Santiago A. Toledo, Ph.D.

Affiliations: 
2009 University of Washington, Seattle, Seattle, WA 
Area:
Inorganic Chemistry, Biochemistry
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"Santiago Toledo"
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Julie A. Kovacs grad student 2009 University of Washington
 (Synthesis and reactivity of an expanded family of superoxide reductase (SOR) model complexes using N-heterocyclic, thiolate-containing ligands: Towards a better understanding of structural-functional relationships.)
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Publications

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Toledo S, Yan Poon PC, Gleaves M, et al. (2021) Increasing reactivity by incorporating π-acceptor ligands into coordinatively unsaturated thiolate-ligated iron(II) complexes. Inorganica Chimica Acta. 524
Blade GA, Parveen R, Jaimes JL, et al. (2020) A family of structural and functional models for the active site of a unique dioxygenase: Acireductone dioxygenase (ARD). Journal of Inorganic Biochemistry. 212: 111253
Poon PCY, Dedushko MA, Sun X, et al. (2019) How Metal Ion Lewis Acidity and Steric Properties Influence the Barrier to Dioxygen Binding, Peroxo O-O Bond Cleavage, and Reactivity. Journal of the American Chemical Society
Ivan DA, Gremillion AJ, Sanchez A, et al. (2018) The first structural model for the resting state of the active site of nickel acireductone dioxygenase (Ni-ARD) Inorganic Chemistry Communications. 89: 37-40
Brines LM, Coggins MK, Poon PC, et al. (2015) Water-soluble Fe(II)-H2O complex with a weak O-H bond transfers a hydrogen atom via an observable monomeric Fe(III)-OH. Journal of the American Chemical Society. 137: 2253-64
Coggins MK, Toledo S, Kovacs JA. (2013) Isolation and characterization of a dihydroxo-bridged iron(III,III)(μ-OH)2 diamond core derived from dioxygen. Inorganic Chemistry. 52: 13325-31
Coggins MK, Toledo S, Shaffer E, et al. (2012) Characterization and dioxygen reactivity of a new series of coordinatively unsaturated thiolate-ligated manganese(II) complexes. Inorganic Chemistry. 51: 6633-44
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