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Zhongliang Zhu, Ph.D.

Affiliations: 
2009 Chemistry University of California, Davis, Davis, CA 
Area:
Inorganic chemistry
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"Zhongliang Zhu"
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Philip Power grad student 2009 UC Davis
 (Synthesis and reaction chemistry of homonuclear metal-metal bonded group 12 (zinc, cadmium and mercury) and group 13 (gallium and indium) organometallic compounds ArMMAr (Ar = terphenyl ligands) and related species.)

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Publications

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Caputo CA, Zhu Z, Brown ZD, et al. (2011) Activation of olefins with low-valent gallium compounds under ambient conditions. Chemical Communications (Cambridge, England). 47: 7506-8
Wang X, Peng Y, Zhu Z, et al. (2010) Synthesis and characterization of two of the three isomers of a germanium-substituted bicyclo[2.2.0]hexane diradicaloid: stretching the Ge-Ge bond. Angewandte Chemie (International Ed. in English). 49: 4593-7
Peng Y, Guo JD, Ellis BD, et al. (2009) Reaction of hydrogen or ammonia with unsaturated germanium or tin molecules under ambient conditions: oxidative addition versus arene elimination. Journal of the American Chemical Society. 131: 16272-82
Wang X, Zhu Z, Peng Y, et al. (2009) Room-temperature reaction of carbon monoxide with a stable diarylgermylene. Journal of the American Chemical Society. 131: 6912-3
Zhu Z, Fischer RC, Ellis BD, et al. (2009) Synthesis, characterization and real molecule DFT calculations for neutral organogallium(I) aryl dimers and monomers: weakness of gallium-gallium bonds in digallenes and digallynes. Chemistry (Weinheim An Der Bergstrasse, Germany). 15: 5263-72
Wang X, Ni C, Zhu Z, et al. (2009) N-H and N=C bond formation via germanium(III) diradicaloid intermediates and C-S bond cleavage in reactions of the digermyne Ar'GeGeAr' (Ar' = C6H3-2,6-(C6H3-2,6-Pr(i)2)2) with azides. Inorganic Chemistry. 48: 2464-70
Zhu Z, Wang X, Olmstead MM, et al. (2009) Synthesis and characterization of [Ar'GaC(Ph)CH]2 and K2[Ar'GaC(Ph)CH]2OEt2: from digallene to digallacyclohexadiene to digallatabenzene. Angewandte Chemie (International Ed. in English). 48: 2027-30
Zhu Z, Wang X, Peng Y, et al. (2009) Addition of hydrogen or ammonia to a low-valent group 13 metal species at 25 degrees C and 1 atmosphere. Angewandte Chemie (International Ed. in English). 48: 2031-4
Zhu Z, Wright RJ, Brown ZD, et al. (2009) Chalcogenide/chalcogenolate structural isomers of organo group 13 element derivatives: reactions of the dimetallenes Ar#MMAr# (Ar# = CH - 2,6-(CH - 2,6-Pr; M = Ga or In) with NO or S to give (Ar#ME) (E = O or S) and the synthesis and characterization of [Ar#EM] (M = In or Tl; E = O, S) Organometallics. 28: 2512-2519
Zhu Z, Fettinger JC, Olmstead MM, et al. (2009) Steric enhancement of group 12 metal hydride stability and the reaction of an arylzinc hydride with tetramethylpiperidinyl oxide (TEMPO) Organometallics. 28: 2091-2095
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