Chengzao Sun, Ph.D.

Affiliations: 
2001 Brown University, Providence, RI 
Area:
total synthesis of several marine natural products as well as vitamin D derivatives, characterization of reactive intermediates such as enolate anions and amide bases
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"Chengzao Sun"
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SNBCP

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Paul G. Williard grad student 2001 Brown
 (Syntheses, structures and applications of mixed aggregates containing chiral lithium amides and alkyllithiums or lithium enolates.)
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Publications

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Kagan G, Li W, Sun C, et al. (2011) Synthesis, characterization, and reaction of a ketone-derived 1,4-dienolate compound. The Journal of Organic Chemistry. 76: 65-70
Li D, Sun C, Williard PG. (2008) Characterization of a chiral enolate aggregate and observation of 6Li-1H scalar coupling. Journal of the American Chemical Society. 130: 11726-36
Liu J, Li D, Sun C, et al. (2008) Analysis of an asymmetric addition with a 2:1 mixed lithium amide/n-butyllithium aggregate. The Journal of Organic Chemistry. 73: 4045-52
Li D, Sun C, Liu J, et al. (2008) Aggregation studies of complexes containing a chiral lithium amide and n-Butyllithium. The Journal of Organic Chemistry. 73: 2373-81
Williard PG, Sun C. (1997) Mixed aggregates containing n-butyl, sec-butyl-, or tert-butyllithium and a chiral lithium amide derived from N-isopropl-O-methyl valinol Journal of the American Chemical Society. 119: 11693-11694
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