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Peter P. Gaspar

Affiliations: 
Washington University, Saint Louis, St. Louis, MO 
Area:
Organic Chemistry
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"Peter Gaspar"
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Parents

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William von Eggers Doering grad student 1964

Children

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William C. Eckelmann grad student 1962-1968 Washington University
Diana M. Ivanova grad student 2006 Washington University

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Publications

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Gulotty EM, Staples RJ, Biros SM, et al. (2018) Crystal structures of 2-bromo-1,1,1,3,3,3-hexa-methyl-2-(tri-methyl-sil-yl)tris-ilane and 2-bromo-1,1,1,3,3,3-hexa-isopropyl-2-(triiso-propyl-sil-yl)tri-silane. Acta Crystallographica. Section E, Crystallographic Communications. 74: 1142-1146
Bundhun A, Ramasami P, Gaspar PP, et al. (2012) Stannylenes: structures, electron affinities, ionization energies, and singlet-triplet gaps of SnX2/SnXY and XSnR/SnR2/RSnR′ species (X; Y = H, F, Cl, Br, I, and R; R' = CH3, SiH3, GeH3, SnH3). Inorganic Chemistry. 51: 851-63
Russell AL, Rohrs HW, Read D, et al. (2009) Radical Cation/Radical Reactions: A Fourier Transform Ion Cyclotron Resonance Study of Allyl Radical Reacting with Aromatic Radical Cations. International Journal of Mass Spectrometry. 287: 8-15
Nag M, Gaspar PP. (2009) Theoretical calculations on the tetramethyldisilene rearrangement: a new approach to an old mechanistic problem. Chemistry (Weinheim An Der Bergstrasse, Germany). 15: 8526-32
Nag M, Gaspar PP. (2009) A computational study of the mechanism of addition of singlet carbene analogues to 1,3-butadiene to form 1,1-dimethylmetallacyclopent-3enes [MMe 2C 4H 6, M = Si, Ge, Sn] and their reverse retro-addition reactions Organometallics. 28: 5612-5622
Zhou D, Reiche C, Nag M, et al. (2009) Synthesis of 1-stannacyclopent-3-enes and their pyrolysis to stannylenes Organometallics. 28: 2595-2608
Sekiguchi A, Tanaka T, Ichinohe M, et al. (2008) Tri-tert-butylsilylsilylenes with alkali metal substituents ((t)Bu3Si)SiM (M = Li, K): electronically and sterically accessible triplet ground states. Journal of the American Chemical Society. 130: 426-7
Zhou D, Nag M, Russel AL, et al. (2007) A retro-Diels Alder route to tetramethyldisilene Me2Si= SiMe2 revisited: Flow pyrolysis of 1,1,2,2-Tetramethyl-1,2-disilacyclohex-4-ene Silicon Chemistry. 3: 117-122
Becerra R, Gaspar PP, Harrington CR, et al. (2005) Direct detection of dimethylstannylene and tetramethyldistannene in solution and the gas phase by laser flash photolysis of 1,1-dimethylstannacyclopent-3-enes. Journal of the American Chemical Society. 127: 17469-78
Lam WH, Gaspar PP, Hrovat DA, et al. (2005) Computational studies of the thermal fragmentation of P-arylphosphiranes: have arylphosphinidenes been generated by this method? Journal of the American Chemical Society. 127: 9886-94
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