Catherine J. Bergquist, Ph.D.
Affiliations: | 2001 | Columbia University, New York, NY |
Area:
main group and transition metal chemistryGoogle:
"Catherine Bergquist"Mean distance: 8.7 | S | N | B | C | P |
Parents
Sign in to add mentor| Gerard (Ged) F.R. Parkin | grad student | 2001 | Columbia | |
| ((I) Zinc aqua and alkoxide complexes: Models of zinc enzymes. (II) Estimation of the Bronsted acidity of aquatris(perfluorophenyl)borane.) | ||||
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Publications
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| Bergquist C, Fillebeen T, Morlok MM, et al. (2003) Protonation and reactivity towards carbon dioxide of the mononuclear tetrahedral zinc and cobalt hydroxide complexes, [Tp(Bu)t(,Me)]ZnOH and [Tp(Bu)t(,Me)]CoOH: comparison of the reactivity of the metal hydroxide function in synthetic analogues of carbonic anhydrase. Journal of the American Chemical Society. 125: 6189-99 |
| Lipton AS, Bergquist C, Parkin G, et al. (2003) Solid-State 67Zn NMR spectroscopic studies and ab initio molecular orbital calculations on a synthetic analogue of carbonic anhydrase. Journal of the American Chemical Society. 125: 3768-72 |
| Bergquist C, Koutcher L, Vaught AL, et al. (2002) Reactivity of the B-H Bond in tris(pyrazolyl)hydroborato zinc complexes: unexpected example of zinc hydride formation in a protic solvent and its relevance towards hydrogen transfer to NAD(+) mimics by tris(pyrazolyl)hydroborato zinc complexes in alcoholic media. Inorganic Chemistry. 41: 625-7 |
| Bergquist C, Storrie H, Koutcher L, et al. (2000) Factors influencing the thermodynamics of zinc alkoxide formation by alcoholysis of the terminal hydroxide complex, [TpBut,Me]ZnOH: An experimental and theoretical study relevant to the mechanism of action of liver alcohol dehydrogenase Journal of the American Chemical Society. 122: 12651-12658 |
| Bergquist C, Bridgewater BM, Harlan CJ, et al. (2000) Aqua, alcohol, and acetonitrile adducts of tris(perfluorophenyl)borane: Evaluation of Bronsted acidity and ligand lability with experimental and computational methods Journal of the American Chemical Society. 122: 10581-10590 |
| Bergquist C, Parkin G. (1999) Modeling the Catalytic Cycle of Liver Alcohol Dehydrogenase: Synthesis and Structural Characterization of a Four-Coordinate Zinc Ethoxide Complex and Determination of Relative Zn-OR versus Zn-OH Bond Energies. Inorganic Chemistry. 38: 422-423 |
| Bergquist C, Parkin G. (1999) Protonation of the Hydroxide Ligand in a Synthetic Analogue of Carbonic Anhydrase, [TpBut,Me]ZnOH: Inhibition of Reactivity Towards CO2 Journal of the American Chemical Society. 121: 6322-6323 |