John M. Rowland, Ph.D.

Affiliations: 
University of California, Santa Cruz, Santa Cruz, CA, United States 
Area:
Inorganic Chemistry, Protein Active Site Modeling, Design and Syntheses of NO- and CO-donors, Green Chemistry
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"John Rowland"
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Pradip K. Mascharak grad student 2002 UC Santa Cruz
 (Iron(III), cobalt(III) and copper(II) complexes with carboxamide ligands that assist characterization of metal peroxide intermediates.)
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Publications

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Afshar RK, Bhalla R, Rowland JM, et al. (2006) Syntheses, structures, and properties of Co(III) complexes derived from polypyridine ligands containing one carboxamido nitrogen donor Inorganica Chimica Acta. 359: 4105-4113
Patra AK, Rowland JM, Marlin DS, et al. (2003) Iron nitrosyls of a pentadentate ligand containing a single carboxamide group: syntheses, structures, electronic properties, and photolability of NO. Inorganic Chemistry. 42: 6812-23
Patra AK, Afshar RK, Rowland JM, et al. (2003) Thermally induced stoichiometric and catalytic O-atom transfer by a non-heme iron(III)-nitro complex: first example of reversible [Fe-NO]7<-->FeIII-NO2 transformation in the presence of dioxygen. Angewandte Chemie (International Ed. in English). 42: 4517-21
Rowland JM, Olmstead MM, Mascharak PK. (2002) Unusual reactivity of methylene group adjacent to pyridine-2-carboxamido moiety in iron(III) and cobalt(III) complexes. Inorganic Chemistry. 41: 2754-60
Rowland JM, Olmstead MM, Mascharak PK. (2002) Chiral monomeric and homochiral dimeric copper(II) complexes of a new chiral ligand, N-(1,2-bis(2-pyridyl)ethyl)pyridine-2-carboxamide: an example of molecular self-recognition. Inorganic Chemistry. 41: 1545-9
Rowland JM, Olmstead MM, Mascharak PK. (2002) Synthesis, structure and properties of bis[N,N-bis(2-pyridylmethyl)amine-N-ethyl-2-pyridine-2-carboxamidecopper(II)] perchlorate Inorganica Chimica Acta. 332: 37-40
Rowland JM, Olmstead M, Mascharak PK. (2001) Syntheses, structures, and reactivity of low spin iron(III) complexes containing a single carboxamido nitrogen in a [FeN5L] chromophore. Inorganic Chemistry. 40: 2810-7
Rowland JM, Thornton ML, Olmstead MM, et al. (2001) Structure variation due to ligand flexibility: Syntheses and structures of the copper(II) complexes [CU(APPy)] and [CU2(AEPy)2] where APPyH2 = Bis[3-(2-pyridinecarboxamido)propyl]-methylamine and AEPyH2: Bis[3-(2-pyridine-carboxamido)ethyl]methylamine Inorganic Chemistry. 40: 1069-1073
Rowland JM, Olmstead MM, Mascharak PK. (2000) Monomeric and dimeric copper(II) complexes of a novel tripodal peptide ligand: structures stabilized via hydrogen bonding or ligand sharing. Inorganic Chemistry. 39: 5326-32
Rowland JM, Mascharak PK. (2000) O2 activation by nonheme iron complexes: A monomeric Fe(III)-oxo complex derived from O2 Chemtracts. 13: 763-769
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