Michael T. Scerba, Ph.D.

Affiliations: 
2011 Johns Hopkins University, Baltimore, MD 
Area:
Synthetic Organic Chemistry and Catalysis
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"Michael Scerba"
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Thomas Lectka grad student 2011 Johns Hopkins
 (1.) Charged Nitrogen Hydride-Fluorine Hydrogen Bonding in a Fluorinated Proton Sponge Derivative: Integration of Solution, Solid State, Gas Phase and Computational Studies 2.) Polyfunctional, Asymmetric Reactions of Chiral Ketene Enolates 3.) Catalysis In)
Daniel H. Appella post-doc 2016 National Institues of Health
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Publications

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Struble MD, Holl MG, Scerba MT, et al. (2015) Search for a Symmetrical C-F-C Fluoronium Ion in Solution: Kinetic Isotope Effects, Synthetic Labeling, and Computational, Solvent, and Rate Studies. Journal of the American Chemical Society. 137: 11476-90
Struble MD, Scerba MT, Siegler M, et al. (2013) Evidence for a symmetrical fluoronium ion in solution. Science (New York, N.Y.). 340: 57-60
Deblase AF, Scerba MT, Lectka T, et al. (2013) Vibrational predissociation spectroscopy of Ar-tagged, trisubstituted silyl cations Chemical Physics Letters. 568: 9-13
Scerba MT, DeBlase AF, Bloom S, et al. (2012) Characterization of highly unusual NH+-O hydrogen bonding to ester ether oxygen atoms through spectroscopic and computational studies. The Journal of Physical Chemistry. A. 116: 3556-60
Scerba MT, Bloom S, Haselton N, et al. (2012) Interaction of a C-F bond with the π-system of a C═C bond or "head on" with a proximate C-H bond. The Journal of Organic Chemistry. 77: 1605-9
Scerba MT, Leavitt CM, Diener ME, et al. (2011) NH+-F hydrogen bonding in a fluorinated "proton sponge" derivative: integration of solution, solid-state, gas-phase, and computational studies. The Journal of Organic Chemistry. 76: 7975-84
Bloom S, Scerba MT, Erb J, et al. (2011) Tricomponent catalytic α,α-difluorination of acid chlorides. Organic Letters. 13: 5068-71
Erb J, Alden-Danforth E, Kopf N, et al. (2010) Combining asymmetric catalysis with natural product functionalization through enantioselective alpha-fluorination. The Journal of Organic Chemistry. 75: 969-71
Abraham CJ, Paull DH, Bekele T, et al. (2008) A surprising mechanistic "switch" in Lewis acid activation: a bifunctional, asymmetric approach to alpha-hydroxy acid derivatives. Journal of the American Chemical Society. 130: 17085-94
Paull DH, Scerba MT, Alden-Danforth E, et al. (2008) Catalytic, asymmetric alpha-fluorination of acid chlorides: dual metal-ketene enolate activation. Journal of the American Chemical Society. 130: 17260-1
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