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Jeremy M. Perotti, Ph.D.

Affiliations: 
2005 University of California, Irvine, Irvine, CA 
Area:
Inorganic and Organometallic Chemistry; Rare Earth, Actinide, and Bismuth Metal Chemistry
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"Jeremy Perotti"
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William J. Evans grad student 2005 UC Irvine
 (Synthesis and structure of organosamarium metallocenes including the carbon-hydrogen and carbon-carbon bond cleavage reactivity of unsolvated tris(pentamethylcyclopentadienyl) samarium complexes.)

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Publications

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Evans WJ, Perotti JM, Ziller JW. (2005) Trialkylboron/lanthanide metallocene hydride chemistry: polydentate bridging of (HBEt3)- to lanthanum. Inorganic Chemistry. 44: 5820-5
Evans WJ, Perotti JM, Ziller JW. (2005) Synthetic utility of [(C5Me5)2Ln][(mu-Ph)2BPh] in accessing [(C5Me5)2LnR]x unsolvated alkyl lanthanide metallocenes, complexes with high C-H activation reactivity. Journal of the American Chemical Society. 127: 3894-909
Evans WJ, Perotti JM, Ziller JW. (2005) Formation of a bridging planar trimethylenemethane dianion from a neopentyl precursor via sequential beta-alkyl elimination and C-H activation. Journal of the American Chemical Society. 127: 1068-9
Evans WJ, Perotti JM, Kozimor SA, et al. (2005) Synthesis and comparative η 1-alkyl and sterically induced reduction reactivity of (C 5Me 5) 3Ln complexes of La, Ce, Pr, Nd, and Sm Organometallics. 24: 3916-3931
Evans WJ, Lee DS, Rego DB, et al. (2004) Expanding dinitrogen reduction chemistry to trivalent lanthanides via the LnZ3/alkali metal reduction system: evaluation of the generality of forming Ln2(mu-eta2:eta2-N2) complexes via LnZ3/K. Journal of the American Chemical Society. 126: 14574-82
Evans WJ, Perotti JM, Brady JC, et al. (2003) Tethered olefin studies of alkene versus tetraphenylborate coordination and lanthanide olefin interactions in metallocenes. Journal of the American Chemical Society. 125: 5204-12
Evans WJ, Perotti JM, Ziller JW, et al. (2003) Evaluation of a silylene divalent lanthanide interaction in the metallocene complex (C5Me5)2Sm[SiNtBuCHCHNtBu ] Organometallics. 22: 1160-1163
Evans WJ, Davis BL, Nyce GW, et al. (2003) Structural studies of lanthanide and yttrium metallocene oxides Journal of Organometallic Chemistry. 677: 89-95
Evans WJ, Perotti JM, Doedens RJ, et al. (2001) The tetramethylpiperidinyl-1-oxide anion (TMPO-) as a ligand in lanthanide chemistry: synthesis of the per(TMPO-) complex [(ONC5H6Me4)2Sm(mu-ONC5H6Me4)]2. Chemical Communications (Cambridge, England). 2326-7
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