Leah N. Appelhans, Ph.D.

Affiliations: 
Yale University, New Haven, CT 
Area:
organometallics, inorganic
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"Leah Appelhans"
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Robert H. Crabtree grad student 2007 Yale
 (Rhodium and iridium complexes of Fischer and N-heterocyclic carbenes: Synthesis and reactivity.)
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Publications

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Appelhans LN, Incarvito CD, Crabtree RH. (2008) Synthesis of monodentate bis(N-heterocyclic carbene) complexes of iridium: Mixed complexes of abnormal NHCs, normal NHCs, and triazole NHCs Journal of Organometallic Chemistry. 693: 2761-2766
Voutchkova AM, Appelhans LN, Chianese AR, et al. (2005) Disubstituted imidazolium-2-carboxylates as efficient precursors to N-heterocyclic carbene complexes of Rh, Ru, Ir, and Pd. Journal of the American Chemical Society. 127: 17624-5
Appelhans LN, Zuccaccia D, Kovacevic A, et al. (2005) An anion-dependent switch in selectivity results from a change of C-H activation mechanism in the reaction of an imidazolium salt with IrH5(PPh3)2. Journal of the American Chemical Society. 127: 16299-311
Clot E, Chen J, Lee DH, et al. (2004) Double geminal C-H activation and reversible alpha-elimination in 2-aminopyridine iridium(III) complexes: the role of hydrides and solvent in flattening the free energy surface. Journal of the American Chemical Society. 126: 8795-804
Li X, Appelhans LN, Faller JW, et al. (2004) Stoichiometric C-C coupling reactions in the coordination sphere of an iridium(III) alkyl Organometallics. 23: 3378-3387
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