Nicholas S. Perch, Ph.D.

Affiliations: 
2003 Duke University, Durham, NC 
Area:
organotransition metal catalysis
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"Nicholas Perch"
Mean distance: 8.12
 

Parents

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Ross A. Widenhoefer grad student 2003 Duke
 (Development of enantioselective methodology for, and mechanistic investigation of palladium-catalyzed cyclization/hydrosilylation of functionalized dienes.)
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Publications

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Neukom JD, Perch NS, Wolfe JP. (2011) Intramolecular insertion of alkenes into Pd-N bonds. Effects of substrate and ligand structure on the reactivity of (P-P)Pd(Ar)[N(Ar 1)(CH 2) 3CR=CHR′] complexes Organometallics. 30: 1269-1277
Neukom JD, Perch NS, Wolfe JP. (2010) Intramolecular alkene aminopalladation reactions of (dppf)Pd(Ar)[N(Ar(1))(CH(2))(3)CH=CH(2)] complexes. insertion of unactivated alkenes into Pd-N bonds. Journal of the American Chemical Society. 132: 6276-7
Perch NS, Widenhoefer RA. (2004) Mechanism of palladium-catalyzed diene cyclization/hydrosilylation: direct observation of intramolecular carbometalation. Journal of the American Chemical Society. 126: 6332-46
Perch NS, Widenhoefer RA. (2001) Direct observation of the conversion of a palladium 5-hexenyl chelate complex to a palladium cyclopentylmethyl complex Organometallics. 20: 5251-5253
Perch NS, Pei T, Widenhoefer RA. (2000) Enantioselective diene Cyclization/Hydrosilylation catalyzed by optically active palladium bisoxazoline and pyridine-oxazoline complexes. The Journal of Organic Chemistry. 65: 3836-45
Perch NS. (2000) Reductive cyclization of dimethyl diallylmalonate catalyzed by palladium-bisoxazoline complexes in the presence of silane and water Organometallics. 19: 2541-2545
Perch NS, Kisanga P, Widenhoefer RA. (2000) ChemInform Abstract: Reductive Cyclization of Dimethyl Diallylmalonate Catalyzed by Palladium-Bisoxazoline Complexes in the Presence of Silane and Water. Cheminform. 31: no-no
Perch NS, Widenhoefer RA. (1999) Asymmetric cyclization/hydrosilylation of functionalized 1,6-dienes catalyzed by enantiomerically pure palladium pyridine-oxazoline complexes [13] Journal of the American Chemical Society. 121: 6960-6961
Widenhoefer RA, Perch NS. (1999) Silane-promoted cycloisomerization of functionalized 1,6-dienes catalyzed by a cationic (π-allyl)palladium complex Organic Letters. 1: 1103-1105
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