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John Picione, Ph.D.

Affiliations: 
2004 University of Illinois at Chicago, Chicago, IL, United States 
Area:
diastereoselective free radical chemistry, acyl radical chemistry, enantioselective synthesis of á-disubstituted amino acids, and carbohydrate chemistry
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"John Picione"
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David Crich grad student 2004 University of Illinois, Chicago
 (Novel protecting group strategies in the direct, stereoselective formation of beta-rhamnopyranosides.)

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Publications

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Crich D, Smith M, Yao Q, et al. (2010) ChemInform Abstract: 2,4,6-Tri-tert-butylpyrimidine (TTBP): A Cost Effective, Readily Available Alternative to the Hindered Base 2,6-Di-tert-butylpyridine and Its 4-Substituted Derivatives in Glycosylation and Other Reactions. Cheminform. 32: no-no
Crich D, Vinod AU, Picione J, et al. (2005) Approximate H(5) Ring Conformation of 2,3-O-Carbonate Protected α- and β-L-Rhamnopyranosides as Confirmed by X-Ray Crystallography. Arkivoc : Free Online Journal of Organic Chemistry / Arkat-Usa, Inc. 2005: 339-344
Crich D, Hutton TK, Banerjee A, et al. (2005) Disarming, non-participating 2-O-protecting groups in manno- and rhamnopyranosylation: Scope and limitations of sulfonates, vinylogous esters, phosphates, cyanates, and nitrates Tetrahedron Asymmetry. 16: 105-119
Crich D, Vinod AU, Picione J, et al. (2005) Approximate OH5 ring conformation of 2,3-O-carbonate protected α- and β-L-rhamnopyranosides as confirmed by X-ray crystallography Arkivoc. 2005: 339-344
Crich D, Vinod AU, Picione J. (2003) The 3,4-O-carbonate protecting group as a beta-directing group in rhamnopyranosylation in both homogeneous and heterogeneous glycosylations as compared to the chameleon-like 2,3-O-carbonates. The Journal of Organic Chemistry. 68: 8453-8
Crich D, Picione J. (2003) Direct synthesis of the beta-l-rhamnopyranosides. Organic Letters. 5: 781-4
Crich D, Picione J. (2003) 1-Benzenesulfinyl piperidine (BSP)/triflic anhydride: An effective combination for the hydrolysis of dithioacetals Synlett. 1257-1258
Crich D, Picione J. (2003) Direct Synthesis of the β-L-Rhamnopyranosides. Cheminform. 34
Crich D, Smith M, Yao Q, et al. (2001) 2,4,6-Tri-tert-butylpyrimidine (TTBP): A Cost Effective, Readily Available Alternative to the Hindered Base 2,6-Di-tert-butylpyridine and its 4-Substituted Derivatives in Glycosylation and Other Reactions Synthesis. 2001: 0323-0326
Crich D, Smith M, Yao Q, et al. (2001) 2,4,6-Tri-tert-butylpyrimidine (TTBP): A cost effective, readily available alternative to the hindered base 2,6-di-tert-butylpyridine and its 4-substituted derivatives in glycosylation and other reactions Synthesis. 323-326
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