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Xiaofan Yang, Ph.D.

Affiliations: 
Chemistry Indiana University, Bloomington, Bloomington, IN, United States 
Area:
Catalysis, transition metal hydride chemistry
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"Xiaofan Yang"
Mean distance: 8.74
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Kenneth G. Caulton grad student 2008 Indiana University Bloomington
 (Application of density functional theory on water oxidation catalysts and a combined experimental/theoretical study of carbene complexes (arene)M=C(Ph2P=NPh)2 (M = ruthenium and osmium).)

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Publications

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Walstrom AG, Pink M, Yang X, et al. (2009) Synthesis and reactivity of a Ru(I) dimer devoid of pi-acid ligands. Dalton Transactions (Cambridge, England : 2003). 6001-6
Yang X, Baik MH. (2008) The mechanism of water oxidation catalysis promoted by [tpyRu(IV)=O]2L3+: a computational study. Journal of the American Chemical Society. 130: 16231-40
Fullmer BC, Pink M, Fan H, et al. (2008) The effect of one valence electron: contrasting (PNP)Ni(CO) with (PNP)Ni(NO) to understand the half-bent NiNO unit. Inorganic Chemistry. 47: 3888-92
Ketterer NA, Fan H, Blackmore KJ, et al. (2008) Pi*-pi* bonding interactions generated by halogen oxidation of zirconium(IV) redox-active ligand complexes. Journal of the American Chemical Society. 130: 4364-74
Yang X, Walstrom A, Tsvetkov N, et al. (2007) Influence of chelate substituents on the structure and spin state of unsaturated [N(SiMe2CH2PtBu2)2]Ru-X. Inorganic Chemistry. 46: 4612-6
Kilgore UJ, Yang X, Tomaszewski J, et al. (2006) Activation of atmospheric nitrogen and azobenzene N=N bond cleavage by a transient Nb(III) complex. Inorganic Chemistry. 45: 10712-21
Yang X, Baik MH. (2006) cis,cis-[(bpy)2RuVO]2O4+ catalyzes water oxidation formally via in situ generation of radicaloid RuIV-O*. Journal of the American Chemical Society. 128: 7476-85
Ingleson MJ, Yang X, Pink M, et al. (2005) [(tBu2PCH2SiMe2)2N]RuCH3: the origin of extremely facile, double H-C(sp3) activation generating a "hydrido-carbene" complex. Journal of the American Chemical Society. 127: 10846-7
Walstrom A, Pink M, Yang X, et al. (2005) A facile approach to a d4 RuN: moiety. Journal of the American Chemical Society. 127: 5330-1
Yang X, Baik MH. (2004) Electronic structure of the water-oxidation catalyst [(bpy)2(OHx)RuORu(OHy)(bpy)2]z+: weak coupling between the metal centers is preferred over strong coupling. Journal of the American Chemical Society. 126: 13222-3
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