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Ryan C. Kunz, Ph.D.

Affiliations: 
2007 Biochemistry The University of Nebraska - Lincoln, Lincoln, NE 
Area:
Microbiology Biology, Molecular Biology, General Biophysics
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Stephen W. Ragsdale grad student 2007 University of Nebraska - Lincoln
 (On the catalytic mechanism and activation of methyl coenzyme M reductase (MCR): Two sides of the same coin.)

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Publications

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Pearl NM, Wilcoxen J, Im S, et al. (2016) Protonation of the hydroperoxo intermediate of cytochrome P450 2B4 is slower in the presence of cytochrome P450 reductase than in the presence of cytochrome b5. Biochemistry
Dey M, Li X, Kunz RC, et al. (2010) Detection of organometallic and radical intermediates in the catalytic mechanism of methyl-coenzyme M reductase using the natural substrate methyl-coenzyme M and a coenzyme B substrate analogue. Biochemistry. 49: 10902-11
Li X, Telser J, Kunz RC, et al. (2010) Observation of organometallic and radical intermediates formed during the reaction of methyl-coenzyme M reductase with bromoethanesulfonate. Biochemistry. 49: 6866-76
Kunz RC, Dey M, Ragsdale SW. (2008) Characterization of the thioether product formed from the thiolytic cleavage of the alkyl-nickel bond in methyl-coenzyme M reductase. Biochemistry. 47: 2661-7
Dey M, Kunz RC, Lyons DM, et al. (2007) Characterization of alkyl-nickel adducts generated by reaction of methyl-coenzyme m reductase with brominated acids. Biochemistry. 46: 11969-78
Dey M, Telser J, Kunz RC, et al. (2007) Biochemical and spectroscopic studies of the electronic structure and reactivity of a methyl-Ni species formed on methyl-coenzyme M reductase. Journal of the American Chemical Society. 129: 11030-2
Dey M, Kunz RC, Van Heuvelen KM, et al. (2006) Spectroscopic and computational studies of reduction of the metal versus the tetrapyrrole ring of coenzyme F430 from methyl-coenzyme M reductase. Biochemistry. 45: 11915-33
Kunz RC, Horng YC, Ragsdale SW. (2006) Spectroscopic and kinetic studies of the reaction of bromopropanesulfonate with methyl-coenzyme M reductase. The Journal of Biological Chemistry. 281: 34663-76
Choi DW, Antholine WE, Do YS, et al. (2005) Effect of methanobactin on the activity and electron paramagnetic resonance spectra of the membrane-associated methane monooxygenase in Methylococcus capsulatus Bath. Microbiology (Reading, England). 151: 3417-26
Choi DW, Kunz RC, Boyd ES, et al. (2003) The membrane-associated methane monooxygenase (pMMO) and pMMO-NADH:quinone oxidoreductase complex from Methylococcus capsulatus Bath. Journal of Bacteriology. 185: 5755-64
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