SA. Comparison of cationic rhodium and iridium complexes in directed homogeneous hydrogenation Tetrahedron. 41: 4639-4646. DOI: 10.1016/S0040-4020(01)82359-0  0.376
1985 Brown JM, Hall SA. Stereochemical control by carboxylate groups in homogeneous hydrogenation Journal of Organometallic Chemistry. 285: 333-341. DOI: 10.1016/0022-328X(85)87378-2  0.359
1985 Brown JM, John RA, Lucy AR. Observations on olefin oxidation by neutral and cationic phosphineiridium complexes Journal of Organometallic Chemistry. 279: 245-257. DOI: 10.1016/0022-328X(85)87022-4  0.3
1985 Brown JM, Schubert JE, Brown CE, Geiger JS, Smith DR. The far-infrared laser magnetic resonance spectra of the OD radical in ground and vibrationally excited states Journal of Molecular Spectroscopy. 114: 185-196. DOI: 10.1016/0022-2852(85)90347-9  0.325
1985 Steimle TC, Brazier CR, Brown JM. Studies of copper monofluoride in the b3Π state by microwave-optical double resonance and intermodulated fluorescence Journal of Molecular Spectroscopy. 110: 39-52. DOI: 10.1016/0022-2852(85)90210-3  0.537
1984 Brown JM, Curl RF, Evenson KM. The far-infrared laser magnetic resonance spectrum of the SiH radical and determination of ground state parameters The Journal of Chemical Physics. 81: 2884-2890. DOI: 10.1063/1.448062  0.346
1984 Alcock NW, Brown JM, MacLean TD. High stereo- and regio-selectivity in the reaction of 1,2-bis-(dimethylphosphino)ethanehydridomethylplatinum with p-chlorophenyl isonitrile Journal of the Chemical Society, Chemical Communications. 1689-1690. DOI: 10.1039/C39840001689  0.341
1984 Brown JM, Canning LR, Lucy AR. Contrasting reactivity of mono- and di-nuclear dihydrido-trans-bisphosphine-rhodium and -iridium complexes towards alkenes Journal of the Chemical Society, Chemical Communications. 915-917. DOI: 10.1039/C39840000915  0.346
1984 Brown JM, Lucy AR. On the accessibility of cis-bisphosphine intermediates in homogeneous hydrogenation catalysed by Wilkinson's complex, ClRh(PPh3)3 Journal of the Chemical Society, Chemical Communications. 914-915. DOI: 10.1039/C39840000914  0.337
1984 Brown JM, Hall SA. Scope and limitations of the stereoselective homogeneous hydrogenation of methylenecyclohexanols by cationic rhodium complexes Tetrahedron Letters. 25: 1393-1396. DOI: 10.1016/S0040-4039(01)80167-2  0.344
1984 Brown JM, Canning LR. Mono- and di-nuclear rhodium complexes of meso- and dl-1,1,4,7,10,10-hexaphenyl-1,4,7,10-tetraphosphadecane. Stereochemical control of reactivity and complexation geometry Journal of Organometallic Chemistry. 267: 179-190. DOI: 10.1016/0022-328X(84)80173-4  0.351
1983 Brown JM, Chaloner PA, Morris GA. Identification of a further transient species relating to rhodium-complex catalysed asymmetric hydrogenation Journal of the Chemical Society, Chemical Communications. 58: 664-666. DOI: 10.1039/C39830000664  0.311
1983 Brown JM, Canning LR. Rhodium complexes of 2,5-bisdiphenylphosphinofuran, a ligand selective for binuclear chelation Journal of the Chemical Society, Chemical Communications. 460-462. DOI: 10.1039/C39830000460  0.303
1983 Brown JM, Canning LR, Downs AJ, Forster AM. Equilibration of ortho- and para-hydrogen by homogeneous hydrogenation catalysts in solution; A test for the reversibility of hydrogen addition using Raman spectroscopy Journal of Organometallic Chemistry. 255: 103-111. DOI: 10.1016/0022-328X(83)80178-8  0.351
1983 Brazier CR, Brown JM, Steimle TC. The identification of the b3Π state of copper monofluoride Journal of Molecular Spectroscopy. 97: 449-453. DOI: 10.1016/0022-2852(83)90282-5  0.51
1983 Brown JM, Chaloner PA. Asymmetric Hydrogenation Reactions Using Chiral Diphosphine Complexes of Rhodium Cheminform. 15: 137-165. DOI: 10.1007/978-1-4613-3623-5_4  0.362
1982 Brown JM, Schubert JE, Evenson KM, Radford HE. The far-infrared spectrum of the OH radical The Astrophysical Journal. 258: 899. DOI: 10.1086/160136  0.314
1982 Brown JM, Midgley I, Albery WJ. Site-specific and random degenerate rearrangements in η6- and η4-cycloheptatriene metal complexes Journal of the Chemical Society-Perkin Transactions 1. 13: 767-772. DOI: 10.1039/P29820000767  0.334
1982 Brown JM, Chaloner PA. The mechanism of asymmetric homogeneous hydrogenation. Rhodium complexes formed by dehydroamino-acids co-complexed with trans-4,5-bisdiphenylphosphino-2,2-dimethyldioxolan and achiral models Journal of the Chemical Society-Perkin Transactions 1. 13: 711-719. DOI: 10.1039/P29820000711  0.367
1982 Brown JM, Murrer BA. The mechanism of asymmetric hydrogenation. Chiral bis(diphenylphosphino)-α-phenylalkane complexes in catalytic and structural studies Journal of the Chemical Society-Perkin Transactions 1. 13: 489-497. DOI: 10.1039/P29820000489  0.325
1982 Brown JM, Kent AG. Structure and dynamics of the stable rhodium–acyl complex formed during hydroformylation Journal of the Chemical Society, Chemical Communications. 723-725. DOI: 10.1039/C39820000723  0.312
1982 Brown JM, Naik RG. Chelate control in the rhodium-catalysed homogeneous hydrogenation of chiral allylic and homoallylic alcohols Journal of the Chemical Society, Chemical Communications. 348-350. DOI: 10.1039/C39820000348  0.328
1982 Brown JM, Parker D. Mechanism of asymmetric homogeneous hydrogenation. Rhodium-catalyzed reductions with deuterium and hydrogen deuteride Organometallics. 1: 950-956. DOI: 10.1021/Om00067A010  0.503
1982 Brown JM, Parker D. Mechanism of asymmetric hydrogenation. Rhodium complexes formed by unsaturated carboxylic acids, carboxylates, and carboxamides Journal of Organic Chemistry. 47: 2722-2730. DOI: 10.1021/Jo00135A008  0.529
1982 Steimle TC, Brazier CR, Brown JM. Rotational and hyperfine structure in the yellow system of CuF Journal of Molecular Spectroscopy. 91: 137-149. DOI: 10.1016/0022-2852(82)90037-6  0.512
1982 Brown JM, Parker D. Mechanism of asymmetric hydrogenation. Rhodium complexes formed by unsaturated carboxylic acids, carboxylates, and carboxamides Cheminform. 13. DOI: 10.1002/Chin.198248129  0.529
1981 Brown JM, Parker D. Determination of optical purity at isotopically chiral sites by 2H NMR Tetrahedron Letters. 22: 2815-2818. DOI: 10.1016/S0040-4039(01)90560-X  0.489
1981 Brown JM, Chaloner PA, Kent AG, Murrer BA, Nicholson PN, Parker D, Sidebottom PJ. The mechanism of asymmetric homogeneous hydrogenation. Solvent complexes and dihydrides from rhodium diphosphine precursors Journal of Organometallic Chemistry. 216: 263-276. DOI: 10.1016/S0022-328X(00)85766-6  0.558
1981 Brown JM, Chaloner PA, Murrer BA, Parker D. Rational Approaches To Asymmetric Hydrogenation Cheminform. 12. DOI: 10.1002/Chin.198109388  0.48
1980 Brown JM, Chaloner PA. Structural characterisation of a transient intermediate in rhodium-catalysed asymmetric homogeneous hydrogenation Journal of the Chemical Society, Chemical Communications. 344-346. DOI: 10.1039/C39800000344  0.314
1980 Brown JM, Parker D. Intermediates in the asymmetric hydrogenation of unsaturated carboxylic acid derivatives Journal of the Chemical Society, Chemical Communications. 342-344. DOI: 10.1039/C39800000342  0.541
1980 Brown JM, Chaloner PA. The mechanism of asymmetric homogeneous hydrogenation. Rhodium(I) complexes of dehydroamino acids containing asymmetric ligands related to bis(1,2-diphenylphosphino)ethane Journal of the American Chemical Society. 102: 3040-3048. DOI: 10.1021/Ja00529A029  0.338
1980 Brown JM, Murrer BA. Reversal of chirality induced by ortho-methoxyl substitution of arylphosphine ligands in rhodium-catalysed asymmetric hydrogenation Tetrahedron Letters. 21: 581-584. DOI: 10.1016/S0040-4039(01)85562-3  0.332
1980 brown JM, chaloner PA, glaser R, geresh S. Intermediates in asymmetric hydrogenation Tetrahedron. 36: 815-825. DOI: 10.1016/S0040-4020(01)93700-7  0.358
1980 Barnes CE, Brown JM, Radford HE. The EPR and LMR spectra of the DO2 radical: Determination of ground-state parameters Journal of Molecular Spectroscopy. 84: 179-196. DOI: 10.1016/0022-2852(80)90252-0  0.326
1979 Murrer BA, Brown JM, Chaloner PA, Nicholson PN, Parker D. Synthesis of trans-4,5-Bis[diphenylarsinomethyl]-2,2-dimethyl-1,3-dioxolan and an Improved Preparation of its Phosphine Analogue (DIOP) Synthesis. 1979: 350-352. DOI: 10.1055/S-1979-28676  0.503
1979 Alcock NW, Brown JM, Conneely JA, Williamson DH. Further studies on metal-promoted vinylcyclopropane to cyclopentene rearrangements. Structure and thermolysis of rhodium complexes of exo-6-vinylbicyclo[3.1.0]hex-2-ene and the crystal structure of the 1,6–8-η4-5-allylcyclopent-2-enyl(hexafluoroacetylacetonato)rhodium(III) tetramer Journal of the Chemical Society-Perkin Transactions 1. 962-971. DOI: 10.1039/P29790000962  0.378
1979 Brown JM, Darwent JR. Proximity effects in the reactions of surfactant p-nitrophenyl esters with peroxide nucleophiles Journal of the Chemical Society, Chemical Communications. 171-172. DOI: 10.1039/C39790000171  0.314
1979 Brown JM, Darwent JR. Hydrophobic effects in the micellar reactions of peroxide nucleophiles Journal of the Chemical Society, Chemical Communications. 169-170. DOI: 10.1039/C39790000169  0.307
1979 Brown JM, Murrer BA. - phenyl diphenylphosphinoethane; structural studies pertaining to rhodium - catalysed asymmetric hydrogenation Tetrahedron Letters. 20: 4859-4862. DOI: 10.1016/S0040-4039(01)86733-2  0.329
1979 Brown JM, Molinari H. Supported rhodium-phosphine hydrogenation catalysts of high mobility and reactivity Tetrahedron Letters. 20: 2933-2936. DOI: 10.1016/S0040-4039(01)86456-X  0.312
1978 Brown JM, Dumper K, Parent CR. A determination of the molecular parameters of SeO in the X3Σ- state Molecular Physics. 36: 1149-1160. DOI: 10.1080/00268977800102241  0.308
1978 Brown JM, Golding BT, Stofko JJ. cis-Divinylcyclopropane and the hexafluoroacetylacetonatorhodium(I) complexes of cis- and trans-divinylcyclopropane Journal of the Chemical Society-Perkin Transactions 1. 9: 436-441. DOI: 10.1039/P29780000436  0.325
1978 Brown JM, Chaloner PA, Nicholson PN. Diversity of behaviour of bicyclo[2.2.1]heptadiene–bis-phosphine–rhodium complexes on hydrogenation in methanol Journal of the Chemical Society, Chemical Communications. 646-647. DOI: 10.1039/C39780000646  0.318
1978 Brown JM, Chaloner PA. Mechanism of asymmetric hydrogenation catalysed by rhodium(I)trans-4,5-bis(diphenylphosphinomethyl)-2,2-dimethyldioxolan (DIOP) complexes Journal of the Chemical Society, Chemical Communications. 321-322. DOI: 10.1039/C39780000321  0.351
1978 Brown JM, Chaloner PA. Enantiomer recognition and conformational equilibriums in platinum(0) complexes of 2,3-isopropylidene-2,3-trans-dihydroxy-1,4-bis(diphenylphosphino)butane (diop) Journal of the American Chemical Society. 100: 4307-4309. DOI: 10.1021/Ja00481A052  0.315
1978 Brown JM, Chaloner PA. The mechanism of asymmetric hydrogenation catalysed by rhodium (I) di pamp complexes. Tetrahedron Letters. 19: 1877-1880. DOI: 10.1016/S0040-4039(01)94697-0  0.326
1977 Brown JM, Chaloner PA. Strong amide–halothane hydrogen-bonding observed by nuclear magnetic resonance Canadian Journal of Chemistry. 55: 3380-3383. DOI: 10.1139/V77-475  0.319
1977 Brown JM, Martens DRM. An assessment of the mobility of squalene in part-aqueous solutions from carbon magnetic resonance spin-lattice relaxation times : Comparison with squalene and 2,3-dihydroxy-2,3-dihydrosqualene Tetrahedron. 33: 931-935. DOI: 10.1016/0040-4020(77)80204-4  0.303
1976 Alcock NW, Brown JM, Conneely JA, Williamson DH. REACTIVE RHODIUM COMPLEXES DERIVED FROM TRANS-6-VINYLBICYCLO(3.1.0)HEX-2-ENE. MECHANISTIC STUDIES AND X-RAY STRUCTURE OF η4-3,1′-3′-(4-ALLYLCYCLOPENT-1-ENYL)HEXAFLUOROACETYLACETONATORHODIUM TETRAMER Cheminform. 7. DOI: 10.1002/Chin.197601335  0.315
1975 Aris V, Brown JM, Conneely JA, Golding BT, Williamson DH. Synthesis and thermolysis of rhodium and iridium complexes of endo-6-vinylbicyclo[3.1.0]hex-2-ene. A metal-promoted vinylcyclopropane to cyclopentene rearrangement Journal of the Chemical Society-Perkin Transactions 1. 6: 4-10. DOI: 10.1039/P29750000004  0.352
1975 Alocock NW, Brown JM, Conneely JA, Williamson DH. Reactive rhodium complexes derived from trans-6-vinylbicyclo[3.1.0.]hex-2-ene. Mechanistic studies and X-ray structure of η4-3,1′–3′(4-allylcyclopent-1-enyl)hexafluoroacetylacetonatorhodium tetramer Journal of the Chemical Society, Chemical Communications. 792-793. DOI: 10.1039/C39750000792  0.332
1975 Alcock NW, Brown JM, Jeffery JC. Structural And Chemical Aspects Of Phosphino-Ethers As Chelating Ligands In Rhodium(I) Cationic Complexes, X-Ray Crystal Structures Of Two Phosphino-Ether Rhodium Carbonyl Complexes Cheminform. 6. DOI: 10.1002/Chin.197504400  0.307
1974 Brown JM, Conneely JA, Mertis K. Reactions of potassium carbonyl(π-cyclopentadienyl)nickelate with butenyl and cyclopropylmethyl halides Journal of the Chemical Society-Perkin Transactions 1. 5: 905-907. DOI: 10.1039/P29740000905  0.362
1974 Aris V, Brown JM, Golding BT. Synthesis of meso- and (±)-3,4-dimethylhexa-1,5-diene and their acetylacetonatorhodium(I) complexes Journal of the Chemical Society-Perkin Transactions 1. 5: 700-704. DOI: 10.1039/P29740000700  0.329
1974 Alcock NW, Brown JM, Jeffery JC. Structural and chemical aspects of phosphino-ethers as chelating ligands in rhodium(I) cationic complexes. X-Ray crystal structures of two phosphino ether rhodium carbonyl complexes Journal of the Chemical Society, Chemical Communications. 829-830. DOI: 10.1039/C39740000829  0.311
1973 Brown JM, Mertis K. Mechanistic studies on the course of a σ-but-3-enyl- to 1–3-η-but-2-enyl-nickel transformation Journal of the Chemical Society-Perkin Transactions 1. 5: 1993-2001. DOI: 10.1039/P29730001993  0.34
1967 Breslow R, Brown J, Gajewski JJ. Antiaromaticity of cyclopropenyl anions Journal of the American Chemical Society. 89: 4383-4390. DOI: 10.1021/Ja00993A023  0.515
Low-probability matches (unlikely to be authored by this person)
1997 Hoek Gvd, Brown JM. Rotational Analysis of Bands in the 360-nm System of NiCl2: Indications of Interacting States Journal of Molecular Spectroscopy. 182: 163-177. DOI: 10.1006/Jmsp.1996.7211  0.3
1988 Nelis T, Brown JM, Evenson KM. The spectroscopic observation of the CH radical in its a 4Σ- state The Journal of Chemical Physics. 88: 2087-2088. DOI: 10.1063/1.454086  0.3
1997 Fernandez E, Hooper MW, Knight FI, Brown JM. Catalytic asymmetric hydroboration–amination Chemical Communications. 173-174. DOI: 10.1039/A606918E  0.299
2002 Maeda K, Brown JM. Efficient kinetic resolution in hydroboration of 1,2-dihydronaphthalenes. Chemical Communications (Cambridge, England). 310-1. PMID 12120049 DOI: 10.1039/B111175B  0.299
1999 Wilson C, Brown JM. Identification of New Hot Bands in the Blue and Green Band Systems of FeH Journal of Molecular Spectroscopy. 197: 188-198. PMID 10479583 DOI: 10.1006/Jmsp.1999.7924  0.299
2001 Davidson SA, Evenson KM, Brown JM. A measurement of the rotational spectrum of the CH radical in the far-infrared Astrophysical Journal. 546: 330-337. DOI: 10.1086/318255  0.298
2001 Wilson C, Cook HM, Brown JM. Complete characterization of the a6Δ state of the FeH radical Journal of Chemical Physics. 115: 5943-5956. DOI: 10.1063/1.1399300  0.298
1997 Beattie IR, Brown JM, Crozet P, Ross AJ, Yiannopoulou A. On the Geometry of the CuCl(2) Molecule. Inorganic Chemistry. 36: 3207-3208. PMID 11669980 DOI: 10.1021/Ic961509R  0.298
1997 Lakin NM, Hoek Gvd, Beattie IR, Brown JM. The identification of In2O in the gas phase by high resolution electronic spectroscopy Journal of Chemical Physics. 107: 4439-4442. DOI: 10.1063/1.474786  0.297
1996 Lakin NM, Whitham CJ, Brown JM. Evidence for Renner-Teller coupling in the upper, triplet electronic state of the 370 nm system of InOH Chemical Physics Letters. 250: 9-13. DOI: 10.1016/0009-2614(95)01395-4  0.297
2001 Beaton SA, Gillett DA, Brown JM, Fehér M, Rohrbacher A. The Infrared Laser Spectrum of the 101211 Hot Band of CCN Journal of Molecular Spectroscopy. 209: 60-65. DOI: 10.1006/Jmsp.2001.8407  0.297
1983 Brown JM, Dayrit FM, Lightowler D. Interconversion of cis- and trans- dihydrides derived from chelate biphosphine iridium cations Journal of the Chemical Society, Chemical Communications. 414-415. DOI: 10.1039/C39830000414  0.296
2007 Hill C, Brown JM. A reduced form of the spin–spin centrifugal distortion Hamiltonian for orthorhombic asymmetric top molecules Journal of Molecular Spectroscopy. 241: 7-14. DOI: 10.1016/J.Jms.2006.10.010  0.295
2002 Farrington EJ, Martinez Viviente E, Williams BS, van Koten G, Brown JM. Synthesis and reactivity of a ferrocene-derived PCP-pincer ligand. Chemical Communications (Cambridge, England). 308-9. PMID 12120048 DOI: 10.1039/B108585A  0.295
1989 Brown JM, Evans PL, Maddox PJ, Sutton KH. Stereochemical course of hydrogen addition to bis[(S,S-2,3-bis(diphenylphosphino)butane]iridium(I). Crystal structure of dihydrogen bis[(S,S)-2,3-bis(diphenylphosphino)butanel]-iridium(I) tetrafluoroborate Journal of Organometallic Chemistry. 359: 115-125. DOI: 10.1016/0022-328X(89)85257-X  0.295
1994 Carter RT, Brown JM. Observation and identification of the g 6Φ–a 6Δ transition in the blue system of FeH at 493 nm The Journal of Chemical Physics. 101: 2699-2709. DOI: 10.1063/1.467651  0.295
1986 Cooksy AL, Saykally RJ, Brown JM, Evenson KM. Accurate determination of the fine-structure intervals in the 3P ground states of C-13 and C-12 by far-infrared laser magnetic resonance The Astrophysical Journal. 309: 828. DOI: 10.1086/164651  0.295
1999 Hullah DF, Barrow RF, Brown JM. Low-lying energy levels of the FeH molecule Molecular Physics. 97: 93-103. DOI: 10.1080/00268979909482812  0.294
1985 Brown JM, Curl RF, Evenson KM. The microwave and far-infrared spectra of the SiH radical The Astrophysical Journal. 292: 188. DOI: 10.1086/163145  0.294
1996 Brookes MD, Clift DJM, Low RJ, Brown JM, Howard BJ. The structure of CO–OCS: a spectroscopic and theoretical investigation Molecular Physics. 88: 899-914. DOI: 10.1080/00268979650025966  0.294
1977 Alcock NW, Brown JM, Jeffery JC. Rhodium phosphinoether complexes. Part 2. Crystal and molecular structures of trans-[1,8-bis(diphenylphosphino)-3,6-dioxaoctane-P,P′]-carbonyl(ethanol)rhodium(I) hexafluorophosphate and trans-[1,5-bis(diphenylphosphino)-3-oxapentane-P,P′]carbonylchlororhodium(I) dimer Journal of the Chemical Society-Dalton Transactions. 888-893. DOI: 10.1039/Dt9770000888  0.294
2006 Hodges PJ, Brown JM, Ashworth SH. The observation of hot bands in the 288 nm system of the FeCl2 radical Journal of Molecular Spectroscopy. 240: 265-268. DOI: 10.1016/J.Jms.2006.10.006  0.294
1987 Brown JM, Cheung AS-, Merer AJ. Λ-Type doubling parameters for molecules in Δ electronic states Journal of Molecular Spectroscopy. 124: 464-475. DOI: 10.1016/0022-2852(87)90157-3  0.293
1981 Brown JM, Field IP, Sidebottom PJ. Structural specificity in asymmetric charge-transfer complexation of helicenes Tetrahedron Letters. 22: 4867-4870. DOI: 10.1016/S0040-4039(01)92367-6  0.293
1985 Brown JM, Cutting I. Effective kinetic resolution in the asymmetric hydrogenation of α-(hydroxyalkyl)acrylate esters Journal of the Chemical Society, Chemical Communications. 578-579. DOI: 10.1039/C39850000578  0.293
2008 Jackson M, Zink LR, McCarthy MC, Perez L, Brown JM. The far-infrared and microwave spectra of the CH radical in the v=1 level of the X2Π state Journal of Molecular Spectroscopy. 247: 128-139. DOI: 10.1016/J.Jms.2007.11.001  0.293
2004 Crowther SA, Brown JM. The 313 nm band system of SeO2. Part 1: vibrational structure Journal of Molecular Spectroscopy. 225: 196-205. DOI: 10.1016/J.Jms.2004.03.005  0.292
2005 Cooper RI, Cowley AR, Capito E, Brown JM, Ricci A. Chloro{1-[(dimethylamino)methyl-κN]-1H-indolyl-κC 2}(triphenylphosphine-κP)-palladium(II) dichloromethane solvate Acta Crystallographica Section E: Structure Reports Online. 61: m585-m586. DOI: 10.1107/S1600536804033227  0.292
1982 Brown JM, Canning LR, Kent AG, Sidebottom PJ. Observation of dicarbonyldiphosphinerhodium hydrides and their olefin-trapping ability Journal of the Chemical Society, Chemical Communications. 721-723. DOI: 10.1039/C39820000721  0.292
1979 Brown JM, Chaloner PA, Colens A. Acyl transfer reactions in functional micelles studied by proton magnetic resonance at 270 MHz Journal of the Chemical Society-Perkin Transactions 1. 10: 71-76. DOI: 10.1039/P29790000071  0.291
2006 Harrison JJ, Brown JM, Halfen DT, Ziurys LM. Improved frequencies of rotational transitions of52CrH in the 6Σ+ ground state Astrophysical Journal. 637: 1143-1147. DOI: 10.1086/498428  0.291
2006 Hodges PJ, Ashworth SH, Beattie IR, Brown JM. Dispersed fluorescence spectroscopy of jet-cooled FeCl2: A determination of ground-state vibrational parameters Chemical Physics Letters. 422: 160-164. DOI: 10.1016/J.Cplett.2006.02.044  0.291
2001 Blackmond DG, McMillan CR, Ramdeehul S, Schorm A, Brown JM. Origins of asymmetric amplification in autocatalytic alkylzinc additions [3] Journal of the American Chemical Society. 123: 10103-10104. PMID 11592892 DOI: 10.1021/Ja0165133  0.29
2004 Gridnev ID, Serafimov JM, Brown JM. Solution structure and reagent binding of the zinc alkoxide catalyst in the Soai asymmetric autocatalytic reaction. Angewandte Chemie (International Ed. in English). 43: 4884-7. PMID 15372571 DOI: 10.1002/Anie.200353572  0.29
2005 Alcarazo M, Roseblade SJ, Cowley AR, Fernández R, Brown JM, Lassaletta JM. Imidazo[1,5-a]pyridine: a versatile architecture for stable N-heterocyclic carbenes. Journal of the American Chemical Society. 127: 3290-1. PMID 15755141 DOI: 10.1021/Ja0423769  0.289
2007 Hill C, Brown JM. Determination of the spin–spin centrifugal distortion parameters for deuterated selenoformaldehyde in its first excited triplet state Journal of Molecular Spectroscopy. 241: 15-17. DOI: 10.1016/J.Jms.2006.10.011  0.288
2006 Perez R, Brown JM, Utkin Y, Han J, Curl RF. Observation of hot bands in the infrared spectrum of H2CO Journal of Molecular Spectroscopy. 236: 151-157. DOI: 10.1016/J.Jms.2006.01.006  0.288
1994 Brown JM. Catalytic Asymmetric Synthesis Synthesis. 1994: 335-335. DOI: 10.1055/S-1994-25470  0.288
1996 Brown JM, Evenson KM, Zink LR, Vasconcellos ECC. Laser magnetic resonance measurement of the 3P1-3P0 fine-structure separation of P+ Astrophysical Journal. 464: L203-L206. DOI: 10.1086/310101  0.288
1979 Brown JM, Sears TJ. A reduced form of the spin-rotation Hamiltonian for asymmetric-top molecules, with applications to HO2 and NH2 Journal of Molecular Spectroscopy. 75: 111-133. DOI: 10.1016/0022-2852(79)90153-X  0.287
2001 Kermode SM, Brown JM. The Ultraviolet Spectrum of the FeF Radical: A Study of the (6)Pi-X(6)Delta and (6)Phi-X(6)Delta Band Systems at 330 and 323 nm Respectively. Journal of Molecular Spectroscopy. 207: 161-171. PMID 11397104 DOI: 10.1006/Jmsp.2001.8350  0.287
1975 BROWN JM, BUNTON CA. ChemInform Abstract: STEREOSELECTIVE MICELLE-PROMOTED ESTER HYDROLYSIS Chemischer Informationsdienst. 6: no-no. DOI: 10.1002/Chin.197509128  0.286
2001 Brown JM. Nobel Prizes in Chemistry; Asymmetric Hydrogenation Recognised! Advanced Synthesis & Catalysis. 343: 755-756. DOI: 10.1002/1615-4169(20011231)343:8<755::Aid-Adsc755>3.0.Co;2-1  0.286
1982 Sears TJ, Bunker PR, McKellar ARW, Evenson KM, Jennings DA, Brown JM. The rotational spectrum and hyperfine structure of the methylene radical CH2 studied by far-infrared laser magnetic resonance spectroscopy The Journal of Chemical Physics. 77: 5348-5362. DOI: 10.1002/Chin.198308047  0.286
2008 Xu Y, Mingos DM, Brown JM. Crabtree's catalyst revisited; ligand effects on stability and durability. Chemical Communications (Cambridge, England). 199-201. PMID 18092086 DOI: 10.1039/B711979H  0.285
2003 Brown JM. The rotational dependence of the Renner-Teller interaction: a new term in the effective Hamiltonian for linear triatomic molecules in Π electronic states Molecular Physics. 101: 3419-3426. DOI: 10.1080/00268970310001645864  0.285
1998 Hullah DF, Wilson C, Barrow RF, Brown JM. New Assignments in the Green and Red Band Systems of the FeH Radical Journal of Molecular Spectroscopy. 192: 191-197. PMID 9770403 DOI: 10.1006/Jmsp.1998.7663  0.285
2008 Harrison JJ, Brown JM. Measurement of the Magnetic Properties of FeH in Its X4Δ and F4Δ States from Sunspot Spectra The Astrophysical Journal. 686: 1426-1431. DOI: 10.1086/591541  0.284
1979 Brown JM, Chaloner PA, Descotes G, Glaser R, Lafont D, Sinou D. Asymmetric hydrogenation catalysed by rhodium complexes of (2R,4R)-bis(diphenylphosphinomethyl)dioxolan. A stable rhodium dihydride derived from a chelating diphosphine complex Journal of the Chemical Society, Chemical Communications. 611-613. DOI: 10.1039/C39790000611  0.284
1976 Alcock NW, Brown JM, Jeffery JC. Rhodium Phosphinoether Complexes. Part 1. Crystal and Molecular Structures of trans-[1,5-Bis(diphenylphosphino)-3-oxapentane-O,P,P′]-carbonylrhodium(I) Hexafluorophosphate and trans-Aquo[1,11-bis-(diphenylphosphino)-3,6,9-trioxaundeca Cheminform. 7. DOI: 10.1002/Chin.197625068  0.284
1988 Baker KV, Brown JM, Cooley NA. Geminally 13c‐labelled vinyl iodides; E‐2′‐iodo‐4‐methoxyphenyl[2′‐13C]ethene from [13C]iodoform Journal of Labelled Compounds and Radiopharmaceuticals. 25: 1229-1233. DOI: 10.1002/Jlcr.2580251109  0.282
1991 Towle JP, Brown JM. The infrared spectrum of the TeD radical by laser magnetic resonance Molecular Physics. 74: 465-470. DOI: 10.1080/00268979100102351  0.282
1994 Brown JM, Evenson KM, Zink LR. Atomic sulfur: Frequency measurement of the J = 0 left arrow 1 fine-structure transition at 56.3 microns by laser magnetic resonance The Astrophysical Journal. 431. DOI: 10.1086/187494  0.282
2002 Farrington EJ, Brown JM, Barnard CF, Rowsell E. Ruthenium-catalyzed oxidative Heck reactions. Angewandte Chemie (International Ed. in English). 41: 169-71. PMID 12491475 DOI: 10.1002/1521-3773(20020104)41:1<169::Aid-Anie169>3.0.Co;2-S  0.281
1976 Alcock NW, Brown JM, Jeffery JC. Rhodium phosphinoether complexes. Part I. Crystal and molecular structures of trans-[1,5-bis(diphenylphosphino)-3-oxapentane-O,P,P′]-carbonylrhodium(I) hexafluorophosphate and trans-aqua[1,11-bis-(diphenylphosphino)-3,6,9-trioxaundecane-P,P′]carbonylrhodium(I)hexafluorophosphate Journal of the Chemical Society-Dalton Transactions. 583-588. DOI: 10.1039/Dt9760000583  0.28
2007 Nguyen B, Chernous K, Endlar D, Odell B, Piacenti M, Brown JM, Dorofeev AS, Burasov AV. Alkyl radical generation in water under ambient conditions - a new look at the Guareschi reaction of 1897. Angewandte Chemie (International Ed. in English). 46: 7655-8. PMID 17786904 DOI: 10.1002/Anie.200700632  0.28
1992 Burkholder JB, Hammer PD, Howard CJ, Towle JP, Brown JM. Fourier transform spectroscopy of the ν2 and ν3 bands of HO2 Journal of Molecular Spectroscopy. 151: 493-512. DOI: 10.1016/0022-2852(92)90582-9  0.279
1983 Mizushima M, Evenson KM, Mucha JA, Jennings DA, Brown JM. Laser magnetic resonance of the O2 molecule at 699 μm Journal of Molecular Spectroscopy. 100: 303-315. DOI: 10.1016/0022-2852(83)90088-7  0.278
2005 Cowley AR, Cooper RI, Capito E, Brown JM, Ricci A. Acetato[1-(oxazolin-2-ylmethyl-κN)indol-2-yl]-(triphenylphosphine) palladium(II) dichloromethane solvate Acta Crystallographica Section E: Structure Reports Online. 61: m582-m584. DOI: 10.1107/S1600536804032891  0.278
1975 Aris KR, Brown JM, Taylor KA. Ligand Lability In Carbonyl(Eta-Cyclopentadienyl)Triphenylphosphineiron Derivatives Cheminform. 6. DOI: 10.1002/Chin.197501365  0.278
1979 Brown JM, Chaloner PA. Asymmetric homogeneous hydrogenation catalysed by rhodium complexes; the binding modes of enamides defined by 13C n.m.r. spectroscopy Journal of the Chemical Society, Chemical Communications. 613-615. DOI: 10.1039/C39790000613  0.278
1975 Alcock NW, Brown JM, Conneely JA, Stofko JJ. Organorhodium complexes of cis- and trans-divinylcyclopropane; the crystal structure of (±)-ZZ-1,2,3-η-5,6,7-η-heptadienediylrhodium(I) hexafluoroacetylacetonate Journal of the Chemical Society, Chemical Communications. 234-235. DOI: 10.1039/C39750000234  0.278
1989 Birtwistle DH, Brown JM, Herbert RH, James AP, Lee K-, Taylor RJ. Conformational analysis in the directed hydrogenation of homoallylic alchols Journal of the Chemical Society, Chemical Communications. 194-196. DOI: 10.1039/C39890000194  0.278
2007 Gayral M, Brown JM. A Protocol for the Direct Conversion of Aldehydes into Arenes - Proof of -Principle Synlett. 2007: 2823-2826. DOI: 10.1055/S-2007-991088  0.277
1981 Brown JM, Milton DJ, Watson JKG, Zare RN, Albritton DL, Horani M, Rostas J. Higher-order fine structure of the a4Πu state of O2+ Journal of Molecular Spectroscopy. 90: 139-151. DOI: 10.1016/0022-2852(81)90338-6  0.277
1996 Ross AJ, Crozet P, Bacis R, Churassy S, Erba B, Ashworth SH, Lakin NM, Wickham MR, Beattie IR, Brown JM. Laser-induced fluorescence from CuCl2 in a free-jet expansion: High-resolution fourier transform spectra Journal of Molecular Spectroscopy. 177: 134-142. DOI: 10.1006/Jmsp.1996.0125  0.277
1986 Brown JM, Cook SJ, Jones RH, Khan R. Structural comparison of trehalose anomers; the X-ray crystal structures of αα-(2,3,4-tri-0-methyl-6-methanesulphonyl)glucopyranosyl-1-0-(2' 3' 4'-tri-o-methyl-6'- methanesulphonyl)glucopyranose, and its ββ-isomer Tetrahedron. 42: 5089-5096. DOI: 10.1016/S0040-4020(01)88061-3  0.276
1998 Brown JM, Körsgen H, Evenson KM. Fe+ in its ground6D state: A direct measurement of the J = 1/2-3/2 and J = 3/2-5/2 fine-structure intervals Astrophysical Journal. 509: 927-930. DOI: 10.1086/306539  0.276
2012 Gehring T, Quaranta M, Odell B, Blackmond DG, Brown JM. Observation of a transient intermediate in Soai's asymmetric autocatalysis: insights from 1H NMR turnover in real time. Angewandte Chemie (International Ed. in English). 51: 9539-42. PMID 22936384 DOI: 10.1002/Anie.201203398  0.276
2005 Hill C, Brown JM. Extended perturbation formulae for Jahn–Teller molecules Journal of Molecular Spectroscopy. 229: 207-215. DOI: 10.1016/J.Jms.2004.09.002  0.275
1981 Brown JM, Sidebottom PJ. The proton magnetic resonance spectrum of amphotericin B Tetrahedron. 37: 1421-1428. DOI: 10.1016/S0040-4020(01)92461-5  0.274
2003 Hill C, Newnham DA, Brown JM. Pressure-shift measurements of the oxygen A-band by Fourier-transform spectroscopy Journal of Molecular Spectroscopy. 219: 65-69. DOI: 10.1016/S0022-2852(03)00017-1  0.273
2002 Tamassia F, Brown JM, Watson JKG. The accurate determination of magnetic hyperfine and Zeeman parameters for 2∏ diatomic molecules from experimental data Molecular Physics. 100: 3485-3492. DOI: 10.1080/00268970210155635  0.273
1984 Brown JM, Cook SJ, Kimber SJ. Olefin displacement from 4,5-bis(diphenylphosphinomethyl)- 2,2-dimethyl-1,3-dioxolan ethyleneplatinum(0) under mild conditions Journal of Organometallic Chemistry. 269. DOI: 10.1016/S0022-328X(84)80001-7  0.273
1991 Schwalbe CH, Chopra G, Freeman S, Brown JM, Carey JV. Solid state conformations of six 1,3,2-oxazaphospholidines derived from (–)-ephedrine: X-ray crystal structures of the 2-phenoxy-2-oxo, 2-phenyl-2-oxo and 2-phenyl-2-thio analogues Journal of the Chemical Society-Perkin Transactions 1. 2081-2090. DOI: 10.1039/P29910002081  0.273
1986 Birtwistle DH, Brown JM, Foxton MW. Stereoselectivity in the hydroboration of chiral cyclohexane-derived allylic alcohols Tetrahedron Letters. 27: 4367-4370. DOI: 10.1016/S0040-4039(00)94276-X  0.272
1995 Brown JM, Evenson KM. Atomic iron in its 5D ground state: A direct measurement of the J = 0←1 and J = 1←2 fine-structure intervals Astrophysical Journal. 441: L97-L100. DOI: 10.1086/187799  0.271
1999 Brown JM, Evenson KM. Direct measurement of the fine-structure interval of 27Al in its ground 2P state Physical Review a - Atomic, Molecular, and Optical Physics. 60: 956-961. DOI: 10.1103/Physreva.60.956  0.27
2000 Hullah DF, Brown JM. The Electronic Spectrum of Tellurium Dioxide. Journal of Molecular Spectroscopy. 200: 261-265. PMID 10708539 DOI: 10.1006/Jmsp.1999.8044  0.269
1982 Brown JM, Jørgensen F. Anharmonic corrections for linear triatomic molecules subject to the Rennet-Teller effect Molecular Physics. 47: 1065-1086. DOI: 10.1080/00268978200100782  0.268
1988 Brown JM, Cooley NA. Carbon-carbon bond formation through organometallic elimination reactions Chemical Reviews. 88: 1031-1046. DOI: 10.1021/Cr00089A003  0.268
1980 Brown JM, Sears TJ, Watson JK. The isotopic dependence of the spin-rotation interaction for an asymmetric top molecule Molecular Physics. 41: 173-182. DOI: 10.1080/00268978000102661  0.268
1974 Brown JM, Bunton CA, Diaz S. Micellar general base-catalysed hydrolysis of diphenyl p-nitrophenyl phosphate Journal of the Chemical Society, Chemical Communications. 971-972. DOI: 10.1039/C39740000971  0.267
1975 Brown JM, Schofield JD. Localised regions of reduced mobility in micelles; 13C n.m.r. spin-lattice relaxation times of functional surfactants in aqueous solution Journal of the Chemical Society, Chemical Communications. 434-435. DOI: 10.1039/C39750000434  0.266
1977 Brown JM, Watson JKG. Spin-orbit and spin-rotation coupling in doublet states of diatomic molecules Journal of Molecular Spectroscopy. 65: 65-74. DOI: 10.1016/0022-2852(77)90358-7  0.266
2004 Brown JM. Mechanism in homogeneous catalysis; NMR as a prime mover Journal of Organometallic Chemistry. 689: 4006-4015. DOI: 10.1016/J.Jorganchem.2004.07.018  0.265
1982 Brown JM, Elliott RJ, Richards WG. Ab initio molecular orbital calculations on allylic anion–olefin interactions Journal of the Chemical Society-Perkin Transactions 1. 13: 485-488. DOI: 10.1039/P29820000485  0.265
1994 Brown JM, Zink LR, Evenson KM. A measurement of the J = 2 ← 1 fine-structure interval for 28Si and 29Si in the ground 3P state Astrophysical Journal. 423: L151-L154. DOI: 10.1086/187259  0.265
1999 Thomas IP, Ramsden JA, Kovacs TZ, Brown JM. Covalent adhesion; organic reactivity at a solid–solid interface through an inter-bead Diels–Alder reaction† Chemical Communications. 1507-1508. DOI: 10.1039/A901643K  0.263
1974 Brown JM, Ogilvy MM. Relative Ease Of Epimerization Of Syn-9-Fluoro-, Syn-9-Methoxy-, And Syn-9-Dimethylaminobicyclo(6.1.0)Nonatriene Cheminform. 5. DOI: 10.1002/Chin.197412155  0.263
2003 Ganser H, Urban W, Brown JM. The sensitive detection of NO by Faraday modulation spectroscopy with a quantum cascade laser Molecular Physics. 101: 545-550. DOI: 10.1080/00268970210159460  0.263
1987 Vasconcellos ECC, Davidson SA, Brown JM, Leopold KR, Evenson KM. Rotational and hyperfine constants of vibrationally excited NH (a1Δ; v = 1) Journal of Molecular Spectroscopy. 122: 242-245. DOI: 10.1016/0022-2852(87)90233-5  0.262
1974 Brown JM, Bunton CA. Stereoselective micelle-promoted ester hydrolysis Journal of the Chemical Society, Chemical Communications. 969-971. DOI: 10.1039/C39740000969  0.261
1997 Wienkoop M, Urban W, Brown JM. The NCN 211310Hot Band Measured by Infrared Laser Magnetic Resonance Spectroscopy Journal of Molecular Spectroscopy. 185: 185-186. PMID 9344810 DOI: 10.1006/Jmsp.1997.7346  0.261
1977 Alcock NW, Brown JM, Jeffery JC. Rhodium Phosphinoether Complexes. Part 2. Crystal and Molecular Structures of trans-[1,8-Bis(diphenylphosphino)-3,6-dioxaoctane-P,P′]carbonyl(ethanol)rhodium(l)Hexafluorophosphate and trans-[1,5-Bis(diphenylphosphino)-3-oxapentane-P,P Cheminform. 8. DOI: 10.1002/Chin.197729080  0.26
1988 Evenson KM, Jennings DA, Brown JM, Zink LR, Leopold KR. Frequency measurement of the J = 1-0 rotational transition of HD The Astrophysical Journal. 330: L135. DOI: 10.1086/185221  0.259
1988 Zink LR, Brown JM, Gilson TR, Beattie IR. the dispersed fluorescence of nickel dichloride under molecular beam conditions: A determination of ground-state vibrational intervals Chemical Physics Letters. 146: 501-506. DOI: 10.1016/0009-2614(88)87488-8  0.258
1988 Beaton SP, Evenson KM, Nelis T, Brown JM. Detection of the free radicals FeH, CoH, and NiH by far infrared laser magnetic resonance The Journal of Chemical Physics. 89: 4446-4448. DOI: 10.1063/1.454781  0.258
1984 Sears TJ, McKellar ARW, Bunker PR, Evenson KM, Brown JM. Infrared and far-infrared transition frequencies for the CH2 radical The Astrophysical Journal. 276: 399. DOI: 10.1086/161624  0.257
1991 Baker KV, Brown JM, Hughes N, Skarnulis AJ, Sexton A. Mechanical activation of magnesium turnings for the preparation of reactive Grignard reagents Journal of Organic Chemistry. 56: 698-703. DOI: 10.1021/Jo00002A039  0.257
1988 Brown JM, Jennings DA, Vanek M, Zink LR, Evenson KM. The pure rotational spectrum of ArH+ Journal of Molecular Spectroscopy. 128: 587-589. DOI: 10.1016/0022-2852(88)90173-7  0.257
2019 Bellini M, Inguscio M, Varberg TD, Brown JM. Precise experimental test of models for the breakdown of the Born-Oppenheimer separation: The rotational spectra of isotopic variants of lithium hydride. Physical Review. a, Atomic, Molecular, and Optical Physics. 52: 1954-1960. PMID 9912453 DOI: 10.1103/Physreva.52.1954  0.255
1973 Aris KR, Aris V, Brown JM. (13)C-Nmr-Spektren Von Metallorganischen Pi-Propen-Komplexen Cheminform. 4. DOI: 10.1002/Chin.197301081  0.255
1985 Brown JM, Derome AE, Kimber SJ. Association of alkali metal salts with polyene macrolides in methanol solution Tetrahedron Letters. 26: 253-256. DOI: 10.1016/S0040-4039(00)61893-2  0.254
1972 Brown JM, Uehara H. On the effective Zeeman Hamiltonian for a linear molecule in an orbitally degenerate state Molecular Physics. 24: 1169-1174. DOI: 10.1080/00268977200102241  0.254
1975 Alcock NW, Brown JM, Conneely JA, Stofko JJJ. Organorhodium Complexes Of Cis- And Trans-Divinylcyclopropane, The Crystal Structure Of (+-)-Zz-1,2,3-Eta-5,6,7-Eta-Heptadienediylrhodium(I) Hexafluoroacetylacetonate Cheminform. 6. DOI: 10.1002/Chin.197524396  0.253
2007 Cheng M, Brown JM, Rosmus P, Linguerri R, Komiha N, Myers EG. Dipole moments and orientation polarizabilities of diatomic molecular ions for precision atomic mass measurement Physical Review A. 75: 12502. DOI: 10.1103/Physreva.75.012502  0.252
1983 Broadhurst MJ, Brown JM, John RA. Kinetic and Thermodynamic Control in the Reaction of (Ph3P)2Pto2 with (E)-2-Butenal Angewandte Chemie. 22: 47-48. DOI: 10.1002/Anie.198300471  0.252
1985 BROWN JM, MACINTYRE JE. ChemInform Abstract: ALLYLIC ALKYLATION CATALYZED BY PLATINUM COMPLEXES: STRUCTURE AND REACTIVITY OF INTERMEDIATES, AND THE OVERALL STEREOSELECTIVITY Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198543336  0.251
1951 Burtner RR, Brown JM. Synthetic Choleretics. I. Naphthol Derivatives1 Journal of the American Chemical Society. 73: 897-900. DOI: 10.1021/Ja01147A004  0.25
2011 Prabagar J, Cowley AR, Brown JM. Electrophilic Routes to TertiaryAdamantyl and Diamantyl Phosphonium Salts Synlett. 2011: 2351-2354. DOI: 10.1055/S-0030-1260303  0.25
2007 Klankermayer J, Gridnev ID, Brown JM. Role of the isopropyl group in asymmetric autocatalytic zinc alkylations. Chemical Communications (Cambridge, England). 3151-3. PMID 17653371 DOI: 10.1039/B705978G  0.247
1994 Brown JM. Handbook of enantioselective catalysis with transition metal compounds Journal of Organometallic Chemistry. 479. DOI: 10.1016/0022-328X(94)84125-X  0.245
1964 Brown JM. Proton magnetic resonance spectra of phenoxide ions Tetrahedron Letters. 5: 2215-2218. DOI: 10.1016/S0040-4039(00)75157-4  0.243
1979 ALCOCK NW, BROWN JM, CONNEELY JA, WILLIAMSON DH. ChemInform Abstract: FURTHER STUDIES ON META Chemischer Informationsdienst. 10. DOI: 10.1002/Chin.197942076  0.242
1990 Leitão MLP, Pilcher G, Meng-Yan Y, Brown JM, Conn AD. Enthalpies of combustion of γ-butyrolactone, γ-valerolactone, and δ-valerolactone The Journal of Chemical Thermodynamics. 22: 885-891. DOI: 10.1016/0021-9614(90)90176-Q  0.241
2005 Hill C, Brown JM. Erratum to “Extended perturbation formulae for Jahn–Teller molecules” [J. Mol. Spectrosc. 229 (2005) 207–215] Journal of Molecular Spectroscopy. 232: 115. DOI: 10.1016/J.Jms.2005.03.001  0.241
2006 Hodges PJ, Beattie IR, Brown JM. The observation of the electronic spectrum of Fe2Cl6 in the gas phase. Physical Chemistry Chemical Physics : Pccp. 8: 2696-9. PMID 16763699 DOI: 10.1039/B605200B  0.241
2009 Xu Y, Celik MA, Thompson AL, Cai H, Yurtsever M, Odell B, Green JC, Mingos DM, Brown JM. Tetrameric iridium hydride-rich clusters formed under hydrogenation conditions. Angewandte Chemie (International Ed. in English). 48: 582-5. PMID 19067451 DOI: 10.1002/Anie.200804484  0.24
1991 Brown JM. Synthesis with a strong hand Nature. 350: 191-191. DOI: 10.1038/350191A0  0.24
1981 Brown JM, Elliott RL, Griggs CG, Helmchen G, Nill G. Selective Micellar Catalysis with Histidinyl Surfactants of Defined Absolute Configuration Angewandte Chemie. 20: 890-892. DOI: 10.1002/Anie.198108901  0.239
2000 Bosch E, Crozet P, Ross AJ, Brown JM. Fourier Transform Spectra of the E(2)Pi(u)-X(2)Pi(g)((3/2)) System of CuCl(2). Journal of Molecular Spectroscopy. 202: 253-261. PMID 10877955 DOI: 10.1006/Jmsp.2000.8128  0.238
2000 Brown JM, Giernoth R. New mechanistic aspects of the asymmetric homogeneous hydrogenation of alkenes. Current Opinion in Drug Discovery & Development. 3: 825-32. PMID 19649910  0.238
2005 Lockhart A, Ye L, Judd DB, Merritt AT, Lowe PN, Morgenstern JL, Hong G, Gee AD, Brown J. Evidence for the presence of three distinct binding sites for the thioflavin T class of Alzheimer's disease PET imaging agents on beta-amyloid peptide fibrils. The Journal of Biological Chemistry. 280: 7677-84. PMID 15615711 DOI: 10.1074/Jbc.M412056200  0.238
1998 Whitham CJ, Beaton SA, Ito Y, Brown JM. Laser Excitation Spectroscopy of theB̃2A1–X̃2A1Transition of the CaOCH3Radical☆ Journal of Molecular Spectroscopy. 191: 286-294. PMID 9753563 DOI: 10.1006/Jmsp.1998.7642  0.236
1997 Hughes RA, Brown JM. A Determination of the Vibrational Anharmonicity of PD in Its X3Sigma;ms State Journal of Molecular Spectroscopy. 185: 197-201. PMID 9344815 DOI: 10.1006/Jmsp.1997.7405  0.236
1973 Brown JM, Golding BT, Stofko JJ. Isolation and characterisation of cis-divinylcyclopropane Journal of the Chemical Society, Chemical Communications. DOI: 10.1039/C3973000319B  0.235
1973 Aris V, Brown JM, Golding BT. Umorientierung Des Verlaufs Der Cope-Umlagerung Durch Koordinierung, Die Thermolyse Von Endo-6-Vinyl-Bicyclo(3,1,0)Hex-2-En-Rhodium(I)-Acetylacetonat Cheminform. 4. DOI: 10.1002/Chin.197308132  0.234
1987 Brown JM. Intramolekular gesteuerte katalytische Hydrierungen in homogener Phase Angewandte Chemie. 99: 169-182. DOI: 10.1002/Ange.19870990304  0.233
1947 Burtner RR, Brown JM. Antispasmodics; diarylacetic acid esters of some pyridyl and piperidyl alkanols. Journal of the American Chemical Society. 69: 630-633. PMID 20289450 DOI: 10.1021/Ja01195A048  0.232
1993 Brown JM, Evenson KM, Zink LR. Laser magnetic-resonance measurement of the 3P1-3P2 fine-structure splittings in 17O and 18O. Physical Review. A. 48: 3761-3763. PMID 9910047 DOI: 10.1103/Physreva.48.3761  0.231
1989 Brown JM, Conn AD, Pilcher G, Leitão MLP, Meng-Yan Y. On the strain energy of 5-ring and 6-ring lactones Journal of the Chemical Society, Chemical Communications. 1817-1819. DOI: 10.1039/C39890001817  0.23
2005 Rainville S, Thompson JK, Myers EG, Brown JM, Dewey MS, Kessler EG, Deslattes RD, Börner HG, Jentschel M, Mutti P, Pritchard DE. World Year of Physics: a direct test of E=mc2. Nature. 438: 1096-7. PMID 16371997 DOI: 10.1038/4381096A  0.229
2009 Brown J, Deeth R. Ist die Enantioselektivität bei der asymmetrischen Katalyse vorhersagbar? Angewandte Chemie. 121: 4544-4547. DOI: 10.1002/Ange.200900697  0.228
2009 Brown JM, Deeth RJ. Is enantioselectivity predictable in asymmetric catalysis? Angewandte Chemie (International Ed. in English). 48: 4476-9. PMID 19431177 DOI: 10.1002/Anie.200900697  0.227
1982 Brown JM, Elliott RL, Griggs CG, Helmchen G, Nill G. Selektive micellare Katalyse mit Histidinyl‐Tensiden definierter absoluter Konfiguration. Cheminform. 13. DOI: 10.1002/Chin.198204070  0.227
1981 Brown JM, Elliott RL, Griggs CG, Helmchen G, Nill G. Selektive micellare Katalyse mit Histidinyl‐Tensiden definierter absoluter Konfiguration Angewandte Chemie. 93: 906-907. DOI: 10.1002/Ange.19810931019  0.227
1974 Brown J, Langlois JR, Lauren DR, Stoochnoff BK, Williams RE. Water-soluble Lysine-containing Polypeptides. I. The Synthesis and Characterization of Several Sequential Lysine–Glycine Polypeptides Including a Preliminary Study of their Interaction with DNA Canadian Journal of Chemistry. 52: 3140-3148. DOI: 10.1139/V74-461  0.223
2012 Pina C, Fugazza C, Tipping AJ, Brown J, Soneji S, Teles J, Peterson C, Enver T. Inferring rules of lineage commitment in haematopoiesis. Nature Cell Biology. 14: 287-94. PMID 22344032 DOI: 10.1038/Ncb2442  0.223
1996 Brown JM, Ramsden JA. Supports for solid-phase synthesis with high fluidity and high functionality Chemical Communications. 2117-2118. DOI: 10.1039/Cc9960002117  0.223
1993 Ashworth SH, Grieman FJ, Brown JM, Jones PJ, Beattie IR. Structure of nickel dichloride Journal of the American Chemical Society. 115: 2978-2979. DOI: 10.1021/Ja00060A057  0.222
1991 Brown JM, Woodward S. Selective ortho lithiation of (2,5-dimethoxyphenyl)diphenylphosphine oxide and trapping of the resulting aryllithium with electrophiles Journal of Organic Chemistry. 56: 6803-6809. DOI: 10.1021/Jo00024A019  0.217
2002 Ashworth SH, Hodges PJ, Brown JM. The detection of the electronic spectrum of FeCl2 in the gas phase Physical Chemistry Chemical Physics. 4: 5923-5924. DOI: 10.1039/B209523H  0.217
2003 Hill C, Brown JM, Newnham DA. An upper limit for the magnitude of pressure shifts in the O2 band Journal of Molecular Spectroscopy. 221: 286-287. DOI: 10.1016/S0022-2852(03)00227-3  0.217
1976 Brown JM, Jenkins JA. Micelle-related heterogeneous catalysis. Anion-activation by polymer-linked cationic surfactants Journal of the Chemical Society, Chemical Communications. 458-459. DOI: 10.1039/C39760000458  0.214
1994 Hirota E, Brown JM, Hougen JT, Shida T, Hirota N. Symbols for fine and hyperfine structure parameters (IUPAC Recommendations 1994) Pure and Applied Chemistry. 66: 571-576. DOI: 10.1351/Pac199466030571  0.214
1998 Jones P, May G, Healy L, Brown J, Hoyne G, Delassus S, Enver T. Stromal Expression of Jagged 1 Promotes Colony Formation by Fetal Hematopoietic Progenitor Cells Blood. 92: 1505-1511. DOI: 10.1182/Blood.V92.5.1505.417K42_1505_1511  0.214
1998 Brown JM, Zink LR, Evenson KM. 19F+atom in its ground3Pstate: TheJ=0←1fine-structure interval Physical Review A. 57: 2507-2510. DOI: 10.1103/Physreva.57.2507  0.213
2015 Brown JM. New Trends in Cross-Coupling – Theory and Applications. Edited by Thomas J. Colacot Angewandte Chemie. 54: 5003-5003. DOI: 10.1002/Anie.201501713  0.213
1984 Cook SJ, Khan R, Brown JM. A simple route toβ,β-trehalose via trichloroacetimidates Journal of Carbohydrate Chemistry. 3: 343-348. DOI: 10.1080/07328308408058825  0.212
1973 Brown JM, Golding BT, Stofko JJ. Isolierung Und Charakterisierung Von Cis-Divinyl-Cyclopropan Cheminform. 4. DOI: 10.1002/Chin.197330218  0.211
2009 Cheng M, Brown JM, Rosmus P, Linguerri R, Komiha N, Myers EG. Erratum: Dipole moments and orientation polarizabilities of diatomic molecular ions for precision atomic mass measurement [Phys. Rev. A 75, 012502 (2007)] Physical Review A. 79: 59903. DOI: 10.1103/Physreva.79.059903  0.209
1975 Brown J, Hougen J, Huber K, Johns J, Kopp I, Lefebvre-Brion H, Merer A, Ramsay D, Rostas J, Zare R. The labeling of parity doublet levels in linear molecules Journal of Molecular Spectroscopy. 55: 500-503. DOI: 10.1016/0022-2852(75)90291-X  0.207
1957 Brown J, Svensson M. Additions and Corrections: The Stability of Potassium Borohydride in Alkaline Solutions. Journal of the American Chemical Society. 79: 6581-6581. DOI: 10.1021/Ja01581A654  0.206
1983 Broadhurst MJ, Brown JM, John RA. Kinetische und thermodynamische Kontrolle der Reaktion von (Ph3P),PtO2 mit (E)‐2‐ Butenal. Cheminform. 14. DOI: 10.1002/Chin.198316297  0.205
1981 Kukla G, Berger A, Lotti R, Brown J. Orbital signature of interglacials Nature. 290: 295-300. DOI: 10.1038/290295A0  0.205
1988 BROWN JM, EVANS PL, LUCY AR. ChemInform Abstract: Stereochemistry of Intermediates in Homogeneous Hydrogenation Catalyzed by Tristriphenylphosphinerhodium Chloride, Employing NMR Magnetization Transfer. Cheminform. 19. DOI: 10.1002/chin.198809331  0.203
1953 Burtner RR, Brown JM. Synthetic Choleretics. II. Phenol Derivatives1 Journal of the American Chemical Society. 75: 2334-2340. DOI: 10.1021/Ja01106A014  0.202
1965 Brown JM. Isolation of a cis-1,2-divinylcyclopropane Chemical Communications (London). 226-227. DOI: 10.1039/C19650000226  0.2
1980 BROWN JM, CHALONER AP. ChemInform Abstract: THE MECHANISM OF ASYMMETRIC HOMOGENEOUS HYDROGENATION. RHODIUM(I) COMPLEXES OF DEHYDROAMINO ACIDS CONTAINING ASYMMETRIC LIGANDS RELATED T BIS(1,2-DIPHENYLPHOSPHINO)ETHANE Chemischer Informationsdienst. 11. DOI: 10.1002/chin.198030319  0.197
1965 Brown JM, Occolowitz JL. A non-classical carbanion Chemical Communications (London). 376-377. DOI: 10.1039/C19650000376  0.194
2012 Paton RS, Brown JM. Zweikernige Palladiumkomplexe - Vorstufen oder Katalysatoren? Angewandte Chemie. 124: 10598-10600. DOI: 10.1002/Ange.201205417  0.194
1980 Brown JM, Bunton CA, Diaz S, Ihara Y. Dephosphorylation in functional micelles. The role of the imidazole group The Journal of Organic Chemistry. 45: 4169-4174. DOI: 10.1021/Jo01309A021  0.194
1980 BROWN JM, MURRER BA. ChemInform Abstract: R-PHENYL BIS(DIPHENYLPHOSPHINO)ETHANE; STRUCTURAL STUDIES PERTAINING TO RHODIUM-CATALYZED ASYMMETRIC HYDROGENATION Chemischer Informationsdienst. 11. DOI: 10.1002/chin.198010132  0.194
2015 Brown JM. New Trends in Cross‐Coupling – Theory and Applications. Herausgegeben von Thomas J. Colacot Angewandte Chemie. 127: 5087-5087. DOI: 10.1002/Ange.201501713  0.193
1978 Brown JM. Selective homogenous and heterogeneous catalysis Ciba Foundation Symposium. 149-173. PMID 246778  0.193
1996 Brown JM, Kuok K. Die Charakterisierung reaktiver Zwischenstufen in der Palladium‐katalysierten Arylierung von Methylacrylat (Heck‐Reaktion) Angewandte Chemie. 108: 679-682. DOI: 10.1002/Ange.19961080610  0.189
1999 Dickson TJ, Gurudutt V, Nguyen AQ, Kumfer K, Maxted W, Brown J, Mahomed Y, Sharp T, Aufiero TX, Fineberg N, March KL. Establishment of a clinically correlated human pericardial fluid bank: evaluation of intrapericardial diagnostic potential. Clinical Cardiology. 22: I40-2. PMID 9929767 DOI: 10.1002/Clc.4960221311  0.189
1959 Bernstein S, Littlell R, Brown J, Ringler I. Additions and Corrections: 16-Hydoxylated Steroids. XII. The 16a,-17a-Acetonides of Synthetic Non-halogenated Corticoids. Journal of the American Chemical Society. 81: 6537-6537. DOI: 10.1021/Ja01533A651  0.188
1984 Cook SJ, Khan R, Brown JM. A SIMPLE ROUTE TO β,β-TREHALOSE VIA TRICHLOROACETIMIDATES Cheminform. 15. DOI: 10.1002/Chin.198446349  0.187
2010 Fiaud J, Brown JM. Henri Kagan; an 80th birthday appreciation Tetrahedron-Asymmetry. 21: 1017-1018. DOI: 10.1016/J.Tetasy.2010.06.016  0.182
1988 BROWN JM, CHALONER PA, MORRIS GA. ChemInform Abstract: The Catalytic Resting State of Asymmetric Homogeneous Hydrogenation. Exchange Processes Delineated by NMR Saturation-Transfer (DANTE) Techniques. Cheminform. 19. DOI: 10.1002/chin.198809330  0.179
1984 Brazier CR, Brown JM. A measurement of the lambda-type doubling spectrum of the CH radical by microwave-optical double resonance: further characterization of the A2Δ state Canadian Journal of Physics. 62: 1563-1578. DOI: 10.1139/p84-201  0.178
1989 ALCOCK NW, BROWN JM, EVANS PL. ChemInform Abstract: Phosphino Sulfoxide Rhodium Complexes. Synthesis, Crystal Structure, and Catalytic Chemistry of ((2,3,5,6-η)-Bicyclo(2.2.1)hepta-2,5-diene)(P,O-diphenyl(phenylsulfinylmeth# yl)phosphine)rhodium(I) Trifluoromethanesulfonate and Asymmet Cheminform. 20. DOI: 10.1002/chin.198920275  0.178
2005 Parker CA, Matthews JC, Brown J, Gee AD, Rabiner EA. The effect of ionic environments on the affinity of D2-dopamine receptor radioligands Journal of Cerebral Blood Flow and Metabolism. 25. DOI: 10.1038/Sj.Jcbfm.9591524.0616  0.176
2007 Pina C, Atzberger A, Soneji S, Guo Y, Brown J, May G, Enver T. Identifying MLLT3 as a novel regulator of erythropoiesis Blood Cells Molecules and Diseases. 38: 173. DOI: 10.1016/J.Bcmd.2006.10.120  0.171
1983 BROWN JM. ChemInform Abstract: REACTIVITY AND SELECTIVITY IN CATALYSIS BY RHODIUM COMPLEXES Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198306360  0.171
2004 Deeth RJ, Smith A, Brown JM. Electronic control of the regiochemistry in palladium-phosphine catalyzed intermolecular heck reactions Journal of the American Chemical Society. 126: 7144-7151. DOI: 10.1021/ja0315098  0.164
2010 DOUCET H, BROWN JM. ChemInform Abstract: Synthesis of 1′-(2-(Diarylphosphino)1-naphthyl)isoquinolines; Variation of the Aryl Substituent. Cheminform. 29: no-no. DOI: 10.1002/chin.199812145  0.164
2010 BROWN JM, PEARSON M, JASTRZEBSKI TBH, VAN KOTEN G. ChemInform Abstract: Intramolecular Facilitation of Aryl-Transfer from Tin in Palladium- Catalyzed, Cross-Coupling. Cheminform. 24: no-no. DOI: 10.1002/chin.199303116  0.158
1989 BROWN JM. ChemInform Abstract: Chirality Recognition in Synthesis: Catalytic Kinetic Resolution Cheminform. 20. DOI: 10.1002/chin.198909345  0.151
2010 Carmichael D, Doucet H, Brown JM. ChemInform Abstract: Hybrid P-Chiral Diphosphines for Asymmetric Hydrogenation. Cheminform. 30: no-no. DOI: 10.1002/chin.199922036  0.147
1988 BROWN JM, KENT AG. ChemInform Abstract: Structural Characterization in Solution of Intermediates in Rhodium-Catalyzed Hydroformylation and Their Interconversion Pathways. Cheminform. 19. DOI: 10.1002/chin.198810349  0.146
2010 ALCOCK NW, BROWN JM, HULMES DI. ChemInform Abstract: Synthesis and Resolution of 1-(2-Diphenylphosphino-1-naphthyl) isoquinoline; a P-N Chelating Ligand for Asymmetric Catalysis. Cheminform. 24: no-no. DOI: 10.1002/chin.199331216  0.146
1985 Poeppelmeier K, Newsam J, Brown J. The structural interrelationship between the three polymorphs of Rh2O3 and Rh2S3, Rh2Se3, and Ir2S3 Journal of Solid State Chemistry. 60: 68-73. DOI: 10.1016/0022-4596(85)90164-1  0.144
2015 Lermyte F, Williams JP, Brown JM, Martin EM, Sobott F. Extensive Charge Reduction and Dissociation of Intact Protein Complexes Following Electron Transfer on a Quadrupole-Ion Mobility-Time-of-Flight MS. Journal of the American Society For Mass Spectrometry. 26: 1068-76. PMID 25862188 DOI: 10.1007/s13361-015-1124-z  0.143
2015 Harvey SR, Yan J, Brown JM, Hoyes E, Wysocki VH. Extended gas-phase trapping followed by surface-induced dissociation of non-covalent protein complexes. Analytical Chemistry. PMID 26641730 DOI: 10.1021/Acs.Analchem.5B03479  0.14
2018 Mistarz UH, Chandler SA, Brown JM, Benesch JLP, Rand KD. Probing the Dissociation of Protein Complexes by Means of Gas-Phase H/D Exchange Mass Spectrometry. Journal of the American Society For Mass Spectrometry. PMID 30460642 DOI: 10.1007/s13361-018-2064-1  0.14
2023 Brown J, Forero-Saboya J, Baptiste B, Karlsmo M, Rousse G, Grimaud A. A guanidium salt as a chaotropic agent for aqueous battery electrolytes. Chemical Communications (Cambridge, England). 59: 12266-12269. PMID 37750815 DOI: 10.1039/d3cc03769j  0.136
2023 Brown J, Grimaud A. Proton-donating and chemistry-dependent buffering capability of amino acids for the hydrogen evolution reaction. Physical Chemistry Chemical Physics : Pccp. 25: 8005-8012. PMID 36876498 DOI: 10.1039/d3cp00552f  0.134
2015 Lermyte F, Verschueren T, Brown JM, Williams JP, Valkenborg D, Sobott F. Characterization of top-down ETD in a travelling-wave ion guide. Methods (San Diego, Calif.). 89: 22-9. PMID 26014039 DOI: 10.1016/j.ymeth.2015.05.019  0.132
2012 Bhattacharya P, Kim SH, Chen P, Chen R, Spuches AM, Brown JM, Lamm MH, Ke PC. Dendrimer-Fullerenol Soft-Condensed Nanoassembly. The Journal of Physical Chemistry. C, Nanomaterials and Interfaces. 116: 15775-15781. PMID 23185644 DOI: 10.1021/Jp3036692  0.128
2014 Johnson EA, Rice SL, Preimesberger MR, Nye DB, Gilevicius L, Wenke BB, Brown JM, Witman GB, Lecomte JT. Characterization of THB1, a Chlamydomonas reinhardtii truncated hemoglobin: linkage to nitrogen metabolism and identification of lysine as the distal heme ligand. Biochemistry. 53: 4573-89. PMID 24964018 DOI: 10.1021/bi5005206  0.125
1974 BEEBY PJ, BROWN JM, GARRATT PJ, SONDHEIMER F. ChemInform Abstract: BRIDGED DIDEHYDROAZA(17)ANNULENYL ANIONS, A GROUP OF STRONGLY DIATROPIC HETEROCYCLES Chemischer Informationsdienst. 5: no-no. DOI: 10.1002/chin.197420365  0.122
2015 Brown JM. ChemInform Abstract: Rhodium Asymmetric Hydrogenation Observed During Its Exponential Growth Phase Cheminform. 46: no-no. DOI: 10.1002/chin.201504277  0.115
1983 Brazier CR, Brown JM, Purnell MR. Nuclear hyperfine splittings for copper monofluoride in the a3Σ+ state Journal of Molecular Spectroscopy. 99: 279-287. DOI: 10.1016/0022-2852(83)90313-2  0.115
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