Luis M. Alcazar-Roman, Ph.D.

Affiliations: 
2001 Yale University, New Haven, CT 
Area:
reactions catalyzed by transition metal complexes
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"Luis Alcazar-Roman"
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John F. Hartwig grad student 2001 Yale
 (Mechanism of the palladium -catalyzed amination of aryl halides: Kinetic studies of the oxidative addition of aryl halides and sulfonates to phosphine complexes of Pd(0) and of the catalytic reaction of amines with aryl halides and base.)
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Zhang D, Xu J, Alcazar-Roman L, et al. (2004) Isotactic polymers with alternating lactic acid and oxetane subunits from the endoentropic polymerization of a 14-membered ring Macromolecules. 37: 5274-5281
Alcazar-Roman LM, O'Keefe BJ, Hillmyer MA, et al. (2003) Electronic influence of ligand substituents on the rate of polymerization of ε-caprolactone by single-site aluminium alkoxide catalysts Dalton Transactions. 3082-3087
Alcazar-Roman LM, Hartwig JF. (2002) Mechanistic studies on oxidative addition of aryl halides and triflates to Pd(BINAP)2 and structural characterization of the product from aryl triflate addition in the presence of amine Organometallics. 21: 491-502
Alcazar-Roman LM, Hartwig JF. (2001) Mechanism of aryl chloride amination: base-induced oxidative addition. Journal of the American Chemical Society. 123: 12905-6
Alcazar-Roman LM, Hartwig JF, Rheingold AL, et al. (2000) Mechanistic studies of the palladium-catalyzed amination of aryl halides and the oxidative addition of aryl bromides to Pd(BINAP)2 and Pd(DPPF)2: An unusual case of zero-order kinetic behavior and product inhibition Journal of the American Chemical Society. 122: 4618-4630
Hartwig JF, Kawatsura M, Hauck SI, et al. (1999) Room-Temperature Palladium-Catalyzed Amination of Aryl Bromides and Chlorides and Extended Scope of Aromatic C-N Bond Formation with a Commercial Ligand. The Journal of Organic Chemistry. 64: 5575-5580
Doyle DF, Waldner JC, Parikh S, et al. (1996) Changing the transition state for protein (Un) folding. Biochemistry. 35: 7403-11
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