Hee J. Hwang, Ph.D.

Affiliations: 
2006 University of Illinois, Urbana-Champaign, Urbana-Champaign, IL 
Area:
metalloproteins, DNAzymes, nanomaterials
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"Hee Hwang"
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Yi Lu grad student 2006 UIUC
 (Modulation of metal coordination and redox properties of the engineered purple copper(A) and ferrocene centers in azurin.)
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Publications

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Xie X, Gorelsky SI, Sarangi R, et al. (2008) Perturbations to the geometric and electronic structure of the CuA site: factors that influence delocalization and their contributions to electron transfer. Journal of the American Chemical Society. 130: 5194-205
Sarangi R, Gorelsky SI, Basumallick L, et al. (2008) Spectroscopic and density functional theory studies of the blue-copper site in M121SeM and C112SeC azurin: Cu-Se versus Cu-S bonding. Journal of the American Chemical Society. 130: 3866-77
Sieracki NA, Hwang HJ, Lee MK, et al. (2008) A temperature independent pH (TIP) buffer for biomedical biophysical applications at low temperatures. Chemical Communications (Cambridge, England). 823-5
Farver O, Hwang HJ, Lu Y, et al. (2007) Reorganization energy of the CuA center in purple azurin: impact of the mixed valence-to-trapped valence state transition. The Journal of Physical Chemistry. B. 111: 6690-4
Garner DK, Vaughan MD, Hwang HJ, et al. (2006) Reduction potential tuning of the blue copper center in Pseudomonas aeruginosa azurin by the axial methionine as probed by unnatural amino acids. Journal of the American Chemical Society. 128: 15608-17
Hwang HJ, Nagraj N, Lu Y. (2006) Spectroscopic characterizations of bridging cysteine ligand variants of an engineered Cu2(Scys)2 CuA azurin. Inorganic Chemistry. 45: 102-7
Hwang HJ, Carey JR, Brower ET, et al. (2005) Blue ferrocenium azurin: an organometalloprotein with tunable redox properties. Journal of the American Chemical Society. 127: 15356-7
Hwang HJ, Berry SM, Nilges MJ, et al. (2005) Axial methionine has much less influence on reduction potentials in a CuA center than in a blue copper center. Journal of the American Chemical Society. 127: 7274-5
Hwang HJ, Lu Y. (2004) pH-dependent transition between delocalized and trapped valence states of a CuA center and its possible role in proton-coupled electron transfer. Proceedings of the National Academy of Sciences of the United States of America. 101: 12842-7
Hwang HJ, Lu Y. (2004) Spectroscopic evidence for interactions between hexacyanoiron(II/III) and an engineered purple CuA azurin. Journal of Inorganic Biochemistry. 98: 797-802
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