Kengkaj Sukcharoenphon, Ph.D.

Affiliations: 
University of Miami, Coral Gables, FL 
Area:
Organometallic Chemistry
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"Kengkaj Sukcharoenphon"
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Carl D. Hoff grad student 2003 University of Miami
 (The activation of N-heterocyclic thiols and disulfides by Group VI organometallic complexes: A kinetic and thermodynamic study.)
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McDonough JE, Weir JJ, Sukcharoenphon K, et al. (2006) Comparison of thermodynamic and kinetic aspects of oxidative addition of PhE-EPh (E = S, Se, Te) to Mo(CO)3(PR3)2, W(CO)3(PR3)2, and Mo(N[tBu]Ar)3 complexes. The role of oxidation state and ancillary ligands in metal complex induced chalcogenyl radical generation. Journal of the American Chemical Society. 128: 10295-303
McGrath TD, Stone FG, Sukcharoenphon K. (2005) Substitution, cage functionalization, and oxidation of the charge-compensated triruthenium monocarbollide cluster complex [1-SMe2-2,2-(CO)2-7,11-(mu-H)2-2,7,11-{Ru2(CO)6}-closo-2,1-RuCB10H8]. Dalton Transactions (Cambridge, England : 2003). 2500-7
Sukcharoenphon K, Moran D, Schleyer Pv, et al. (2003) Increased reactivity of the *Cr(CO)3(C5Me5) radical with thiones versus thiols: a theoretical and experimental investigation. Inorganic Chemistry. 42: 8494-503
Sukcharoenphon K, Ju TD, Abboud KA, et al. (2002) Dinuclear oxidative addition of N-H and S-H bonds at chromium. Reaction of (*)Cr(CO)(3)(C(5)Me(5)) with [o-(HA)C(6)H(4)S-Cr(CO)(3)(C(5)Me(5))] (A = S, NH) yielding [eta(2)-o-(mu-A)C(6)H(4)S-Cr(C(5)Me(5))](2) and H-Cr(CO)(3)(C(5)Me(5)). Inorganic Chemistry. 41: 6769-74
Moran D, Sukcharoenphon K, Puchta R, et al. (2002) 2-Pyridinethiol/2-pyridinethione tautomeric equilibrium. A comparative experimental and computational study. The Journal of Organic Chemistry. 67: 9061-9
Sukcharoenphon K, Capps KB, Abboud KA, et al. (2001) Synthesis and structure of W(eta(2)-mp)(2)(CO)(3) (mp = monoanion of 2-mercaptopyridine) and its reactions with 2,2'-pyridine disulfide and/or NO to yield W(eta(2)-mp)(4), W(eta(2)-mp)(2)(NO)(2), and W(eta(2)-mp)(3)(NO). Inorganic Chemistry. 40: 2402-8
Capps KB, Bauer A, Sukcharoenphon K, et al. (1999) Kinetic and Thermodynamic Studies of Reaction of *Cr(CO)(3)C(5)Me(5), HCr(CO)(3)C(5)Me(5), and PhSCr(CO)(3)C(5)Me(5) with *NO. Reductive Elimination of Thermodynamically Unstable Molecules HNO and RSNO Driven by Formation of the Strong Cr-NO Bond. Inorganic Chemistry. 38: 6206-6211
Capps KB, Bauer A, Sukcharoenphon K, et al. (1999) Kinetic and thermodynamic studies of reaction of •Cr(CO)3C5Me5, HCr(CO)3C5Me5, and PhSCr(CO)3C5Me5 with •NO. Reductive elimination of thermodynamically unstable molecules HNO and RSNO driven by formation of the strong CR-NO bond Inorganic Chemistry. 38: 6206-6211
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