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Matthew T. Olsen, Ph.D.

Affiliations: 
2011 Chemistry University of Illinois, Urbana-Champaign, Urbana-Champaign, IL 
Area:
synthetic inorganic, bioinorganic, and organometallic chemistry
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Thomas B. Rauchfuss grad student 2011 UIUC
 (Synthetic models of [FeFe]-hydrogenase: Case studies utilizing azadithiolate and nitrosyl coligands.)

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Drab DM, Willauer HD, Olsen MT, et al. (2013) Hydrocarbon synthesis from carbon dioxide and hydrogen: A two-step process Energy and Fuels. 27: 6348-6354
Olsen MT, Rauchfuss TB, Zaffaroni R. (2012) Reaction of Aryl Diazonium Salts and Diiron(I) Dithiolato Carbonyls: Evidence for Radical Intermediates. Organometallics. 31: 3447-3450
Silakov A, Olsen MT, Sproules S, et al. (2012) EPR/ENDOR, Mössbauer, and quantum-chemical investigations of diiron complexes mimicking the active oxidized state of [FeFe]hydrogenase. Inorganic Chemistry. 51: 8617-28
Olsen MT, Gray DL, Rauchfuss TB, et al. (2011) Stereochemistry of electrophilic attack at 34e⁻ dimetallic complexes: the case of diiron dithiolato carbonyls + MeS⁺. Chemical Communications (Cambridge, England). 47: 6554-6
Olsen MT, Rauchfuss TB, Wilson SR. (2010) Role of the azadithiolate cofactor in models for [FeFe]-hydrogenase: novel structures and catalytic implications. Journal of the American Chemical Society. 132: 17733-40
Barton BE, Olsen MT, Rauchfuss TB. (2010) Artificial hydrogenases. Current Opinion in Biotechnology. 21: 292-7
Schaub T, Radius U, Brucks A, et al. (2010) Carbene Ligands and Complexes: 1,3-Dialkyl-Imidazole-2-Ylidenes Inorganic Syntheses. 35: 78-83
Schaub T, Radius U, Brucks A, et al. (2010) 1,3-dialkyl-imidazole-2-ylidenes Inorganic Syntheses. 35: 78-91
Olsen MT, Barton BE, Rauchfuss TB. (2009) Hydrogen activation by biomimetic diiron dithiolates. Inorganic Chemistry. 48: 7507-9
Barton BE, Olsen MT, Rauchfuss TB. (2008) Aza- and oxadithiolates are probable proton relays in functional models for the [FeFe]-hydrogenases. Journal of the American Chemical Society. 130: 16834-5
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