Kevin E. Janak, Ph.D.

Affiliations: 
2001 University of Southern California, Los Angeles, CA, United States 
Area:
Inorganic Chemistry
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Thomas C. Flood grad student 2001 USC
 (Carbon-hydrogen bond activation: Investigation into the dynamics and energetics of alkane complexes within a hard-ligated rhodium system.)
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Publications

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Sattler A, Janak KE, Parkin G. (2011) Modeling aspects of hydrodesulfurization by molybdenum hydride compounds: Desulfurization of thiophene and benzothiophene and C-S bond cleavage of dibenzothiophene Inorganica Chimica Acta. 369: 197-202
Kristian KE, Iimura M, Cummings SA, et al. (2009) Mechanism of the reaction of alkynes with a "constrained geometry" zirconaaziridine. PMe 3 dissociates more rapidly from the constrained geometry complex than from its Cp 2 analogue Organometallics. 28: 493-498
Zhu G, Janak KE, Parkin G. (2006) A normal equilibrium isotope effect for oxidative addition of H2 to (eta6-anthracene)Mo(PMe3)3. Chemical Communications (Cambridge, England). 2501-3
Janak KE, Shin JH, Parkin G. (2004) Molybdenocene trihydride complexes: influence of a [Me2Si] ansa bridge on classical versus nonclassical nature, stability with respect to elimination of dihydrogen, and acidity. Journal of the American Chemical Society. 126: 13054-70
Janak KE, Shin JH, Parkin G. (2004) Molybdenocene trihydride complexes: Influence of a [Me2Si] Ansa bridge on classical versus neoclassical nature, stability with respect to elimination of dihydrogen, and acidity Journal of the American Chemical Society. 126: 13054-13070
Churchill DG, Janak KE, Wittenberg JS, et al. (2003) Normal and inverse primary kinetic deuterium isotope effects for C-H bond reductive elimination and oxidative addition reactions of molybdenocene and tungstenocene complexes: evidence for benzene sigma-complex intermediates. Journal of the American Chemical Society. 125: 1403-20
Guan H, Iimura M, Magee MP, et al. (2003) Effect of chelate ring size on the rate of hydride transfer from CpRu(P-P)H (P-P = chelating diphosphine) to an iminium cation Organometallics. 22: 4084-4089
Zhu G, Tanski JM, Churchill DG, et al. (2002) The reactivity of Mo(PMe3)(6) towards heterocyclic nitrogen compounds: transformations relevant to hydrodenitrogenation. Journal of the American Chemical Society. 124: 13658-9
Hascall T, Murphy VJ, Janak KE, et al. (2002) The syntheses and structures of coordinatively unsaturated aryloxy-hydride complexes of molybdenum, Mo(PMe3)4(OAr)H: Reversible C-H bond activation and comparison with their tungsten analogues Journal of Organometallic Chemistry. 652: 37-49
Flood TC, Janak KE, Iimura M, et al. (2000) Deuterium migration in {(1,4,7- triazacyclononane)Rh(alkyl)D[P(OMe)3]}+ evidence for mobility of rhodium along linear alkane chains in inferred rhodium-alkane complexes [10] Journal of the American Chemical Society. 122: 6783-6784
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