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High-probability grants
According to our matching algorithm, Rinaldo Poli is the likely recipient of the following grants.
Years |
Recipients |
Code |
Title / Keywords |
Matching score |
1993 — 1995 |
Kozarich, John (co-PI) [⬀] Poli, Rinaldo Eichhorn, Bryan (co-PI) [⬀] Falvey, Daniel (co-PI) [⬀] |
N/AActivity Code Description: No activity code was retrieved: click on the grant title for more information |
Upgrade of An Epr Spectrometer @ University of Maryland College Park
This award from the Chemistry Research Instrumentation Program will assist the Department of Chemistry at the University of Maryland in the purchase of an upgrade for an electron spin resonance (ESR) spectrometer. This upgrade is essential if the PI's are to make much more effective of the present equipment. The research projects that will be enhanced by the acquisition of this equipment include: 1) Studies of the electronic structure of organometallic 15-electron complexes, 2) Formation and electonic structure studies of 17 electron dihydride complexes, 3) Photochemical and electrochemical generation of arylnitrenium (Ar-N-R+) ions, probable intermediates in chemical carcinogenesis, and the study of their electronic structure, 4) ESR studies of organometallic and molecular-based inorganic polymers with bulk ferromagnetism and low dimensional conductivity, 5) ESR studies of enzyme-stablized radicals in biological processes. %%% An electron spin resonance (ESR) spectrometer provides information about the electronic structure of molecules and can detect the presence of "free radicals" which play an important in many chemical and biological interactions.
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1 |
1995 — 1998 |
Poli, Rinaldo Eichhorn, Bryan [⬀] |
N/AActivity Code Description: No activity code was retrieved: click on the grant title for more information |
Organometallic Chemistry of Open-Shell Systems @ University of Maryland College Park
With this award, the Inorganic, Bioinorganic, and Organometallic Program supports research on odd-electron organometallic compounds by Dr. Rinaldo Poli of the Chemistry Department, University of Maryland at College Park. Dr. Poli will prepare new organometallic compounds of molybdenum, chromium, vanadium, and tungsten which contain 15 or 17 electrons and investigate their reactivity using EPR and other methods. Pairing energies and orbital splittings for the stabilization of these `open shells` in organometallic systems will be determined, thus increasing understanding of reactive intermediates in catalytic cycles. Most stable organometallic compounds contain 18 valence electrons, or in some instances 16, and do not exhibit a wide variety of oxidation states. By investigating species which have an odd number of electrons and accommodate a wider variety of ligands, information on the role of spin pairing in reaction kinetics will be obtained. This information will be valuable in the design of reactive species which may serve as new catalytic agents for organic synthesis.
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1 |