Donald J. Knobloch, Ph.D.

Affiliations: 
2011 Cornell University, Ithaca, NY, United States 
Area:
application of organometallic molecules to chemical synthesis
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"Donald Knobloch"
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Paul J. Chirik grad student 2011 Cornell
 (Dinitrogen functionalization: Exploring dinitrogen cleavage and nitrogen-carbon bond forming reactions with group 4 metallocene compounds.)
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Publications

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Semproni SP, Knobloch DJ, Milsmann C, et al. (2013) Redox-induced N2 hapticity switching in zirconocene dinitrogen complexes. Angewandte Chemie (International Ed. in English). 52: 5372-6
Knobloch DJ, Semproni SP, Lobkovsky E, et al. (2012) Studies into the mechanism of CO-induced N2 cleavage promoted by an ansa-hafnocene complex and C-C bond formation from an observed intermediate. Journal of the American Chemical Society. 134: 3377-86
Pun D, Knobloch DJ, Lobkovsky E, et al. (2011) Cyclisation of α,ω-dienes promoted by bis(indenyl)zirconium sandwich and ansa-titanocene dinitrogen complexes. Dalton Transactions (Cambridge, England : 2003). 40: 7737-47
Knobloch DJ, Lobkovsky E, Chirik PJ. (2010) Dinitrogen cleavage and functionalization by carbon monoxide promoted by a hafnium complex. Nature Chemistry. 2: 30-5
Knobloch DJ, Lobkovsky E, Chirik PJ. (2010) Functionalization of hafnium oxamidide complexes prepared from CO-induced N2 cleavage. Journal of the American Chemical Society. 132: 15340-50
Knobloch DJ, Lobkovsky E, Chirik PJ. (2010) Carbon monoxide-induced dinitrogen cleavage with group 4 metallocenes: reaction scope and coupling to N-H bond formation and CO deoxygenation. Journal of the American Chemical Society. 132: 10553-64
Knobloch DJ, Benito-Garagorri D, Bernskoetter WH, et al. (2009) Addition of methyl triflate to a hafnocene dinitrogen complex: stepwise n(2) methylation and conversion to a hafnocene hydrazonato compound. Journal of the American Chemical Society. 131: 14903-12
Knobloch DJ, Toomey HE, Chirik PJ. (2008) Carboxylation of an ansa-zirconocene dinitrogen complex: regiospecific hydrazine synthesis from N2 and CO2. Journal of the American Chemical Society. 130: 4248-9
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