William John Smith

2002

William R. Roush	grad student	2002	University of Michigan
(Selected studies in asymmetric synthesis: I. Factors which control the stereochemistry of methyl ketone aldol reactions. II. An experimental test for the involvement of boat-like transition states in methyl ketone aldol reactions. III. Studies directed to)

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Handa M, Smith WJ, Roush WR. (2008) Studies on the synthesis of apoptolidin A. 2. Synthesis of the disaccharide unit. The Journal of Organic Chemistry. 73: 1036-9
Liu CM, Smith WJ, Gustin DJ, et al. (2005) Experimental evidence for chair-like transition states in aldol reactions of methyl ketone lithium enolates: stereoselective synthesis and utilization of a deuterium-labeled enolate as a probe of reaction stereochemistry. Journal of the American Chemical Society. 127: 5770-1
Roush WR, Bannister TD, Wendt MD, et al. (2002) An NMR method for assigning relative stereochemistry to beta-hydroxy ketones deriving from aldol reactions of methyl ketones. The Journal of Organic Chemistry. 67: 4284-9
Sawyer JS, Schmittling EA, Palkowitz JA, et al. (1998) Synthesis of Diaryl Ethers, Diaryl Thioethers, and Diarylamines Mediated by Potassium Fluoride-Alumina and 18-Crown-6: Expansion of Scope and Utility(1). The Journal of Organic Chemistry. 63: 6338-6343