Gary D. Kasper, Ph.D.

Affiliations: 
2009 Johns Hopkins University, Baltimore, MD 
Area:
inorganic and bioinorganic chemistry
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"Gary Kasper"
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David Philip Goldberg grad student 2009 Johns Hopkins
 (Synthesis, characterization, and reactivity of mixed nitrogen/sulfur non -heme iron complexes.)
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Publications

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Stasser J, Namuswe F, Kasper GD, et al. (2010) X-ray absorption spectroscopy and reactivity of thiolate-ligated Fe(III)-OOR complexes. Inorganic Chemistry. 49: 9178-90
Jiang Y, Widger LR, Kasper GD, et al. (2010) Iron(II)-thiolate S-oxygenation by O2: synthetic models of cysteine dioxygenase. Journal of the American Chemical Society. 132: 12214-5
Namuswe F, Hayashi T, Jiang Y, et al. (2010) Influence of the nitrogen donors on nonheme iron models of superoxide reductase: high-spin Fe(III)-OOR complexes. Journal of the American Chemical Society. 132: 157-67
Namuswe F, Kasper GD, Sarjeant AA, et al. (2008) Rational tuning of the thiolate donor in model complexes of superoxide reductase: direct evidence for a trans influence in Fe(III)-OOR complexes. Journal of the American Chemical Society. 130: 14189-200
Krishnamurthy D, Kasper GD, Namuswe F, et al. (2006) A low-spin alkylperoxo-iron(III) complex with weak Fe-O and O-O bonds: implications for the mechanism of superoxide reductase. Journal of the American Chemical Society. 128: 14222-3
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