Sara E. Lorenz, Ph.D.

Affiliations: 
2009 University of California, Irvine, Irvine, CA 
Area:
Inorganic and Organometallic Chemistry; Rare Earth, Actinide, and Bismuth Metal Chemistry
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"Sara Lorenz"
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William J. Evans grad student 2009 UC Irvine
 (Examination of ligand effects on the reactivity and reduction chemistry of trivalent lanthanide metallocene complexes.)
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Publications

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Fang M, Bates JE, Lorenz SE, et al. (2011) (N2)3- radical chemistry via trivalent lanthanide salt/alkali metal reduction of dinitrogen: new syntheses and examples of (N2)2- and (N2)3- complexes and density functional theory comparisons of closed shell Sc3+, Y3+, and Lu3+ versus 4f(9) Dy3+. Inorganic Chemistry. 50: 1459-69
Demir S, Lorenz SE, Fang M, et al. (2010) Synthesis, structure, and density functional theory analysis of a scandium dinitrogen complex, [(C(5)Me(4)H)(2)Sc](2)(mu-eta(2):eta(2)-N(2)). Journal of the American Chemical Society. 132: 11151-8
Lorenz SE, Schmiege BM, Lee DS, et al. (2010) Synthesis and reactivity of bis(tetramethylcyclopentadienyl) yttrium metallocenes including the reduction of Me(3)SiN(3) to [(Me(3)Si)(2)N](-) with [(C(5)Me(4)H)(2)Y(THF)](2)(mu-eta(2):eta(2)-N(2)). Inorganic Chemistry. 49: 6655-63
Evans WJ, Lorenz SE, Ziller JW. (2009) Investigating metal size effects in the Ln2(mu-eta2:eta2-N2) reduction system: reductive reactivity with complexes of the largest and smallest trivalent lanthanide ions, La3+ and Lu3+. Inorganic Chemistry. 48: 2001-9
Evans WJ, Schmiege BM, Lorenz SE, et al. (2008) Reductive reactivity of the organolanthanide hydrides, [(C5Me5)2LnH]x, leads to ansa-allyl cyclopentadienyl (eta(5)-C5Me4CH2-C5Me4CH2-eta(3))2- and trianionic cyclooctatetraenyl (C8H7)3- ligands. Journal of the American Chemical Society. 130: 8555-63
Evans WJ, Lorenz SE, Ziller JW. (2007) Yttrium metallocene borane chemistry: isolation of 9-BBN substitution and coordination complexes in a single crystal, {(C(5)Me(5))(2)Y[eta(3)-C(3)H(4)(BC(8)H(14))]} and {(C(5)Me(5))(2)Y(micro-H)(2)BC(8)H(14)}. Chemical Communications (Cambridge, England). 4662-4
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