Ned J. Hardman, Ph.D.

Affiliations: 
2002 University of California, Davis, Davis, CA 
Area:
Inorganic chemistry
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"Ned Hardman"
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Philip Power grad student 2002 UC Davis
 (The use of sterically encumbered terphenyl and beta-diketiminate ligands to synthesize low coordinate, multiply bonded, and hyride derivaties of heavier group 13 and 15 elements.)
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Publications

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Kempter A, Gemel C, Hardman NJ, et al. (2006) Insertion of the Ga(I) bis-imidinate Ga(DDP) into the metal halogen bonds of Rh(I) complexes. How electrophilic are coordinated Ga(DDP) fragments? Inorganic Chemistry. 45: 3133-8
Hardman NJ, Fang X, Scott BL, et al. (2005) High-spin diimine complexes of iron(II) reject binding of carbon monoxide: theoretical analysis of thermodynamic factors inhibiting or favoring spin-crossover. Inorganic Chemistry. 44: 8306-16
Giesbrecht GR, Collis GE, Gordon JC, et al. (2004) Mono-cyclopentadienyl complexes of lanthanum: Synthesis and characterization of anilido derivatives Journal of Organometallic Chemistry. 689: 2177-2185
Hardman NJ, Wright RJ, Phillips AD, et al. (2003) Structures, bonding, and reaction chemistry of the neutral organogallium(I) compounds (GaAr)n(n = 1 or 2) (Ar = terphenyl or related ligand): an experimental investigation of Ga-Ga multiple bonding. Journal of the American Chemical Society. 125: 2667-79
Hardman NJ, Wright RJ, Phillips AD, et al. (2002) Synthesis and characterization of the neutral "digallene" Ar'GaGaAr' and its reduction to Na(2)Ar'GaGaAr' (Ar'=2,6-Dipp(2)C(6)H(3), Dipp=2,6-iPr(2)C(6)H(3)). Angewandte Chemie (International Ed. in English). 41: 2842-4
Wright RJ, Phillips AD, Hardman NJ, et al. (2002) The "diindene" ArInInAr (Ar = C(6)H(3)-2,6-Dipp(2), Dipp = C(6)H(3)-2,6-Pr(i)(2)). Dimeric versus monomeric in(I) aryls: para-substituent effects in terphenyl ligands. Journal of the American Chemical Society. 124: 8538-9
Burford N, Ragogna PJ, Robertson KN, et al. (2002) Coordination chemistry umpolung: a gallane ligand on a phosphine lewis acceptor. Journal of the American Chemical Society. 124: 382-3
Hardman NJ, Twamley B, Stender M, et al. (2002) Unusual structures of lithium terphenyl derivatives Journal of Organometalic Chemistry. 643: 461-467
Hardman NJ, Cui C, Roesky HW, et al. (2001) Stable, Monomeric Imides of Aluminum and Gallium: Synthesis and Characterization of [{HC(MeCDippN) }MN-2,6-Trip C H ] (M=Al or Ga; Dipp=2,6-iPr C H ; Trip=2,4,6-iPr C H ). Angewandte Chemie (International Ed. in English). 40: 2172-2174
Hardman NJ, Power PP, Gorden JD, et al. (2001) Gallium-boron donor-acceptor bonds. Chemical Communications (Cambridge, England). 1866-7
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