Brian M. Eklov, Ph.D.

Affiliations: 
2005 University of Minnesota, Twin Cities, Minneapolis, MN 
Area:
Organic Chemistry
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"Brian Eklov"
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Thomas Robert Hoye grad student 2005 UMN
 (I. No-D (No-Deuterium) proton NMR spectroscopy. II. Toward computing the relative configurations of structurally complex compounds. III. Toward a total synthesis of (-)-gigantecin.)
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Publications

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Walker DP, Eklov BM, Bedore MW. (2012) Practical synthesis of 3-oxa-6-azabicyclo[31.1]heptane hydrotosylate; A novel morpholine-based building block Synthesis (Germany). 44: 2859-2862
Denmark SE, Williams BJ, Eklov BM, et al. (2010) Design, validation, and implementation of a rapid-injection NMR system. The Journal of Organic Chemistry. 75: 5558-72
Denmark SE, Eklov BM, Yao PJ, et al. (2009) On the mechanism of Lewis base catalyzed aldol addition reactions: kinetic and spectroscopic investigations using rapid-injection NMR. Journal of the American Chemical Society. 131: 11770-87
Denmark SE, Eklov BM. (2008) Neutral and cationic phosphoramide adducts of silicon tetrachloride: synthesis and characterization of their solution and solid-state structures. Chemistry (Weinheim An Der Bergstrasse, Germany). 14: 234-9
Hoye TR, Eklov BM, Jeon J, et al. (2006) Sequencing of three-component olefin metatheses: total synthesis of either (+)-gigantecin or (+)-14-deoxy-9-oxygigantecin. Organic Letters. 8: 3383-6
Hoye TR, Aspaas AW, Eklov BM, et al. (2005) Reaction titration: a convenient method for titering reactive hydride agents (Red-Al, LiAlH4, DIBALH, L-Selectride, NaH, and KH) by No-D NMR spectroscopy. Organic Letters. 7: 2205-8
Hoye TR, Eklov BM, Voloshin M. (2004) No-D NMR spectroscopy as a convenient method for titering organolithium (RLi), RMgX, and LDA solutions. Organic Letters. 6: 2567-70
Hoye TR, Eklov BM, Ryba TD, et al. (2004) No-D NMR (no-deuterium proton NMR) spectroscopy: a simple yet powerful method for analyzing reaction and reagent solutions. Organic Letters. 6: 953-6
Hoye TR, Ayyad SE, Eklov BM, et al. (2002) Toward computing relative configurations: 16-epi-latrunculin B, a new stereoisomer of the actin polymerization inhibitor latrunculin B. Journal of the American Chemical Society. 124: 7405-10
Cramer CJ, Kormos BL, Winget P, et al. (2001) A cooperative molecular modeling exercise - The hypersurface as classroom Journal of Chemical Education. 78: 1202-1205
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