Steven Tymonko, Ph.D.

Affiliations: 
2007 University of Illinois, Urbana-Champaign, Urbana-Champaign, IL 
Area:
synthesis of complex molecular structures
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"Steven Tymonko"
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Scott E. Denmark grad student 2007 UIUC
 (Palladium-catalyzed cross-coupling reactions of organosilanols: I. New methods that employ alkynylsilanols and bissilyl reagents. II. Mechanistic analysis of the cross-coupling of aryldimethylsilanolates.)
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Conlon DA, Natalie KJ, Cuniere N, et al. (2016) Development of a Practical Synthesis of Functionalized Azaxanthene-Derived Nonsteroidal Glucocorticoid Receptor Modulators Organic Process Research and Development. 20: 921-933
Lou S, McKenna GM, Tymonko SA, et al. (2015) Syn-Selective Synthesis of β-Branched α-Amino Acids by Alkylation of Glycine-Derived Imines with Secondary Sulfonates. Organic Letters. 17: 5000-3
Tymonko SA, Smith RC, Ambrosi A, et al. (2015) Mechanistic significance of the si-o-pd bond in the palladium-catalyzed cross-coupling reactions of arylsilanolates. Journal of the American Chemical Society. 137: 6200-18
Tymonko SA, Smith RC, Ambrosi A, et al. (2015) Mechanistic significance of the si-o-pd bond in the palladium-catalyzed cross-coupling reactions of alkenylsilanolates. Journal of the American Chemical Society. 137: 6192-9
Young IS, Haley MW, Tam A, et al. (2015) A Scalable Synthesis of (R,R)-2,6-Dimethyldihydro-2H-pyran-4(3H)-one Organic Process Research and Development. 19: 1360-1368
Denmark SE, Smith RC, Tymonko SA. (2007) Phosphine Oxides as Stabilizing Ligands for the Palladium-Catalyzed Cross-Coupling of Potassium Aryldimethylsilanolates. Tetrahedron. 63: 5730-5738
Denmark SE, Neuville L, Christy ME, et al. (2006) A qualitative examination of the effects of silicon substituents on the efficiency of cross-coupling reactions. The Journal of Organic Chemistry. 71: 8500-9
Dorow RL, Tymonko SA. (2006) Formation of scalemic α,β-epoxysulfones Tetrahedron Letters. 47: 2493-2495
Denmark SE, Tymonko SA. (2005) Sequential cross-coupling of 1,4-bissilylbutadienes: synthesis of unsymmetrical 1,4-disubstituted 1,3-butadienes. Journal of the American Chemical Society. 127: 8004-5
Denmark SE, Tymonko SA. (2003) Cross-coupling of alkynylsilanols with aryl halides promoted by potassium trimethylsilanolate. The Journal of Organic Chemistry. 68: 9151-4
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