Walter A. Salamant, Ph.D.

Affiliations: 
2009 University of California, Irvine, Irvine, CA 
Area:
Organic Chemistry
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"Walter Salamant"
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Keith A. Woerpel grad student 2009 UC Irvine
 (The influence of nucleophile reactivities on stereoselectivities in the substitutions of acetals and the associated mechanistic implications.)
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Garcia A, Otte DA, Salamant WA, et al. (2015) Influence of alkoxy groups on rates of acetal hydrolysis and tosylate solvolysis: electrostatic stabilization of developing oxocarbenium ion intermediates and neighboring-group participation to form oxonium ions. The Journal of Organic Chemistry. 80: 4470-80
Garcia A, Otte DA, Salamant WA, et al. (2015) Acceleration of acetal hydrolysis by remote alkoxy groups: evidence for electrostatic effects on the formation of oxocarbenium ions. Angewandte Chemie (International Ed. in English). 54: 3061-4
Krumper JR, Salamant WA, Woerpel KA. (2009) Correlations between nucleophilicities and selectivities in the substitutions of tetrahydropyran acetals. The Journal of Organic Chemistry. 74: 8039-50
Krumper JR, Salamant WA, Woerpel KA. (2008) Continuum of mechanisms for nucleophilic substitutions of cyclic acetals. Organic Letters. 10: 4907-10
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