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Dimitrios G. Giarikos, Ph.D.

Affiliations: 
2003 University of California, Irvine, Irvine, CA 
Area:
Inorganic and Organometallic Chemistry; Rare Earth, Actinide, and Bismuth Metal Chemistry
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"Dimitrios Giarikos"
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William J. Evans grad student 2003 UC Irvine
 (The chemistry of ternary and binary lanthanide-based isoprene polymerization catalysts.)

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Publications

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Evans WJ, Champagne TM, Giarikos DG, et al. (2005) Lanthanide metallocene reactivity with dialkyl aluminum chlorides: Modeling reactions used to generate isoprene polymerization catalysts Organometallics. 24: 570-579
Evans WJ, Giarikos DG, Workman PS, et al. (2004) Utility of anhydrous neodymium nitrate as a precursor to extended organoneodymium nitrate networks. Inorganic Chemistry. 43: 5754-60
Evans WJ, Giarikos DG. (2004) Chloride Effects in Lanthanide Carboxylate Based Isoprene Polymerization Macromolecules. 37: 5130-5132
Evans WJ, Giarikos DG, Josell D, et al. (2003) Synthesis and structure of polymeric networks of silver hexafluoroacetylacetonate complexes of THF, toluene, and vinyltrimethylsilane. Inorganic Chemistry. 42: 8255-61
Evans WJ, Giarikos DG, Allen NT. (2003) Polymerization of isoprene by a single component lanthanide catalyst precursor Macromolecules. 36: 4256-4257
Evans WJ, Giarikos DG, Ziller JW. (2003) Synthesis and reactivity of a tethered diene cyclopentadiene, (C5Me4H)SiMe2(CH2 CH=CHCH=CH2), and its alkali metal salts Journal of Organometallic Chemistry. 688: 200-205
Evans WJ, Giarikos DG, Johnston MA, et al. (2002) Reactivity of the europium hexafluoroacetylacetonate (hfac) complex, Eu(hfac)3(diglyme), and related analogs with potassium: Formation of the fluoride hfac "ate" complexes, [LnF(hfac)3K(diglyme)]2 Journal of the Chemical Society, Dalton Transactions. 520-526
Evans WJ, Brady JC, Fujimoto CH, et al. (2002) The bent metallocene geometries of potassium polyalkyl cyclopentadienyl THF solvates: Monosolvated [(THF)K(μ-C5Me5)]n, disolvated [(THF)2K(μ-C5Me5)n and the tethered olefin complex [(THF)K(μ-C5Me4 SiMe2CH2CH=CH2)]n Journal of Organometallic Chemistry. 649: 252-257
Evans W, Giarikos D, Greci M, et al. (2002) Direct Synthesis of Heterometallic Europium/Barium Complexes: H2[Eu2Ba6O2(OiPr)16(THF)4] and EuBa2(OC6H4Me-4)7(diglyme)2(DME) European Journal of Inorganic Chemistry. 2002: 453-456
Evans WJ, Giarikos DG, Ziller JW. (2001) Lanthanide carboxylate precursors for diene polymerization catalysis: Syntheses, structures, and reactivity with Et2AlCl Organometallics. 20: 5751-5758
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