Joseph M. Keane, Ph.D.

Affiliations: 
2003 University of Virginia, Charlottesville, VA 
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"Joseph Keane"
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W Dean Harman grad student 2003 UVA
 (Synthesis and nucleophilic activity of eta-2 arene complexes.)
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Publications

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Bennov RR, Berko DA, Burgess SA, et al. (2015) Molybdenum complexes of chiral C2-symmetric picchxn-type ligands: Synthesis, characterization, and structural studies Inorganica Chimica Acta. 438: 64-75
Liebov BK, Weigle CE, Keinath KV, et al. (2011) Topological variations of the PDP ligand and its prospects in molybdenum(0) dearomatization agents. Inorganic Chemistry. 50: 4677-9
Dilsky S, Palomaki PKB, Rubin JA, et al. (2007) Synthesis and reactivity of cationic bipyridine tungsten(0) and molybdenum(0) nitrosyl complexes Inorganica Chimica Acta. 360: 2387-2396
Ha Y, Dilsky S, Graham PM, et al. (2006) Development of group 6 dearomatization agents Organometallics. 25: 5184-5187
Keane JM, Harman WD. (2005) A new generation of π-basic dearomatization agents Organometallics. 24: 1786-1798
Smith PL, Keane JM, Shankman SE, et al. (2004) Michael addition reactions with eta2-coordinated anisoles: controlling the stereochemistry of the para and benzylic carbons. Journal of the American Chemical Society. 126: 15543-51
Keane JM, Chordia MD, Mocella CJ, et al. (2004) Transition metal-stabilized arenium cations: protonation of arenes dihapto-coordinated to pi-basic metal fragments. Journal of the American Chemical Society. 126: 6806-15
Ding F, Valahovic MT, Keane JM, et al. (2004) Diastereo- and enantioselective dearomatization of rhenium-bound naphthalenes. The Journal of Organic Chemistry. 69: 2257-67
Keane JM, Ding F, Sabat M, et al. (2004) Solid-state induced control of kinetically unstable stereoisomers. Journal of the American Chemical Society. 126: 785-9
Mocella CJ, Delafuente DA, Keane JM, et al. (2004) Coordination chemistry and properties of unusually π-basic molybdenum fragments Organometallics. 23: 3772-3779
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