Scott Brownridge, Ph.D.

University of New Brunswick (Canada) 
Inorganic Main Group Chemistry
"Scott Brownridge"
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Jack Passmore grad student 2001 University of New Brunswick (Canada)
 (Preparation and characterisation of some novel cationic and radical species of electronegative elements.)
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Brownridge S, Calhoun L, Jenkins HD, et al. (2009) 77Se NMR spectroscopic, DFT MO, and VBT investigations of the reversible dissociation of solid (Se6I2)[AsF6]2.2SO2 in Liquid SO2 to solutions containing 1,4-Se6I2(2+) in equilibrium with Se(n)2+ (n = 4, 8, 10) and seven binary selenium iodine cations: preliminary evidence for 1,1,4,4-Se4Br4(2+) and cyclo-Se7Br+. Inorganic Chemistry. 48: 1938-59
Brownridge S, Crawford MJ, Du H, et al. (2007) Accounting for the differences in the structures and relative energies of the highly homoatomic np pi-np pi (n > or = 3)-bonded S2I4 2+, the Se-I pi-bonded Se2I4 2+, and their higher-energy isomers by AIM, MO, NBO, and VB methodologies. Inorganic Chemistry. 46: 681-99
Brownridge S, Cameron TS, Du H, et al. (2005) The highest bond order between heavier main-group elements in an isolated compound? Energetics and vibrational spectroscopy of S2I4(MF6)2 (M = As, Sb). Inorganic Chemistry. 44: 1660-71
Antorrena G, Brownridge S, Cameron TS, et al. (2002) The neutral diradical 5,5′-bis(1,3,2,4-dithiadiazolyl) [SNSNC-CNSNS], the first main group radical to exhibit a dramatic increase in paramagnetism on mechanical grinding Canadian Journal of Chemistry. 80: 1568-1583
Brownridge S, Calhoun L, Laitinen RS, et al. (2001) Reversible dissociation of (Se6I2)(AsF6)2 in SO2(I) Phosphorus, Sulfur and Silicon and Related Elements. 168: 105-110
Brownridge S, Du H, Fairhurst SA, et al. (2000) The isolation, characterisation, gas phase electron diffraction and crystal structure of the thermally stable radical [CF3CSNSCCF3] Journal of the Chemical Society, Dalton Transactions. 3365-3382
Brownridge S, Krossing I, Passmore J, et al. (2000) Recent advances in the understanding of the syntheses, structures, bonding and energetics of the homopolyatomic cations of Groups 16 and 17 Coordination Chemistry Reviews. 197: 397-481
Brownridge S, Passmore J, Sun X. (1998) The electrophilic substitution reaction of the dithionitronium cation [SNS]+ with benzene Canadian Journal of Chemistry. 76: 1220-1231
Brownridge S, Cameron TS, Passmore J, et al. (1998) The preparation, x-ray crystal structure, and spectroscopic characterization of pentafluorophenyl-bis(pentafluorophenylthio)sulfonium hexafluoroarsenate, [(C6F5S)2SC6F5][AsF6] Canadian Journal of Chemistry. 76: 1050-1059
Brownridge S, Cameron TS, Passmore J, et al. (1996) Preparation, structural and spectroscopic characterisation of the salts M3X3AF6 (A = As or Sb, M = S or Se, X = Cl or Br) containing the novel sulfur-and selenium-halogen cations (X2MMMX)+ Journal of the Chemical Society - Dalton Transactions. 2553-2570
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