Stefan J. Pastine, Ph.D.

Affiliations: 
2006 Columbia University, New York, NY 
Area:
organic synthesis
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"Stefan Pastine"
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Dalibor Sames grad student 2006 Columbia
 (Design and exploration of different approaches to a common goal: Catalytic carbon-hydrogen functionalization.)
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Publications

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Downs JR, Pastine SJ, Schady DA, et al. (2010) ChemInform Abstract: Preparation of 1H-Pyrazole-5-carboxamides from Dilithiated C(α),N-Phenylhydrazones and Lithiated Ethyl Oxanilates or Lithiated Ethyl Oxamate. Cheminform. 32: no-no
Gribkov DV, Pastine SJ, Schnürch M, et al. (2007) Ruthenium catalyzed decarbonylative arylation at sp3 carbon centers in pyrrolidine and piperidine heterocycles. Journal of the American Chemical Society. 129: 11750-5
Sames D, Pastine S, Gribkov D. (2007) trans-Selective sp3 C-H Bond Arylation of Pyrrolidines and Piperidines Synfacts. 2007: 0181-0181
Pastine SJ, Gribkov DV, Sames D. (2006) sp3 C-H bond arylation directed by amidine protecting group: alpha-arylation of pyrrolidines and piperidines. Journal of the American Chemical Society. 128: 14220-1
Pastine SJ, Sames D. (2005) Room temperature intramolecular hydro-O-alkylation of aldehydes: sp3 C-H functionalization via a Lewis acid catalyzed tandem 1,5-hydride transfer/cyclization. Organic Letters. 7: 5429-31
Pastine SJ, McQuaid KM, Sames D. (2005) Room temperature hydroalkylation of electron-deficient olefins: sp3 C-H functionalization via a lewis acid-catalyzed intramolecular redox event. Journal of the American Chemical Society. 127: 12180-1
DeBoef B, Pastine SJ, Sames D. (2004) Cross-coupling of sp(3) C-H bonds and alkenes: catalytic cyclization of alkene-amide substrates. Journal of the American Chemical Society. 126: 6556-7
Youn SW, Pastine SJ, Sames D. (2004) Ru(III)-catalyzed cyclization of arene-alkene substrates via intramolecular electrophilic hydroarylation. Organic Letters. 6: 581-4
Downs JR, Grant SP, Townsend JD, et al. (2004) Preparation of 4-anilino-6-aryl-2H-pyran-2-ones from trilithiated acetoacetanilides and aromatic esters Canadian Journal of Chemistry. 82: 659-664
Pastine SJ, Sames D. (2003) Concise synthesis of the chemopreventitive agent (+/-)-deguelin via a key 6-endo hydroarylation. Organic Letters. 5: 4053-5
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