James E. McDonough, Ph.D.
Affiliations: | University of Miami, Coral Gables, FL |
Area:
Organometallic ChemistryGoogle:
"James McDonough"Mean distance: 9.71 | S | N | B | C | P |
Parents
Sign in to add mentor| Carl D. Hoff | grad student | 2005 | University of Miami | |
| (Thermodynamic and kinetic studies of ligand binding, oxidative addition, and group/atom transfer in group VI metal complexes.) | ||||
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Publications
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| Germain ME, Temprado M, Castonguay A, et al. (2009) Coordination-mode control of bound nitrile radical complex reactivity: intercepting end-on nitrile-Mo(III) radicals at low temperature. Journal of the American Chemical Society. 131: 15412-23 |
| Achord P, Fujita E, Muckerman JT, et al. (2009) Experimental and computational studies of binding of dinitrogen, nitriles, azides, diazoalkanes, pyridine, and pyrazines to M(PR(3))(2)(CO)(3) (M = Mo, W; R = Me, (i)Pr). Inorganic Chemistry. 48: 7891-904 |
| Temprado M, McDonough JE, Mendiratta A, et al. (2008) Thermodynamic and kinetic studies of H atom transfer from HMo(CO)3(eta(5)-C5H5) to Mo(N[t-Bu]Ar)3 and (PhCN)Mo(N[t-Bu]Ar)3: direct insertion of benzonitrile into the Mo-H bond of HMo(N[t-Bu]Ar)3 forming (Ph(H)C=N)Mo(N[t-Bu]Ar)3. Inorganic Chemistry. 47: 9380-9 |
| McDonough JE, Mendiratta A, Curley JJ, et al. (2008) Thermodynamic, kinetic, and computational study of heavier chalcogen (S, Se, and Te) terminal multiple bonds to molybdenum, carbon, and phosphorus. Inorganic Chemistry. 47: 2133-41 |
| Fortman GC, Isrow D, McDonough JE, et al. (2008) Kinetic and thermodynamic studies of the reactivity of (trimethylsilyl) diazomethane with HMo(CO)3(C5R5) (R = H, Me). Estimation of the Mo-N2CH2SiMe3 bond strength and experimental determination of the enthalpy of formation of (trimethylsilyl)diazomethane Organometallics. 27: 4873-4884 |
| Weir JJ, McDonough JE, Fortman G, et al. (2007) Synthesis, structure, and thermochemistry of the formation of the metal-metal bonded dimers [Mo(mu-TeAr)(CO)3(PiP3)]2 (Ar = phenyl, naphthyl) by phosphine elimination from *Mo(TePh)(CO)3(PiPr3)2. Inorganic Chemistry. 46: 652-9 |
| McDonough JE, Weir JJ, Sukcharoenphon K, et al. (2006) Comparison of thermodynamic and kinetic aspects of oxidative addition of PhE-EPh (E = S, Se, Te) to Mo(CO)3(PR3)2, W(CO)3(PR3)2, and Mo(N[tBu]Ar)3 complexes. The role of oxidation state and ancillary ligands in metal complex induced chalcogenyl radical generation. Journal of the American Chemical Society. 128: 10295-303 |
| Mendiratta A, Cummins CC, Kryatova OP, et al. (2006) Benzonitrile extrusion from molybdenum(IV) ketimide complexes obtained via radical C-E (E = O, S, Se) bond formation: toward a new nitrogen atom transfer reaction. Journal of the American Chemical Society. 128: 4881-91 |
| Stephens FH, Johnson MJ, Cummins CC, et al. (2005) Mechanism of white phosphorus activation by three-coordinate molybdenum(III) complexes: a thermochemical, kinetic, and quantum chemical investigation. Journal of the American Chemical Society. 127: 15191-200 |
| McDonough JE, Weir JJ, Carlson MJ, et al. (2005) Solution calorimetric and stopped-flow kinetic studies of the reaction of *Cr(CO)3C5Me5 with PhSe-SePh and PhTe-TePh. Experimental and theoretical estimates of the Se-Se, Te-Te, H-Se, and H-Te bond strengths. Inorganic Chemistry. 44: 3127-36 |