Cheryl J. Bourgeois, Ph.D.

2007 Chemistry Dartmouth College, Hanover, NH, United States 
Organometallic mechanism and synthesis, CF bond activation, catalysis
"Cheryl Bourgeois"
Mean distance: 11.45


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Russell P. Hughes grad student 2007 Dartmouth
 (Carbon -fluorine bond activation of iridium(III) compounds induced by acids and reducing agents.)
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Yuan J, Bourgeois CJ, Rheingold AL, et al. (2015) Synthesis, structure, and reactivity of iridium perfluorocarbene complexes: regio- and stereo-specific addition of HCl across a metal carbon double bond. Dalton Transactions (Cambridge, England : 2003)
Huang H, Hurubeanu NR, Bourgeois CJ, et al. (2009) Octahedral perfluoroalkyl complexes of Ir(III) formed by oxidative addition of perfluoroalkyl iodides to Ir(acac)(CO)2 Canadian Journal of Chemistry. 87: 151-160
Bourgeois CJ, Huang H, Larichev RB, et al. (2007) Variable-temperature NMR determination of the barriers to rotation about the Ir-C σ-bond in a series of primary perfluoroalkyl iridium complexes [IrCp*{(CF2)nCF3}(PMe3) 2]+X- [n = 1, 2, 3, 5, 7, 9, 11; X = I, OT f] Organometallics. 26: 264-271
Bourgeois CJ, Garratt SA, Hughes RP, et al. (2006) Synthesis and structural characterization of (perfluoroalkyl) fluoroiridium(III) and (perfluoroalkyl)methyliridium(III) compounds Organometallics. 25: 3474-3480
Bourgeois CJ, Hughes RP, Yuan J, et al. (2006) α- and β-fluorine elimination reactions induced by reduction of iridium - Fluoroalkyl complexes. Selective formation of fluoroalkylidene and hydrofluoroalkene ligands Organometallics. 25: 2908-2910
Bourgeois CJ, Hughes RP, Husebo TL, et al. (2005) Reactions of perfluoroalkyl iodides with M(C 5H 5)(CO)(PMe 3) [M = Rh, Ir]; evidence for direct fluoroalkylation at a CO ligand Organometallics. 24: 6431-6439
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