Timothy W. Chapp, Ph.D.

Affiliations: 
2010 Chemistry Dartmouth College, Hanover, NH, United States 
Area:
Homogeneous catalysis, asymmetric catalysis, sustainable energy
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"Timothy Chapp"
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David S. Glueck grad student 2010 Dartmouth
 (Preparation of sterically hindered bis(secondary phosphines): Structure-selectivity relationships in platinum-catalyzed asymmetric phosphination and synthesis and structure of metal-phosphido complexes.)
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Publications

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Muldoon J, Varga B, Deegan M, et al. (2018) Inversion of Configuration at the Phosphorus Nucleophile in Diastereoselective and Enantioselective Synthesis of P-Stereogenic syn-Phosphiranes from Chiral Epoxides. Angewandte Chemie (International Ed. in English)
Chapp TW, Benvenuto MA. (2013) Introduction Acs Symposium Series. 1156: 1-3
Guino-O MA, Zureick AH, Blank NF, et al. (2012) Synthesis and structure of platinum bis(phospholane) complexes Pt(diphos*)(R)(X), catalyst precursors for asymmetric phosphine alkylation Organometallics. 31: 6900-6910
Chapp TW, Schoenfeld AJ, Sanderson MD, et al. (2012) Synthesis, structure, dynamics, and selective methylation of platinum and palladium diphosphametallacyclobutane complexes Organometallics. 31: 5573-5585
Lane EM, Chapp TW, Hughes RP, et al. (2010) Synthesis of gold phosphido complexes derived from bis(secondary) phosphines. structure of tetrameric [Au(MesP(CH(2))(3)PMes)Au](4). Inorganic Chemistry. 49: 3950-7
Chapp TW, Glueck DS, Golen JA, et al. (2010) Platinum-catalyzed asymmetric alkylation of bis(isitylphosphino)ethane: Stereoselectivity reversal in successive formation of two P-C bonds Organometallics. 29: 378-388
Chapp TW, Schoenfeld AJ, Glueck DS. (2010) Effects of linker length on the rate and selectivity of platinum-catalyzed asymmetric alkylation of the bis(isitylphosphino)alkanes IsHP(CH 2)nPHIs (Is = 2,4,6-(i -Pr)3C6H 2, n = 1-5) Organometallics. 29: 2465-2473
Ilagan RP, Chapp TW, Hiller RG, et al. (2006) Optical spectroscopic studies of light-harvesting by pigment-reconstituted peridinin-chlorophyll-proteins at cryogenic temperatures. Photosynthesis Research. 90: 5-15
Ilagan RP, Christensen RL, Chapp TW, et al. (2005) Femtosecond time-resolved absorption spectroscopy of astaxanthin in solution and in alpha-crustacyanin. The Journal of Physical Chemistry. A. 109: 3120-7
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